Fisher Chemical

Hazard and precautionary statementsHazard Class and categoryAsp. Tox. 1 Aspiration hazard; Category 1Acute Tox. 1 Acute toxicity (oral); Category 1Acute Tox. 2 Acute toxicity (oral); Category 2Acute Tox. 3 Acute toxicity (oral); Category 3Acute Tox. 4 Acute toxicity (oral); Category 4Acute Tox. 1 Acute toxicity (dermal); Category 1Acute Tox. 2 Acute toxicity (dermal); Category 2Acute Tox. 3 Acute toxicity (dermal); Category 3Acute Tox. 4 Acute toxicity (dermal); Category 4Acute Tox. 1 Acute toxicity (inhalation); Category 1Acute Tox. 2 Acute toxicity (inhalation); Category 2Acute Tox. 3 Acute toxicity (inhalation); Category 3Acute Tox. 4 Acute toxicity (inhalation); Category 4Skin Corr. 1A Skin corrosion/irritation; Category 1ASkin Corr. 1B Skin corrosion/irritation; Category 1BSkin Corr. 1C Skin corrosion/irritation; Category 1CSkin Irrit. 2 Skin corrosion/irritation; Category 2Eye Dam. 1 Serious eye damage/eye irritation; Category 1Eye Irrit. 2 Serious eye damage/eye irritation; Category 2Resp. Sens. 1 Respiratory sensitisation; Category 1Skin Sens. 1 Skin sensitisation; Category 1Muta. 1A Germ cell mutagenicity; Category 1AMuta. 1B Germ cell mutagenicity; Category 1BMuta. 2 Germ cell mutagenicity; Category 2Carc. 1A Carinogenicity; Category 1ACarc. 1B Carcinogenicity; Category 1BCarc. 2 Carcinogenicity; Category 2Repr. 1A Reproductive toxicity; Category 1ARepr. 1B Reproductive toxicity; Category 1BRepr. 2 Reproductive toxicity; Category 2STOT SE 1 Specific target organ toxicity - single exposure;Category 1STOT SE 2 Specific target organ toxicity - single exposure;Category 2STOT SE 3 Specific target organ toxicity - single exposure;Category 3STOT RE 1 Specific target organ toxicity - repeated exposure;Category 1STOT RE 2Specific target organ toxicity - repeated exposure;Category 2Aquatic Acute 1 Hazardous to the aquatic environment - acute hazard;Category 1Aquatic Chronic 1 Hazardous to the aquatic environment - chronic hazard;Category 1Aquatic Chronic 2 Hazardous to the aquatic environment - chronic hazard;Category 2Aquatic Chronic 3 Hazardous to the aquatic environment - chronic hazard;Category 3Aquatic Chronic 4 Hazardous to the aquatic environment - chronic hazard;Category 4Ozone Hazardous to the ozone layer; Category 1Flam. Liq. 1 Flammable liquid; Category 1Flam. Liq. 2 Flammable liquid; Category 2Flam. Liq. 3 Flammable liquid; Category 3Flam. Sol. 1 Flammable solid; Category 1Flam. Sol. 2 Flammable solid; Category 2Org. Perox. COrg. Perox. DOrganic peroxide; Type COrganic peroxide; Type DOx. Liq. 1 Oxidising liquid; Category 1Ox. Liq. 2 Oxidising liquid; Category 2Ox. Liq. 3 Oxidising liquid; Category 3Ox. Sol. 1 Oxidising solid; Category 1Ox. Sol. 2 Oxidising solid; Category 2Ox. Sol. 3 Oxidising solid; Category 3Pyr. Sol. 1 Pyrophoric solid; Category 1Self-heat. 1 Self-heating substance/mixture; Category 1Self-react. CSelf-reactive substance; Type CMet. Corr. 1 Substance/mixture corrosive to metal; Category 1Water-react. 1Water-react. 2Water-react. 3Substance/mixture which, in contact with water,emits flammable gases; Category 1Substance/mixture which, in contact with water,emits flammable gases; Category 2Substance/mixture which, in contact with water,emits flammable gases; Category 3EUH PhrasesEUH001 Explosive when dryEUH006 Explosive with or without contact with airEUH014 Reacts violently with waterEUH018 In use, may form flammable/explosive vapor-air mixtureEUH019 May form explosive peroxidesEUH029 Contact with water liberates toxic gasEUH031 Contact with acids liberates toxic gasEUH032 Contact with acids liberates very toxic gasEUH044 Risk of explosion if heated under confinementEUH059 Hazardous to the ozone layerEUH066 Repeated exposure may cause skin dryness or crackingEUH070 Toxic by eye contactEUH071 Corrosive to the respiratory tractEUH201 Contains lead. Should not be used on surfaces liable to be chewedor sucked by childrenEUH201A Warning! Contains leadEUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds.Keep out of the reach of childrenEUH203 Contains chromium (VI). May produce an allergic reactionEUH204 Contains isocyanates. May produce an allergic reactionEUH205 Contains epoxy constituents. May produce an allergic reactionEUH206 Warning! Do not use together with other products.May release dangerous gases (chlorine)EUH207 Warning! Contains cadmium. Dangerous fumes are formed duringuse. See information supplied by the manufacturer. Comply withthe safety instructionsEUH208 May produce an allergic reactionEUH209 Can become highly flammable in useEUH210 Safety data sheet available on requestEUH401 To avoid risks to human health and the environment, comply withthe instructions for useH PhrasesH200 Unstable explosiveH201 Explosive; mass explosion hazardH202 Explosive; severe projection hazardH203 Explosive; fire, blast or projection hazardH204 Fire or projection hazardH205 May mass explode in fireH220 Extremely flammable gasH221 Flammable gasH222 Extremely flammable aerosolH223 Flammable aerosolH224 Extremely flammable liquid and vaporH225 Highly flammable liquid and vaporH226 Flammable liquid and vaporH227 Combustible liquidH228 Flammable solidH240 Heating may cause an explosionH241 Heating may cause a fire or explosionH242 Heating may cause a fireH250 Catches fire spontaneously if exposed to airH251 Self-heating: may catch fireH252 Self-heating in large quantities; may catch fireH260 In contact with water releases flammable gases which mayignite spontaneouslyH261 In contact with water releases flammable gasesH270 May cause or intensify fire; oxidizerH271 May cause fire or explosion; strong oxidizerH272 May intensify fire; oxidizerH280 Contains gas under pressure; may explode if heatedH281 Contains refrigerated gas; may cause cryogenic burns or injuryH290 May be corrosive to metalsH300 Fatal if swallowedH301 Toxic if swallowedH302 Harmful if swallowedH303 May be harmful if swallowedH304 May be fatal if swallowed and enters airwaysH305 May be harmful if swallowed and enters airwaysH310 Fatal in contact with skinH311 Toxic in contact with skinH312 Harmful in contact with skinH313 May be harmful in contact with skinH314 Causes severe skin burns and eye damageH315 Causes skin irritationH316 Causes mild skin irritationH317 May cause an allergic skin reactionH318 Causes serious eye damageH319 Causes serious eye irritationH320 Causes eye irritationH330 Fatal if inhaledH331 Toxic if inhaledH332 Harmful if inhaledH333 May be harmful if inhaledH334 May cause allergy or asthma symptoms or breathing difficultiesif inhaledH335 May cause respiratory irritationH336 May cause drowsiness or dizzinessH340 May cause genetic defectsH341 Suspected of causing genetic defectsH350 May cause cancerH350i May cause cancer by inhalationH351 Suspected of causing cancerH360 May damage fertility or the unborn childH360D May damage the unborn childH360Df May damage the unborn child. Suspected of damaging fertilityH360F May damage fertilityH360Fd May damage fertility. Suspected of damaging the unborn childH361 Suspected of damaging fertility or the unborn childH361d Suspected of damaging the unborn childH361f Suspected of damaging fertilityH361fd Suspected of damaging fertility. Suspected of damagingthe unborn childH362 May cause harm to breast-fed childrenH370 Causes damage to organsH371 May cause damage to organsH372 Causes damage to organs through prolonged or repeated exposureH373 May cause damage to organs through prolongedor repeated exposureH400 Very toxic to aquatic lifeH401 Toxic to aquatic lifeH402 Harmful to aquatic lifeH410 Very toxic to aquatic life with long lasting effectsH411 Toxic to aquatic life with long lasting effectsH412 Harmful to aquatic life with long lasting effectsH413 May cause long lasting harmful effects to aquatic lifeH420 Harms public health and the environment by destroying ozonein the upper atmosphereP PhrasesP101 If medical advice is needed, have product container or label at handP102 Keep out of reach of childrenP103 Read label before useP201 Obtain special instructions before useP202 Do not handle until all safety precautions have been readand understoodP210 Keep away from heat/sparks/open flames/hot surfaces.- No smokingP211 Do not spray on an open flame or other ignition sourceP220 Keep/Store away from clothing/ combustible materialsP221 Take any precaution to avoid mixing with combustiblesP222 Do not allow contact with airP223 Keep away from any possible contact with water, because of violentreaction and possible flash fireP230 Keep wetted with .?P231 Handle under inert gasP231 + P232 Handle under inert gas. Protect from moistureP232 Protect from moistureP233 Keep container tightly closedP234 Keep only in original containerP235 Keep coolP235 + P410 Keep cool. Protect from sunlightP240 Ground/Bond container and receiving equipmentP241 Use explosion-proof electrical/ ventilating/ lighting/ equipmentP242 Use only non-sparking toolsP243 Take precautionary measures against static dischargeP244 Keep reduction valves free from grease and oilP250 Do not subject to grinding/shock/frictionP251 Pressurized container: Do not pierce or burn, even after useP260 Do not breathe dust/fume/gas/mist/vapors/sprayP261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ sprayP262 Do not get in eyes, on skin, or on clothingP263 Avoid contact during pregnancy/ while nursingP264 Wash face, hands and any exposed skin thoroughly after handlingP270 Do not eat, drink or smoke when using this productP271 Use only outdoors or in a well-ventilated areaP272 Contaminated work clothing should not be allowedout of the workplaceP273 Avoid release to the environmentP280 Wear protective gloves/ protective clothing/ eye protection/face protectionP281 Use personal protective equipment as requiredP282 Wear cold insulating gloves/ face shield/ eye protectionP283 Wear fire/ flame resistant/ retardant clothingP284 Wear respiratory protectionP285 In case of inadequate ventilation wear respiratory protection496497