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Arts - Buffalo State College

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104<br />

Physical Geography, Sciences, and Mathematics<br />

Studies of Growth and Optical Properties<br />

of LuFe2O4 Thin Films<br />

Aaron Sprow, Physics and Anthony Delmont, Physics<br />

Faculty Mentor: Professor Ram Rai, Physics<br />

Our research was primarily concerned with the preparation<br />

method and optical characterization of epitaxial lutetium iron oxide<br />

LuFe2O4 (LFO) thin films. Growth parameters considered included<br />

pellet composition, pellet size, evaporation method, substrate<br />

composition, and substrate temperature. Successful results were<br />

achieved using stoichiometric proportions of Fe2O3 and Lu2O3 that<br />

were ground and pressed into approximately 3 gram per pellet,<br />

followed by sintering at 1100 0C. The LFO thin film deposition<br />

process started with heating the target pellet by an electron beam<br />

for roughly an hour, and then slowly evaporating LFO onto (001)<br />

LNO, (111) YSZ, (001) sapphire, and (001) quartz substrates at 750<br />

0C, to a thickness of about 300 nm. We measured transmittance<br />

and absorbance on the annealed LFO thin films as a function of<br />

wavelength, varying from ultra-violet to near infrared wavelengths<br />

(200 – 3000 nm). The optical data demonstrate that LFO is an<br />

insulator having a well-defined energy gap and several electronic<br />

excitations associated with charge transfer transitions. Estimating<br />

from the absorption spectra, the energy band gap was found to be<br />

about 2.20 eV at 300K.<br />

Presentation Type and Session: Poster VI<br />

Studies of the Gap Junction Protein<br />

Connexin31<br />

Orlando McEwan, BIO 498: Biology Honors<br />

Faculty Mentor: Professor Martha Skerrett, Biology<br />

Gap junction channels allow direct communication between<br />

adjacent cells. Gap junction channels of chordates are composed<br />

of connexins, with six connexins required to create a half-channel,<br />

also known as a connexon or hemichannel in each adjacent cell.<br />

An intercellular gap junction channel is created when a connexon<br />

from one cell docks with a connexon from an adjacent cell. In<br />

humans, twenty connexins are expressed in specific but overlapping<br />

patterns to create gap junctions with a diverse set of properties.<br />

Connexin31 (Cx31) is expressed in the auditory system and skin<br />

of humans where it is expected to interact heterotypically and<br />

heteromerically with several other connexins. Mutations in Cx31<br />

are associated with multiple human diseases including deafness<br />

and erythrokeratodermia variabilis (EKV). The mutation Cx31L34P<br />

causes EKV and this study was designed to further assess the<br />

characteristics of this mutation at a molecular level. The amino<br />

acid leucine at position 34, was modified to tryptophan (Cx31<br />

L34W) using site-directed mutagenesis. Other studies suggest that<br />

the amino acid at position 34 interacts closely with another protein<br />

domain and we aimed to confirm this for Cx31 by substituting<br />

tryptophan for the native leucine at position 34.<br />

Presentation Type and Session: Poster VI<br />

Surface Water Quality and Risk Analysis In<br />

a Peri-Urban Area, Thailand<br />

Jameieka Price, Masters Multidisciplinary Studies<br />

Faculty Mentor: Professor Kim Irvine, Geography and Planning<br />

The Rangsit Canal, Pathum Thani, Thailand, receives runoff and<br />

contaminant inputs from urban and agricultural activities. Water<br />

quality in a section of the canal was examined by comparing sample<br />

results with Thailand’s water quality standards, the approximate<br />

delta method to characterize system metabolism, and a microbial<br />

risk analysis to assess potential for waterborne infections. Dissolved<br />

oxygen and BOD levels did not meet Thailand’s Class 3 standards.<br />

Continuous, automated monitoring of dissolved oxygen revealed a<br />

pronounced diel trend driven by photosynthesis during the day and<br />

respiration at night. Compared to many water bodies, however, the<br />

primary production of the canal was low and can be classified as<br />

heterotrophic. Based on a microbial risk assesment and considering<br />

infection risk standards, E.coli levels measured in the local sewer<br />

system (10^6 CFU/100 mL) and canal (10^4 CFU/100 mL)<br />

produced unacceptably high risk for activities that included<br />

swimming, vegetable farming, fishing, and sewer pump station<br />

operations. E.coli in piped water to an informal community on the<br />

canal was 0 CFU/100 mL in half the samples. The highest E.coli level<br />

(800 CFU /100mL) associated with the piped water source was found<br />

in a tradiontal (uncoverd) water storage jar, which emphasizes the<br />

importance of appropriate water storage.<br />

Presentation Type and Session: Oral – Science, Mathematics<br />

and Technology<br />

Textural and Structural Connections<br />

Along the Metamorphic Field Gradient In<br />

Philadelphia, PA<br />

Jennifer Wehrfritz, Earth Sciences and Geology and Albert<br />

Tahan, Geology<br />

Faculty Mentor: Professor Gary Solar, Earth Sciences and Science<br />

Education<br />

The Wissahickon schist type locality along Wissahickon Creek<br />

in SE Pennsylvania (Philadelphia), is composed of pelitic schist<br />

(metamorphosed shale) interlayered with psammitic gneiss and<br />

quartzite (metamorphosed sandstone). The type locality is known<br />

for its complete record of [Barrovian] metamorphic zones. The<br />

metamorphic field gradient increases SSE in the creek valley<br />

for 5km from chlorite to second sillimanite zone, and at a high<br />

angle to the trend of the mineral-defined structures (fabrics). The<br />

chlorite zone in the N is within and adjacent to the ENE-striking,<br />

dextral-transcurrent Huntingdon Valley shear zone system (active<br />

at 300 million years ago). A transect along the creek is across<br />

both the metamorphic zones and the structural grain, permitting<br />

documentation of the relations between the metamorphic and<br />

deformation fabrics. We mapped along the east valley slope starting<br />

in the chlorite zone to the SSE for 2.8km, into the kyanite zone.

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