Corrosion Protection Systems - TIB Chemicals AG

www.tib-chemicals.comCPS_0112_EN

BASIC CHEMICALS | INORGANIC SPECIALTY CHEMICALS | COATING SYSTEMSCorrosion Protection Systems | PROTEGOL ®High Performance Coatings

LEADERS IN QUALITY AND SERVICETIB Chemicals was born following the merger ofGoldschmidt TIB of Germany and Goldschmidt Químicade México. The nickel chemicals specialist Königswarter& Ebell joined the TIB Chemicals Group in 2010.The company is a leading international supplier of awide range of basic chemicals, innovative inorganicspecialty chemicals and high-performance coatingsystems.The largest production facilities are located inMannheim and Hagen, Germany and San Luis Potosí,México. Our sales and distribution organisationoperates worldwide. TIB Chemicals has more than350 highly qualified employees who draw on thecompany’s over 130 years of experience and accumulatedexpertise. Currently they produce and processmore than 400,000 tonnes of chemicals and generaterevenues of about 150 million euros a year, with anaccelerating trend.For years, the growth of TIB Chemicals has outpacedthe industry average. Our success is based on the highqualityproducts and tailor-made solutions we developfor our customers, backed by a flexible logistics service.We are committed to supporting our customers andhelping them to achieve business success.The company is divided into three business units:Basic Chemicals, Inorganic Specialty Chemicals andCoating Systems. All three act flexibly and quickly tomeet our customers' wishes and needs. Together theyform a strong unit with a solid financial base and thelogistical and organisational structure of a largecorporation.

CHEMICALSBASIC CHEMICALSZinc ChemicalsINORGANICSPECIALTY CHEMICALSMetal Finishing ChemicalsCOATING SYSTEMSCorrosion Protection SystemsAcidsCopper ChemicalsThermal Curing SystemsSulphur ChemicalsCatalystsBitumen SpecialtiesProcess AdditivesTHE THREE BUSINESS UNITS OF TIB CHEMICALSBASIC CHEMICALSINORGANICSPECIALTY CHEMICALSCOATING SYSTEMSThese products include acids,zinc- and sulphur-based chemicalsfor chemical companies, the metalworkingindustry, hot-dip galvanising,electroplating, the textile andplastics industries, water treatmentand production of foods andbeverages.Based on the elements tin, zinc,copper, nickel, bismuth andchromium. These special chemicalshave numerous applications intodays high tech industries electroplatingin the electronics and metalworkingindustries, performanceenhancement in automotive andchemical industries, Catalysts formanufacturing resins, coatings andpaints, process additives in glass,building and ceramic industries areour key markets.Polyurethane- and epoxy-basedcoating systems to prevent corrosionof pipelines and valves, watertreatment facilities and power plants.Thermal Curing Systems, such ashot dip coatings for electroplatingand tool manufacturing, as well asstoving varnishes for the packagingindustry. Bitumen Specialties foruse in building construction, civilengineering and road paving.Our Corrosion Protection Systems are presented on the following pages.| 2

PROTEGOL ® - HIGH PERFORMANCE COATING SYSTEMSEnergy consumption and the demand for water aregrowing rapidly. Thus, liquid and gaseous media haveto be transported via pipeline networks over increasingdistances. Additionally, existing distribution pipelinesare reaching the age where refurbishment is inevitable.Hence, industries are in need of anticorrosive protectivecoatings which demonstrate both innovative andflexible characteristics.With its diversified product portfolio of various multicomponentliquid PROTEGOL ® coatings for pipes, valvesand fittings, TIB Chemicals offers a wide range of bothinternal and external coating systems that are not onlyfast curing and easy to apply, but which conform tointernational norms, standards and regulations.We, TIB Chemicals, have been one of the leading manufacturersof high-tech coating systems for decades anda recognised reliable supplier to all of our customers.Our extensive experience is the trademark of our highqualitycoating systems and the result of constantresearch and development activities. We provide ourcustomers worldwide with both standardized and tailormadecoating solutions. Furthermore, we stronglybelieve that the development of our coating systemscan only succeed if we work closely with eachindividual customer and create products that aim toexceed requirements.

PROTEGOL ® COATINGS AND THEIR CHEMISTRYPOLYURETHANE REACTIONHO – R 1 – OH + O = C = N – R 2 – N = C = OdioldiisocyanatePolyadditionO=R 1 C R 2 CO O N NH H npolyurethaneO=EPOXY REACTIONR 1 NH 2+primary amineOoxiranPolyadditionOHHOR 2 NOR 2secondary amineR 1R 1OHHN OR 2 +secondary amineOoxiranOR 2PolyadditionR 1OHOHIR 2 O NOR 2epoxy resinPROTEGOL ® - PROVIDING EFFICIENCY WITHIN NUMEROUS INDUSTRIAL AREASEach year, the corrosion of steel structures causesbillions of Euros of damage worldwide. Therefore,companies are constantly striving to find durable andlong lasting products.PROTEGOL ® liquid polyurethane and epoxy coatingsoffer reliable protection for gas, oil and water pipelines;this is the core focus of our activity.In addition, they have an extensive track record in beingused with transmission lines within refineries, powerplants, sewage water facilities, condensers and coolingwater pipes as well as in tanks and vessels. PROTEGOL ®corrosion protection systems are mainly applied directlyto the metallic surfaces such as steel, stainless steeland cast iron, and as a top coat over FBE or concrete.| 4

A WIDE RANGE OF APPLICATIONS: GAS - OIL - WATER - OTHER INDUSTRIESTIB Chemicals’ coating systems are used within a widerange of corrosion protection areas such as fieldapplication, generally for pipeline rehabilitation as wellas external girth weld coating, and factory application.In both of these areas, PROTEGOL ® has a proven trackrecord of long-term protection, together with its technicalperformance values and benefits relating to abrasionand impact resistance. PROTEGOL ® has distinguisheditself from many other corrosion protection systems dueto its fast curing properties and chemical resistancecharacteristics even under harsh climatic conditionsin regions such as Russia, the Middle East and SouthEast Asia.This versatility of application allows PROTEGOL ® coatingsto be applied in either factory or field conditions.Factory application can be completed with relativelyminor modifications to the existing equipment with thesimple introduction of plural component airless hot sprayequipment. This is compatible with most online factorycoating facilities, even with those for multi-layer PE andPP systems.In the field PROTEGOL ® polyurethane and epoxy coatingsare often used in rehabilitation projects, for field jointcoatings and for new construction projects. They arespecially selected for their fast curing properties, whichallows inspection and backfilling to take place within ashort period. Uneconomic downtime can be substantiallyreduced.

PROTEGOL ® - LONG LIFE PROTECTION AGAINST CORROSION ATTACKA few facts at a glance:• PROTEGOL ® solvent-free coating systems offerreliable protection against corrosion attacks evenunder severe soil stress conditions.• PROTEGOL ® polyurethane and epoxy coatings complywith DIN EN 10290 and DIN EN 10289 standards.• PROTEGOL ® product portfolio includes systemswhich have been awarded potable water certification.• PROTEGOL ® corrosion protection systems haveexcellent bonding properties to steel and cast ironsubstrates and are extremely abrasion and chemicalresistant.• PROTEGOL ® coatings have been designed andformulated to be applied individually without theneed for a primer.• PROTEGOL ® polyurethane coatings, due to theirhigh abrasion resistance, can be applied as a firstline of defence in HDD sections, as both a single andsupporting protective coating over FBE.• PROTEGOL ® coatings can be applied within a widetemperature range without the need for pre-heatingor post-curing.• PROTEGOL ® coatings can be applied and operatedas non-shielding (fail/safe) coatings which do notimpede CP systems.• PROTEGOL ® coatings feature highly economiccharacteristics such as fast curing and shortback-in-service times.| 6

PROTEGOL ® - PROTECTION FOR THE GAS INDUSTRYOur expertise lies in offering coating solutionswithin diverse areas of the gas industry. Over thepast decades, we have gained profound experience incoating products for pipeline segments, transmissionpipes, valves, bends and fittings. We are specialistsin the development and manufacture of external andinternal coatings.PROTEGOL ® polyurethane and epoxy based productscomply with DIN EN 10290 and DIN EN 10289 standardsrespectively, fulfilling all of the stringent requirements.In addition, product modifications can be carried out tosuit specific project needs.Gas pipelines often demand extremely high cathodicdisbonding properties and a protective system operatingwith or without CP current, when the pipeline is grounded.PROTEGOL ® , with its non-shielding properties, meetsthese requirements far better than many other coatingsused in the industry.Our PROTEGOL ® Flowcoat products are developed forthe internal protection of steel pipelines for non-corrosivegases and are designed to reduce friction within thepipeline.

PROTEGOL ® COATINGS FOR THE GAS INDUSTRY32 - 45 R 32 - 55 R 32 - 55 PN 32 - 60 32 - 89 S 130 HTFlowcoat06 LTFlowcoat08Polyurethane-basedEpoxy resin-basedApplication by 2K airlessequipmentApplication by 1K airlessequipment or manualApplication by air-assistedequipment (twin cartridges)Gravimetric mixing ratio 3.65 : 1 4.55 : 1 3 : 1 1 : 1 2.23 : 1 2.23 : 1 1.38 : 1 6.67 : 1Volumetric mixing ratio 3 : 1 3.5 : 1 2.5 : 1 1 : 1 2 : 1 2.2 : 1 1 : 1 4.35 : 1Maximum application thicknessin one pass [μm]2,000 2,000 5,000 2,000 1,200 800 100 150Density comp. A+B [g/cm³] 1.45 1.63 1.50 1.20 1.49 1.45 1.30 1.34Density comp. A [g/cm³] 1.52 1.72 1.60 1.20 1.54 1.45 1.51 1.45Density comp. B [g/cm³] 1.24 1.24 1.24 1.20 1.39 1.45 1.09 0.95Pot life spray applicationat 60 °C [sec]30 30 30 10 120 120Pot life manual applicationat 30 °C [min]23 180CertificatesDIN EN10290DIN EN10290,DIN30677-2ISO21809-3DIN EN10290DIN EN10289DIN EN10289DIN EN10301,ISO15741DIN EN10301,ISO15741Internal applicationExternal applicationRepair material available(2 kg and 0.5 kg twin packs)RemarksFrictionreducing,water-basedFrictionreducing,solventbased| 8

PROTEGOL ® - PROTECTION FOR THE OIL INDUSTRYPROTEGOL ® two-component solvent-free liquidpolyurethane and epoxy coatings have been successfullyapplied as internal and external coatings for oilpipelines all around the world.Our corrosion protection systems comply with DIN EN10290 and DIN EN 10289 standards respectively, fulfillingall of the stringent requirements.The fact that PROTEGOL ® conforms to the specificationstandards of most of the major oil companies expressesand confirms its flexible range of application.Furthermore, our conductive products can be utilised forthe internal lining of tanks for oil and its derivatives.When it comes to technically challenging requirements inparticular, PROTEGOL ® has proven its high performancein various oil and gas projects, even in temperatureenvironments ranging from -60 °C up to +150 °C.

PROTEGOL ® COATINGS FOR THE OIL INDUSTRY32 - 45 R 32 - 55 R 32 - 55 PN 32 - 60 32 - 89 S 130 HT TB 55 AS TB 55Polyurethane-basedEpoxy resin-basedApplication by 2K airlessequipmentApplication by 1K airlessequipment or manualApplication by air-assistedequipment (twin cartridges)Gravimetric mixing ratio 3.65 : 1 4.55 : 1 3 : 1 1 : 1 2.23 : 1 2.23 : 1 4 : 1 4 : 1Volumetric mixing ratio 3 : 1 3.5 : 1 2.5 : 1 1 : 1 2 : 1 2.2 : 1 2.7 : 1 2.7 : 1Maximum application thicknessin one pass [μm]2,000 2,000 5,000 2,000 1,200 800 800 800Density comp. A+B [g/cm³] 1.45 1.63 1.50 1.20 1.49 1.45 1.35 1.35Density comp. A [g/cm³] 1.52 1.72 1.60 1.20 1.54 1.45 1.45 1.45Density comp. B [g/cm³] 1.24 1.24 1.24 1.20 1.39 1.45 1.00 1.00Pot life spray applicationat 60 °C [sec]Certificates30 30 30 10 120 120 n.a. n.a.DIN EN10290DIN EN10290,DIN30677-2ISO21809-3DIN EN10290DIN EN10289DIN EN10289Tank liningTank liningInternal applicationExternal applicationRepair material available(2 kg and 0.5 kg twin packs)RemarksConductive,mediumresistanceIB1, IB3 andIB4bMediumresistanceIB1, IB3 andIB4b| 10

PROTEGOL ® - PROTECTION FOR THE HYDRO INDUSTRYThe result of our constant research and developmenthas led to high performance coating systems thatcan be applied to water pipelines and components incontact with water, as an external coating and internallining. Our product portfolio extends to coatingsolutions for steel and ductile iron pipes.Our approvals for drinking water include:• The German Federal Environmental Agency (UBA)“Guideline for the Hygienic Assessment of OrganicMaterials in Contact with Drinking Water (KTWGuideline)”The application fields of PROTEGOL ® for the waterindustry comprise sewage water plants, potable waterreservoirs and hydro-electric power plants.• The German Association of the Gas and Water Industry(DVGW) worksheet W270 “The Growth of Micro-Organisms on Materials Intended for Use in DrinkingWater Systems – Examination and Assessment”• The French Association of Standardisation (AFNOR)standard XP P41-250 “Effects of Materials on theQuality of Water Intended for Human Consumption –Organic Materials”

PROTEGOL ® COATINGS FOR THE HYDRO INDUSTRY32 - 45 32 - 55 R 32 - 55 PN 32 - 60 32 - 48 32 - 49 32 - 99EP ConcretePrimer forPU CoatingsEP ConcretePrimer forEP CoatingsPolyurethane-basedEpoxy resin-basedApplication by 2K airlessequipmentApplication by 1K airlessequipment or manualGravimetric mixing ratio 3.65 : 1 4.55 : 1 3 : 1 1 : 1 2.13 : 1 3 : 1 1.5 : 1 1.82 : 1 2 : 1Volumetric mixing ratio 3 : 1 3.5 : 1 2.5 : 1 1 : 1 2 : 1 2.5 : 1 1.75 : 1 1.58 : 1 2.60 : 1Maximum application thicknessin one pass [μm]1,000 2,000 5,000 2,000 1,500 1,500 900 n.a. n.a.Density comp. A+B [g/cm³] 1.45 1.63 1.50 1.20 1.28 1.35 1.50 1.10 1.10Density comp. A [g/cm³] 1.52 1.72 1.60 1.20 1.,31 1.45 1.43 1.15 1.15Density comp. B [g/cm³] 1.24 1.24 1.24 1.20 1.22 1.20 1.66 1.00 1.00Pot life spray applicationat 60 °C [sec]30 30 30 10 30 30540 (at 20 °C50 min)20 min at30 °C15 min at30 °CCertificatesDIN EN10290DIN EN10290,DIN30677-2ISO21809-3DIN EN10290Potable water certificatesUBA,W270UBA,W270UBA,W270,XP P41-250Internal applicationExternal applicationRepair material available(2 kg and 0.5 kg twin packs)RemarksApplicableon castand zincprimedcastironApplicableon castand zincprimedcastironPriming ofconcreteunder PUcoatingsPriming ofconcreteunder EPcoatings| 12

OTHER INDUSTRIAL SECTORSPROTEGOL ® polyurethane and epoxy coatings offerexcellent properties and are being applied in variousindustrial sectors. They are chemically and mechanicallyreliable and meet international quality standards thatassure long-term durable corrosion protection.Their flexibility is demonstrated by the fact that they cannot only be applied to metallic surfaces such as steel,stainless steel and cast iron, but also as a top coat overFBE and concrete.Our high performance products are being utilised aseffective coating systems on steel structures in theconventional and the renewable energy sector.Other fields of application include the internal andexternal coating of slurry pipelines by providing highabrasion resistance as well as the coating of piling pipesfor platforms by ensuring heavy-duty corrosion protection.The application range of PROTEGOL ® extends to theanticorrosive coating of small tanks, large bullet tanksand gas storage reservoirs.

PROTEGOL ® - DEVELOPING SOLUTIONS FOR OUR CUSTOMERSSustainability and innovative solutions, quality, flexibilityand forward thinking are the key factors of ourvision. When engineering innovative and practicablesolutions, our goal is to enhance our customers’competitiveness.As a customer-minded organization, our R & D strives tomeet our customers’ standards and requirements, bothby developing new products and by adaptingexisting ones.Our qualified and experienced personnel provide inhouseexpertise, providing a qualified response within ashort period of time. We work closely together with ourclients to meet their expectations at all times.While developing optimum tailor-made solutions wenaturally act in accordance with prevailing safety andsecurity regulations and quality standards.| 14

METHODS OF APPLICATIONA coating systems’ effectiveness is governed bythe selection of the best possible protective coatingmaterials and the proper method of application.Without the right application method, any coatingsystem will fail to excel to its full potential.It is part of TIB Chemicals’ approval criteria that thecorrect application procedures in the factory and in thefield are carried out exclusively by specialists. Thesepersonnel have to possess credentials which demonstratetheir experienced and skilled technique.PROTEGOL ® coating systems can be applied in a varietyof ways: from plural component airless hot spraying forlarge areas to conventional air-assisted spraying andmanual application by brush or roller, which is mostsuitable for repair work and small or limited accessibleareas.

AUTOMATIC APPLICATIONThe fastest PROTEGOL ® application rates can be achievedby means of the automatic spray ring. This method hasproven to be the most productive and reliable methodand is not only suited for short distances such as bellhole rehabilitation, but also for the coating of the entirepipeline – either in or over the ditch and even when thepipeline is in service.TIB Chemicals has been actively involved within theresearch and development phase of the first automaticspray ring for application of PROTEGOL ® in the field.PROTEGOL ® two-component liquid coatings are thepreferred choice, when application in the field isrequired. Pioneered in the early 1990s as the firsttwo-component polyurethane coating to be selectedfor the external protection of field joints of pipespre-coated in the factory with multi-layer PE and PPsystems, PROTEGOL ® continues setting the standardfor field joint coating utilising MCL (Multi ComponentLiquid) systems. It remains the most widely recognisedliquid coating system for field joint application today.MANUAL APPLICATIONManual spraying involves airless and air-assisted sprayingmethods. With the plural component airless hot spraymachine, production rates are increased. High coatingthicknesses of PROTEGOL ® coating systems can beachieved in just one single pass resulting in ahomogenous and pinhole free coating.Another PROTEGOL ® method of application consistsof manual application using a brush, spatula or rollerand can be utilised to stripe-coat edges and welds or totouch up damaged areas.PROTEGOL ® coatings supplied in cartridges can beapplied efficiently using an air-assisted spray gun.This is preferably used on smaller areas and wherelimited working space could make application work witha plural component airless system difficult.| 16

SURFACE PREPARATION – A FUNDAMENTAL PRE-REQUISITEIn order to obtain satisfactory coating applicationresults, the following fundamental factors have tobe observed:• The steel surfaces to be coated must be dry, cleanand free from all release agents (e.g. oil, grease andold paint) and must constitute a good profile.• The degree of cleanliness should comply with ISO8501-1, Sa 2 1/2 (SSPC-SP 10/ NACE No. 2).• The surface inspection should be in accordance withISO 8501-3.• The surface temperature during the coatingapplication process must be at least 3 °C above thedew point.• Suitable substrate preparation methods such as gritblasting must be used.

GERMANYTIB Chemicals AGBusiness Unit Coating SystemsMülheimer Strasse 16 – 2268219 MannheimP.O. Box 81 02 2068202 MannheimTel. +49 621 8901 0Fax +49 621 8901 902info.cps@tib-chemicals.comwww.tib-chemicals.comRainer KuprionDirector Business Unit Coating SystemsTel. +49 621 8901 812Mobile +49 162 293 95 16rainer.kuprion@tib-chemicals.comMaja HornigSenior Sales ManagerTel. +49 621 8901 824maja.hornig@tib-chemicals.comJean Marc WitzSenior Sales ManagerFrancophony, Africa and TurkeyTel. +33 388 571 189Fax +33 388 571 189Mobile +33 609 165 11jeanmarc.witz@tib-chemicals.comFabrizio ScesaSenior Sales Manager, ItalyTel. +39 037 3975 224Fax +39 037 3975 260Mobile +39 348 2541 850fabrizio.scesa@tib-chemicals.comPriyanka SinghSales ManagerTel. +49 621 8901 854priyanka.singh@tib-chemicals.comLutz HoppadietzSalesTel. +49 621 8901 793lutz.hoppadietz@tib-chemicals.comHans-Jürgen SerbserSalesTel. +49 621 8901 831hans-juergen.serbser@tib-chemicals.comThomas KunathTechnical Sales ManagerTel. +49 621 8901 837Mobile +49 162 293 95 39thomas.kunath@tib-chemicals.comMichael NiedermeyerTechnical Sales ManagerTel. +49 621 8901 739michael.niedermeyer@tib-chemicals.comAlfred MaierHead of Research & DevelopmentTel. +49 621 8901 852Fax +49 621 8901 904Mobile +49 162 293 95 44alfred.maier@tib-chemicals.comDr. Christina NicoaraResearch & DevelopmentTel. +49 621 8901 255Fax +49 621 8901 904christina.nicoara@tib-chemicals.comEUROPEASIASlovakiaAREKO, s.r.oTel. +421 243 634 044Fax +421 243 634 046areko@areko.skwww.areko.skSpainEFA 2000, S.L.Eckard ArltTel. +34 918 151 172Fax +34 918 151 477Mobile +34 609 001 325eckard@composites-rtm.comwww.composites-rtm.comRussiaPROTECOR JSCTel. +7 495 9891 882Fax +7 495 9891 883info@protecor.ruwww.protecor.ru| 18