Aluminum Electrolytic Capacitors
Aluminum Electrolytic Capacitors Aluminum Electrolytic Capacitors
ALUMINUM ELECTROLYTICTECHNICAL NOTE CAPACITORS3 To calculate Balance when connecting inseries3-1 Circuit layoutCircuit for connecting two capacitors (C1, C2) in seriesand equivalent circuit can be illustrated as below figure.Formula to calculate a balance resistance RB of belowfigure is shown as follows.voltage.Balance resistance RB will be.852(k)®C1C2RBRBFollowing are the preconditions of the circuit. V2 shall be the rated voltage (V0). (V1V2) V shall be a times V02. V2aV0 (a1) R2 shall equal R1b. (b1) (1)3-2 Formulas to calculate [RB]3-2-1 Following formula can be established frombalanced condition.1 1 1 1V1 V2 R1 RB R2 RB3-2-3 Put formulas (1), (3) and (4’) in formula (2).R1R23-2-2 Following formula can be established frompreconditions.V2 V0 (3)V1 V V2 (4)2aV0 V2 (4’)R1 RB bR1 RB(2aV0V2)V2R1 RB bR1 RB2abV0(R1RB)V2 {b(R1RB)bR1RB}2ab(R1RB) 2bR1(1b)RBAccordingly, balance resistance R shall be thefollowing formula.RBRB(1a)RB(2a1) • b1V1V2(2)(5)V4 Regarding Recovery Voltage• After charging and then discharging the aluminumelectrolytic capacitor, and further causing short-circuitto the terminals and leave them alone, the voltagebetween the two terminals will rise again after someinterval. Voltage caused in such case is called recoveryvoltage. Following is the process that causes thisphenomenon :• When the voltage is impressed on a dielectric,electrical transformation will be caused inside thedielectric due to dielectric action, and electrificationwill occur in positive-negative opposite to the voltageimpressed on the surface of the dielectric. Thisphenomenon is called polarization action.• After the voltage is impressed with this polarizationaction, and if the terminals are discharged till theterminal voltage reaches 0 and are left open for a while,an electric potential will arise between the two terminalsand thus causes recovery voltage.• Recovery voltage comes to a peak around 10 to 20days after the two terminals are left open, and thengradually declines. Recovery voltage has a tendency tobecome bigger as the component (stand-alone basetype) becomes bigger.• If the two terminals are short-circuited after therecovery voltage is generated, a spark may scare theworkers working in the assembly line, and may put lowvoltagedriven components (CPU, memory, etc.) indanger of being destroyed. Measures to prevent this isto discharge the accumulated electric charge withresistor of about 100 to 1k before using, or ship outby making the terminals in short-circuit condition bycovering them with an aluminum foil at the productionstage. Please consult us for adequate procedures.3-3 Calculation Example.Calculate the value of the balance resistance in thecase of connecting two 400V 470µF ( LC standardvalue : 1.88mA) capacitors in series.R1 400(V)1.88(mA)213(k)CAT.No.2010/2011E
®ALUMINUM ELECTROLYTICCAPACITORS5 Electrode Foil Development Technology5-1 Corrosion inhibition of cathode foilInactive treatment is implemented to ensure long life byinhibiting natural corrosion of the cathode foil. Fig. 3-1shows its effects with values of the polarizationresistance inversely proportional to the corrosion rateusing the AC impedance method(FRA). This indicatesthat the cathode foil used in the High reliability capacitorshas the polarization resistance higher than that of theconventional capacitors owing to corrosion inhibition.Resistance (W)High reliability capacitorsFig. 3-1Reference5-2 Sealing material permeability of electrolyteTo ensure long life, a low permeable lactone solvent forthe sealing material is used as the main solvent of theelectrolyte of the High reliability capacitor. Fig. 3-2 showsthe test results on the permeability obtained by changingthe weight of the capacitors produced with differenttypes of electrolytes at a high temperature.Exponent of weight changes100101()10 510 410 310 2; High reliability capacitors; Amidic solvent; Lactonic productTECHNICAL NOTEExponent of weight changesTime (h)Fig. 3-35-4 Long-time stability of electrolyteThe electrolyte used in the High reliability capacitor is stablewith low initial resistivity and small secularchanges at a high temperature. Fig. 3-4 showschange in resistivity at 105°C.Exponent of resistivityLC (µA)100102001001Time (h)Fig. 3-4; High reliability capacitors; Reference; High reliability capacitors; Reference5-5 Dielectric formation voltage and leakage currentcharacteristics of anode foilTo increase the operating life by controlling the gasgeneration inside capacitor because of 1.5 to 2 timesthe rated voltage, while that of the previous capacitoris about 1.3 times the rated voltage.1001010 1000 20000 1000 20000 1000 2000Time (h)Fig. 3-25-3 Airtightness of sealing materialSince the electrolyte is stable for hours, the key elementfor capacitor’s life is the sealing material. By optimizingthe crosslinking density of the sealing material polymer,the sealing material of the High reliability capacitor attainsits long life with electrolyte permeability less than that ofthe conventional capacitors.Fig. 3-3 shows the test results on the airtightness ofthe sealing material obtained by changing the weightof the capacitors at a high temperature, producingcapacitors with the conventional sealing material andimproved one both containing the electrolyte used inthe High reliability capacitor.Voltage ratioFig. 3-55-6 Lowered ESR of Electrode FoilTo reduce the ESR of electrolytic capacitor, we haveimproved our chemical conversion technology foranode foil to develop lower ESR electrode foil comparedto the conventional product as shown in Fig. 3-6ESR Index0.1100.501 1.52 2.520 50 80 105Fig. 3-6 ESR Index of Anode Foil; High reliability capacitors; ReferenceCAT.No.2010/2011E
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ALUMINUM ELECTROLYTICTECHNICAL NOTE CAPACITORS3 To calculate Balance when connecting inseries3-1 Circuit layoutCircuit for connecting two capacitors (C1, C2) in seriesand equivalent circuit can be illustrated as below figure.Formula to calculate a balance resistance RB of belowfigure is shown as follows.voltage.Balance resistance RB will be.852(k)®C1C2RBRBFollowing are the preconditions of the circuit. V2 shall be the rated voltage (V0). (V1V2) V shall be a times V02. V2aV0 (a1) R2 shall equal R1b. (b1) (1)3-2 Formulas to calculate [RB]3-2-1 Following formula can be established frombalanced condition.1 1 1 1V1 V2 R1 RB R2 RB3-2-3 Put formulas (1), (3) and (4’) in formula (2).R1R23-2-2 Following formula can be established frompreconditions.V2 V0 (3)V1 V V2 (4)2aV0 V2 (4’)R1 RB bR1 RB(2aV0V2)V2R1 RB bR1 RB2abV0(R1RB)V2 {b(R1RB)bR1RB}2ab(R1RB) 2bR1(1b)RBAccordingly, balance resistance R shall be thefollowing formula.RBRB(1a)RB(2a1) • b1V1V2(2)(5)V4 Regarding Recovery Voltage• After charging and then discharging the aluminumelectrolytic capacitor, and further causing short-circuitto the terminals and leave them alone, the voltagebetween the two terminals will rise again after someinterval. Voltage caused in such case is called recoveryvoltage. Following is the process that causes thisphenomenon :• When the voltage is impressed on a dielectric,electrical transformation will be caused inside thedielectric due to dielectric action, and electrificationwill occur in positive-negative opposite to the voltageimpressed on the surface of the dielectric. Thisphenomenon is called polarization action.• After the voltage is impressed with this polarizationaction, and if the terminals are discharged till theterminal voltage reaches 0 and are left open for a while,an electric potential will arise between the two terminalsand thus causes recovery voltage.• Recovery voltage comes to a peak around 10 to 20days after the two terminals are left open, and thengradually declines. Recovery voltage has a tendency tobecome bigger as the component (stand-alone basetype) becomes bigger.• If the two terminals are short-circuited after therecovery voltage is generated, a spark may scare theworkers working in the assembly line, and may put lowvoltagedriven components (CPU, memory, etc.) indanger of being destroyed. Measures to prevent this isto discharge the accumulated electric charge withresistor of about 100 to 1k before using, or ship outby making the terminals in short-circuit condition bycovering them with an aluminum foil at the productionstage. Please consult us for adequate procedures.3-3 Calculation Example.Calculate the value of the balance resistance in thecase of connecting two 400V 470µF ( LC standardvalue : 1.88mA) capacitors in series.R1 400(V)1.88(mA)213(k)CAT.No.2010/2011E