Material Safety Data Sheet - Scott Technical Sales Company

Material Safety Data SheetRevision Number: 001.1 Issue date: 11/10/20091. PRODUCT AND COMPANY IDENTIFICATIONProduct name: HYSOL 9432NA 2LB CN IDH number: 398480Product type: Epoxy resin Item number: 83217Region:United StatesCompany address:Contact information:Henkel CorporationTelephone: 860.571.5100One Henkel WayEmergency telephone: 860.571.5100Rocky Hill, Connecticut 06067Internet: www.henkelna.com2. HAZARDS IDENTIFICATIONEMERGENCY OVERVIEWHMIS:Physical state: Liquid HEALTH: *2Color: Milky, Gray FLAMMABILITY: 1Odor: Slight PHYSICAL HAZARD: 1Personal Protection: See MSDS Section 8WARNING: MAY CAUSE ALLERGIC SKIN REACTION.MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION.Relevant routes of exposure:Skin, Inhalation, Eyes, IngestionPotential Health EffectsInhalation:Skin contact:Eye contact:Ingestion:Existing conditions aggravated byexposure:Mild respiratory tract irritation.May cause allergic skin reaction. Moderate skin irritation. Itching. Redness.Moderate eye irritation. Redness.May irritate mouth, throat, and stomach if swallowed.Eye, skin, and respiratory disorders. Skin allergies.This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR1910.1200).See Section 11 for additional toxicological information.3. COMPOSITION / INFORMATION ON INGREDIENTSHazardous components CAS NUMBER %Epichlorohydrin-4,4'-isopropylidene diphenol resin 25068-38-6 30 - 60Aluminum 7429-90-5 10 - 30Cyanoguanidine 461-58-5 5 - 10Treated fumed silica 67762-90-7 5 - 10Reaction product, 4,4'-(1-methylethylidene )bisph 134091-76-2 1 - 5Polyglycol Triepoxide~ Proprietary 1 - 5Glass Proprietary 1 - 54. FIRST AID MEASURESInhalation:Move to fresh air. If not breathing, give artificial respiration. If breathing isdifficult, give oxygen. If symptoms develop and persist, get medical attention.IDH number: 398480Page 1 of 5Product name: HYSOL 9432NA 2LB CN

Skin contact:Eye contact:Ingestion:Immediately flush skin with plenty of water (using soap, if available). Removecontaminated clothing and footwear. Wash clothing before reuse. If symptomsdevelop and persist, get medical attention.Immediately flush eyes with plenty of water for at least 15 minutes. Getmedical attention.DO NOT induce vomiting unless directed to do so by medical personnel. Keepindividual calm. If symptoms develop and persist, get medical attention.5. FIRE FIGHTING MEASURESFlash point:Autoignition temperature:Flammable/Explosive limits - lower:Flammable/Explosive limits - upper:Extinguishing media:Special firefighting procedures:Unusual fire or explosion hazards:Hazardous combustion products:96.11 °C (205°F) Setaflash Closed CupNot availableNot availableNot availableFoam, dry chemical or carbon dioxide.Wear self-contained breathing apparatus and full protective clothing, such asturn-out gear.In case of fire, keep containers cool with water spray. Closed containers mayrupture (due to build up of pressure) when exposed to extreme heat.Oxides of carbon. Irritating organic fragments. Acids. Aldehydes.6. ACCIDENTAL RELEASE MEASURESUse personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotectedpersonnel.Environmental precautions:Clean-up methods:Do not allow product to enter sewer or waterways.Remove all sources of ignition. Immediately contact emergency personnel.Scrape up as much material as possible. Clean residue with soap and water.Store in a closed container until ready for disposal.7. HANDLING AND STORAGEHandling:Storage:Keep container closed. Avoid contact with eyes, skin and clothing. Washthoroughly after handling.Store in original container until ready to use.For information on product shelf life contact Henkel Customer Service at (800) 243-4874.8. EXPOSURE CONTROLS / PERSONAL PROTECTIONEmployers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposurecontrols and protective equipment for each task performed.IDH number: 398480Page 2 of 5Product name: HYSOL 9432NA 2LB CN

Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHEREpichlorohydrin-4,4'-isopropylidene diphenol resin None None None None15 mg/m3 TWA (asAl) Total dust.1 mg/m3 TWAAluminum5 mg/m3 TWA (as NoneNoneRespirable fraction.Al) Respirabledust.Cyanoguanidine None None None NoneTreated fumed silica10 mg/m3 TWAInhalable dust.3 mg/m3 TWARespirable fraction.15 mg/m3 TWATotal dust.5 mg/m3 TWARespirable fraction.Reaction product, 4,4'-(1-methylethylidene )bisph None None None NonePolyglycol Triepoxide~ None None None NoneGlass10 mg/m3 TWAInhalable dust.3 mg/m3 TWARespirable fraction.5 mg/m3 TWAInhalable fraction.None None NoneNoneNoneEngineering controls:Respiratory protection:Eye/face protection:Skin protection:Use local exhaust ventilation if the potential for airborne exposure exists.Use NIOSH approved respirator if there is potential to exceed exposurelimit(s).Safety goggles or safety glasses with side shields.Chemical resistant, impermeable gloves.9. PHYSICAL AND CHEMICAL PROPERTIESPhysical state:LiquidColor:Milky, GrayOdor:SlightOdor threshold:Not availablepH:Not availableVapor pressure:Not availableBoiling point/range:Not availableMelting point/ range:Not availableSpecific gravity: 1.45Vapor density: > 1Flash point:96.11 °C (205°F) Setaflash Closed CupFlammable/Explosive limits - lower:Not availableFlammable/Explosive limits - upper:Not availableAutoignition temperature:Not availableEvaporation rate:Not availableSolubility in water:NegligiblePartition coefficient (n-octanol/water):Not availableVOC content: 0 %10. STABILITY AND REACTIVITYStability:Hazardous reactions:Hazardous decomposition products:Incompatible materials:Conditions to avoid:StableWill not occur.NoneStrong acids and strong bases. Strong oxidizing agents. Amines. Water.Store away from incompatible materials. Failure to observe these precautionsmay result in excessive heat build-up causing an exotherm.IDH number: 398480Page 3 of 5Product name: HYSOL 9432NA 2LB CN

11. TOXICOLOGICAL INFORMATIONHazardous components NTP Carcinogen IARC CarcinogenOSHA Carcinogen(Specifically Regulated)Epichlorohydrin-4,4'-isopropylidenediphenol resinNo No NoAluminum No No NoCyanoguanidine No No NoTreated fumed silica No No NoReaction product, 4,4'-(1-methylethylidene )bisphNo No NoPolyglycol Triepoxide~ No No NoGlass No Group 2B NoHazardous componentsEpichlorohydrin-4,4'-isopropylidene diphenol resinAluminumCyanoguanidineTreated fumed silicaReaction product, 4,4'-(1-methylethylidene )bisphPolyglycol Triepoxide~GlassHealth Effects/Target OrgansAllergen, IrritantCentral nervous system, Irritant, LungAllergen, Central nervous system, Eyes, IrritantIrritantNo RecordsNo DataAllergen, Respiratory12. ECOLOGICAL INFORMATIONEcological information:Not available13. DISPOSAL CONSIDERATIONSInformation provided is for unused product only.Recommended method of disposal:Hazardous waste number:Follow all local, state, federal and provincial regulations for disposal.Not a RCRA hazardous waste.U.S. Department of Transportation Ground (49 CFR)Proper shipping name:Not regulatedHazard class or division:NoneIdentification number:NonePacking group:NoneInternational Air Transportation (ICAO/IATA)Proper shipping name:14. TRANSPORT INFORMATIONEnvironmentally hazardous substance, liquid, n.o.s. (Bisphenol-A Epichlorhydrineresin)Hazard class or division: 9Identification number: UN 3082Packing group:IIIWater Transportation (IMO/IMDG)Proper shipping name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol-AEpichlorhydrine resin)Hazard class or division: 9Identification number: UN 3082Packing group:IIIMarine pollutant:Bisphenol-A Epichlorhydrine resinExceptions: Classified per IMDG Amendment 34; Effective Jan 1, 2010.IDH number: 398480Page 4 of 5Product name: HYSOL 9432NA 2LB CN

15. REGULATORY INFORMATIONUnited States Regulatory InformationTSCA 8 (b) Inventory Status:TSCA 12(b) Export Notification:CERCLA/SARA Section 302 EHS:CERCLA/SARA Section 311/312:CERCLA/SARA 313:California Proposition 65:All components are listed or are exempt from listing on the Toxic Substances Control ActInventory.None above reporting de minimusNone above reporting de minimusImmediate Health, Delayed HealthNone above reporting de minimusThis product contains a chemical known in the State of California to cause cancer. Thisproduct contains a chemical known to the State of California to cause birth defects or otherreproductive harm.Canada Regulatory InformationCEPA DSL/NDSL Status:WHMIS hazard class:Contains one or more components listed on the Non-Domestic Substances List. All othercomponents are listed on or are exempt from listing on the Domestic Substances List.Components listed on the NDSL must be tracked by all Canadian Importers of Record asrequired by Environment Canada. They may be imported into Canada in limited quantities.Please contact Regulatory Affairs for additional details.D.2.A, D.2.B16. OTHER INFORMATIONThis material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheetformat.Prepared by: Gary Pierson, Sr. Regulatory Affairs SpecialistDISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However,Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods HenkelCorporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or anyproduction methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for theprotection of property and persons against any hazards that may be involved in the handling and use of any of HenkelCorporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express orimplied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of HenkelCorporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of anykind, including lost profits.IDH number: 398480Page 5 of 5Product name: HYSOL 9432NA 2LB CN