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evidence of the formation ofhydrocarbons without biology(Terrestrial natural gas is composedprimarily of methane). Somecomets contain massive amounts ofan organic material almost identicalto high grade oil shale (kerogen),the equivalent of cubic kilometersof such mixed with other material;for instance, correspondinghydrocarbons were detected duringa probe fly-by through the tail ofComet Halley in 1986.The Biotic Theory:Most petroleum geologists preferthe theory that attributes oilorigination to vast quantities ofdead marine plankton or plantmaterial that sank into the mud ofshallow seas. Under the resultinganaerobic conditions, organiccompounds remained in a reducedstate where anaerobic bacteriaconverted the lipids (fats, oils andwaxes) into a waxy substancecalled kerogen.As the source rock was burieddeeper, overburden pressureraised temperatures into the oilwindow, between 80 and 180°C.Most of the organic compoundsdegraded into the straight-chainhydrocarbons that comprise mostof petroleum. This process is calledthe generation kitchen. Once crudeoil formed, it became very fluidand migrated upward through therock strata. This process is calledoil expulsion. Eventually it waseither trapped in an oil reservoir oroil escaped to the surface and wasbiodegraded by soil bacteria.<strong>Oil</strong> buried deeper entered the "gaswindow" of more than 160 °C andwas converted into natural gas bythermal cracking. Thus, this theorypredicts that only unassociatedgas—not oil—will be foundbelow a certain depth. At greaterdepths, even natural gas would bepyrolyzed.Tectonic structures do not necessarily correlate with oil deposits.Abiogenic Hydrocarbons Forming in the MantleThis image illustrates the theory of abiogenic formation of hydrocarbons in theupper mantle. These hydrocarbons then can migrate upward into the crust,and become trapped under impermeable minerals.This visual demonstrates the theory of biotic oil formation.October - December 2012 33

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