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Book - School of Science and Technology

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The CO 2 present in the combustion products, with 25% excess air would be:Combustion products, by volume0:9m 3 <strong>of</strong> methanecombines with 0:9 2 ˆ 1:8m 3 <strong>of</strong> O 2produces 1:8(79:1/20:9) ˆ 6:8m 3 <strong>of</strong> N 2produces 0:9 1 ˆ 0:9m 3 <strong>of</strong> CO 20:05 m 3 <strong>of</strong> ethanecombines with 0:05 3:5 ˆ 0:175 m 3 <strong>of</strong> O 2produces 0:175(79:1/20:9) ˆ 0:66 m 3 <strong>of</strong> N 2produces 0:05 2 ˆ 0:1m 3 <strong>of</strong> CO 20:01 m 3 <strong>of</strong> propanecombines with 0:01 5 ˆ 0:05 m 3 <strong>of</strong> O 2produces 0:05(79:1/20:9) ˆ 0:19 m 3 <strong>of</strong> N 2produces 0:01 3 ˆ 0:03 m 3 <strong>of</strong> CO 2Thus, volume <strong>of</strong> CO 2 in products (m 3 )ˆ 0:005 ‡ (0:9 ‡ 0:1 ‡ 0:03) ˆ 1:035<strong>and</strong> volume <strong>of</strong> N 2 in products (m 3 )ˆ 0:035 ‡ (6:8 ‡ 0:66 ‡ 0:19) ˆ 7:685<strong>and</strong> excess air volume (m 3 )ˆ 0:25[7:685/(79:1/100)] ˆ 2:429Thus,CO 2 ˆ 1:035(1:035 ‡ 7:685 ‡ 2:429) ˆ 9:3%Chimneys 323ChimneysThe purpose <strong>of</strong> a chimney is to provide a means whereby the products <strong>of</strong> combustion maybe exhausted in such a manner as either to avoid pollution or, at worst, to provide means<strong>of</strong> dispersion such that pollution is diluted to an acceptable level. Obviously, the nature <strong>of</strong>the pollutants will vary with the nature <strong>of</strong> the fuel used. Particulate matter may be carriedover in some cases, acid vapours in others <strong>and</strong> in some the discharge may be no more thana thermal carrier-plume.Chimney design is a task which may involve a number <strong>of</strong> disciplines in the solution <strong>of</strong>problems related to the aesthetic, structural <strong>and</strong> functional aspects. Very many chimneysare concealed for much <strong>of</strong> their height within the massing <strong>of</strong> a tall building but thisapproach to concealment may lead to local difficulties as a result <strong>of</strong> lee-side downwash orvortex effects. It is not possible to discuss these matters here <strong>and</strong>, in any event, they arebest resolved through model tests in a wind tunnel using techniques which are now wellestablished.There are certain principles applying to all chimneys, regardless <strong>of</strong> fuel type, which arenow recognised as being fundamental to good design. These are:. The velocity <strong>of</strong> the gases through the stack should be as high as possible commensuratewith the draught available.

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