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User Guide to Thresholds and Classification - Environmental ...

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86<strong>User</strong> <strong>Guide</strong> for <strong>Thresholds</strong> <strong>and</strong> <strong>Classification</strong>sa. The substance is listed in the UN Model Regulations as having a classification, division, orsubsidiary risk of an oxidising substance, division 5.1, <strong>and</strong> is assigned PG I.b. The substance is a solid <strong>and</strong> when mixed with dried cellulose it forms a mixture that eitherspontaneously ignites or shows a mean burning time faster (that is, a shorter time) than the meanburning time of a 3:2 reference mixture by mass of potassium bromate <strong>and</strong> cellulose, under thesame conditions when tested as prescribed for solids in Test O.1 (para 34.4.1, UN Manual of Tests<strong>and</strong> Criteria).c. The substance is a liquid <strong>and</strong> when mixed with dry cellulose it forms a mixture that eitherspontaneously ignites or shows a mean pressure rise time faster than the mean pressure rise time ofa 1:1 reference mixture by mass of 50% perchloric acid <strong>and</strong> cellulose, under the same conditionswhen tested as prescribed for liquids in Test O.2 (para 34.4.2, UN Manual of Tests <strong>and</strong> Criteria).Category B (oxidising substances that are solids or liquids: medium hazard) – classification 5.1.1B(equivalent <strong>to</strong> UN PG II)a. The substance is listed in the UN Model Regulations as having a classification, division, orsubsidiary risk of an oxidising substance, division 5.1, <strong>and</strong> is assigned PG II.b. The substance is a solid <strong>and</strong> when mixed with dry cellulose it forms a mixture that shows a meanburning time equal <strong>to</strong> or faster (that is, a shorter time) than the mean burning time of a 2:3 referencemixture by mass of potassium bromate <strong>and</strong> cellulose, under the same conditions when tested asprescribed for solids in Test O.1 (para 34.4.1, UN Manual of Tests <strong>and</strong> Criteria), <strong>and</strong> the criteria for aclassification of category A are not met.c. The substance is a liquid <strong>and</strong> when mixed with dry cellulose it forms a mixture that shows a meanpressure rise time equal <strong>to</strong> or faster than the mean pressure rise time of a 1:1 reference mixture bymass of 40% aqueous sodium chlorate solution <strong>and</strong> cellulose, under the same conditions whentested as prescribed for liquids in Test O.2 (para 34.4.2, UN Manual of Tests <strong>and</strong> Criteria), <strong>and</strong> thecriteria for a classification of category A are not met.Category C (oxidising substances that are solids or liquids: low hazard) – classification 5.1.1C(equivalent <strong>to</strong> UN PG III)a. The substance is listed in the UN Model Regulations as having a classification, division, orsubsidiary risk of an oxidising substance, division 5.1, <strong>and</strong> is assigned UN PG III.b. The substance is a solid <strong>and</strong> when mixed with dry cellulose it forms a mixture which shows a meanburning time equal <strong>to</strong> or faster (that is, a shorter time) than the mean burning time of a 3:7 referencemixture by mass of potassium bromate <strong>and</strong> cellulose, under the same conditions when tested asprescribed for solids in Test O.1 (para 34.4.1, UN Manual of Tests <strong>and</strong> Criteria), <strong>and</strong> the criteria for aclassification of category A or category B are not met.c. The substance is a liquid <strong>and</strong> when mixed with dry cellulose it forms a mixture which shows a meanpressure rise time equal <strong>to</strong> or faster than the mean pressure rise time of a 1:1 reference mixture byJanuary 2012 EPA0109

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