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(BAT) Reference Document for the Production of Chlor-alkali ...

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Chapter 2<br />

Source: [ 147, Arkema 2011 ]<br />

Figure 2.18: View <strong>of</strong> a chlorine absorption unit<br />

The purpose <strong>of</strong> a typical chlorine absorption system is two-fold:<br />

To continuously absorb chlorine gas arising in streams such as tail gas from liquefaction, air<br />

blown from waste brine or chlorine condensate dechlorination or and also wet and dry<br />

maintenance headers. Up to 5 % but normally less than 1 % <strong>of</strong> <strong>the</strong> plant production is<br />

absorbed in this way.<br />

To absorb <strong>the</strong> full cell room production during emergency <strong>for</strong> an adequate period, usually<br />

not less than 15 to 30 minutes, to enable corrective measures to be taken or <strong>the</strong> plant to be<br />

shut down in a safe manner. Gravity-fed head tanks or pumps supplied with backup power<br />

supplies may be used to give increased reliability and operation under power failure<br />

conditions.<br />

The above functions could be undertaken in separate purpose-built units, providing <strong>the</strong> integrity<br />

<strong>of</strong> <strong>the</strong> systems is maintained by having backup scrubbers. The a<strong>for</strong>ementioned purposes can be<br />

achieved by using one or several systems, usually composed <strong>of</strong> several absorption units placed<br />

in series or in parallel to ensure a high level <strong>of</strong> availablility by redundancy. Some additional<br />

equipment is <strong>of</strong>ten installed as back up. Packed towers and/or ejector systems are usually used<br />

in <strong>the</strong> absorption unit [ 3, Euro <strong>Chlor</strong> 2011 ].<br />

WORKING DRAFT IN PROGRESS<br />

56 December 2011 TB/EIPPCB/CAK_Draft_1

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