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Book - School of Science and Technology

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Criteria which affect human comfort ± definitions 5Table 1.2 Temperature ScalesDegreesAbsolutezeroFreezingpointBoilingpointCentigrade C 273 200 100 18 0 10 16 20 28 40 60 71 82 100 200Fahrenheit F 460 328 200 0 32 50 61 68 82 104 140 160 180 212 392Kelvin K 0 ± ± ± 273 ± ± ± ± ± ± ± ± 373 ±that <strong>of</strong> ice. Ice, however, may be said to be hot, or at a high temperature, relative to liquidair at 190 C. Following the adoption <strong>of</strong> the SysteÁme International, temperature ismeasured in units <strong>of</strong> C or K. The Celsius scale has a convenient false zero (0 C), whichcorresponds to the temperature at which water freezes, <strong>and</strong> has equal intervals above thisto the temperature at which water boils under atmospheric pressure (100 C). The thermodynamicor absolute scale, established from the study <strong>of</strong> pressure effects upon gases, usesthe same intervals as the Celsius scale but with a true zero corresponding to the minimumpossible temperature obtainable. The intervals here are kelvin (K) <strong>and</strong>, with this scale,water freezes at 273 K.In order to avoid confusion in terminology, it was the accepted convention in Imperialunits that temperature level (or potential) should be expressed in terms <strong>of</strong> F, whereastemperature difference (or interval) was in terms <strong>of</strong> deg. F. Similarly, under strict SI rules,temperature level is expressed in C <strong>and</strong> difference in K <strong>and</strong>, although this usage is notobligatory, it is an aid to clarity <strong>and</strong> will be adopted throughout this book. For the benefit<strong>of</strong> those readers who were educated prior to the adoption <strong>of</strong> metric units, a conversiontable, Celsius to Fahrenheit, will be found in Appendix I. Table 1.2 shows the relationshipbetween the various scales <strong>and</strong> some notable conversions. Reference will be made later inthis chapter to a variety <strong>of</strong> different temperature notations: dry-bulb; wet-bulb; globe <strong>and</strong>radiant. These relate to methods <strong>of</strong> measurement for particular purposes <strong>and</strong> all use theCelsius or absolute scales noted above.Conduction, convection <strong>and</strong> radiationThese three terms have already been mentioned as being associated with heat transfer <strong>and</strong>it is necessary, for the discussions which follow, that there should be a clear perception <strong>of</strong>the difference between them.ConductionThis may be described as heat transfer from one particle to another by contact. Forexample, if two blocks <strong>of</strong> metal, one hot <strong>and</strong> one cold, were to be placed in contact, thenheat would be conducted from the one to the other until both reached an intermediatetemperature. If both blocks were <strong>of</strong> the same metal, then this temperature could becalculated by the simple process <strong>of</strong> relating the mass <strong>and</strong> temperature <strong>of</strong> one to those <strong>of</strong>the other:but if the materials were not the same, it would be necessary to take account <strong>of</strong>the different specific heat capacities as noted earlier.Conductivity is a measure <strong>of</strong> the quantity <strong>of</strong> heat that will be transferred through unitarea <strong>and</strong> thickness in unit time for a unit temperature difference (J m/s m 2 K ˆ W/m K).Table 1.1 lists values <strong>of</strong> this property for various materials <strong>and</strong> it will be noted thatmetals have a high conductivity, whereas, at the other end <strong>of</strong> the scale, materials known

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