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Copy 2 of DOC - Caltechcampuspubs - California Institute of ...

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90<br />

CALIFORNIA INSTITUTE OF TECHNOLOGY<br />

salts, and distribution between phases. The second term is deyoted<br />

to exact qualitative analysis, where these principles and<br />

those relating to oxidation and reduction are further applied to<br />

solutions; and the third term is given to the highly important<br />

field <strong>of</strong> chemical reactions between gases and between gases and<br />

solids, which is <strong>of</strong>ten neglected in elementary instruction.<br />

The second-year work in chemistry, which is taken by all students<br />

in the Course in Science, consists on the laboratory side<br />

<strong>of</strong> gravimetric, advanced qualitative, and electrometric analysis;<br />

but the class work is largely devoted to the discussion <strong>of</strong> the<br />

principles relating to mass-action, the ionic theory, oxidation,<br />

and the periodic law. In the second and third terms, and also<br />

in the subjects <strong>of</strong> physical and organic chemistry taken in the<br />

later years, the abler students, after a few weeks <strong>of</strong> introductory<br />

work, undertake minor researches in place <strong>of</strong> the regular work..<br />

The chcmical subjects <strong>of</strong> the junior and senior year consist<br />

<strong>of</strong> courses in physical, advanced inorganic, organic, and applied<br />

chemistry. The junior and senior courses in physical chemistry,<br />

here known as "Chemical Principles," are .not descriptive courses<br />

<strong>of</strong> the usual type; but from beginning to end are presented as a<br />

series <strong>of</strong> problems to be solved by the student. Also in the subjects<br />

<strong>of</strong> organic and applied chemistry problems are a feature.<br />

The supervision <strong>of</strong> the research work <strong>of</strong> graduate students is<br />

distributed among the whole staff <strong>of</strong> the Division <strong>of</strong> Chemistry.<br />

Each staff member takes charge <strong>of</strong> only three to five students<br />

who desire to work in his special field, so that each student re­<br />

ceives a large amount <strong>of</strong> attention. Thus in physical chemistry<br />

the lines <strong>of</strong> research now being actively pursued by graduate<br />

students in cooperation with the staff are: equilibria and freeenergies<br />

at high temperatures; reduction-potentials in solution,<br />

especially <strong>of</strong> the rarer elements; the rates <strong>of</strong> homogeneous gas<br />

reactions; the photochemistry <strong>of</strong> reactions; band spectra in their<br />

chemical relations; crystal and molecular structure determined by<br />

X-rays; and the absorption <strong>of</strong> X-rays in its chemical relations.

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