MATERIAL SAFETY DATA SHEET - Kaap Agri

MATERIAL SAFETY DATA SHEETKENOPEL 40 SLConforms to 93/112/EC and ISO 11014-11.IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THECOMPANY/UNDERTAKINGProduct nameChemical name of activeingredient(s)Code no.Supplier: KENOPEL 40 SL: Guazatine acetates.: R-16317.SA: Irvita Plant Protection N.V.Pos Cabai Office Park, Unit 13P.O. Box 403CuraçaoNetherlands AntillesTelephone: (599-9) 738-4096 / 738-4040Fax: (599-9) 738-40052. COMPOSITION/INFORMATION ON INGREDIENTSSubstance/preparation : PreparationInformation on hazardous ingredients *Common name CAS No. % EC Number Symbol R-PhrasesGuazatine acetate 115044-19-4 38 236-855-3 T+ N R21/22-26-37/38-41-50/53* Occupational Exposure Limit(s), if available, are listed in section 83.HAZARDS IDENTIFICATIONHuman health hazardsEnvironmental hazards: Toxic by inhalation.Irritating to respiratory system.Harmful if swallowed.Irritating to eyes.: Very toxic to aquatic organisms, may cause long-term adverse effects inthe aquatic environment4.FIRST-AID MEASURESEffects and symptomsFirst-aid measuresInhalation: Remove victim to fresh air. Immediately get medical attention.Ingestion: If swallowed, seek medical advice immediately and show this container orlabel.Skin contact: After contact with skin, wash immediately with plenty of water.Eye contact : Wash out with plenty of water with the eyelid held wide open. Immediatelyconsult an eye specialist.Notes to a physician : No antidotes known. Treat symptomatically and give supportive therapy.Date of issue: 02/03/2004Version: 001.00.00Page 1 of 5

MATERIAL SAFETY DATA SHEETKENOPEL 40 SLConforms to 93/112/EC and ISO 11014-15.FIRE-FIGHTING MEASURESExtinguishing mediaSuitableHazardous thermal(de)composition productsProtection of fire-fighters: Not flammable. In case of fire, use foam, CO 2 , dry chemical, waterspray.: COx, NO x .: Self-contained breathing apparatus.6. ACCIDENTAL RELEASE MEASURESPersonal precautionsEnvironmental precautionsMethods for cleaning up: Wear suitable protective clothing and safety glasses.: Do not empty into drains.: Absorb in sand or other inert material. Collect spilled material with shovel,place into a clean container. Dispose of this material and its container athazardous or special waste collection point.7. HANDLING AND STORAGEHandlingStoragePackaging materialsSuitable: Wear suitable protective clothing, gloves and eye/face protection.Do not breathe vapour. Use breathing apparatus. Use only inwell-ventilated areas.When using do not eat, drink or smoke.: Keep away from food, drink and animal feedingstuffs.: High density polyethylene extrusion blow containers.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONEngineering measuresHygiene measuresOccupational ExposureLimitsPersonal protectiveequipment: Ventilation required. Facilities storing or utilizing this material should beequipped with an eyewash facility and safety shower.: Wash hands thoroughly after handling.: No occupational exposure limits have been established.: Wear protective clothing, neoprene gloves. Wear eye/face protection.9. PHYSICAL AND CHEMICAL PROPERTIESPhysical state: Liquid.Colour : Colourless.Odour: Weak acetic acidBoiling point : 100ºCDensity: 1.055pH : 4.5 - 6.5Flash point : > 100º C.Flammability: Not flammable.Explosion properties : Not explosive.Date of issue: 02/03/2004Version: 001.00.00Page 2 of 5

MATERIAL SAFETY DATA SHEETKENOPEL 40 SLConforms to 93/112/EC and ISO 11014-110. STABILITY AND REACTIVITYStability: Stable under normal conditions.Materials to avoid: Corrosive to iron and alloys thereof.Hazardous reactions : None known.Hazardous decomposition : COx, NOx.products11. TOXICOLOGICAL INFORMATIONAcute toxicity - Oral : LD 50 = 705 mg/kg (M); 1161 mg/l (F) - rat.Acute toxicity - Dermal : LD 50 > 2000 mg/kg (rat).Acute toxicity - Inhalation : LC 50 = 0.85 mg/l, 4 hours, (rat) *Skin irritation: Not irritating to skin (rabbit).Eye irritationSensitization: Irritating to eyes (rabbit).: Guinea pig maximization test: Non sensitizer - (active ingredient).* Acute inhalation test for a similar product (35 LS).12.ECOLOGICAL INFORMATIONNo ecological information is known on the product.For the Technical:Ecotoxicity: Fish: LC 50 = 0.4 mg/l (trout).Daphnia: EC 50 = 0.15 mg/l (4 hours).Algae: EbC 50 = 5.4 µg/l; ErC 50 = 8.7 µg/l.13.DISPOSAL CONSIDERATIONSMethods of disposal: Disposal according to the local legislation.Product and Contaminated packaging: Incinerate in a licensedinstallation.14.TRANSPORT INFORMATIONInternational transport regulationsUN number: 2902Land - Road/RailwayProper shipping name : Pesticide, liquid, toxic, N.O.S. (38% Guazatine acetates).ADR/RID Class: 6.1Packing group: llInland waterwaysSeaProper shipping name : Pesticide, liquid, toxic, N.O.S. (38% Guazatine acetates).IMDG Class : 6.1Packing group: llAirProper shipping name : Pesticide, liquid, toxic, N.O.S..Date of issue: 02/03/2004Version: 001.00.00Page 3 of 5

MATERIAL SAFETY DATA SHEETKENOPEL 40 SLConforms to 93/112/EC and ISO 11014-1National transport regulationsNo additional national transport regulations are known to the supplier15. REGULATORY INFORMATIONClassification : This product is provisionally labelled by the supplier in accordance with thesuppliers understanding of the EU regulations.Hazard symbol(s) : T, NTOXICDANGEROUS FOR THEENVIRONMENTRisk phrases: R22: Harmful if swallowed.R23: Toxic by inhalation.R36: Irritating to eyes.R37: Irritating to respiratory system.R50/53: Very toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment.Safety phrases : S13: Keep away from food, drink and animal feedingstuffs.S20/21: When using do not eat, drink or smoke.S23: Do not breathe gas/fumes/vapour/sprayS26: In case of contact with eyes, rinse immediately with plenty of waterand seek medical advice.S36/37/39: Wear suitable protective clothing, gloves and eye/faceprotection.S38: In case of insufficient ventilation, wear suitable respiratoryequipment.S45: In case of accident or if you feel unwell, seek medical adviceimmediately (show the label where possible).S57: Use appropriate containment to avoid environmentalcontamination.16.OTHER INFORMATIONRecommended use: Fungicide.Date of issue: 02/03/2004Version: 001.00.00Page 4 of 5

MATERIAL SAFETY DATA SHEETKENOPEL 40 SLConforms to 93/112/EC and ISO 11014-1Text of R-phrases appearing in section 2:R21: Harmful in contact with skinR22: Harmful if swallowedR26: Very toxic by inhalationR37: Irritating to respiratory systemR38: Irritating to skinR41: Risk of serious damage to eyesR50: Very toxic to aquatic organismsR53: May cause long-term adverse effects in the aquatic environmentThe information contained in the Safety Data sheet is correct to the best of our knowledge at the date ofissue. It is intended as a guide for the safe use, handling, disposal, storage and transportation and is notintended as a warranty or as a specification. The information relates only to the product specified and maynot be suitable for combinations with other materials or in processes other than those specifically describedherein.HISTORYDate of printing: 02/03/2004Date previous issue : 02/03/2004Date of issue: 02/03/2004Version : 001.00.00The version-number is made up of three parts; part 1 is a general information code, part 2 acountry-specific code and part 3 a language-specific codeDate of issue: 02/03/2004Version: 001.00.00Page 5 of 5