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User Guide to Thresholds and Classification - Environmental ...

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102<strong>User</strong> <strong>Guide</strong> for <strong>Thresholds</strong> <strong>and</strong> <strong>Classification</strong>siii.the substance is an organic peroxide <strong>and</strong> does not propagate a de<strong>to</strong>nation as defined in UN TestSeries A <strong>and</strong> does not propagate a deflagration as defined in UN Test Series C <strong>and</strong> displays loweffect or no effect when heated under confinement as defined in UN Test Series E <strong>and</strong> is intended <strong>to</strong>be s<strong>to</strong>red or transported in bulk <strong>and</strong> displays an explosive power of ‗not low‘ as defined in UN TestSeries F or no data is available for Test Series F.These classification criteria are summarised in Table 7.7. A substance is assigned <strong>to</strong> this category if itmeets all of the criteria in any of the rows comprising the table.Table 7.7: Criteria for allocation <strong>to</strong> organic peroxide category Ei.Listed in UNRecommendationas 5.2 Type Eii.Does notpropagate ade<strong>to</strong>nation UNTest Series ADoes notpropagate adeflagration UNTest Series CLow or no effectwhen heatedunder definedconfinement UNTest Series ENot intended <strong>to</strong> bes<strong>to</strong>red ortransported in bulkiii.Does notpropagate ade<strong>to</strong>nation UNTest Series ADoes notpropagate adeflagration UNTest Series CLow or no effectwhen heatedunder definedconfinement UNTest Series EIntended <strong>to</strong> bes<strong>to</strong>red ortransported in bulkExplosive powernot low UN TestSeries Ff. Organic peroxide subclass 5.2 category F (equivalent <strong>to</strong> UN Type F)A substance is classified as organic peroxide subclass 5.2 category F if:i. the substance is listed in the UN Model Regulations as having a classification or division of anorganic peroxide (classification division 5.2) <strong>and</strong> is designated as Type F; orii.the substance is an organic peroxide <strong>and</strong> does not propagate a de<strong>to</strong>nation as defined in UN TestSeries A <strong>and</strong> does not propagate a deflagration as defined in UN Test Series C <strong>and</strong> displays low orno effect when heated under confinement as defined in UN Test Series E <strong>and</strong>, when tested for bulkcontainers, displays no explosive power as defined in UN Test Series F <strong>and</strong> displays a low effectwhen heated under confinement as defined in UN Test Series E; oriii.the substance is an organic peroxide <strong>and</strong> does not propagate a de<strong>to</strong>nation as defined in UN TestSeries A <strong>and</strong> does not propagate a deflagration as defined in UN Test Series C <strong>and</strong> displays low orno effect when heated under confinement as defined in UN Test Series E <strong>and</strong> is intended <strong>to</strong> bes<strong>to</strong>red or transported in bulk <strong>and</strong> displays low explosive power as defined UN Test Series F; oriv.the substance is an organic peroxide <strong>and</strong> does not propagate a de<strong>to</strong>nation as defined in UN TestSeries A <strong>and</strong> does not propagate a deflagration as defined in UN Test Series C <strong>and</strong> displays noeffect when heated under confinement as defined in UN Test Series E including when it is assessedfor bulk containers <strong>and</strong> it has no explosive power as defined in UN Test Series F <strong>and</strong> has either anSADT less than 60°C or a 50 kg quantity of the substance or, if the substance is a mixture thatJanuary 2012 EPA0109

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