SPE Automotive TPO Global Conference 2009 - Auto-tpo.com
SPE Automotive TPO Global Conference 2009 - Auto-tpo.com
SPE Automotive TPO Global Conference 2009 - Auto-tpo.com
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<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />
Wel<strong>com</strong>e to the Annual <strong>SPE</strong> <strong>Global</strong> <strong>TPO</strong> <strong>Conference</strong><br />
The Society of Plastic Engineers (Detroit Chapter), leading OEMs, Tier 1, and <strong>TPO</strong> suppliers<br />
have pooled their resources to create the 11 th Annual <strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong>.<br />
The conference is a dynamic, interactive, and cost-effective learning experience “put together”<br />
and “contributed to” by the world’s foremost authorities on materials, processes, applications,<br />
and market trends.<br />
The pledge of the conference <strong>com</strong>mittee is simple. We strive to bring you the best,<br />
knowledgeable people who will share useful information on the latest <strong>TPO</strong>-related<br />
developments and trends.<br />
Last year, over 400 attendees from OEMs, Tier 1s, and resin and equipment suppliers<br />
participated in this event. Many new materials, application developments, and technologies<br />
were introduced.<br />
This year's event is expected to be as exciting with over 30 technical papers and presentations<br />
and a special half-day session on Injection Molding & Advanced Process Control. Additionally,<br />
there are 4 keynote speakers: Dr. David Cole, chairman of the Center for <strong><strong>Auto</strong>motive</strong> Research<br />
(CAR) in Ann Arbor, Michigan, Neil De Koker, founding president and CEO of the Original<br />
Equipment Suppliers Association (OESA), Nazeer Bhore, Senior Technology Advisor-Corporate<br />
Planning at ExxonMobil Chemical, and Mr. Maurice Sessel, Vice-President, Product<br />
Engineering at IAC.<br />
An Executive Management panel discussion, including representatives from Ford, General<br />
Motors, LyondellBasell, Toyota, and Dr. Cole is scheduled on Tuesday. The subject is:<br />
<strong><strong>Auto</strong>motive</strong> Paradigm Shift Opportunities for <strong>TPO</strong> materials.<br />
A new feature of the <strong>Conference</strong> is a special half-day session focused on a single subject. Last<br />
year it was on thermoforming. This year, as stated above, is on advanced process control and<br />
trouble-shooting for the injection-molding process. The objective is to help participants achieve<br />
a <strong>com</strong>petitive advantage in today's global market. The session will provide an overview of<br />
polymerization, discussion about the <strong>com</strong>pounding of propylene, polyethylene, etc. into a <strong>TPO</strong><br />
alloy, review decoupled molding strategies, and end with a troubleshooting discussion that<br />
includes a lab demonstration via video link to RJG's Traverse City location.<br />
We thank you for attending this conference, and we look forward to seeing you year after year.<br />
We appreciate your <strong>com</strong>ments and feedback as we are continuing to strive to meet your needs.<br />
Bill Windscheif Paula D. Fasulo<br />
Co-Chairman Co-Chairman<br />
Advanced Innovative Solutions, Ltd. General Motors Corporation<br />
President Staff Scientist, Retired
Bill Windscheif<br />
Co-Chairman<br />
Advanced Innovation Solutions, Ltd.<br />
Sandra McClelland – Chevron Phillips Chemical<br />
<strong>SPE</strong> President<br />
Detroit Section<br />
Dr. Norm Kakarala<br />
Inteva Products L.L.C.<br />
Technical Program Chair<br />
Dave Okonski<br />
Moderator – Materials Development<br />
General Motors Corporation<br />
Mitesh Shah<br />
Scholarship/Moderator-Materials Development<br />
LyondellBasell Industries<br />
Robert Eller<br />
Moderator – Applications Development<br />
Robert Eller Associates, L.L.C.<br />
Thomas Pickett<br />
Moderator – Applications Development<br />
General Motors Corporation<br />
Patti Tibbenham<br />
Moderator – Process Development<br />
Ford Motor Company<br />
Duane Lewis<br />
Moderator – Surface Enhancements<br />
ExxonMobil Chemical Corporation<br />
Dr. Rose Ryntz<br />
Moderator – Surface Enhancements<br />
International <strong><strong>Auto</strong>motive</strong> Components<br />
<strong>2009</strong> Planning Committee Members<br />
Paula Fasulo<br />
Co-Chairman.<br />
General Motors Corporation –retired<br />
Kelly Beauchamp<br />
Proceedings Book<br />
DME<br />
Lisa Wujkowski<br />
House Coordinator<br />
Dow <strong><strong>Auto</strong>motive</strong><br />
Sanjay Patel<br />
Audio/Visual/Web Master<br />
Flint Hills Resources<br />
Tom Powers<br />
Budget/Finance<br />
Consultant<br />
Ron Price<br />
Panel Discussion/Communications<br />
<strong>Global</strong> Polymer Solutions<br />
Nippani Rao<br />
Sponsorships<br />
RAOAssociates<br />
Anthony Gasbarro<br />
Committee Member<br />
Advanced Composites<br />
Ed Bearse<br />
Committee Member<br />
Advanced Plastics Consultants<br />
Pat Levine<br />
Registration<br />
<strong>SPE</strong>/<strong><strong>Auto</strong>motive</strong> Division & Detroit Section
7:30-8:30am Registration/Coffee<br />
<strong>2009</strong> <strong>SPE</strong>® <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> Program<br />
Monday October 5, <strong>2009</strong><br />
8:30am Opening Remarks: Bill Windscheif - Advanced Innovative Solutions, Ltd; Paula Fasulo - General Motors (Retired)<br />
8:45-9:15am Keynote Address: Interior Challenge<br />
Maurice Sessel: Vice President Product Engineering, International <strong><strong>Auto</strong>motive</strong> Components<br />
9:15am Technical Program: Norm Kakarala: Inteva Products<br />
Materials Development Session<br />
(Moderators: David Okonski: General Motors & Mitesh Shah: LyondellBasell Industries)<br />
9:30-10:00am Scratch Performance of Talc-PP and Talc-<strong>TPO</strong> Compounds<br />
Saied H. Kochesfahani, Denis Lejour, Frederic Jouffret, Wolfgang Jonischket: Rio Tinto Minerals<br />
High Performance Reinforcement: A Pathway to Density Reduction While Maintaining Physical Properties of Polyolefin<br />
10:00-10:30am<br />
Composites<br />
K. David Lake: Milliken Chemical<br />
10:30-10:45am Break<br />
10:45-11:15am MOS Hige Fiber for Light Weighting, Fast Cycle Time & Improved Quality <strong>TPO</strong>s<br />
Donald Beuke: Mitsui Plastics<br />
11:15-11:45am Improved Glass-Fiber Reinforced Polypropylene for Structural Applications<br />
Alberto Prieto and Steve Davis: LyondellBasell Industries<br />
11:45-12:15pm High-Performance TPEs for Stringent <strong><strong>Auto</strong>motive</strong> Applications<br />
John Chiao and Keith Dunlap: Kraiburg TPE<br />
12:15-1:30pm Lunch & Keynote Presentation: The <strong><strong>Auto</strong>motive</strong> Industry in Transition: A New Beginning<br />
Neil De Koker: CEO, Original Equipment Suppliers Association<br />
1:30-2:00pm Polypropylene Property Modification using Vistamaxx Specialty Elastomers & Exact Plastomers<br />
Felix Zacarias: ExxonMobil Chemical<br />
2:00-2:30pm New Higher Impact Efficiency Elastomers for High Performance Rigid <strong>TPO</strong>s<br />
Kim Walton, Mark Berard, Theresa Hermel-Davidock, Phillip Hustad, Jim Hemphill, Didem Oner-Deliormanli, Russell Barry: The Dow<br />
Chemical Company<br />
2:30-3:00pm Low Density <strong>TPO</strong> Development for <strong><strong>Auto</strong>motive</strong> Exterior and Interior Applications<br />
Todd Glogovsky: LyondellBasell Industries<br />
3:00-3:15pm Break<br />
3:15-3:45pm Breaking New Ground with Thermoplastic Polyolefin Body Panels<br />
Neil Fuenmayor, Mitesh Shah, and Todd Glogovsky: LyondellBasell Industries<br />
Effect of Edge Functionalized Layered Silicates on the Strain Hardening Property of Polymer-Clay Nano<strong>com</strong>posite Melts in<br />
3:45-4:15pm Extensional Flow<br />
Tanmay Pathak and Prof. K. Jayaraman: Michigan State University<br />
4:15-4:45pm The Flaming of Parting-Line Flash and its Effects on Paint Adhesion<br />
Brent Nixon, Kyle Sinko, David Okonski and Elmer Santos: Ferris State University & General Motors<br />
4:45-5:15pm Unique Flow of Polypropylene at the Weld-Line Behind an Obstacle in Injection Molding<br />
Yutaka Kobayashi, Gensei Teramoto and Toshitaka Kanai: Kanazawa University, Japan<br />
5:30pm ExxonMobil Reception (Open for All <strong>Conference</strong> Participants )
7:00-8:00am Registration/Coffee<br />
<strong>2009</strong> <strong>SPE</strong>® <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> Program<br />
Tuesday October 6, <strong>2009</strong><br />
8:00-8:30am Keynote Address: The Outlook for Energy: A View to 2030<br />
Dr. Nazeer Bhore: Senior Technology Advisor-Corporate Planning, ExxonMobil Corporation<br />
Injection Molding & Advanced Process Control Seminar<br />
(Moderators: David Okonski: General Motors & Shane Vandekerkhof: RJG, Inc.)<br />
8:30-9:00am Polymer Basics: Morphology and Microstructures<br />
9:00-9:30am Decoupled Molding Strategies: Separating Fill from Pack<br />
9:30-9:45am Break<br />
9:45-10:15am Troubleshooting the Injection Molding Process: Cause and Effect of Some Common Defects<br />
10:15-10:45am Troubleshooting the Injection Molding Process: Defect Focus from Simple to More Advanced<br />
10:45-11:30am Lab Demonstration via Video Linked to RJG Laboratory<br />
11:30-12:00am Keynote Speaker: The <strong>Auto</strong> Future: A New Beginning?<br />
Dr. David Cole: Chair, Center for <strong><strong>Auto</strong>motive</strong> Research<br />
12:00-2:00pm<br />
Lunch & Panel Discussion: Challenges & Opportunities in the New <strong><strong>Auto</strong>motive</strong> Industry<br />
(Moderators: Bob Eller: Robert Eller Assoc., LLC & Ron Price: <strong>Global</strong> Polymer Solutions<br />
Executives: Matt Carroll: General Motors Co., Dr. David Cole: Center for Autmotive Research, Stephen Dwyer: LyondellBasell Industries,<br />
Nand Kochhar: Ford Motor Co., Jeff Makarewicz: Toyota Motor Corp.<br />
Applications Development<br />
(Moderators: Bob Eller: Robert Eller Assoc., LLC & Tom Pickett, General Motors Co.)<br />
2:00-2:30pm <strong>TPO</strong> Position in the <strong>Global</strong> <strong><strong>Auto</strong>motive</strong> Market & Effects of <strong>Global</strong> Economic Situation<br />
Bob Eller, Robert Eller Assoc., LLC<br />
2:30-3:00pm <strong>TPO</strong> Development for the 2010 and Beyond<br />
Sassan Tarahomi, IAC North America<br />
3:00-3:30pm Over-Molding New Cost Effective Soft Touch TPV on PP Substrates with Improved Properties<br />
Jeff Valentage & Hermann-Josef Holz: ExxonMobil Chemical<br />
3:30-3:45pm Break<br />
3:45-4:15pm Digital Color Solutions for <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> Applications<br />
Jim Harper, Techmer PM<br />
4:15-4:45pm Structure-Property Relationship of Novel Metallocene-Based R-<strong>TPO</strong> for Interior Parts<br />
Motoko Ito, Shouichi Fukunaga, Kenji Matsuoka, Kouichi Honda, and Kiyoshi Yukawa: Japan Polypropylene Corporation<br />
4:45-5:15pm Superior Appearance Material in Airbag Cover Applications<br />
Dr. Nadeem Bokhari: <strong>Auto</strong>liv North America; Kousuke Ohtani, Tetsuya Hisayama, & Noboru Yamaguchi: Sumitomo Chemicals Co. Ltd.<br />
5:15-5:45pm Optimization of Scratch Resistance for Molded in Color (MIC) Interior <strong>TPO</strong> Injection Molded Plastics<br />
Renee Hotton: General Motors Co.<br />
5:45pm <strong>SPE</strong> Detroit Section Reception (Open for All <strong>Conference</strong> Participants, Cash Bar )
7:00am Registration/Coffee (Concurrent Sessions)<br />
<strong>2009</strong> <strong>SPE</strong>® <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> Program<br />
Wednesday October 7, <strong>2009</strong><br />
Process Development: Aluminum Tooling for Injection Molding Seminar<br />
(Moderator: Patti Tibbenham - Ford Motor Co.)<br />
8:00-8:15am Plenary Presentation: Aluminum Tooling for Injection Molding of <strong>TPO</strong> Materials<br />
Patti Tibbenham, Ford Motor Company<br />
8:15-9:00am Mold Design Improvements, Surface Coatings, Heat Transfer and Part Price Opportunities<br />
Robert Beard, P.E., President of Robert A. Beard & Associates Inc.<br />
9:00-9:30am Properties of Aluminum Materials for Injection Molds<br />
Dave Wirth, Clinton Aluminum<br />
9:30-10:00am Designing Production Aluminum Molds<br />
Greg Eidenberger, Paragon Die & Engineering<br />
10:00-10:15am Break<br />
10:15-10:45am Case Studies of Production Aluminum Tooling<br />
Dave Dickerson: DRS Industries<br />
10:45-11:15am Manifold Considerations (Thermal 2-3d Analysis)<br />
Rich Oles: Plastic Services Group Inc. (PSG)<br />
11:15-11:45am Lessons Learned in Graining and Repair of Aluminum Tooling for Injection Molding<br />
Ron Smierciak: Alcoa<br />
Surface Enhancements<br />
(Moderators: Duane Lewis: ExxonMobil Chemical & Dr. Rose Ryntz: International <strong><strong>Auto</strong>motive</strong> Components)<br />
8:00-8:30am Plenary Presentation: Interior <strong><strong>Auto</strong>motive</strong> Plastic Aesthetic and Performance Trends<br />
Dr. Rose Ryntz: International <strong><strong>Auto</strong>motive</strong> Components<br />
8:30-9:00am Mar Resistance Testing and Evaluation of the Thermoplastic Olefins<br />
Robert Browning, George Wei, & Hung-Jue Sue: Texas A&M University; Kevin Reid: Phillips Sumika<br />
9:00-9:30am Mechanical Modeling of Scratch Induced Periodic Damage<br />
Han Jiang, John Whit<strong>com</strong>b & Hung-Jue Sue: Texas A&M University<br />
Update on Developments for Scratch and Mar Additives: Effect of the Additive Formulation on the Scratch Performance and<br />
9:30-10:00am Other Secondary Attributes<br />
Nikolas Kaprinidis, Per Magnus Kristiansen, Martin Brunner and Johanne Wilson: Ciba Corporation, a part of the BASF Group<br />
10:00-10:15am Break<br />
10:15-10:45am Atmospheric Pressure Plasma: Surface Treatment for Painting without Wet Chemistry<br />
Shaun Glogauer: Plasma Treat North America<br />
10:45-11:15am Latest Developments in Coatings Technology that Provides Striking Appearance and Durability over <strong>TPO</strong><br />
Arjun Dhake: Dhake Industries<br />
11:15-11:45am Study of Scratch Resistance of Polypropylene Blend for <strong>Auto</strong>mobile<br />
Shan Jin, Yonghua Li, Bo Yang, Zhongfu Luo: Kingfa SCI 7 TECH., CO., LTD.<br />
11:45-12:15pm New and Innovative Testing Technologies for Effect Finishes<br />
Greg Shrider and Richard Scott: BYK - Gardner USA<br />
12:15-12:45pm Conventional and Low VOC Bonding Solutions for <strong>TPO</strong>s<br />
Walt Polifka: Adchem Corporation
Sponsors/Exhibitors
Thank you sponsors for your support.
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080131_Polymotive Eigenanzeige_D3 3 14.02.2008 13:29:51
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Information When You Need It!<br />
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<strong><strong>Auto</strong>motive</strong> Engineer<br />
<strong><strong>Auto</strong>motive</strong> Engineer is Europe’s leading and most authoritative<br />
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www.ae-plus.<strong>com</strong><br />
Other publications which might be of interest to you include...<br />
Proceedings of the Institution of Mechanical Engineers: Part D<br />
Journal of <strong>Auto</strong>mobile Engineering<br />
The Journal of <strong>Auto</strong>mobile Engineering reflects the continual development and<br />
changing needs of the diverse automotive industry <strong>com</strong>munity.<br />
For a free trial or<br />
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Published 12 times per year<br />
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Proceedings of the Institution of Mechanical Engineers: Part L<br />
Journal of Materials: Design and Applications<br />
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wide range of materials including metals, ceramics, <strong>com</strong>posites and<br />
engineering polymers.<br />
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ISSN:1464/4207<br />
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Americhem, Inc.<br />
155 E. Steels Corners Dr.<br />
Cuyahoga Falls, Ohio 44224<br />
Web Site: www.americhem.<strong>com</strong><br />
Phone: (330) 926-4000<br />
Fax: (330) 926-2100<br />
E-Mail: bconway@americhem.<strong>com</strong><br />
Contact Name: Brett Conway<br />
Job Title: Sales Manager<br />
Phone: (419) 349-2109<br />
E-mail: bconway@americhem.<strong>com</strong><br />
t h e a d h e s i v e t a p e e n g i n e e r s<br />
1852 Old Country Road<br />
Riverhead, New York 11901<br />
www.adchem.<strong>com</strong><br />
Phone: 631-727-6000<br />
Fax: 631-727-6010<br />
E-Mail: info@adchem.<strong>com</strong><br />
Contact: Walt Polifka<br />
Job Title: Business Development Manager<br />
Phone: 631-727-6000 X323<br />
E-mail: wpolifka@adchem.<strong>com</strong><br />
<br />
Products & Services:<br />
• Color and Additive Masterbatches<br />
• 100:1 Color Masterbatch<br />
• Scratch & Mar Technology<br />
• Special Effects<br />
• Exterior Paint Replacement Technology<br />
Adchem Corporation manufactures a<br />
<strong>com</strong>plete line of adhesive tape systems,<br />
including double-coated papers, films,<br />
tissues, foams and fabrics; transfer tapes;<br />
single-side-coated products; and other<br />
custom-coated specialty products. Their<br />
100% solids adhesives, solvent acrylics and<br />
solvent rubber adhesives are used in many<br />
different industries, including transportation,<br />
electronic, medical and others.
1062 Fourth Ave<br />
Sidney, OH 45365<br />
Web Site: www.advcmp.<strong>com</strong><br />
Phone: (937) 575-9800<br />
Fax: (937) 492-0306<br />
Contact Name: Brian Williams<br />
Job Title: Marketing Manager<br />
Phone: (937) 575-9800<br />
E-mail: brian.williams@advcmp.<strong>com</strong><br />
321 Brentwood Drive<br />
Reading, PA 19611<br />
WWW.Brentwoodindustries.<strong>com</strong><br />
Phone: 610-376-1900<br />
Fax: 610-736-1209<br />
Contact: David Fry<br />
Sales Manager<br />
610-236-1107<br />
David.fry@brentw.<strong>com</strong><br />
Products & Services:<br />
� Mold-In-Color <strong>TPO</strong> Technology.<br />
� High Impact Polymers (100% ductility at -40°C)<br />
� Seamless Airbag Instrument Panels.<br />
� Bumper Fascia Polymers.<br />
� Low Gloss Interior Polymers.<br />
� High Gloss Exterior Polymers.<br />
� Lightweight Polymers.<br />
� Fast Cycle Time Polymers.<br />
� Technical Services (Processing, Mold-Flow, Tool and Part<br />
Design Re<strong>com</strong>mendations).<br />
______________________________________________________<br />
Custom Thermoform Service<br />
• Heavy gauge thermoforming, Precision CNC<br />
Trimming, materials up to ½” thick<br />
• Light gauge thermoforming, Medical Packaging,<br />
Consumer Packaging, Complete Design Capability
BYK-Gardner USA<br />
9104 Guilford Road<br />
Columbia, MD 21046<br />
Phone 800-343-7721 or 301-483-6500<br />
Fax 800-394-8215 or 301-483-6555<br />
General Email info.BYK.Gardner.USA@altana.<strong>com</strong><br />
Web www.byk.<strong>com</strong>/instruments<br />
Contact Karen Nance<br />
Title Inside Sales Manager<br />
Email Karen.Nance@altana.<strong>com</strong><br />
BYK-Gardner, a worldwide partner of the automotive, paint and<br />
plastic industries, offers quality control instrumentation to measure<br />
color and appearance properties such as metallic and solid color,<br />
gloss, orange peel, DOI and haze. We also provide a full line of<br />
physical testing instruments- applicators and drawdown cards; film<br />
thickness gages; impact, flexibility and hardness testers;<br />
vis<strong>com</strong>eters and more.<br />
Great people. Great products.<br />
Great <strong>com</strong>pany.<br />
Combining existing BASF capabilities with the people, products<br />
and technology acquired with Ciba gives BASF a more powerful<br />
portfolio to help automotive OEMs make their products better.<br />
Great people, great products. The Chemical Company.<br />
Visit us at the <strong>2009</strong> <strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Conference</strong>.<br />
www.basf.us<br />
Light stabilizers<br />
Scratch resistance<br />
additives<br />
Antioxidants<br />
Colorants and<br />
effect pigments<br />
UV absorbers<br />
Antistatic agents<br />
Flame retardants
29111 Stephenson Hwy<br />
Madison Heights, MI 48071<br />
www.DME.net<br />
Contact: Kelly Beauchamp<br />
DME Sales Representative<br />
248-705-4188<br />
kelly_beauchamp@dme.net<br />
Dow Elastomers<br />
4520 E. Ashman St.<br />
9008 Building<br />
Midland, MI 48642<br />
www.dowelastomers.<strong>com</strong><br />
Phone: 800-441-4369<br />
E-Mail: CUSTINFOGRP1@dow.<strong>com</strong><br />
Contact: Customer Information Group<br />
An Essential Mold Technology Resource<br />
• Hot Runner Systems<br />
• Hot Runner Service Center<br />
• Mold bases & Plate Items<br />
• Mud Quick-Change Systems<br />
• Mold & Die Components<br />
• Moldflow Analysis<br />
• Heating & Cooling Components<br />
• Control Systems<br />
• Molding Equipment & supplies<br />
• Moldmaking Supplies<br />
• Applications Engineering<br />
• Technical Service<br />
Products & Services:<br />
Dow is delivering solutions to the interior and exterior hard <strong>TPO</strong><br />
industry by enabling:<br />
• Impact strength / toughness / resiliency<br />
• Excellent processability<br />
• Gloss Control<br />
• Paintability<br />
We will introduce the next generation to the ENGAGE TM family –<br />
which will deliver superior performance while meeting your<br />
material and handling needs.
1250 Harmon Road<br />
Auburn Hills, MI 48326<br />
phone: 248-391-6300<br />
www.dowautomotive.<strong>com</strong><br />
Contact: Kelly Pippine<br />
Marketing Manager<br />
248-393-3068<br />
email: kpippine@dow.<strong>com</strong><br />
LyondellBasell Industries Phone: 517-336-2400<br />
2727 Alliance Drive Fax: 517-336-2415<br />
Lansing, MI 48910<br />
http://polymers.lyondellbasell.<strong>com</strong><br />
Dow <strong><strong>Auto</strong>motive</strong> Systems is a leading provider of<br />
polyurethanes, elastomers, films, fluids, adhesives,<br />
emissions solutions and acoustic-management<br />
materials to the global transportation industry. By<br />
working collaboratively with passenger vehicle,<br />
<strong>com</strong>mercial transportation and aftermarket<br />
customers, Dow <strong><strong>Auto</strong>motive</strong> Systems is developing<br />
industry-leading solutions to address a wide range of<br />
critical market needs – increasing energy efficiency,<br />
improving safety and health, reducing exhaust<br />
emissions and enhancing vehicle quality and appeal.<br />
For additional information about Dow <strong><strong>Auto</strong>motive</strong>,<br />
visit www.dowautomotive.<strong>com</strong><br />
Lyondellbasell delivers sustainable value to the automotive industry by offering innovative resins that address customers' most<br />
challenging application requirements.<br />
Be it bumpers, grilles, instrument panels, interior trim, under-the-hood applications or structural parts and body panels – the versatility and<br />
economics of LyondellBasell’s polypropylene creates customer opportunities for cost-effective and innovative design concepts that can enhance<br />
both passenger safety, <strong>com</strong>fort and quality. Our lower density resins can help improve fuel economy and reduce raw material costs.<br />
LyondellBasell’s worldwide network of strategically located supply facilities target uniformity of specifications – wherever in the world<br />
materials are sourced.
Sumitomo Chemical America, Inc Headquarter: 212-572-8200 David Risetter<br />
28175 Haggerty Road Fax: 248-994-7673 General Manager, Petrochemicals Division<br />
Novi, MI 49127 269-921-3354<br />
www.sumichem.<strong>com</strong> drisetter@sumichem.<strong>com</strong>www.espolex.<strong>com</strong><br />
Reaching New heights in <strong>Global</strong> Supply<br />
Sumitomo Chemical’s Petrochemicals & Plastics Division engages in the development, manufacture and sale of a wide range of petrochemical<br />
products, including plastics such as polyethylene and polypropylene; synthetic rubber; and organic chemicals such as propylene oxide and<br />
styrene monomer.<br />
In order to meet the needs of a diverse customer base, our focus is on the development, manufacture and sale of high-performance resins like<br />
Thermoplastic Elastomer and Polymer Alloys as well as concentrating on application development utilizing advanced manufacturing and<br />
application technologies in foamed, extruded and molding applications.<br />
The Sumitomo Chemical Group global network includes production and sales operations in North America, South America, Japan, Europe,<br />
Korea, China, South Asia and Middle East.<br />
ExxonMobil Chemical Company<br />
13501 Katy Freeway<br />
Houston, Texas, U.S.A. 77079<br />
www.exxonmobilchemical.<strong>com</strong><br />
About ExxonMobil Chemical<br />
ExxonMobil Chemical is one of the world’s premier petrochemical <strong>com</strong>panies with manufacturing, technology and<br />
marketing operations around the world. The <strong>com</strong>pany delivers a broad portfolio of products and solutions efficiently and<br />
responsibly, with a <strong>com</strong>mitment to create outstanding customer and shareholder value. ExxonMobil Chemical endorses the<br />
principles of sustainable development, including the need to balance economic growth, social development and<br />
environmental considerations.
1330 Lake Robbins Dr., Ste.400<br />
The Woodlands, TX 77380<br />
Sanjay Patel<br />
734-451-2072<br />
sanjay.patel@fhr.<strong>com</strong><br />
Polypropylene Products<br />
• High impact and low temperature ductility<br />
• High quality zero gap interior trim products<br />
• Stiffness and Impact balanced materials<br />
<strong>TPO</strong> Products<br />
• Cold temperature impact ready<br />
• Energy management designed for HIC and SABIC<br />
• Exterior and underhood capable<br />
Totally "Green" Recovery of Painted Plastic <strong>TPO</strong> Scrap<br />
<strong><strong>Auto</strong>motive</strong> Reactor Grades Products for Demanding<br />
Applications<br />
GPRI offers patented new "green" technology for removing paint from your plastic scrap without material degradation.<br />
Like sprues and risers, recovered plastic is restored to the original pre-painted "as molded" condition and is ready to be<br />
remolded into the "Class A Surface" part as originally intended. All coating colors, including white, are <strong>com</strong>pletely<br />
removed from scrap material with zero material loss and without residual paint adhesion problems. 26 different plastics<br />
and coatings have been successfully processed to date, including "soft touch". Consignment processing service is<br />
available as well as in-plant/in-line systems for high volume producers. The 100% EPA approved, closed loop process<br />
will end your scrap issues and reduce costs. For more information contact: Ron Janik, V.P. of Sales<br />
Ph: 248 522-6929 - Cell: 248 924-4421 - E-mail: r.janik@globlalplasticsrecovery.<strong>com</strong>
IMI Fabi LLC<br />
Second and Marshall<br />
Benwood, WV 26031<br />
WWW.IMIFabi.<strong>com</strong><br />
Phone: 304-233-0050<br />
Fax: 304-232-0793<br />
info@imifabi.<strong>com</strong><br />
2625 N. berkeley Lake Road, Suite 100<br />
Duluth, GA 30096<br />
Web Site: www.Kraiburg-TPE.<strong>com</strong><br />
Phone: 678-584-5020<br />
Fax: 678-584-0500<br />
E-Mail: Info-USA@Kraiburg-TPE.<strong>com</strong><br />
Contact Name Keith W. Dunlap<br />
Job Title: Director, Sales and Marketing<br />
Phone: 678-584-5193<br />
E-mail: Keith.Dunlap@Kraiburg-TPE.<strong>com</strong><br />
Talc Powders for Plastics<br />
Compacted and powder HTP, HM, BT, CH, NB, GT<br />
• IMIFAbI Talc Company, a leading talc manufacturer;<br />
with mining, milling facilities supplying performing talc<br />
grades around the world.<br />
• Headquartered in Milan, Italy, IMIFAbI talc has been<br />
growing over the years to reach an international dimension,<br />
having operations in Europe, the USA, and in Asia, all<br />
equipped with same milling and micronizing processes,<br />
allowing IMIFABI talc to have a unique service: supply<br />
consistent products world wide at local lead time<br />
conditions.<br />
• IMI Fabi Talc Company has invested in various talc<br />
deposits around the word, thus offering diversified talc<br />
grades with million of tons in proven reserves. IMI Fabi is<br />
the right partner for all of your current and future projects.<br />
KRAIbURG TPE Corporation<br />
2625 N. berkeley Lake Road, Suite 100<br />
Duluth, GA 30096 USA<br />
Phone: (678) 584-5020 • Fax: (678) 584-0500<br />
Website: www.kraiburg-tpe.<strong>com</strong><br />
Custom engineered TPE and more…<br />
KRAIBURG TPE manufactures thermoplastic elastomers based on<br />
HSBC (hydrogenated styrene block copolymers) and markets them all<br />
around the world. In addition to custom solutions, the <strong>com</strong>pany offers,<br />
under the THERMOLAST® and HIPEX® brand names, a broad<br />
spectrum of standardized <strong>com</strong>pounds to cover a wide range of<br />
applications. The <strong>com</strong>pany produces at sites in Germany, the US and<br />
Malaysia. KRAIBURG TPE also maintains sales offices in the USA, UK,<br />
France, Italy, Spain, China and India.
Milacron LLC<br />
29111 Stephenson Highway<br />
Madison Heights, MI 48071<br />
Contact: Steve Wood<br />
<strong><strong>Auto</strong>motive</strong> Accounts Manager<br />
Office/cell: 513-702-2197<br />
E-mail: steve_wood@milacron.<strong>com</strong><br />
1403 Port Road<br />
Jeffersonville, IN 47130<br />
www.mytexpolymers.<strong>com</strong><br />
Phone: 812-280-2900<br />
Fax: 812-280-2904<br />
E-Mail: customer_service@mytexpolymers.<strong>com</strong><br />
Contact: Eric Short<br />
Job Title: Sales Manager<br />
Phone: 248-705-2830<br />
E-mail: eric_short@mytexpolymers.<strong>com</strong><br />
Injection Molding Machines<br />
All-Electric, Hydraulic, Multi-Component<br />
6 ton to 6600 ton<br />
Process Support Equipment<br />
Auxiliary equipment, robots and automation systems<br />
Products & Services:<br />
Contract Services<br />
Retrofit controls – 2 nd /3 rd Injection Units<br />
� Major North American Supplier of Interior and<br />
Exterior Advanced Polypropylene Materials.<br />
� Wholly owned by the Mitsubishi Chemical Company.<br />
� 235,000 Square Foot Facility Centrally Located in<br />
Southern Indiana.<br />
� Additional Detroit Based Sales and Technical<br />
Support.<br />
� <strong>Global</strong> Resource Expertise from Strategically Located<br />
<strong>Global</strong> Affiliates.<br />
� Ability to Formulate New Advanced<br />
Products/Precision Formulas for Consistent Quality<br />
Products.<br />
� Commercial & Developmental Compounding Lines.<br />
� A2LA Certified Test Laboratory.<br />
� 24 Hour Customer Service and Technical Support.<br />
� Material Approvals from both U.S. & J.T. OEM’s.<br />
� ISO TS 16949:2002 / ISO 17025
4855 Thirty Seventh St. SE<br />
Grand Rapids, MI 49512-4068<br />
Contact Name: Stu Allen<br />
Job Title: Sales and Distribution Manager<br />
Phone: 616-581-7287<br />
E-mail: stu.allen@noblepolymers.<strong>com</strong><br />
803 Mountain View Dr.<br />
P.O. Box 368<br />
Willsboro, NY 12996<br />
www.ny<strong>com</strong>inerals.<strong>com</strong><br />
Phone: 518-963-4262<br />
Fax: 518-963-4187<br />
E-Mail: info@ny<strong>com</strong>inerals.<strong>com</strong><br />
Contact Name: Gary Phillips<br />
Job Title: VP of Marketing and Application<br />
Development<br />
Phone: 313-388-7241<br />
E-mail: gary.phillips@ny<strong>com</strong>inerals.<strong>com</strong><br />
Products & Services:<br />
Noble Polymers is a custom <strong>com</strong>pounder that provides innovative<br />
solutions to engineering problems.<br />
• Supply Array of Commercial Resins<br />
– Ecobarrier® - soft, highly filled <strong>TPO</strong>’s with recycle<br />
content for sound deadening<br />
– Regis® - rigid, high strength, low shrink <strong>TPO</strong>’s for<br />
exterior trim<br />
– Forte® - PP based nano<strong>com</strong>posites for automotive interior<br />
trim, leisure & recreation, HVAC<br />
– Flextuff® - extrusion grade TPE<br />
• Contract Manufacturing – toll<br />
• Compound Custom Development<br />
– Resins tailored to given application<br />
– Development & testing for individual projects (A2LA<br />
Certified Polymer Laboratory)<br />
• TS 16949 and ISO 14001 certified<br />
NYCO Wollastonite - Proven Reinforcements for<br />
Balancing Costs and Performance<br />
• Improved mechanicals<br />
• Lowers CLTE (no gap)<br />
• Excellent melt strength<br />
• High stiffness with good ductility<br />
• Lower density – thin wall <strong>com</strong>posites<br />
• Improved mar/scratch and gouge resistance<br />
• Odorless, non-dusting
RTM.Plactics.<strong>TPO</strong>.Ad 7/18/08 9:58 AM Page 1<br />
www.riotintominerals.<strong>com</strong><br />
Minerals that make a difference<br />
Solutions that make a difference<br />
4000 Embassy Parkway<br />
Suite 208<br />
Akron, OH 44333<br />
Web Site: http://www.robertellerassoc.<strong>com</strong><br />
Contact: Robert Eller<br />
President<br />
Phone: 330-670-9566<br />
Fax: 330-670-9844<br />
Rio Tinto Minerals is the acknowledged<br />
world leader in developing industrial<br />
minerals, and developing solutions<br />
for customers<br />
• Scratch and Mar Resistance<br />
• Color Control<br />
• Odor Control<br />
• Higher Stiffness<br />
• Higher Impact<br />
• Cost Effective Flame Retardancy<br />
Cimpact CB7<br />
Luzenac R7<br />
Steaplast 9502<br />
JetFil 7C<br />
Cimpact 710R<br />
Cimpact 710HS<br />
HAR-Talcs<br />
Jetfine Talcs<br />
Strategies to support autoplastic management<br />
decision making for:<br />
• Market participation<br />
• Product positioning<br />
• Technology diversification<br />
• Acquisitions/mergers<br />
• Asia market presence<br />
Firebrake ZB<br />
Firebrake 415<br />
Firebrake 500
ShINIL ChEMICAL INDUSTRY<br />
Sihwa Industrial Complex 5Ba-104Ho,<br />
675-4, Sunggokdong, Danwon,<br />
Ansansi, Kyunggido, KOREA<br />
Postal Code : 425-836<br />
http://www.shinil-chemical.net<br />
PJ YOON<br />
R&D Director<br />
pj.yoon@shinil-chemial.net<br />
Phone: +82-31-499-2430<br />
Fax: +82-31-499-1080<br />
E-Mail: shinilchemical@shinil-chemical.net<br />
World Headquarters & Technical Center<br />
1401 Crooks Road<br />
Troy, MI 48346<br />
Insight. Inside. Inteva.<br />
www.intevaproducts.<strong>com</strong><br />
Phone: 248.655.8886<br />
E-mail: info@intevaproducts.<strong>com</strong><br />
Contact Name: Norm Kakarala<br />
Job Title: Senior Technical Fellow<br />
Phone: 249-655-8483<br />
E-Mail: nkakarala@intevaproducts.<strong>com</strong><br />
Products & Services:<br />
SHINCON – Conductive Polymer<br />
SHINSTRA – Engineering Plastic<br />
CNT MASTER BATCH<br />
SHINSTAT – ESD Control Polymer<br />
POLYGLUE – Adhesive Resin<br />
SHINNANO – Nano Polymer<br />
SHINFLAM – Flame Retardant<br />
SPYLON - Thermoplastic Resin<br />
Products & Services:<br />
Inteva has deep roots of more than 90 years as a leading supplier of<br />
Interiors and Closures for leading OEMS around the globe. From<br />
past to present, our innovative excellence helped these systems and<br />
<strong>com</strong>ponents evolve from simply meeting functional needs to fitting<br />
precise buyer lifestyles.<br />
• Interior Systems that meet precise needs for driving<br />
<strong>com</strong>fort, convenience, look and feel<br />
• Cockpits that raise the bar with <strong>com</strong>plete integration,<br />
assembly, and sequencing services.<br />
• Latch & Closure Systems that embody <strong>com</strong>plexity for<br />
functional simplicity<br />
• Door Modules & Window Lift Systems that reduce costs<br />
and increase reliability
1 Quality Circle<br />
Clinton, TN 37716<br />
Web Site: www.techmerpm.<strong>com</strong><br />
Phone: 865-457-6700<br />
Fax: 865-457-3012<br />
E-Mail: jmurphy@techmerpm.<strong>com</strong><br />
Contact: Jack Murphy<br />
Job Title: Director of Sales .<br />
Phone: 865-457-6700<br />
Techmer PM offers a <strong>com</strong>plete line of<br />
colorant and additive masterbatch<br />
designed for automotive applications.<br />
SWT PC-25 Direct to <strong>TPO</strong> Water Based Coating<br />
The SWT Group Headquarter: 519-967-0020 Stephen Regular<br />
1591 Kildare Rd. Fax: 519-967-1220 Coatings Sales and Technology Manager<br />
Windsor, Ontario, N8W 2W2 519-967-0020, ext 236<br />
www.swtgroup.<strong>com</strong> sregular@swtgroup.<strong>com</strong><br />
SWT PC-25 Direct to <strong>TPO</strong> Water based Coating<br />
SWT has developed a water based coating that adheres directly to <strong>TPO</strong> and polypropylene substrates with no pretreatment. In adhesion testing,<br />
SWT PC-25 had a result of 5B when applied directly to <strong>TPO</strong> and PP while achieving excellent hardness, flexibility, and solvent and humidity<br />
resistance.<br />
The benefits of this coating could provide cost savings and VOC reduction not only to <strong>com</strong>panies already painting <strong>TPO</strong> and polypropylene but<br />
also to <strong>com</strong>panies that would prefer to use these substrates over easier to coat alternatives such as ABS and polyurethanes
CONFERENCE
Material Development
Improving Scratch Performance of Talc-PP and Talc-<strong>TPO</strong> Compounds<br />
Saied H. Kochesfahani* – Rio Tinto Minerals, Denver, CO<br />
Denis Lejour and Frederic Jouffret, Rio Tinto Minerals, Toulouse, France<br />
The scratch performance of talc-PP and talc-<strong>TPO</strong> <strong>com</strong>pounds has been of great interest<br />
especially in automotive interior and exterior applications where appearance plays an<br />
important role in the customer approval of car quality. While polypropylene or <strong>TPO</strong><br />
based automotive parts offer many cost/performance advantages over other materials,<br />
the scratch and mar performance of these products typically does not fulfill all customer<br />
expectations.<br />
Talc offers a great affinity with polypropylene and is, therefore, the reinforcing additive of<br />
choice in many PP and <strong>TPO</strong> <strong>com</strong>pounds, where it significantly improves the rigidity and<br />
dimensional stability of the products. However, the mineral-filled <strong>TPO</strong> <strong>com</strong>pounds still<br />
lack a desirable scratch and mar performance. Significant effort has been focused on<br />
understanding the scratch and mar behavior of plastics and specifically PP based<br />
material in recent years, in which Rio Tinto Minerals has played a pioneering role in<br />
understanding the effect of talc on scratch performance and identifying solutions to<br />
improve the scratch performance of talc-reinforced plastics.<br />
The objective of this study is to conduct systematic scratch performance analyses<br />
utilizing a very large database of talc-PP and talc-<strong>TPO</strong> samples at Rio Tinto Minerals to<br />
understand the effect of talc parameters (particle size, crystalline structure, mineralogy,<br />
etc.) and scratch additives on the scratch performance of talc-PP and talc-<strong>TPO</strong><br />
<strong>com</strong>pounds, and to identify the best performing talc-based formulations for improved<br />
scratch resistance. The newly developed scratch test method at Texas A&M University<br />
and the associated ASTM and ISO standard methods were used in this study to<br />
consistently <strong>com</strong>pare and evaluate the scratch performance of different samples. This<br />
paper presents the results of these analyses and introduces Rio Tinto Minerals current<br />
best solution for improving scratch performance in talc-PP and talc-<strong>TPO</strong> <strong>com</strong>pounds.<br />
*Speaker: Dr. Saied Kochesfahani is Development Manager for polymer applications at Rio Tinto<br />
Minerals. He holds a Ph.D. in Chemical Engineering from the University of Toronto, and has authored or<br />
co-authored about 40 publications. He has been a member of Tappi for over 13 years and joined <strong>SPE</strong> in<br />
2006. Phone: 303-713-5231, Email: saied.kochesfahani@riotinto.<strong>com</strong>.
Abstract<br />
High Performance Reinforcement:<br />
A Pathway to Density Reduction<br />
While Maintaining Physical Properties of Polyolefin Composites<br />
K. David Lake<br />
Milliken Chemical, 920 Milliken Road<br />
Spartanburg, SC 29304<br />
Light-weighting initiatives in the automotive industry continue to be a driving force for the<br />
development of new lower density / higher performance <strong>com</strong>posites. With new CAFE<br />
standards on the horizon along with the continued development of vehicles using<br />
alternative energy sources, the demand for lighter weight and structurally sound<br />
automotive parts may now be at an all time high.<br />
To address this market need, Milliken Chemical is now <strong>com</strong>mercializing a new mineralbased<br />
reinforcing additive for polyolefin <strong>com</strong>posites. This additive, known as HPR (high<br />
performance reinforcement) will serve to <strong>com</strong>plement and surpass Milliken's current<br />
offering of Hyperform® nucleating agents in enabling excellent physical properties with<br />
reduced density as <strong>com</strong>pared to other conventionally filled polyolefins. For instance,<br />
<strong>com</strong>pared to talc-filled polypropylene, HPR will typically provide <strong>com</strong>parable or superior<br />
performance with only about one-third of conventional talc concentrations. Therefore,<br />
part weight reductions up to 15 - 20% may be readily achieved. Supporting illustrations<br />
in this presentation will include <strong>com</strong>parative data in flexural modulus, shrinkage, tensile<br />
strength, impact strength, and heat deflection temperature.<br />
While imparting exceptional flexural modulus properties to polyolefins that rival those<br />
obtained with chopped glass, HPR may also be considered for high stiffness applications<br />
where a superior surface finish is desired. In this regard, examples relating to scratch<br />
resistance, gloss, and surface appearance will also be provided. These <strong>com</strong>bined<br />
attributes may even provide an environment for light-weighting to be considered via thinwalling<br />
of parts that are now made with conventional unfilled polyolefins.
<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />
Speaker’s Biography<br />
Name:<br />
David Lake<br />
Title:<br />
Development Associate<br />
Company:<br />
Milliken Chemical<br />
Experience (Brief Summary):<br />
David has been employed by Milliken and Co. since 1983 and for<br />
the last 18 years has worked in Milliken Chemical’s Polymer<br />
Additives business. There he has worked in various roles<br />
including research, technical service, field support, project<br />
management, and applications development. He has developed<br />
extensive expertise in formulating, clarifying, and nucleating<br />
polypropylene and has also gained wide experience in<br />
numerous extrusion and molding processes where<br />
polypropylene articles are fabricated. David has played an<br />
integral role for his <strong>com</strong>pany in the development and<br />
<strong>com</strong>mercialization of key successful clarifiers and nucleators in<br />
the Millad® and Hyperform® product lines. He is currently<br />
involved with Milliken Chemical’s efforts to expand into<br />
reinforcing additives for polypropylene. David is the lead or coauthor<br />
of 7 issued US patents.<br />
Education:<br />
B.S. Chemistry, Presbyterian College – 1983<br />
Industry/Trade Affiliations:<br />
American Chemical Society and Society of Plastics Engineers
DonBeuke@aol.<strong>com</strong> - Technical Consultant 918-914-2947<br />
GO GREEN with MOS Hige Fiber for Light Weighting, Fast Cycle Time,<br />
and Improved Quality <strong>TPO</strong>'s<br />
Donald Beuke with Mitsui Plastics Inc.<br />
ABSTRACT<br />
As gasoline prices, manufacturing and materials continue to rise; automobile manufactures are<br />
turning to parts molded with lighter weight filled <strong>TPO</strong>’s. With the advent of MOS Hige fiber<br />
from Ube and marketed and serviced by Mitsui, molder saves money and car <strong>com</strong>pany achieves<br />
improved quality parts and improved fuel efficiency. 8-10 % of a 70% masterbatch of 0.5x15<br />
micron magnesium oxy-sulfate (MOS) whisker fibers at 70% can be <strong>com</strong>bined with 0-10 % talc to<br />
provide <strong>TPO</strong>’s with:<br />
1) Lower cost molded parts (molder);<br />
a. 15-35% reduction in mold cycle time<br />
b. 10-15% weight reduction<br />
2) Fuel savings (consumer) GO GREEN;<br />
a. Reduced weight = fuel savings<br />
3) Quality Improvements (car <strong>com</strong>pany);<br />
a. Low shrinkage<br />
b. reduction of scratch and mar<br />
c. improved molded-in color (higher color saturation from resin rich surface)<br />
d. high flow resulting in smoother, flatter surface.<br />
e. increased sound absorption for quieter interior parts<br />
Talc filled <strong>TPO</strong> with MOS Hige A Talc filled <strong>TPO</strong> control<br />
PP 73-82 % PP 70%<br />
Tafmer 10% Tafmer 10%<br />
Talc 0-7% Talc 20%<br />
70% MOS fiber MB 8-10%<br />
Density 0.92-.099 Density 1.05<br />
Flex Mod 1600-2,500MPa Flex Mod 2,400MPa<br />
MFR 20-50 g/10min MFR 8.7g/10min<br />
Impact -40c 6.6m/sec to -30c N.Izod Impact -30 N. Izod<br />
Part thickness 2.7 mm Part thickness 3.0 mm<br />
Part weight 7.65 lbs Part weight 9 lbs<br />
Cycle time 45 seconds Cycle time 60 seconds<br />
Fuel savings: $3.24 Fuel savings: 0<br />
Presenter: Don Beuke is on his 35 th anniversary as a Chemist and Engineer in product & market development, sales,<br />
and technical service of plastics and additives. He holds a variety of patents with many of the previous <strong>com</strong>panies he<br />
worked for. These <strong>com</strong>panies are; PPG Coatings and Resins Division, Ciba-Geigy Plastics Additives Dept, Phillips 66<br />
Company Plastics Division, Petrolite Polymers Division, Wed-Tech Compounding (now Ingenia) . He is currently,<br />
employed for over 14 years as a Technical and Marketing consultant exclusively with Mitsui & Co. (USA) Inc. and<br />
Mitsui Plastics Inc.
Improved Glass-fiber Reinforced Polypropylene for Structural Applications<br />
Alberto Prieto, Product and Application Development Engineer<br />
Steve Davis, Customer Project Manager<br />
LyondellBasell Industries<br />
Abstract:<br />
Structural applications are one of the fastest growing segments for polypropylene due to advances<br />
such as long glass fiber reinforcement (LGF). Front-end carriers, instrument panel carriers, and<br />
running boards are all examples of applications where the use polypropylene has been enabled by<br />
LGF. There are several approaches possible for making parts reinforced by LGF, including<br />
conventional <strong>com</strong>pounds or to use a direct injection molding <strong>com</strong>pounder (D-LFT) to <strong>com</strong>pound<br />
at the press. More recently, attention has turned to ways to save cost versus LGF <strong>com</strong>pounds.<br />
LyondellBasell has developed a new generation of short glass fiber reinforced materials with<br />
improved stiffness and tensile strength which have replaced LGF in several applications. These<br />
new developments will be discussed in detail with application examples. LyondellBasell has also<br />
contributed to the advancement of the D-LFT process through the development of high melt flow<br />
rate resins and <strong>com</strong>pounds which are successfully used in the D-LFT processes. This includes<br />
two <strong>SPE</strong> Innovation Award-winning applications.<br />
LyondellBasell Industries’ Hosta<strong>com</strong> EYS 755P <strong>com</strong>pounded polypropylene (PP) resin is being used to<br />
produce the front-end carrier for the Volkswagen Golf/Jetta/Bora platform. This application won the 2007<br />
<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> Innovation Award in the Process/Assembly/Enabling Technology category. The part is<br />
produced by AKsys de Mexico, who uses the Krauss-Maffei Injection-Molding Compounder (IMC)<br />
process. This is the first front-end module in North America to use KraussMaffei’s twin-screw Injection<br />
Molding Compounder (IMC) to mix and mold long glass.<br />
Photo: Society of Plastics Engineers
<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong>: Speaker Bios<br />
KRAIBURG TPE Corporation<br />
2625 N. Berkeley Lake Road, Suite 100<br />
Duluth, GA 30096 USA<br />
Phone: (678) 584-5020 • Fax: (678) 584-0500<br />
Website: www.kraiburg-tpe.<strong>com</strong><br />
Custom engineered TPE and more…<br />
KRAIBURG TPE manufactures thermoplastic elastomers based on<br />
HSBC (hydrogenated styrene block copolymers) and markets them<br />
all around the world. In addition to custom solutions, the <strong>com</strong>pany<br />
offers, under the THERMOLAST® and HIPEX® brand names, a<br />
broad spectrum of standardized <strong>com</strong>pounds to cover a wide range<br />
of applications. The <strong>com</strong>pany produces at sites in Germany, the<br />
US and Malaysia. KRAIBURG TPE also maintains sales offices in<br />
the USA, UK, France, Italy, Spain, China and India.<br />
Address line: 2625 N. Berkeley Lake Road<br />
Suite 100<br />
City: Duluth<br />
State/Province: GA<br />
Postal Code: 30096<br />
Web Site: www.Kraiburg-TPE.<strong>com</strong><br />
Phone: 678-584-5020<br />
Fax: 678-584-0500<br />
E-Mail: Info-USA@Kraiburg-TPE.<strong>com</strong><br />
Contact Name Keith W. Dunlap<br />
Job Title: Director, Sales and Marketing<br />
Phone: 678-584-5193<br />
E-mail: Keith.Dunlap@Kraiburg-TPE.<strong>com</strong><br />
High-Performance TPE’s for Stringent <strong><strong>Auto</strong>motive</strong> Applications
High-Performance TPE’s for Stringent <strong><strong>Auto</strong>motive</strong> Applications<br />
John Chiao and Keith Dunlap<br />
Thermoplastic elastomers (TPE’s) have been widely used in the automotive industry for their cost advantages<br />
and performance benefits such as processing versatility and lighter part weight for improved fuel economy.<br />
However However, the the utilization of of TPE’s TPE s in automotive under under-hood hood <strong>com</strong>ponents <strong>com</strong>ponents has been limited limited by the the stringent<br />
requirements of high temperature and medium resistance (oils, fuels, fluids, etc…) Recently, KRAIBURG TPE<br />
has developed an innovative TPE based material technology tailored for these challenging environments and<br />
applications. A series of materials have been launched with properties that were only attainable in the past by<br />
high-performance rubber <strong>com</strong>pounds processed using time-consuming vulcanization. This new generation of<br />
TPE’s, branded as HIPEX ® , , offers similar properties p p of those found in high-performance g p rubber <strong>com</strong>pounds. p<br />
They have <strong>com</strong>bined the ability to withstand temperatures up to 170oC and exhibit chemical resistance to motor<br />
oils, fuels, greases, and coolants. In addition to adhering to polyamide (PA) and polyacetal (POM), HIPEX ®<br />
products demonstrate optimal adhesion to polybutylene terephthalate (PBT), and thus cover most engineering<br />
polymers utilized in the engine <strong>com</strong>partment. The materials show good process-ability under typical<br />
thermoplastic molding conditions. HIPEX ® resins are suitable for a number of applications inside and out outside<br />
th the engine i bbay, iincluding l di seals, l plugs, l caps, gaskets, k t ddrive i bbelts, lt ttubes, b connectors, t hhoses, cables bl and d even<br />
noise and vibration dampening. They can be used as a replacement for acrylic elastomers (ACM) or ethyleneacrylic<br />
elastomers (AEM) and are ideally suited for working temperature performance up to 150oC. This presentation will describe the typical make up of HIPEX ®<br />
and <strong>com</strong>pare p the pperformance of current polymers p y and<br />
technologies used in stringent automotive applications. Finally,<br />
it will <strong>com</strong>pare those polymers in a cost vs. benefit analysis of<br />
materials targeted for rubber replacement, higher cost<br />
polymeric material replacement, processing ease, and need for<br />
secondary operations.<br />
We thank you in advance for your consideration.<br />
Kraiburg TPE Corporation 2625 N. Berkeley Lake Road, Suite 100, Duluth, GA 30096
Keith W. Dunlap, Director of Sales and Marketing, KRAIBURG TPE<br />
Keith has over 15 year experience in the plastics industry with executive level management experience in global<br />
markets with <strong>com</strong>panies that produced and distributed engineering thermoplastic resins, films and sheet systems,<br />
processed plastics for automotive, medical, consumer and industrial applications and <strong>com</strong>pounded elastomeric<br />
materials for specific application requirements. He has held positions of increasing responsibility for <strong>com</strong>panies that<br />
include GE Plastics, Bayer’s Polymers Division, Porex Corporation and KRAIBURG TPE. He is a graduate of Northern<br />
Illinois University in Engineering and has <strong>com</strong>pleted post graduate MBA work at the University of New Hampshire in<br />
addition he holds a minor in Graphic Arts and has business leadership and marketing certifications from the John F.<br />
Welch Leadership Development Center at Crotonville, NY. Keith resides in Atlanta, GA and has a son of 11 years.<br />
John J. Chiao PHD, Senior Scientist, KRAIBURG TPE<br />
Dr. John Chiao manages the quality and development department at KRAIBURG TPE. His daily responsibilities range<br />
from developing new TPE formulations for consumer, industrial and automotive applications, to providing technical<br />
services for worldwide customers. Dr. Chiao has over 11 years of industry experience in specialty chemicals, resins<br />
and polymeric materials. Prior to joining KRAIBURG TPE, he worked as a senior scientist with Cytec Specialty<br />
Chemicals and R&D manager with Tesa Tape. Dr. Chiao has co-authored more than 25 technical publications and<br />
patents on TPEs, UV/EB curable resins, pressure sensitive adhesives, nano<strong>com</strong>posites, and conducting polymers. He<br />
holds a Ph.D. in polymer chemistry from Michigan State University, an MBA in Financial Management from Georgia<br />
State University, and a B.S. in polymer science from Nanjing University (China). John lives in Marietta, GA with his<br />
wife and two children.
Abstract:<br />
Polypropylene Property Modification using Vistamaxx Specialty<br />
Elastomers and Exact Plastomers<br />
Felix Zacarias<br />
ExxonMobil Chemical Company<br />
388 South Main Street<br />
Akron, OH 44311<br />
330-849-5159<br />
This paper presents the basic principles of modifying the properties of polypropylene (PP) using<br />
Vistamaxx specialty elastomers (propylene specialty elastomers) and Exact plastomers in applications<br />
requiring impact modification and flexibility. Although both can be used to gain these properties, the precise<br />
physical properties obtained can be significantly different due to their level of <strong>com</strong>patibility with PP. A<br />
study of different blends of each polymer with PP resin was examined and a side by side <strong>com</strong>parison of the<br />
key properties reported. By using this <strong>com</strong>parison, the <strong>com</strong>pound or dry blend can be optimized by using the<br />
correct polymer selection to meet specific application needs. The results from this work will provide<br />
re<strong>com</strong>mendations on material selections for <strong>com</strong>pounding applications when using propylene specialty<br />
elastomers and plastomers.<br />
Applications Technology Development Engineer<br />
email: felix.zacarias@exxonmobil.<strong>com</strong><br />
phone: 330-849-5159
New Higher Impact Efficiency Elastomers for High Performance Rigid <strong>TPO</strong>s<br />
Kim L. Walton 1 , Mark Berard 1 , Theresa Hermel-Davidock 1 , Phillip Hustad 1 ,<br />
Jim Hemphill 1 , Didem Oner-Deliormanli 1 , Russell Barry 2<br />
Dow Elastomers<br />
The Dow Chemical Company<br />
1 Freeport, TX 77541<br />
2 Horgen, Switzerland<br />
Specifications for rigid <strong>TPO</strong>’s continue to evolve. In a recent Voice of the Customer<br />
survey along the <strong>TPO</strong> <strong>com</strong>pound value chain, the interviewees indicated that new rigid<br />
<strong>TPO</strong> specifications will call for an increase in flexural modulus with no change in lowtemperature<br />
impact resistance. Thus, <strong>TPO</strong> suppliers face increasing challenges to find<br />
the right <strong>com</strong>bination of polypropylene, impact , and reinforcing agent to meet ever more<br />
demanding performance requirements.<br />
A new family of high efficiency impact modifiers has been developed to meet these<br />
increasing demands. The new impact modifier exhibits 15 – 20% higher impact<br />
efficiency than best-in-class, <strong>com</strong>mercial ethylene/1-octene copolymers (EO). It exhibits<br />
equivalent low-temperature, high-speed dart impact efficiency as styrene/ethylene-1butene/styrene<br />
block copolymers with 15% higher modulus in <strong>TPO</strong> at equivalent levels.<br />
Characterization and performance of this new class of impact modifiers will be discussed.<br />
IDI@ -30C, % ductile<br />
60<br />
50<br />
40<br />
30<br />
20<br />
10<br />
0<br />
New Impact Modifier<br />
1700 1800 1900 2000 2100 2200<br />
Chord Modulus, MPa<br />
0.5 dg/min, 0.863 g/cc EO<br />
6.7 m/s dart speed<br />
Figure 1 Comparison of new impact modifier with <strong>com</strong>mercial EO elastomer used in<br />
rigid, reactor-<strong>TPO</strong> <strong>com</strong>pound
Kim L. Walton Biography<br />
Kim Walton received his Bachelor of Science degree in Polymer Science from the<br />
University of Southern Mississippi and his Master of Science degree in Macromolecular<br />
Science from Case Western Reserve University. From 1983 – 1996, Mr. Walton worked<br />
for The Dow Chemical Company in a variety of applications including chlorinated<br />
polyethylene for single ply roofing and vinyl siding impact modification, biaxially<br />
oriented polyethylene film and ethylene/1-octene copolymer based cross-linked foams.<br />
He joined DuPont Dow Elastomers L.L.C in 1996 where his development focus was on<br />
Engage® for flexible automotive interior applications, blow molding, and<br />
thermoforming. He rejoined Dow in July, 2005 and is leading the technical development<br />
for polyolefin elastomers and plastomers. He is a senior member of the Society of<br />
Plastics Engineers. He is an author or co-author of ten patents and twenty two outside<br />
publications.<br />
Contact Information<br />
Kim L. Walton<br />
Dow Elastomers<br />
The Dow Chemical Company<br />
2301 Brazosport Blvd., B-1470<br />
Freeport, TX 77541<br />
Phone: 979-238-3466<br />
Fax: 979-238-0235<br />
email: klwalton@dow.<strong>com</strong>
Abstract:<br />
Low Density <strong>TPO</strong> Development for <strong><strong>Auto</strong>motive</strong> Exterior and Interior Applications<br />
Todd Glogovsky<br />
LyondellBasell Industries<br />
An increase in public awareness regarding environmental issues backed by State and Federal<br />
Agencies has influenced consumers purchasing behavior and North America Businesses.<br />
Federal and State sponsored limits on carbon emissions through initiatives such as “Cap and<br />
Trade” are impacting the North American <strong><strong>Auto</strong>motive</strong> Industry. These initiatives have spawned<br />
new technology developments to meet new environmental requirements. Weight reduction<br />
targets will provide benefits of piece part cost, transportation cost, and environmental saving<br />
which can be applied to the business’s best interest. LyondellBasell Industries has utilized new<br />
catalyst and <strong>com</strong>pounding technologies to develop novel polymers and polymer blends with<br />
equal or better mechanical performance and dimensional control while providing significant<br />
weight reductions. These technologies are being applied to the design of plastic resins for <strong>TPO</strong><br />
exterior and interior <strong>com</strong>ponents. This presentation will summarize these activities.
Breaking New Ground with Thermoplastic Polyolefin Body Panels<br />
Neil Fuenmayor, Customer Project Manager<br />
Todd Glogovsky, Technical and Marketing Manager<br />
LyondellBasell Industries<br />
Abstract:<br />
Thermoplastic Polyolefins (<strong>TPO</strong>s) are <strong>com</strong>monly used for automotive exterior<br />
applications like bumper fascia for their light weight and excellent cost/performance<br />
balance versus other engineering thermoplastics. Improvements in <strong>TPO</strong> stiffness/impact<br />
balance and reduced coefficient of linear thermal expansion (CLTE) have enabled <strong>TPO</strong> to<br />
be considered for vertical body panel applications such as fenders, tailgates, and roof<br />
spoilers. This paper will examine the state of the art of <strong>TPO</strong> materials suitable for body<br />
panel applications and give specific application examples, such as the Ford Kuga<br />
illustrated below.<br />
LyondellBasell Industries’ Hifax TRC 280X <strong>com</strong>pounded polypropylene (PP) resin is<br />
being used to produce the tailgate outer panel and the roof spoiler for the Kuga, Ford’s<br />
new European crossover model. It is the first time Ford in Europe has used an advanced<br />
polyolefin in a body panel application.<br />
Photo: Ford Motor Company
Strain Hardening of Polypropylene-Clay Nano<strong>com</strong>posite Melts in Uniaxial<br />
Extensional Flow<br />
Tanmay Pathak* and K. Jayaraman<br />
Dept. of Chemical Engineering and Materials Science, Michigan State University<br />
Strain hardening of polymer melts in elongational flow is important for a<br />
variety of polymer processing operations such as thermoforming, foaming and blow<br />
molding. It is well known that linear polypropylene does not strain harden in melt<br />
extensional flow. The effect of dispersing two different organoclays at different levels<br />
in linear polypropylene on the transient uniaxial extensional viscosity has been<br />
investigated in this work. The matrix polymer was a linear polypropylene grafted with<br />
maleic anhydride (PP-g-MA); two different grades of organoclay with different ionic<br />
surfactants were used as filler. The neat PP-g-MA matrix did not show any strain<br />
hardening at different extensional strain rates. The nano<strong>com</strong>posite melt with (I.44P)<br />
organoclay exhibited significant level of strain hardening at several extensional strain<br />
rates whereas the nano<strong>com</strong>posite melt with (I.30P) organoclay showed much lesser<br />
strain hardening at those extensional rates, as can be seen in Figure 1. The I.44P clay<br />
has a quaternary ammonium ion surfactant with two C-18 tails as <strong>com</strong>pared to I.30P<br />
clay which has a primary ammonium ion surfactant with single alkyl tail. The extent<br />
of strain hardening for the nano<strong>com</strong>posites was also investigated based on several<br />
other factors such as the amount of maleic anhydride in matrix and its molecular<br />
weight, the clay loading, and also the effect of melt temperature.<br />
η E + (Pas)<br />
1.0E+07<br />
1.0E+06<br />
1.0E+05<br />
1.0E+04<br />
150°C<br />
1.0E+03<br />
Neat PP-g-MA<br />
1.0E+02<br />
1.0E+01<br />
0.1 s-1<br />
0.5 s-1<br />
1.0 s-1<br />
2.0 s-1<br />
0.01 0.1 1 10 100<br />
t (sec)<br />
X 100<br />
X 10<br />
5 wt% I.30P clay<br />
5wt% I.44P clay<br />
Fig 1: Uniaxial melt extensional viscosity: Neat PP-g-MA shows no strain hardening;<br />
Nano<strong>com</strong>posite with 5wt% I.30P clay shows lesser strain hardening, and the one with<br />
5wt% I.44P clay shows significant strain hardening.<br />
*Speaker: Tanmay Pathak is a graduate student at Michigan State University. He<br />
holds a B.E degree in Chemical Engineering and is currently pursuing a doctoral<br />
degree in Chemical Engineering at Michigan State University under the guidance of<br />
Dr K. Jayaraman.
Unique flow of polypropylene at the weld line behind an obstacle in injection molding<br />
Yutaka Kobayashi, 1,3 Gensei Teramoto, 1 Toshitaka Kanai 2,3<br />
1 Prime Polymer Company, Limited, Sodegaura-City, Chiba 299-0265, Japan<br />
2 Idemitsu Kosan Company, Limited, Ichihara-City, Chiba 299-0193, Japan<br />
3 Graduate School of Natural Science & Technology, Kanazawa University, Kanazawa-City,<br />
Ishikawa 920-1192, Japan<br />
Abstract<br />
This paper deals with weld line of metallic mold-in-color polypropylene behind an obstacle in<br />
an injection molded plaque. Broad uneven gloss section was observed visually along weld line<br />
after disappearing V-notch weld. Generally, disk-shaped metallic pigments were oriented<br />
parallel to the wall by laminar flow. The pigments at the weld behind an obstacle were ordered<br />
vertically at the core zone in the plaque. When the pigments were eliminated from PP, black line<br />
was observed at the same position of the metallic weld. From the measurement of crystal<br />
structure, black line was caused by rapid cooling of molten resin. Although an irregular flow<br />
pattern was not simulated by a flow analysis, it was suggested that elongational flow occurred<br />
along weld line after fading away V-notch weld. The unique flow made order the pigments<br />
obliquely at the advancing flow-front and disturb the subsequent flow of hot resin which<br />
transferred heat to the crystallizing place.<br />
Short biography<br />
Yutaka Kobayashi is a senior research associate in Prime Polymer Co. Ltd,.(a joint<br />
<strong>com</strong>pany of Mitsui Chemical and Idemitsu Kosan (Japan)). He entered Idemitsu in 1985.<br />
He has been developing Polypropylene (PP) <strong>com</strong>pounds in Prime Polymer since 2005<br />
and studying in a doctoral program of Kanazawa University (Japan) since <strong>2009</strong>. He<br />
specializes in morphology of PP induced by injection molding.
<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong><strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />
Speaker’s Biography<br />
Name: Yutaka Kobayashi<br />
Title: Senior research associate<br />
Company: Prime Polymer Co. Ltd,.<br />
(a joint <strong>com</strong>pany of Mitsui Chemical and Idemitsu Kosan (Japan))<br />
* Present: Senior researcher & senior manager<br />
Advanced Composites, Inc.<br />
1062 S Fourth avenue, Sidney, OH 45365<br />
Experience (Brief Summary):<br />
<strong>2009</strong> July: Advanced Composites, Inc.<br />
2005 April: Prime Polymer Co., Ltd.<br />
1985 April: Idemitsu Kosan Co., Ltd.<br />
I has been developing Polypropylene (PP) <strong>com</strong>pounds for 24 years. I<br />
specialize in morphology of PP induced by injection molding.<br />
Education:<br />
<strong>2009</strong>- A student in a doctoral program of Kanazawa University<br />
(Japan)<br />
1985; Graduate Gumma University (Japan), MS<br />
1982; Graduate Gumma University (Japan), BA<br />
Industry/Trade Affiliations:
Special Session
About the Instructor<br />
Shane Vandekerkhof<br />
Shane Vandekerkhof joined the RJG Team in 2003 as a member of the Customer Support team, where he quickly<br />
gained knowledge and understanding of RJG’s systems and hardware. He quickly became qualified to conduct on-site<br />
training for RJG customers that included hands-on training on RJG’s software and equipment.<br />
After two years Shane took on the role of Business Development for Europe where he was responsible for creating new<br />
accounts, supporting existing accounts, and working with sales representatives. He traveled extensively during this<br />
period to lay the groundwork for RJG to expand into this region. He established contacts and researched the area for<br />
further expansion.<br />
Shane is currently one of RJG’s Trainer/Consultants. His background, knowledge and abilities made the transition into<br />
this role an easy one. His responsiblities include teaching RJG Systematic courses as well as Master Molder<br />
Certification courses. Shane’s quick grasp of molding essentials have made him a valuable member of the RJG Team.<br />
Before <strong>com</strong>ing to RJG Shane attended Michigan State University, Davenport University, and Northwestern Michigan<br />
College where he studied Computer Information systems.<br />
What some of Shane’s students had to say about their training:<br />
“Course had excellent content which is applicable in a real world setting – not just textbook – instructor was<br />
enthusiastic and presented great real world examples.” Jerry Driscoll – Panduit<br />
“A clear, systematic approach to a very interactive process. RJG’s use of training & techniques coupled with<br />
technology make them a world class partner.” Stephen Balsam – L&L Products<br />
“Great job of breaking the process down to easy to understand pieces.” Chris Benbow –Flextronics<br />
RJG, Inc. ~ 3111 Park Drive ~ Traverse City, MI 49686 USA ~ Phone: 231-946-3111 ~ Fax: 231-947-6403 ~ Web: www.rjginc.<strong>com</strong>
<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />
RJG Special Session – 4 hrs, including video lab demonstration<br />
Session Title: Injection Molding & Advanced Process Control<br />
Session Moderator: David Okonski – General Motors<br />
Session Presenter: Shane Vandekerkhof – RJG, Inc<br />
Description: Special session on advanced process control and trouble-shooting for the<br />
injection-molding process to help participants achieve a <strong>com</strong>petitive<br />
advantage in the global market.<br />
Session Content (via PowerPoint media/presentation):<br />
• Polymer Basics<br />
o Overview of Polymerization – focus on polypropylene (PP) and<br />
polyethylene (PE) and the <strong>com</strong>pounding of PP and PE into a <strong>TPO</strong> alloy<br />
o Commonly used fillers/reinforcements and their effects on the material<br />
properties – such as strength and impact – of <strong>TPO</strong><br />
o Effect of polymer chain variation on morphology:<br />
� Molecular weight / molecular weight distribution<br />
� Polymer viscosity and its impact on the injection-molding process<br />
• Decoupled Molding Strategies – define “Decoupled Molding”<br />
o Define the basic benefits of a Decoupled I Process<br />
o Define the basic benefits of a Decoupled II Process<br />
o Define the basic benefits of a Decoupled III Process<br />
o Define and discuss the underlying principles of “Scientific Injection<br />
Molding for (Advanced) Process Control”<br />
• Troubleshooting the Injection-Molding Process<br />
o Discuss cause/effect of some <strong>com</strong>mon defects:<br />
� Relate material variation (lot-to-lot and mat’l-to-mat’l) to defects<br />
� Relate machine variation to defects<br />
� Relate tool variation to defects<br />
o Defect focus (proceeding from simple to the more advanced):<br />
� A general discussion of Shorts, Flash, & Sink<br />
� Surface defects – such as gloss, tiger striping and gate blush – for<br />
an as-molded, non-grained & grained, class A interior part<br />
� Minimize dimensional variations due to warp for a body-side<br />
cladding<br />
� Minimize the effect of residual stress on the impact properties of a<br />
fascia<br />
Lab demonstration via internet video link to RJG Laboratory in Traverse City, Michigan<br />
• Demo of current eDART (process monitoring) system<br />
• Live troubleshooting lab<br />
o Produce defects and interact with attendees on possible causes<br />
o Verify root causes using eDART system
Application Development
Robert Eller Associates LLC<br />
CONSULTANTS TO THE PLASTICS AND RUBBER INDUSTRIES<br />
TECHNICAL / ECONOMIC / MARKET ANALYSIS & MANAGEMENT DECISIONS<br />
4000 Embassy Parkway · Suite 208 · Akron, OH 44333-8328 USA<br />
Phone 330-670-9566 / Fax 330-670-9844<br />
E-mail: bobeller@robertellerassoc.<strong>com</strong> / Home Page: http://www.robertellerassoc.<strong>com</strong>/<br />
Effects of the <strong>Global</strong> Economic Situation on <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong>s<br />
Robert Eller<br />
Abstract: The global recession has severely impacted automotive markets and demand for automotive<br />
<strong>TPO</strong>s. The recent uptick in the market is promising, but the automotive plastics paradigm and the<br />
associated supply chain have shifted. This new paradigm is creating opportunities for increased<br />
demand for automotive <strong>TPO</strong>s driven by fuel economy requirement shifts, increased emphasis on<br />
weight reduction, increased modular construction and the demand for global vehicle platforms. The<br />
new paradigm offers <strong>TPO</strong> opportunities in:<br />
- Advanced battery applications<br />
- New applications associated with polyolefin-based <strong>com</strong>posites (both mineral filled and advanced<br />
long fiber reinforced)<br />
- Exterior panels<br />
- A new generation of absorption <strong>com</strong>ponents<br />
- Multi-shot molded <strong>com</strong>ponents<br />
- An expanded range of soft touch applications<br />
This paper explores the macroeconomic shifts associated with the global recession and the impacts on<br />
automotive demand, the supply chain, and opportunities for <strong>TPO</strong>s in the new automotive plastics<br />
paradigm.<br />
r/mydox/<strong>SPE</strong> <strong>TPO</strong> <strong>2009</strong>/Abstract REA <strong>SPE</strong> <strong>TPO</strong> <strong>2009</strong>.doc
<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong><br />
Oct 5 – 7, <strong>2009</strong><br />
<strong>TPO</strong> Development for the 2010 and Beyond<br />
Sassan Tarahomi<br />
IAC North America<br />
ABSTRACT 1<br />
2008 was a wake-up call to all of us in the automotive industry, especially the material engineers and<br />
purchasing managers who were shocked by crude oil price rising to $145 per barrel. We all knew chemicals<br />
derived directly from crude oil such as Ethylene, Propylene, Butylenes, Butadiene and so many others would<br />
follow oil price and eventually their prices sky rocketed to new highs. In the summer and fall of 2008<br />
Polypropylene price was hovering around $1.00 /lb which in turn forced <strong>TPO</strong> prices to go up as well.<br />
Do we need more refineries to process more oil to lower resin cost?<br />
Well, in early 1980’s, there were about 300 refineries in the U.S with a <strong>com</strong>bined capacity of 18 million barrels<br />
of oil per day. Now, with great improvement in our efficiency we have only 149 refineries producing same amount<br />
of oil per day as 30 years ago.<br />
Why don’t we build more refineries?<br />
New refineries require tremendous financial <strong>com</strong>mitments which take anywhere from 20 to 30 years to<br />
amortize. With record oil prices in the last year or so, it would make perfect sense to invest in building new<br />
refineries. Then why, there hasn't been a new refinery built in the US since 1976. Answer is oil is depleting at a<br />
very fast rate, there would not be any oil to refine 20 years from now, and therefore building new refineries would<br />
not make sense, because there won't be enough oil left to refine by the time new refineries could pay for<br />
themselves. Answer is not more refineries.<br />
The objective of this paper is to closely examine key factors effecting <strong>TPO</strong> price in the next several decades<br />
and to provide a guideline for developing new <strong>TPO</strong> resins for <strong><strong>Auto</strong>motive</strong> and other industries.<br />
1 Author: Sassan Tarahomi, Material Eng. Manager, IAC N.A., Dearborn, Michigan
Over-Molding New Cost Effective Soft Touch TPV on Polypropylene<br />
Substrates with Improved Surface Durability, Soft / Dry Feel, and High<br />
Temperature Resistance.<br />
Jeffrey Valentage and Hermann-Josef Holz ExxonMobil Chemical Company<br />
<strong>Global</strong> <strong><strong>Auto</strong>motive</strong> Marketing, Polymers<br />
Abstract:<br />
The perceived quality of the vehicle interior is dominated by the “look” and “feel” of the<br />
interior surfaces. A broad range of materials with different levels of perceived quality is<br />
currently used. The products range from injection molded neat PP on the low end up to<br />
assembled multi-layer structures with thermoformed skins or leather for luxury vehicles.<br />
2-Component injection molding (2-K) allows the construction of an all polyolefinic<br />
system consisting of a stiff PP substrate for carrying load and a grained thin top-layer<br />
skin to give improved <strong>com</strong>fort.<br />
A new Santoprene TM TPV product has been developed for 2K molding a soft touch skin<br />
over polypropylene based substrates. The new TPV product offers several performance<br />
advantages, which include:<br />
- High flow for ease of molding a thin skin layer<br />
- Product stability over a broad temperature range<br />
• Maintains dry soft feel<br />
• Minimal gloss change<br />
- High Durability: scratch, mar and abrasion resistance<br />
- Low emissions<br />
- Provides system cost savings while improving the interior appeal: Eliminates the<br />
needed for secondary steps such as soft touch paint or a separate skin/foam laminate<br />
The presentation will focus on the aforementioned performance attributes of the new<br />
product and review the advantages / disadvantages of the various overmolding techniques.<br />
Speaker: Jeffrey Valentage has been involved in the plastics automotive industry for<br />
over 20 years. He began his career as a Process/Project Engineer and Manufacturing<br />
Manager at a major plastics molder, joined the ExxonMobil Chemical-<strong><strong>Auto</strong>motive</strong><br />
Business Unit, Farmington Hills, MI in 1997, and served as an Applications Engineer and<br />
OEM Account Manager. Jeffrey is currently focusing on global automotive marketing<br />
for polymers at the ExxonMobil Chemical Headquarters in Houston, TX. Jeffrey holds a<br />
BS degree in Business Administration from the University of Phoenix.<br />
jeff.valentage@exxonmobil.<strong>com</strong>
Digital Color Solutions for <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> Applications<br />
Jim Harper, Techmer PM, Clinton, TN<br />
Nearly every vehicle system is envisioned and evaluated using virtual, <strong>com</strong>puter-aided imaging tools.<br />
<strong><strong>Auto</strong>motive</strong> parts subject to critical color evaluation, however, have been excluded from the <strong>com</strong>puter<br />
revolution. The nuances of color, its subjective nature, metamerism, textural effects and the like, have<br />
caused development to proceed through a tedious sample-making and visual approval process, only to<br />
converge on a set of <strong>com</strong>promised colors. Digital tools and color development processes now exist to<br />
accelerate the master approval process. The objective of the paper is to describe and illustrate the<br />
advantages of digital color development as a precursor to physical sample making.<br />
<strong>TPO</strong> color, molded in various grains, represents one subset of the overall interior color. Since the color<br />
development plaque issued by an OEM is typically an injection-molded part, <strong>TPO</strong> color matching is<br />
usually straightforward. Obtaining parts approval may be somewhat more <strong>com</strong>plicated since the final<br />
part might be adjusted for lightness/darkness due to grain, lighting, and viewing angles used to<br />
subjectively evaluate the part.<br />
Other <strong>com</strong>ponents, textiles for example,<br />
are dissimilar to the master plaque in<br />
many ways. As thin-section parts,<br />
frequently colorants used in the master<br />
plaque cannot be used in textiles due to<br />
lightfastness considerations. The textile<br />
texture is dramatically different from the<br />
master plaque and every submission is an<br />
interpretation or a guess as to what the<br />
appearance group is trying to achieve. At<br />
the end of the process all of the interior<br />
parts are mutually <strong>com</strong>pared and must<br />
have the same hue in three illuminants.<br />
Obtaining the final, critical match for<br />
every <strong>com</strong>modity that meets the<br />
approver’s subjective standard is difficult.<br />
Digital development, using real-world colorants as the basis for mathematical color modeling, is able to<br />
harmonize color at the front of the process. Color is applied digitally to the various interior textures and<br />
provides the <strong>com</strong>munication interface to evaluate color formulations before samples are made.<br />
Afterwards, a preliminary set of physical samples based on a digital approval can verify color, harmony,<br />
and weathering performance--all at the beginning of the mastering process.
STRUCTURE-PROPERTY RELATIONSHIP STUDY OF NOVEL<br />
METALLOCENE-BASED R-<strong>TPO</strong> FOR INTERIOR PARTS<br />
By Shouichi Fukunaga 1 , Kenji Matsuoka 1 , Kouichi Honda 1 , Kiyoshi Yukawa 2 , and<br />
Motoko Ito 3<br />
1<br />
Japan Polypropylene Corporation, Product Technical Center 1<br />
2<br />
Japan Polypropylene Corporation, Polymerization Technical Center<br />
Toho-cho 1, Yokkaichi, Mie 510-0848, Japan<br />
3<br />
Japan Polypropylene Corporation, Marketing & Overseas Business Group, Sales &<br />
Marketing Division<br />
4-14-1,Shiba, Minato-ku, Tokyo 108-0014, Japan<br />
Abstract<br />
<strong>TPO</strong>s have be<strong>com</strong>e increasingly popular for manufacturing automotive exterior and<br />
interior parts mainly because of their many apparent advantages, including light weight,<br />
recyclability, productivity, low cost, etc. For interior parts applications, <strong>TPO</strong>s are<br />
expected to replace PVC and PU foam materials if further improvements in <strong>TPO</strong><br />
properties, such as softness, gloss, grain retention, stickiness, abrasion, and scratch<br />
resistance, can be made. To address the above challenges, JPP has recently developed an<br />
advanced metallocene catalyst technology for our original gas-phase HORIZONE<br />
process to produce a series of novel R-<strong>TPO</strong>s that possess unique property attributes<br />
unmatched by conventional Z-Nat R-<strong>TPO</strong>s. In this presentation, we will highlight the<br />
attractive physical and mechanical properties of a series of soft R-<strong>TPO</strong>s and show their<br />
p otentials for automotive interior parts applications.<br />
Stickiness<br />
(Anti-Bleed out<br />
Good<br />
Property)<br />
Low Temperature<br />
Resistance -40<br />
(Tg:°C)<br />
Flexural Modulus (MPa)<br />
0<br />
-20<br />
Bad<br />
Worse<br />
0<br />
80<br />
100<br />
120<br />
140<br />
200<br />
400<br />
600<br />
800<br />
80<br />
Heat resistance<br />
(Tm:°C)<br />
40<br />
80<br />
Charpy Impact<br />
Strength(23 °C)<br />
(kJ/m2 Charpy Impact<br />
Strength(23 °C)<br />
(kJ/m ) 2 )<br />
60<br />
40<br />
20<br />
Transparency<br />
(Haze:%(2mm sheet))<br />
WELNEX ® WELNEX ®<br />
Conv. R-<strong>TPO</strong>(RCP Base)<br />
Conv. R-<strong>TPO</strong>(Homo Base)<br />
Fig. 1. Schematic Showing Physical Property Differences of the Novel Metallocene R-<strong>TPO</strong><br />
WELNEX TM Against Conventional R-<strong>TPO</strong>s.
Superior Appearance Material in Airbag Cover Applications<br />
Dr. Nadeem Bokhari<br />
<strong>Auto</strong>liv North America<br />
Kousuke Ohtani<br />
Tetsuya Hisayama<br />
Noboru Yamaguchi<br />
Sumitomo Chemical Co., Ltd.<br />
Abstract:<br />
Airbag covers in automotive applications require a specific rigidity in applications such as in<br />
driver and passenger airbag systems. One key criteria used in evaluating materials has<br />
been their impact strength at low temperature deployments without breaking or tearing<br />
beyond the tear seam design. In addition to this performance criteria, the molded part must<br />
provide good cosmetics since it is clearly visible to the occupants inside the vehicle. To<br />
balance such diversified requirements, olefinic elastomer-based <strong>TPO</strong> and styrenic<br />
elastomer-based TPS have been used in these applications.<br />
Currently, the incumbent technologies have been challenged in trying to satisfy both<br />
performance and cosmetics when producing a non-painted cover. The challenge is trying<br />
to maintain part performance and low gloss through the tear seam where most cosmetic<br />
defects occur. Areas of high or uneven gloss require manufacturers to cover these defects<br />
with paint in order to pass the visual quality requirements of their customers.<br />
Under such circumstances, the authors have developed a new material technology that<br />
delivers the cosmetic requirements on non-painted airbag covers while maintaining the most<br />
demanding performance requirements in cold temperature deployments.<br />
Dr. Nadeem Bokhari<br />
<strong>Auto</strong>liv North America, American Technical Center<br />
TEL: 248-276-7853, FAX: 248-475-9835<br />
E-mail: nadeem.bokhari@autoliv.<strong>com</strong><br />
Sumitomo Chemical Co., Ltd. Petrochemicals Research Laboratory<br />
TEL: +81-436-61-5352, FAX: +81-436-61-5344<br />
E-mail: ohtanik2@sc.sumitomo-chem.co.jp
Optimization of Scratch Resistance for Molded in<br />
Color (MIC) Interior <strong>TPO</strong> Injection Molded Plastics<br />
Abstract<br />
Renee Hotton<br />
General Motors Corporation<br />
As customer dissatisfaction with interior trim pieces is tracked by the JDPowers question<br />
on surface durability there is a need to increase the surface durability of the molded in<br />
color parts. In particular, door lowers are parts that are susceptible to scratching those<br />
results in a poor surface appearance.<br />
An assessment of the various parameters that can affect surface durability was conducted<br />
using talc filled <strong>TPO</strong> materials to determine the optimum set. The following P – diagram<br />
shows the control factors, noise factors, and the outputs used for the evaluation.<br />
Control Factors:<br />
Grain<br />
Gloss<br />
Material<br />
Color<br />
Interior Trim Plaque<br />
Noise Factors:<br />
Molding Condition<br />
Aging<br />
Piece to Piece (Test to Test)<br />
Outputs:<br />
Erickson Score<br />
(STB)<br />
The presentation will include a detailed description of the Design for Six Sigma<br />
methodology used, the factors that were evaluated and the test results that were obtained.<br />
The interpretation of the test results relative to the optimization direction will also be<br />
discussed.<br />
Speaker: Renee Hotton is a Materials Engineer in the Material and Corrosion<br />
Engineering Department at General Motors Corporation. Her current responsibility is in<br />
Interior Plastics for a variety of programs. Renee has a Bachelor of Science Degree in<br />
Chemical Engineering from Michigan State University. Email: renee.a.hotton@gm.<strong>com</strong>.
Process/Surface
Mar Resistance Testing and Evaluation of Thermoplastic<br />
Olefins<br />
Robert L. Browning 1* , Peng Liu 1 , Hung-Jue Sue 1 and Kevin Reid 2<br />
1 Polymer Technology Center, Department of Mechanical Engineering<br />
Texas A&M University, College Station, TX 77843, USA<br />
2 Phillips-Sumika, Bartlesville Technical Center, Bartlesville, OK 74004<br />
Abstract<br />
Throughout the history of the field of tribology, little has been done to assign explicit<br />
definitions to the terms associated with the various types of surface damage from sliding<br />
contacts. A deep investigation reveals that each of these terms can be described by a<br />
unique testing and evaluation scenario.<br />
Our past work in the field of tribology, with close association with various sectors of the<br />
polymer industry, has sought to disambiguate these terms and has been met with a fair<br />
amount of success. This study<br />
aims at investigating “mar”<br />
behavior on polymer surfaces via<br />
development of an effective<br />
testing and analysis methodology<br />
derived from the current<br />
ASTM/ISO scratch test method<br />
and has been applied to model<br />
<strong>TPO</strong> systems with and without<br />
slip additive that possess high and<br />
low gloss surfaces.<br />
Percentage Change<br />
-100<br />
Abrasion Characterization of High Gloss <strong>TPO</strong><br />
150<br />
100<br />
50<br />
0<br />
-50<br />
Gloss<br />
Roughness (Ra)<br />
-150<br />
0 1 2 3 4 5 6<br />
It will be shown how gloss,<br />
Applied Normal Load (N)<br />
surface roughness and digital<br />
image contrast are inter-related regarding mar testing and evaluation of <strong>TPO</strong>s. The<br />
implications of this new test methodology <strong>com</strong>pared to the current industrial practices<br />
will also be discussed.<br />
* Speaker: Robert Browning (B_Squared02@yahoo.<strong>com</strong>) is currently working on <strong>com</strong>pleting his doctoral<br />
degree in Material Science & Engineering. His research is concerned with polymer structure-property<br />
relationships with an emphasis on tribological behavior.
Process Development Session:<br />
Aluminum Tooling for Injection Molding Seminar Agenda<br />
Plenary Presentation: Aluminum Tooling for Injection Molding of <strong>TPO</strong> Materials<br />
Patti Tibbenham, Ford Motor Company<br />
Mold Design Improvements, Surface Coatings, Heat Transfer and Part Price Opportunities<br />
Robert Beard, P.E., President of Robert A. Beard & Associates Inc.<br />
Properties of Aluminum Materials for Injection Molds<br />
Dave Wirth, Clinton Aluminum<br />
Designing Production Aluminum Molds<br />
Greg Eidenberger, Paragon Die & Engineering<br />
Case Studies of Production Aluminum Tooling<br />
Dave Dickerson: DRS Industries<br />
Manifold Considerations (Thermal 2-3d Analysis)<br />
Rich Oles: Plastic Services Group Inc. (PSG)<br />
Lessons Learned in Graining and Repair of Aluminum Tooling for Injection Molding<br />
Ron Smierciak: Alcoa<br />
The automotive industry is constantly driving toward cost opportunities, faster time to<br />
market and improved quality. In addition, the industry is moving toward more niche vehicles<br />
with lower production volumes. These drivers make aluminum tooling a current and important<br />
topic of interest in the automotive plastics industry.<br />
All aspects of aluminum tooling will be included from the perspective of the OEM, tier 1<br />
suppliers, mold manufacturers, to the material suppliers. This discussion will include an open<br />
forum on current and past successes and failures utilizing this technology for production molds.<br />
Aluminum material grades and applications will be reviewed. Mold manufacturing design<br />
details and cost savings opportunities for production aluminum molds will be highlighted. Case<br />
studies of current production tools for automotive applications will be discussed. Additionally,<br />
specific hot runner considerations for aluminum will be covered with 2d and 3d thermal<br />
simulations of the cooling characteristics <strong>com</strong>paring conventional steel and aluminum materials.<br />
Finally, lessons learned in the graining and repair of aluminum tooling for injection molds will<br />
be included.<br />
Aluminum tooling is not appropriate for every automotive plastic <strong>com</strong>ponent, and this is<br />
more apparent once individuals understand the realities of aluminum tooling. All of the speakers<br />
have cooperated to make this seminar an educational opportunity; informing the conference<br />
participants so everyone can make their own individual decisions relative to production<br />
aluminum tooling.<br />
Speakers:<br />
Patricia Tibbenham is a technical expert in Plastics Research at Ford Motor Company. She<br />
holds a BS in Mechanical Engineering from GMI and a MS in Engineering Management from<br />
Wayne State University. Patricia has spent over 20 years working on plastic <strong>com</strong>ponents in the<br />
automotive industry and she holds several U.S. Patents. Email: ptibbenh@ford.<strong>com</strong>
Robert Beard is a licensed Professional Engineer with over 40 years experience in the plastics<br />
industry. He is a Honored Fellow member of <strong>SPE</strong>. For the past 6 years, he has concentrated on<br />
getting existing and new molds to be better heat exchangers and reducing cycle times by 20% to<br />
40%. www.Plastic-Solvers.<strong>com</strong><br />
David Wirth is the North American Aluminum Mold Specialist and Midwest Sales Manager for<br />
Clinton Aluminum and Stainless Steel. He plays an active role in marketing Clinton Aluminum<br />
and is currently working with a mill to develop and bring to market a new alloy for the injection<br />
mold market. David also worked at ThyssenKrupp Specialty Steel Tool Steel Division, covering<br />
Wisconsin, Iowa and Minnesota for Die Cast and Injection Mold Markets.<br />
Greg Eidenberger is the Sales Manager for Paragon D&E located in Grand Rapids, Michigan.<br />
Greg has been with Paragon for over 28 years, as a Detail Draftsman, Tool Designer, Program<br />
Manager, Technical Sales, Business Unit Manager and now the Sales Manager for the last 5<br />
years. Greg has been instrumental in working with many of Paragon's customers who are using<br />
Aluminum Alloy's for Medium and Low Volume Production Tooling.<br />
Dave Dickerson is the Plant Manger for DRS Industries in Holland, Ohio. Dave has been with<br />
the <strong>com</strong>pany since 1989 starting as a plastic injection mold maker apprentice, with a focus solely<br />
on aluminum plastic injection molds. Dave served his apprenticeship with DRS, be<strong>com</strong>ing a<br />
journey mold maker and worked through the years as a working Shop Foreman. The Plant<br />
Manager position was offered to Dave in 1999, where as his duties are to oversee the day to day<br />
operations of an aluminum mold builder/plastic injection molder. In 1999 DRS started to<br />
produce and run aluminum low volume tooling for plastic injection molded parts, and has<br />
be<strong>com</strong>e the authority on the construction and running of production aluminum tools.<br />
Richard Oles started out setting up and operating multi-spindle screw machines, turned Mold<br />
Maker, Engineering manager, IT manager, General Manager, President and CEO over the past<br />
23 years. Each position built off the experience of the prior, and then he entered into the Hot<br />
Runner manifold world in 1999 with a Swiss based firm. This role set the stage for his current<br />
position as CEO of North America operations for the German based Hot Runner manufacturer,<br />
PSG Plastic Service Group, Inc.<br />
Ron Smierciak, Market Development Manager, Alcoa Forgings and Extrusions – Ron has been<br />
engaged with the development of Alcoa’s mold alloy, QC-10, since 2005. He is responsible for<br />
the product development of Alcoa QC-10. Ron actively promotes the benefits of aluminum<br />
tooling to molders and original equipment manufacturers in North America, Europe, and Asia.<br />
Prior to his involvement with Alcoa and QC-10, Ron developed products for thin film coatings<br />
serving the semiconductor and flat panel display industries.
Mechanical Modeling of Scratch Induced Periodic Damage<br />
Han Jiang 1* , John D. Whit<strong>com</strong>b 2 and Hung-Jue Sue 1<br />
Polymer Technology Center, Department of Mechanical Engineering 1<br />
Department of Aerospace Engineering 2<br />
Texas A&M University, College Station, TX 77843, USA<br />
Abstract<br />
Regardless of the polymer type, periodic occurrence of scratch-induced damage features<br />
is <strong>com</strong>monly observed. The above phenomenon is believed to be the result of a “stickslip”<br />
process involving the scratch tip.<br />
The stick-slip process is caused by the presence of a horizontal degree of freedom of the<br />
tip and the oscillation between the static and kinetic frictional behaviors. In addition, the<br />
tip geometry and material<br />
pile-up ahead of the 300 Distance Between Periodic Scratch Damage<br />
scratch tip will further<br />
<strong>com</strong>plicate the scratch tip<br />
movement during scratch.<br />
250<br />
200<br />
1 2<br />
2 [( μμ s − μμ<br />
k ) F n + κκ<br />
δδ<br />
e F n ]<br />
D =<br />
k h<br />
Periodic Distance<br />
To understand this 150<br />
Blunter tip<br />
<strong>com</strong>plex phenomenon, a<br />
simplified analytical<br />
100<br />
Scratch<br />
indentation<br />
model on the stick-slip<br />
phenomenon is proposed<br />
to account for the<br />
observed periodic scratchinduced<br />
damage features<br />
50<br />
0<br />
0 5 10 15<br />
Scratch Normal Load<br />
20<br />
Without<br />
indentation<br />
25 30<br />
on polymer surfaces. Through the above modeling effort, fundamental understanding of<br />
the scratch behavior under various scratch conditions is gained. Implication of the above<br />
study for fundamental understanding of the mechanical nature of the ASTM/ISO scratch<br />
test is also discussed.<br />
* Speaker: Han Jiang (jianghantamu@gmail.<strong>com</strong>) is conducting his post-doctoral research at Texas A&M<br />
University. His research focuses include structure-property relationship of polymers and <strong>com</strong>posites,<br />
damage & failure analysis, tribology, finite element modeling, constitutive relationship, etc.
Update on Developments for Scratch and Mar Additives;<br />
Effect of the additive formulation on the scratch performance<br />
and other secondary attributes<br />
Nikolas Kaprinidis*. Per Magnus Kristiansen, Martin Brunner and Johanne Wilson<br />
Ciba Corporation, a part of the BASF group, 540 White Plains Road, Tarrytown, NY 10591<br />
Abstract<br />
As the automotive industry be<strong>com</strong>es increasingly <strong>com</strong>petitive, scratch and mar performance is<br />
progressively more important to automotive OEM’s. Such performance directly affects consumer<br />
perception, which is being tracked by agencies such as J.D. Powers. This has led to closer<br />
scrutiny by OEM’s on the various test methods and a reconsideration of the acceptable standards<br />
is taking place. The previous benchmark of scratch resistance at 10N loading, usually determined<br />
by the popular 5 finger test method is no longer acceptable by many automotive OEM’s as they<br />
strive for increased product performance.<br />
Improving scratch performance for <strong>TPO</strong>s can be ac<strong>com</strong>plished by additive technologies, of which<br />
there are by now several ones available on the market. Although little differentiation is seen at<br />
scratch levels of 10 N, the differences be<strong>com</strong>e more apparent at loadings of 15 N and higher.<br />
Besides scratch resistance, secondary attributes are be<strong>com</strong>ing even more important and will be<br />
considered by automotive OEM’s since they also contribute to the overall consumer perception of<br />
the vehicle. The efficacy and performance of anti-scratch additives may vary based upon the<br />
<strong>com</strong>position and type of resin, as well as other additives present in the formulation which – in<br />
<strong>com</strong>bination – may lead to undesired effects. The second part of the paper will discuss such “side<br />
effects” caused by other additives.<br />
Figure 1: Comparison of scratch performance in 20% talc filled <strong>TPO</strong> for three <strong>com</strong>mercial<br />
scratch additives using Erichsen Cross-cut test method<br />
ΔL (scratch visibility)<br />
8<br />
6<br />
4<br />
2<br />
0<br />
blank blank<br />
5 N 10 N 15 N<br />
0.5% 0.5% Slip Slip<br />
3% 3% SR2 SR2<br />
3% 3% SR SR 11
* Dr. Nikolas Kaprinidis (Speaker) is responsible for application and product development<br />
department at Ciba – a part of the BASF group. He holds a Ph. D in Physical Organic Chemistry<br />
from New York University and spent two post-doctoral stays at UC Berkeley and Columbia<br />
University. He has published extensively and holds patents in various application areas of<br />
plastics. Dr. Kaprinidis is a member of ACS and has been with the <strong>com</strong>pany 11 years. Tel: 914-<br />
785-2739; e-mail: nikolas.kaprinidis@ciba.<strong>com</strong>
ABSRACT FOR <strong>SPE</strong> AUTOMOTIVE <strong>TPO</strong> <strong>2009</strong> <strong>Conference</strong><br />
Presentation Title: Atmospheric Pressure Plasma: Surface Treatment for Bonding and<br />
Painting Applications Without Wet Chemistry<br />
Speaker Name: Shaun Glogauer<br />
Speaker Job Title: Sales And Marketing Manager – Plasmatreat North America<br />
The presentation for this conference will consist of a brief introduction to plasma and<br />
plasma technology, outlining how the process works in laymen’s terms. Plasma is<br />
basically excited air molecules that work to clean and activate a surface for bonding and<br />
coating applications. This process can often lead to the elimination of aggressive<br />
primers, adhesion promoters, and solvent wiping applications. In other words, there are<br />
some truly revolutionary applications possible with this technology from both an<br />
environmental and quality standpoint. The ultimate goal is to reduce or eliminate wet<br />
chemistry in the process. Following this introduction, there will be a description of<br />
practical applications within the automotive industry as well as a few very short videos to<br />
illustrate the technology. The presentation will conclude with a brief summary and a<br />
question and answer period.
Latest Developments in Coatings Technology that Provides Striking<br />
Appearance and Durability over <strong>TPO</strong><br />
Arjun Dhake<br />
Dhake Industries<br />
Abstract<br />
Thermoplastic polyolefin (<strong>TPO</strong>) substrates continue to be used more and more in various<br />
automotive interior applications. At the same time, automotive designers are demanding<br />
more sophisticated and futuristic finishes on the interior of cars while still meeting all of<br />
the durability requirements.<br />
With the latest developments from Dhake Industries, auto designers can <strong>com</strong>bine the<br />
wanted aesthetic appeal with lower cost materials like <strong>TPO</strong> to give the ultimate in lowcost<br />
yet luxurious interiors.<br />
With the use of proprietary coating formulations, Dhake Industries can apply numerous<br />
types of metallic colors to any <strong>TPO</strong> substrate. This includes the much sought after<br />
chrome-look coatings in the automotive industry. <strong>Auto</strong> designers trend towards bright<br />
chrome or satin chrome plating on many interior <strong>com</strong>ponents. Now coatings that<br />
simulate bright chrome and satin chrome plating can be used on lower cost <strong>TPO</strong><br />
substrates to achieve a similar look at a much lower cost. The material cost is decreased<br />
by using <strong>TPO</strong> instead of typical ABS or PC/ABS for plating. Also, the cost of painting is<br />
much less than the cost of plating.<br />
Dhake Industries has been a leader in chrome-look and metallic coating formulations, and<br />
has developed various products to decorate <strong>TPO</strong> materials with these kinds of colors.<br />
With and without the use of adhesion promoters, this paper will examine the various<br />
methods of coating <strong>TPO</strong> to give the look and durability that the auto industry desires.<br />
Speaker Information:<br />
Arjun Dhake has received his B.S.E. in Chemical Engineering from The University of<br />
Michigan and his M.B.A. from The Ross School of Business at The University of<br />
Michigan. Arjun is currently Vice President of Business Development at Dhake<br />
Industries, a global paint and coating manufacturer for the automotive industry.<br />
Email: adhake@dhakeindustries.<strong>com</strong> Phone: 734-420-0101
Study of Scratch Resistance of Polypropylene Compound for<br />
<strong>Auto</strong>mobile<br />
LI Yonghua, YANG Bo, LUO Zhongfu, JIN Shan<br />
(KingFa Sci.& Tech.Co., Ltd., Guangzhou, 510520,China)<br />
ABSTRACT: Scratch resistance is critical for plastic auto parts to maintain their new<br />
appearance. In this study, the effect of scratch-resistant additive content on the<br />
scratch resistance of talc-filled ethylene-α-olefin copolymer/polypropylene blends for<br />
auto interior parts was investigated by scratch morphology, scratch width, and change<br />
of lightness. The effect of grained surface type on the scratch resistance was also<br />
examined. The results indicated that the addition of 1.5% scratch-resistant additive<br />
significantly improved scratch resistance. Scratch resistance was dependent on the<br />
depth, angle, and concentration of grains. Scratch resistance decreased with<br />
increasing depth, angle, and concentration of grains.<br />
The scratch test followed the Volkswagen interior scratch test standard PV3952. 40×<br />
40mm pattern(Fig 1). 10N was applied at a speed of 1000 mm/min.<br />
Fig 1 Scratch test surface pattern<br />
Speaker: Shan Jin, Graduate Student, Michigan State University, Office Phone:<br />
517-355-2220 email: jinshan@msu.edu<br />
Authors: LI Yonghua, YANG Bo, LUO Zhongfu, Kingfa Science & Tech Co.<br />
Contact Information: LI Yonghua, liyonghua@kingfa.<strong>com</strong>.cn, or liyhp@163.<strong>com</strong>
New and Innovative Testing Technologies for Effect Finishes<br />
Greg Shrider and Richard Scott : BYK - Gardner USA<br />
The look of effect finishes is continuously changing to create distinct visual appearances.<br />
Therefore, the range of effect pigments – different aluminum grades to special pearlescent<br />
pigments – used in automotive and industrial applications is increasing. Designers are<br />
seeking for colors which can change their look depending on the lighting conditions to<br />
pronounce the styling of a product. These types of effect finishes can appear grayish under<br />
cloudy sky, but start to live with colorful sparkling effects in the sunshine.<br />
On the other hand color harmony with add-on parts, uniform application without causing<br />
undesirable effects such as “cloudiness or mottling” and easy as well as cost efficient repair<br />
(liquid metal) is be<strong>com</strong>ing more and more of a challenge.<br />
New and innovative testing technologies were developed to quantify special effects such as<br />
sparkle, graininess and mottling with image analysis. The factors influencing the total color<br />
impression will be discussed and explained using several practical application examples.<br />
1
Abstract<br />
Conventional and Low VOC Bonding Solutions for <strong>TPO</strong><br />
Materials<br />
Walt Polifka<br />
Adchem Corporation<br />
<strong>TPO</strong> materials, with their low surface energy characteristics, present unique bonding challenges for<br />
manufacturers of pressure sensitive adhesives. Add into the equation a second substrate, such as, a foam,<br />
vinyl, other low energy surface finish or material and the bonding challenge increases. Adhesive tape<br />
construction and the adhesive used play a role in a successfully engineered bonding solution. <strong>TPO</strong>’s<br />
engineered for specific applications will require the bonding system also satisfy the requirements of the<br />
application. Emerging interest in Low VOC adhesive systems further <strong>com</strong>plicates bonding choices.<br />
<strong><strong>Auto</strong>motive</strong> interior and other industrial specifications will be impacted by Low VOC adhesive technology.<br />
Adchem will explore available adhesive chemistries, the challenges and solutions they provide for the <strong>TPO</strong><br />
user.<br />
Surface Energy by Substrate<br />
(Dynes/cm)<br />
Stainless Steel 400+<br />
Glass 60+<br />
Polycarbonate 52<br />
Epoxy 48<br />
ABS 46<br />
Anodized Aluminum 34<br />
HDPE 34<br />
Fluoropolymer 32<br />
LDPE 32<br />
Rigid PVC 32<br />
Urethane 32<br />
Polyester 30<br />
PP 30<br />
<strong>TPO</strong> 30<br />
Walt Polifka has been part of the Business Development team of Adchem Corporation for over ten years.<br />
He is responsible for new business development for pressure sensitive tape products in several industrial<br />
markets. His prior experience includes 15 years in fluid handling equipment and 14 years experience with<br />
polyester resin and urethane foam chemistries. Walt holds a B.S. degree in Chemical Engineering from<br />
Lehigh University. He and his wife Nan currently live in the Pocono Mountains region of Pennsylvania.
Executive Panel
Executive Management Panelists<br />
Matt Carroll is engineering group manager-Materials for Body Exterior, Electrical and<br />
Batteries at General Motors Co. Carroll was previously body vehicle systems engineer<br />
for the 2006MY Buick® Lucerne. Before joining the automaker, Carroll worked for both a<br />
<strong>TPO</strong> supplier and a paint supplier. He holds a Master’s Degree in Chemical Engineering<br />
from Wayne State University and was a member of the <strong>SPE</strong> Detroit Section Board from<br />
2005-2007. Carroll also has nine publications and one patent to his credit.<br />
Dr. David Cole, chairman of the Center for <strong><strong>Auto</strong>motive</strong> Research (CAR), is an<br />
internationally renowned speaker, writer, and expert on the automotive industry and<br />
will also be a keynote speaker at this year’s <strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong>.<br />
Cole was formerly director of the Office for the Study of <strong><strong>Auto</strong>motive</strong> Transportation<br />
(OSAT) at the University of Michigan’s Transportation Research Institute. Through CAR,<br />
Cole organizes an annual <strong><strong>Auto</strong>motive</strong> Management Briefing. This year’s event, held<br />
August 4-7, was entitled “Today’s Turmoil: A Foundation for Success.” He has worked<br />
extensively on internal-<strong>com</strong>bustion engines, vehicle design, and overall automotive<br />
industry trends. His recent research has focused on strategic issues related to<br />
restructuring of the North American industry and trends in globalization, technology,<br />
market factors, and human-resource requirements. Cole holds B.S. degrees in<br />
Mechanical Engineering and Mathematics, an M.S.M.E. and a Ph.D. – all from the<br />
University of Michigan.<br />
Stephen Dwyer is senior vice-president at LyondellBasell Polyolefins where he is<br />
responsible for its automotive business in the Americas. He has worked in the olefins<br />
industry for over 28 years at both Exxon Chemicals and LyondellBasell Polyolefins<br />
serving in various leadership roles in both North America and Europe. Dwyer has also<br />
published and presented numerous papers on the olefins industry and technological<br />
developments.<br />
Nand Kochhar is chief engineer-<strong>Global</strong> Materials Engineering & Standards, and<br />
executive technical leader-<strong>Global</strong> CAE at Ford Motor Co. Previous assignments at Ford<br />
have included chief engineer-Core Vehicle Engineering, chief engineer-Vehicle<br />
Attributes & CAE, vehicle engineering manager-F Series® Super Duty truck, and chassis<br />
design & release manager-Mondeo® in Europe. Kochhar has also held several<br />
supervisory and technical specialist positions within North American Product<br />
Development at the automaker.<br />
Jeff Makarewicz has been vice-president-Materials Engineering Division at the Toyota<br />
Technical Center (TTC), the North American research arm for Toyota Motor Engineering<br />
& Manufacturing, North America, Inc. (TEMA) since 2008, where he has responsibility<br />
for materials R&D, including materials research, design, development and evaluation.<br />
Makarewicz joined TTC in 1990 as an engineer in the Materials Engineering Department,<br />
Paint & Finishing Group and spent two years at Toyota Motor Corp. in Nagoya, Japan
working on anti-corrosion materials evaluation, design, and development. Prior to<br />
joining Toyota, Makarewicz worked for BASF in the Paint and Colorants Division. He<br />
holds numerous patents and earned a B.S. degree in Chemistry from the University of<br />
Michigan.<br />
Executive Management Moderators<br />
Bob Eller is president, Robert Eller Associates LLC (REA), a firm specializing in<br />
management consulting for the global plastics and rubber industries where he and his<br />
team carry out numerous technology, strategy, and manufacturing analyses, pricing<br />
forecasts, product positioning analyses, and crisis-management analyses in automotive<br />
plastics for clients around the world. Prior to forming his own firm in 1991, Eller worked<br />
in various positions at ExxonMobil, A. D. Little, Phillip Townsend Associates, Charles<br />
River Associates, and Multibase. Eller holds an undergraduate degree in Chemical<br />
Engineering from Massachusetts Institute of Technology and M.S. degrees in Polymer<br />
Science and Chemical Engineering from Brooklyn Polytechnic.<br />
Ron Price has spent over 35 years in polymer global business management, marketing,<br />
and sales involving both engineering and olefin polymers, primarily in the durable goods<br />
and automotive sectors. In fact, he launched over 20 new polymers and alloys to the<br />
automotive industry. He has worked at <strong>com</strong>panies such as DuPont, Borg Warner<br />
Chemicals, ExxonMobil, and Huntsman and continues to be active as a marketing and<br />
business consultant for new business, strategic marketing, and sales development. He<br />
has published over 25 articles and has made hundreds of presentations at regional,<br />
national, and international events. Price is also a recipient of three awards from the<br />
Detroit Section of <strong>SPE</strong>: Outstanding Achievement (2000), Lifetime Achievement (2005)<br />
and Outstanding Member (2006). He also was inducted as an Honored Service Member<br />
(2007) by <strong>SPE</strong> International.
<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />
75
<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />
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<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />
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<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />
78
<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />
79
<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />
80
<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />
81
<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />
82
<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />
83
<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />
84