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Bogoliubov Excitations of Inhomogeneous Bose-Einstein ...

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2. The <strong>Inhomogeneous</strong> <strong>Bogoliubov</strong> Hamiltonian<br />

is bounded [48]. When even more particles are added to the system, the only<br />

choice to place them is to put them into the ground state. The population<br />

<strong>of</strong> this single quantum state with a macroscopic number <strong>of</strong> particles is called<br />

<strong>Bose</strong>-<strong>Einstein</strong> condensation.<br />

Let us estimate the maximum number <strong>of</strong> particles in excited states. This<br />

is reached for the maximum possible value <strong>of</strong> the chemical potential µ =<br />

ɛ0 = 0. As we treat the ground state separately, it is adequate to compute<br />

the maximum number <strong>of</strong> thermal particles at a given temperature in the<br />

continuum approximation<br />

N max<br />

T<br />

�<br />

=<br />

dɛ ρ(ɛ)<br />

eβɛ , (2.6)<br />

− 1<br />

where the density <strong>of</strong> states ρ(ɛ) typically follows a power law ρ(ɛ) = Cαɛ α−1 ,<br />

at least for the most relevant low-energy range. If the parameter α is large<br />

enough, the integral (2.6) converges. For α > 1, the integral can be evaluated<br />

as<br />

N max<br />

T = Cα(kBT ) α Γ(α)ζ(α), (2.7)<br />

where the product <strong>of</strong> the gamma function Γ(α) = � ∞<br />

0 dx xα−1 e −x and the<br />

Riemann zeta function ζ(α) = � ∞<br />

n=1 n−α is a number <strong>of</strong> order one. The<br />

critical particle number at a given temperature is defined by Nc = N max<br />

T (T ).<br />

For free particles in a box with volume L d , the density <strong>of</strong> states is given<br />

as<br />

d Sd<br />

ρ(ɛ) = L<br />

2(2π) d(2m/�2 ) d<br />

2 ɛ d<br />

2 −1 , (2.8)<br />

with the surface <strong>of</strong> the d-dimensional unit sphere Sd. That means, the<br />

parameter α = d/2 depends on the dimension. True <strong>Bose</strong>-<strong>Einstein</strong> condensation<br />

cannot occur in one or two dimensions, where the integral (2.7)<br />

diverges. In contrast, in three dimensions the critical particle density is<br />

nc = Nc/L3 = ζ( 3<br />

2 ) λ−d<br />

T , where λT =<br />

� 2π� 2<br />

mkBT<br />

is the thermal de Broglie wave<br />

length. As ζ( 3<br />

2 ) ≈ 2.612 is <strong>of</strong> order one, this condition states that <strong>Bose</strong>-<br />

<strong>Einstein</strong> condensation occurs, when the average particle spacing comes close<br />

to the thermal de Broglie wave length, nc(T )λd T = O(1). Remarkably, ideal<br />

<strong>Bose</strong>-<strong>Einstein</strong> condensation can occur at any temperature if the particle density<br />

is high enough, or conversely, at any particle density if the temperature<br />

is low enough.<br />

In harmonic traps, the density <strong>of</strong> states is different from that <strong>of</strong> free-space,<br />

namely ρ(ɛ) ∝ ɛd−1 . Consequently, <strong>Bose</strong>-<strong>Einstein</strong> condensation occurs also<br />

20

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