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SPE Automotive TPO Global Conference 2009 - Auto-tpo.com

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<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />

Wel<strong>com</strong>e to the Annual <strong>SPE</strong> <strong>Global</strong> <strong>TPO</strong> <strong>Conference</strong><br />

The Society of Plastic Engineers (Detroit Chapter), leading OEMs, Tier 1, and <strong>TPO</strong> suppliers<br />

have pooled their resources to create the 11 th Annual <strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong>.<br />

The conference is a dynamic, interactive, and cost-effective learning experience “put together”<br />

and “contributed to” by the world’s foremost authorities on materials, processes, applications,<br />

and market trends.<br />

The pledge of the conference <strong>com</strong>mittee is simple. We strive to bring you the best,<br />

knowledgeable people who will share useful information on the latest <strong>TPO</strong>-related<br />

developments and trends.<br />

Last year, over 400 attendees from OEMs, Tier 1s, and resin and equipment suppliers<br />

participated in this event. Many new materials, application developments, and technologies<br />

were introduced.<br />

This year's event is expected to be as exciting with over 30 technical papers and presentations<br />

and a special half-day session on Injection Molding & Advanced Process Control. Additionally,<br />

there are 4 keynote speakers: Dr. David Cole, chairman of the Center for <strong><strong>Auto</strong>motive</strong> Research<br />

(CAR) in Ann Arbor, Michigan, Neil De Koker, founding president and CEO of the Original<br />

Equipment Suppliers Association (OESA), Nazeer Bhore, Senior Technology Advisor-Corporate<br />

Planning at ExxonMobil Chemical, and Mr. Maurice Sessel, Vice-President, Product<br />

Engineering at IAC.<br />

An Executive Management panel discussion, including representatives from Ford, General<br />

Motors, LyondellBasell, Toyota, and Dr. Cole is scheduled on Tuesday. The subject is:<br />

<strong><strong>Auto</strong>motive</strong> Paradigm Shift Opportunities for <strong>TPO</strong> materials.<br />

A new feature of the <strong>Conference</strong> is a special half-day session focused on a single subject. Last<br />

year it was on thermoforming. This year, as stated above, is on advanced process control and<br />

trouble-shooting for the injection-molding process. The objective is to help participants achieve<br />

a <strong>com</strong>petitive advantage in today's global market. The session will provide an overview of<br />

polymerization, discussion about the <strong>com</strong>pounding of propylene, polyethylene, etc. into a <strong>TPO</strong><br />

alloy, review decoupled molding strategies, and end with a troubleshooting discussion that<br />

includes a lab demonstration via video link to RJG's Traverse City location.<br />

We thank you for attending this conference, and we look forward to seeing you year after year.<br />

We appreciate your <strong>com</strong>ments and feedback as we are continuing to strive to meet your needs.<br />

Bill Windscheif Paula D. Fasulo<br />

Co-Chairman Co-Chairman<br />

Advanced Innovative Solutions, Ltd. General Motors Corporation<br />

President Staff Scientist, Retired


Bill Windscheif<br />

Co-Chairman<br />

Advanced Innovation Solutions, Ltd.<br />

Sandra McClelland – Chevron Phillips Chemical<br />

<strong>SPE</strong> President<br />

Detroit Section<br />

Dr. Norm Kakarala<br />

Inteva Products L.L.C.<br />

Technical Program Chair<br />

Dave Okonski<br />

Moderator – Materials Development<br />

General Motors Corporation<br />

Mitesh Shah<br />

Scholarship/Moderator-Materials Development<br />

LyondellBasell Industries<br />

Robert Eller<br />

Moderator – Applications Development<br />

Robert Eller Associates, L.L.C.<br />

Thomas Pickett<br />

Moderator – Applications Development<br />

General Motors Corporation<br />

Patti Tibbenham<br />

Moderator – Process Development<br />

Ford Motor Company<br />

Duane Lewis<br />

Moderator – Surface Enhancements<br />

ExxonMobil Chemical Corporation<br />

Dr. Rose Ryntz<br />

Moderator – Surface Enhancements<br />

International <strong><strong>Auto</strong>motive</strong> Components<br />

<strong>2009</strong> Planning Committee Members<br />

Paula Fasulo<br />

Co-Chairman.<br />

General Motors Corporation –retired<br />

Kelly Beauchamp<br />

Proceedings Book<br />

DME<br />

Lisa Wujkowski<br />

House Coordinator<br />

Dow <strong><strong>Auto</strong>motive</strong><br />

Sanjay Patel<br />

Audio/Visual/Web Master<br />

Flint Hills Resources<br />

Tom Powers<br />

Budget/Finance<br />

Consultant<br />

Ron Price<br />

Panel Discussion/Communications<br />

<strong>Global</strong> Polymer Solutions<br />

Nippani Rao<br />

Sponsorships<br />

RAOAssociates<br />

Anthony Gasbarro<br />

Committee Member<br />

Advanced Composites<br />

Ed Bearse<br />

Committee Member<br />

Advanced Plastics Consultants<br />

Pat Levine<br />

Registration<br />

<strong>SPE</strong>/<strong><strong>Auto</strong>motive</strong> Division & Detroit Section


7:30-8:30am Registration/Coffee<br />

<strong>2009</strong> <strong>SPE</strong>® <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> Program<br />

Monday October 5, <strong>2009</strong><br />

8:30am Opening Remarks: Bill Windscheif - Advanced Innovative Solutions, Ltd; Paula Fasulo - General Motors (Retired)<br />

8:45-9:15am Keynote Address: Interior Challenge<br />

Maurice Sessel: Vice President Product Engineering, International <strong><strong>Auto</strong>motive</strong> Components<br />

9:15am Technical Program: Norm Kakarala: Inteva Products<br />

Materials Development Session<br />

(Moderators: David Okonski: General Motors & Mitesh Shah: LyondellBasell Industries)<br />

9:30-10:00am Scratch Performance of Talc-PP and Talc-<strong>TPO</strong> Compounds<br />

Saied H. Kochesfahani, Denis Lejour, Frederic Jouffret, Wolfgang Jonischket: Rio Tinto Minerals<br />

High Performance Reinforcement: A Pathway to Density Reduction While Maintaining Physical Properties of Polyolefin<br />

10:00-10:30am<br />

Composites<br />

K. David Lake: Milliken Chemical<br />

10:30-10:45am Break<br />

10:45-11:15am MOS Hige Fiber for Light Weighting, Fast Cycle Time & Improved Quality <strong>TPO</strong>s<br />

Donald Beuke: Mitsui Plastics<br />

11:15-11:45am Improved Glass-Fiber Reinforced Polypropylene for Structural Applications<br />

Alberto Prieto and Steve Davis: LyondellBasell Industries<br />

11:45-12:15pm High-Performance TPEs for Stringent <strong><strong>Auto</strong>motive</strong> Applications<br />

John Chiao and Keith Dunlap: Kraiburg TPE<br />

12:15-1:30pm Lunch & Keynote Presentation: The <strong><strong>Auto</strong>motive</strong> Industry in Transition: A New Beginning<br />

Neil De Koker: CEO, Original Equipment Suppliers Association<br />

1:30-2:00pm Polypropylene Property Modification using Vistamaxx Specialty Elastomers & Exact Plastomers<br />

Felix Zacarias: ExxonMobil Chemical<br />

2:00-2:30pm New Higher Impact Efficiency Elastomers for High Performance Rigid <strong>TPO</strong>s<br />

Kim Walton, Mark Berard, Theresa Hermel-Davidock, Phillip Hustad, Jim Hemphill, Didem Oner-Deliormanli, Russell Barry: The Dow<br />

Chemical Company<br />

2:30-3:00pm Low Density <strong>TPO</strong> Development for <strong><strong>Auto</strong>motive</strong> Exterior and Interior Applications<br />

Todd Glogovsky: LyondellBasell Industries<br />

3:00-3:15pm Break<br />

3:15-3:45pm Breaking New Ground with Thermoplastic Polyolefin Body Panels<br />

Neil Fuenmayor, Mitesh Shah, and Todd Glogovsky: LyondellBasell Industries<br />

Effect of Edge Functionalized Layered Silicates on the Strain Hardening Property of Polymer-Clay Nano<strong>com</strong>posite Melts in<br />

3:45-4:15pm Extensional Flow<br />

Tanmay Pathak and Prof. K. Jayaraman: Michigan State University<br />

4:15-4:45pm The Flaming of Parting-Line Flash and its Effects on Paint Adhesion<br />

Brent Nixon, Kyle Sinko, David Okonski and Elmer Santos: Ferris State University & General Motors<br />

4:45-5:15pm Unique Flow of Polypropylene at the Weld-Line Behind an Obstacle in Injection Molding<br />

Yutaka Kobayashi, Gensei Teramoto and Toshitaka Kanai: Kanazawa University, Japan<br />

5:30pm ExxonMobil Reception (Open for All <strong>Conference</strong> Participants )


7:00-8:00am Registration/Coffee<br />

<strong>2009</strong> <strong>SPE</strong>® <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> Program<br />

Tuesday October 6, <strong>2009</strong><br />

8:00-8:30am Keynote Address: The Outlook for Energy: A View to 2030<br />

Dr. Nazeer Bhore: Senior Technology Advisor-Corporate Planning, ExxonMobil Corporation<br />

Injection Molding & Advanced Process Control Seminar<br />

(Moderators: David Okonski: General Motors & Shane Vandekerkhof: RJG, Inc.)<br />

8:30-9:00am Polymer Basics: Morphology and Microstructures<br />

9:00-9:30am Decoupled Molding Strategies: Separating Fill from Pack<br />

9:30-9:45am Break<br />

9:45-10:15am Troubleshooting the Injection Molding Process: Cause and Effect of Some Common Defects<br />

10:15-10:45am Troubleshooting the Injection Molding Process: Defect Focus from Simple to More Advanced<br />

10:45-11:30am Lab Demonstration via Video Linked to RJG Laboratory<br />

11:30-12:00am Keynote Speaker: The <strong>Auto</strong> Future: A New Beginning?<br />

Dr. David Cole: Chair, Center for <strong><strong>Auto</strong>motive</strong> Research<br />

12:00-2:00pm<br />

Lunch & Panel Discussion: Challenges & Opportunities in the New <strong><strong>Auto</strong>motive</strong> Industry<br />

(Moderators: Bob Eller: Robert Eller Assoc., LLC & Ron Price: <strong>Global</strong> Polymer Solutions<br />

Executives: Matt Carroll: General Motors Co., Dr. David Cole: Center for Autmotive Research, Stephen Dwyer: LyondellBasell Industries,<br />

Nand Kochhar: Ford Motor Co., Jeff Makarewicz: Toyota Motor Corp.<br />

Applications Development<br />

(Moderators: Bob Eller: Robert Eller Assoc., LLC & Tom Pickett, General Motors Co.)<br />

2:00-2:30pm <strong>TPO</strong> Position in the <strong>Global</strong> <strong><strong>Auto</strong>motive</strong> Market & Effects of <strong>Global</strong> Economic Situation<br />

Bob Eller, Robert Eller Assoc., LLC<br />

2:30-3:00pm <strong>TPO</strong> Development for the 2010 and Beyond<br />

Sassan Tarahomi, IAC North America<br />

3:00-3:30pm Over-Molding New Cost Effective Soft Touch TPV on PP Substrates with Improved Properties<br />

Jeff Valentage & Hermann-Josef Holz: ExxonMobil Chemical<br />

3:30-3:45pm Break<br />

3:45-4:15pm Digital Color Solutions for <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> Applications<br />

Jim Harper, Techmer PM<br />

4:15-4:45pm Structure-Property Relationship of Novel Metallocene-Based R-<strong>TPO</strong> for Interior Parts<br />

Motoko Ito, Shouichi Fukunaga, Kenji Matsuoka, Kouichi Honda, and Kiyoshi Yukawa: Japan Polypropylene Corporation<br />

4:45-5:15pm Superior Appearance Material in Airbag Cover Applications<br />

Dr. Nadeem Bokhari: <strong>Auto</strong>liv North America; Kousuke Ohtani, Tetsuya Hisayama, & Noboru Yamaguchi: Sumitomo Chemicals Co. Ltd.<br />

5:15-5:45pm Optimization of Scratch Resistance for Molded in Color (MIC) Interior <strong>TPO</strong> Injection Molded Plastics<br />

Renee Hotton: General Motors Co.<br />

5:45pm <strong>SPE</strong> Detroit Section Reception (Open for All <strong>Conference</strong> Participants, Cash Bar )


7:00am Registration/Coffee (Concurrent Sessions)<br />

<strong>2009</strong> <strong>SPE</strong>® <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> Program<br />

Wednesday October 7, <strong>2009</strong><br />

Process Development: Aluminum Tooling for Injection Molding Seminar<br />

(Moderator: Patti Tibbenham - Ford Motor Co.)<br />

8:00-8:15am Plenary Presentation: Aluminum Tooling for Injection Molding of <strong>TPO</strong> Materials<br />

Patti Tibbenham, Ford Motor Company<br />

8:15-9:00am Mold Design Improvements, Surface Coatings, Heat Transfer and Part Price Opportunities<br />

Robert Beard, P.E., President of Robert A. Beard & Associates Inc.<br />

9:00-9:30am Properties of Aluminum Materials for Injection Molds<br />

Dave Wirth, Clinton Aluminum<br />

9:30-10:00am Designing Production Aluminum Molds<br />

Greg Eidenberger, Paragon Die & Engineering<br />

10:00-10:15am Break<br />

10:15-10:45am Case Studies of Production Aluminum Tooling<br />

Dave Dickerson: DRS Industries<br />

10:45-11:15am Manifold Considerations (Thermal 2-3d Analysis)<br />

Rich Oles: Plastic Services Group Inc. (PSG)<br />

11:15-11:45am Lessons Learned in Graining and Repair of Aluminum Tooling for Injection Molding<br />

Ron Smierciak: Alcoa<br />

Surface Enhancements<br />

(Moderators: Duane Lewis: ExxonMobil Chemical & Dr. Rose Ryntz: International <strong><strong>Auto</strong>motive</strong> Components)<br />

8:00-8:30am Plenary Presentation: Interior <strong><strong>Auto</strong>motive</strong> Plastic Aesthetic and Performance Trends<br />

Dr. Rose Ryntz: International <strong><strong>Auto</strong>motive</strong> Components<br />

8:30-9:00am Mar Resistance Testing and Evaluation of the Thermoplastic Olefins<br />

Robert Browning, George Wei, & Hung-Jue Sue: Texas A&M University; Kevin Reid: Phillips Sumika<br />

9:00-9:30am Mechanical Modeling of Scratch Induced Periodic Damage<br />

Han Jiang, John Whit<strong>com</strong>b & Hung-Jue Sue: Texas A&M University<br />

Update on Developments for Scratch and Mar Additives: Effect of the Additive Formulation on the Scratch Performance and<br />

9:30-10:00am Other Secondary Attributes<br />

Nikolas Kaprinidis, Per Magnus Kristiansen, Martin Brunner and Johanne Wilson: Ciba Corporation, a part of the BASF Group<br />

10:00-10:15am Break<br />

10:15-10:45am Atmospheric Pressure Plasma: Surface Treatment for Painting without Wet Chemistry<br />

Shaun Glogauer: Plasma Treat North America<br />

10:45-11:15am Latest Developments in Coatings Technology that Provides Striking Appearance and Durability over <strong>TPO</strong><br />

Arjun Dhake: Dhake Industries<br />

11:15-11:45am Study of Scratch Resistance of Polypropylene Blend for <strong>Auto</strong>mobile<br />

Shan Jin, Yonghua Li, Bo Yang, Zhongfu Luo: Kingfa SCI 7 TECH., CO., LTD.<br />

11:45-12:15pm New and Innovative Testing Technologies for Effect Finishes<br />

Greg Shrider and Richard Scott: BYK - Gardner USA<br />

12:15-12:45pm Conventional and Low VOC Bonding Solutions for <strong>TPO</strong>s<br />

Walt Polifka: Adchem Corporation


Sponsors/Exhibitors


Thank you sponsors for your support.


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CONFERENCE


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Other publications which might be of interest to you include...<br />

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The Journal of Materials: Design and Applications covers the usage and<br />

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Americhem, Inc.<br />

155 E. Steels Corners Dr.<br />

Cuyahoga Falls, Ohio 44224<br />

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t h e a d h e s i v e t a p e e n g i n e e r s<br />

1852 Old Country Road<br />

Riverhead, New York 11901<br />

www.adchem.<strong>com</strong><br />

Phone: 631-727-6000<br />

Fax: 631-727-6010<br />

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Job Title: Business Development Manager<br />

Phone: 631-727-6000 X323<br />

E-mail: wpolifka@adchem.<strong>com</strong><br />

<br />

Products & Services:<br />

• Color and Additive Masterbatches<br />

• 100:1 Color Masterbatch<br />

• Scratch & Mar Technology<br />

• Special Effects<br />

• Exterior Paint Replacement Technology<br />

Adchem Corporation manufactures a<br />

<strong>com</strong>plete line of adhesive tape systems,<br />

including double-coated papers, films,<br />

tissues, foams and fabrics; transfer tapes;<br />

single-side-coated products; and other<br />

custom-coated specialty products. Their<br />

100% solids adhesives, solvent acrylics and<br />

solvent rubber adhesives are used in many<br />

different industries, including transportation,<br />

electronic, medical and others.


1062 Fourth Ave<br />

Sidney, OH 45365<br />

Web Site: www.advcmp.<strong>com</strong><br />

Phone: (937) 575-9800<br />

Fax: (937) 492-0306<br />

Contact Name: Brian Williams<br />

Job Title: Marketing Manager<br />

Phone: (937) 575-9800<br />

E-mail: brian.williams@advcmp.<strong>com</strong><br />

321 Brentwood Drive<br />

Reading, PA 19611<br />

WWW.Brentwoodindustries.<strong>com</strong><br />

Phone: 610-376-1900<br />

Fax: 610-736-1209<br />

Contact: David Fry<br />

Sales Manager<br />

610-236-1107<br />

David.fry@brentw.<strong>com</strong><br />

Products & Services:<br />

� Mold-In-Color <strong>TPO</strong> Technology.<br />

� High Impact Polymers (100% ductility at -40°C)<br />

� Seamless Airbag Instrument Panels.<br />

� Bumper Fascia Polymers.<br />

� Low Gloss Interior Polymers.<br />

� High Gloss Exterior Polymers.<br />

� Lightweight Polymers.<br />

� Fast Cycle Time Polymers.<br />

� Technical Services (Processing, Mold-Flow, Tool and Part<br />

Design Re<strong>com</strong>mendations).<br />

______________________________________________________<br />

Custom Thermoform Service<br />

• Heavy gauge thermoforming, Precision CNC<br />

Trimming, materials up to ½” thick<br />

• Light gauge thermoforming, Medical Packaging,<br />

Consumer Packaging, Complete Design Capability


BYK-Gardner USA<br />

9104 Guilford Road<br />

Columbia, MD 21046<br />

Phone 800-343-7721 or 301-483-6500<br />

Fax 800-394-8215 or 301-483-6555<br />

General Email info.BYK.Gardner.USA@altana.<strong>com</strong><br />

Web www.byk.<strong>com</strong>/instruments<br />

Contact Karen Nance<br />

Title Inside Sales Manager<br />

Email Karen.Nance@altana.<strong>com</strong><br />

BYK-Gardner, a worldwide partner of the automotive, paint and<br />

plastic industries, offers quality control instrumentation to measure<br />

color and appearance properties such as metallic and solid color,<br />

gloss, orange peel, DOI and haze. We also provide a full line of<br />

physical testing instruments- applicators and drawdown cards; film<br />

thickness gages; impact, flexibility and hardness testers;<br />

vis<strong>com</strong>eters and more.<br />

Great people. Great products.<br />

Great <strong>com</strong>pany.<br />

Combining existing BASF capabilities with the people, products<br />

and technology acquired with Ciba gives BASF a more powerful<br />

portfolio to help automotive OEMs make their products better.<br />

Great people, great products. The Chemical Company.<br />

Visit us at the <strong>2009</strong> <strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Conference</strong>.<br />

www.basf.us<br />

Light stabilizers<br />

Scratch resistance<br />

additives<br />

Antioxidants<br />

Colorants and<br />

effect pigments<br />

UV absorbers<br />

Antistatic agents<br />

Flame retardants


29111 Stephenson Hwy<br />

Madison Heights, MI 48071<br />

www.DME.net<br />

Contact: Kelly Beauchamp<br />

DME Sales Representative<br />

248-705-4188<br />

kelly_beauchamp@dme.net<br />

Dow Elastomers<br />

4520 E. Ashman St.<br />

9008 Building<br />

Midland, MI 48642<br />

www.dowelastomers.<strong>com</strong><br />

Phone: 800-441-4369<br />

E-Mail: CUSTINFOGRP1@dow.<strong>com</strong><br />

Contact: Customer Information Group<br />

An Essential Mold Technology Resource<br />

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• Hot Runner Service Center<br />

• Mold bases & Plate Items<br />

• Mud Quick-Change Systems<br />

• Mold & Die Components<br />

• Moldflow Analysis<br />

• Heating & Cooling Components<br />

• Control Systems<br />

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• Applications Engineering<br />

• Technical Service<br />

Products & Services:<br />

Dow is delivering solutions to the interior and exterior hard <strong>TPO</strong><br />

industry by enabling:<br />

• Impact strength / toughness / resiliency<br />

• Excellent processability<br />

• Gloss Control<br />

• Paintability<br />

We will introduce the next generation to the ENGAGE TM family –<br />

which will deliver superior performance while meeting your<br />

material and handling needs.


1250 Harmon Road<br />

Auburn Hills, MI 48326<br />

phone: 248-391-6300<br />

www.dowautomotive.<strong>com</strong><br />

Contact: Kelly Pippine<br />

Marketing Manager<br />

248-393-3068<br />

email: kpippine@dow.<strong>com</strong><br />

LyondellBasell Industries Phone: 517-336-2400<br />

2727 Alliance Drive Fax: 517-336-2415<br />

Lansing, MI 48910<br />

http://polymers.lyondellbasell.<strong>com</strong><br />

Dow <strong><strong>Auto</strong>motive</strong> Systems is a leading provider of<br />

polyurethanes, elastomers, films, fluids, adhesives,<br />

emissions solutions and acoustic-management<br />

materials to the global transportation industry. By<br />

working collaboratively with passenger vehicle,<br />

<strong>com</strong>mercial transportation and aftermarket<br />

customers, Dow <strong><strong>Auto</strong>motive</strong> Systems is developing<br />

industry-leading solutions to address a wide range of<br />

critical market needs – increasing energy efficiency,<br />

improving safety and health, reducing exhaust<br />

emissions and enhancing vehicle quality and appeal.<br />

For additional information about Dow <strong><strong>Auto</strong>motive</strong>,<br />

visit www.dowautomotive.<strong>com</strong><br />

Lyondellbasell delivers sustainable value to the automotive industry by offering innovative resins that address customers' most<br />

challenging application requirements.<br />

Be it bumpers, grilles, instrument panels, interior trim, under-the-hood applications or structural parts and body panels – the versatility and<br />

economics of LyondellBasell’s polypropylene creates customer opportunities for cost-effective and innovative design concepts that can enhance<br />

both passenger safety, <strong>com</strong>fort and quality. Our lower density resins can help improve fuel economy and reduce raw material costs.<br />

LyondellBasell’s worldwide network of strategically located supply facilities target uniformity of specifications – wherever in the world<br />

materials are sourced.


Sumitomo Chemical America, Inc Headquarter: 212-572-8200 David Risetter<br />

28175 Haggerty Road Fax: 248-994-7673 General Manager, Petrochemicals Division<br />

Novi, MI 49127 269-921-3354<br />

www.sumichem.<strong>com</strong> drisetter@sumichem.<strong>com</strong>www.espolex.<strong>com</strong><br />

Reaching New heights in <strong>Global</strong> Supply<br />

Sumitomo Chemical’s Petrochemicals & Plastics Division engages in the development, manufacture and sale of a wide range of petrochemical<br />

products, including plastics such as polyethylene and polypropylene; synthetic rubber; and organic chemicals such as propylene oxide and<br />

styrene monomer.<br />

In order to meet the needs of a diverse customer base, our focus is on the development, manufacture and sale of high-performance resins like<br />

Thermoplastic Elastomer and Polymer Alloys as well as concentrating on application development utilizing advanced manufacturing and<br />

application technologies in foamed, extruded and molding applications.<br />

The Sumitomo Chemical Group global network includes production and sales operations in North America, South America, Japan, Europe,<br />

Korea, China, South Asia and Middle East.<br />

ExxonMobil Chemical Company<br />

13501 Katy Freeway<br />

Houston, Texas, U.S.A. 77079<br />

www.exxonmobilchemical.<strong>com</strong><br />

About ExxonMobil Chemical<br />

ExxonMobil Chemical is one of the world’s premier petrochemical <strong>com</strong>panies with manufacturing, technology and<br />

marketing operations around the world. The <strong>com</strong>pany delivers a broad portfolio of products and solutions efficiently and<br />

responsibly, with a <strong>com</strong>mitment to create outstanding customer and shareholder value. ExxonMobil Chemical endorses the<br />

principles of sustainable development, including the need to balance economic growth, social development and<br />

environmental considerations.


1330 Lake Robbins Dr., Ste.400<br />

The Woodlands, TX 77380<br />

Sanjay Patel<br />

734-451-2072<br />

sanjay.patel@fhr.<strong>com</strong><br />

Polypropylene Products<br />

• High impact and low temperature ductility<br />

• High quality zero gap interior trim products<br />

• Stiffness and Impact balanced materials<br />

<strong>TPO</strong> Products<br />

• Cold temperature impact ready<br />

• Energy management designed for HIC and SABIC<br />

• Exterior and underhood capable<br />

Totally "Green" Recovery of Painted Plastic <strong>TPO</strong> Scrap<br />

<strong><strong>Auto</strong>motive</strong> Reactor Grades Products for Demanding<br />

Applications<br />

GPRI offers patented new "green" technology for removing paint from your plastic scrap without material degradation.<br />

Like sprues and risers, recovered plastic is restored to the original pre-painted "as molded" condition and is ready to be<br />

remolded into the "Class A Surface" part as originally intended. All coating colors, including white, are <strong>com</strong>pletely<br />

removed from scrap material with zero material loss and without residual paint adhesion problems. 26 different plastics<br />

and coatings have been successfully processed to date, including "soft touch". Consignment processing service is<br />

available as well as in-plant/in-line systems for high volume producers. The 100% EPA approved, closed loop process<br />

will end your scrap issues and reduce costs. For more information contact: Ron Janik, V.P. of Sales<br />

Ph: 248 522-6929 - Cell: 248 924-4421 - E-mail: r.janik@globlalplasticsrecovery.<strong>com</strong>


IMI Fabi LLC<br />

Second and Marshall<br />

Benwood, WV 26031<br />

WWW.IMIFabi.<strong>com</strong><br />

Phone: 304-233-0050<br />

Fax: 304-232-0793<br />

info@imifabi.<strong>com</strong><br />

2625 N. berkeley Lake Road, Suite 100<br />

Duluth, GA 30096<br />

Web Site: www.Kraiburg-TPE.<strong>com</strong><br />

Phone: 678-584-5020<br />

Fax: 678-584-0500<br />

E-Mail: Info-USA@Kraiburg-TPE.<strong>com</strong><br />

Contact Name Keith W. Dunlap<br />

Job Title: Director, Sales and Marketing<br />

Phone: 678-584-5193<br />

E-mail: Keith.Dunlap@Kraiburg-TPE.<strong>com</strong><br />

Talc Powders for Plastics<br />

Compacted and powder HTP, HM, BT, CH, NB, GT<br />

• IMIFAbI Talc Company, a leading talc manufacturer;<br />

with mining, milling facilities supplying performing talc<br />

grades around the world.<br />

• Headquartered in Milan, Italy, IMIFAbI talc has been<br />

growing over the years to reach an international dimension,<br />

having operations in Europe, the USA, and in Asia, all<br />

equipped with same milling and micronizing processes,<br />

allowing IMIFABI talc to have a unique service: supply<br />

consistent products world wide at local lead time<br />

conditions.<br />

• IMI Fabi Talc Company has invested in various talc<br />

deposits around the word, thus offering diversified talc<br />

grades with million of tons in proven reserves. IMI Fabi is<br />

the right partner for all of your current and future projects.<br />

KRAIbURG TPE Corporation<br />

2625 N. berkeley Lake Road, Suite 100<br />

Duluth, GA 30096 USA<br />

Phone: (678) 584-5020 • Fax: (678) 584-0500<br />

Website: www.kraiburg-tpe.<strong>com</strong><br />

Custom engineered TPE and more…<br />

KRAIBURG TPE manufactures thermoplastic elastomers based on<br />

HSBC (hydrogenated styrene block copolymers) and markets them all<br />

around the world. In addition to custom solutions, the <strong>com</strong>pany offers,<br />

under the THERMOLAST® and HIPEX® brand names, a broad<br />

spectrum of standardized <strong>com</strong>pounds to cover a wide range of<br />

applications. The <strong>com</strong>pany produces at sites in Germany, the US and<br />

Malaysia. KRAIBURG TPE also maintains sales offices in the USA, UK,<br />

France, Italy, Spain, China and India.


Milacron LLC<br />

29111 Stephenson Highway<br />

Madison Heights, MI 48071<br />

Contact: Steve Wood<br />

<strong><strong>Auto</strong>motive</strong> Accounts Manager<br />

Office/cell: 513-702-2197<br />

E-mail: steve_wood@milacron.<strong>com</strong><br />

1403 Port Road<br />

Jeffersonville, IN 47130<br />

www.mytexpolymers.<strong>com</strong><br />

Phone: 812-280-2900<br />

Fax: 812-280-2904<br />

E-Mail: customer_service@mytexpolymers.<strong>com</strong><br />

Contact: Eric Short<br />

Job Title: Sales Manager<br />

Phone: 248-705-2830<br />

E-mail: eric_short@mytexpolymers.<strong>com</strong><br />

Injection Molding Machines<br />

All-Electric, Hydraulic, Multi-Component<br />

6 ton to 6600 ton<br />

Process Support Equipment<br />

Auxiliary equipment, robots and automation systems<br />

Products & Services:<br />

Contract Services<br />

Retrofit controls – 2 nd /3 rd Injection Units<br />

� Major North American Supplier of Interior and<br />

Exterior Advanced Polypropylene Materials.<br />

� Wholly owned by the Mitsubishi Chemical Company.<br />

� 235,000 Square Foot Facility Centrally Located in<br />

Southern Indiana.<br />

� Additional Detroit Based Sales and Technical<br />

Support.<br />

� <strong>Global</strong> Resource Expertise from Strategically Located<br />

<strong>Global</strong> Affiliates.<br />

� Ability to Formulate New Advanced<br />

Products/Precision Formulas for Consistent Quality<br />

Products.<br />

� Commercial & Developmental Compounding Lines.<br />

� A2LA Certified Test Laboratory.<br />

� 24 Hour Customer Service and Technical Support.<br />

� Material Approvals from both U.S. & J.T. OEM’s.<br />

� ISO TS 16949:2002 / ISO 17025


4855 Thirty Seventh St. SE<br />

Grand Rapids, MI 49512-4068<br />

Contact Name: Stu Allen<br />

Job Title: Sales and Distribution Manager<br />

Phone: 616-581-7287<br />

E-mail: stu.allen@noblepolymers.<strong>com</strong><br />

803 Mountain View Dr.<br />

P.O. Box 368<br />

Willsboro, NY 12996<br />

www.ny<strong>com</strong>inerals.<strong>com</strong><br />

Phone: 518-963-4262<br />

Fax: 518-963-4187<br />

E-Mail: info@ny<strong>com</strong>inerals.<strong>com</strong><br />

Contact Name: Gary Phillips<br />

Job Title: VP of Marketing and Application<br />

Development<br />

Phone: 313-388-7241<br />

E-mail: gary.phillips@ny<strong>com</strong>inerals.<strong>com</strong><br />

Products & Services:<br />

Noble Polymers is a custom <strong>com</strong>pounder that provides innovative<br />

solutions to engineering problems.<br />

• Supply Array of Commercial Resins<br />

– Ecobarrier® - soft, highly filled <strong>TPO</strong>’s with recycle<br />

content for sound deadening<br />

– Regis® - rigid, high strength, low shrink <strong>TPO</strong>’s for<br />

exterior trim<br />

– Forte® - PP based nano<strong>com</strong>posites for automotive interior<br />

trim, leisure & recreation, HVAC<br />

– Flextuff® - extrusion grade TPE<br />

• Contract Manufacturing – toll<br />

• Compound Custom Development<br />

– Resins tailored to given application<br />

– Development & testing for individual projects (A2LA<br />

Certified Polymer Laboratory)<br />

• TS 16949 and ISO 14001 certified<br />

NYCO Wollastonite - Proven Reinforcements for<br />

Balancing Costs and Performance<br />

• Improved mechanicals<br />

• Lowers CLTE (no gap)<br />

• Excellent melt strength<br />

• High stiffness with good ductility<br />

• Lower density – thin wall <strong>com</strong>posites<br />

• Improved mar/scratch and gouge resistance<br />

• Odorless, non-dusting


RTM.Plactics.<strong>TPO</strong>.Ad 7/18/08 9:58 AM Page 1<br />

www.riotintominerals.<strong>com</strong><br />

Minerals that make a difference<br />

Solutions that make a difference<br />

4000 Embassy Parkway<br />

Suite 208<br />

Akron, OH 44333<br />

Web Site: http://www.robertellerassoc.<strong>com</strong><br />

Contact: Robert Eller<br />

President<br />

Phone: 330-670-9566<br />

Fax: 330-670-9844<br />

Rio Tinto Minerals is the acknowledged<br />

world leader in developing industrial<br />

minerals, and developing solutions<br />

for customers<br />

• Scratch and Mar Resistance<br />

• Color Control<br />

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Cimpact CB7<br />

Luzenac R7<br />

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Strategies to support autoplastic management<br />

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ShINIL ChEMICAL INDUSTRY<br />

Sihwa Industrial Complex 5Ba-104Ho,<br />

675-4, Sunggokdong, Danwon,<br />

Ansansi, Kyunggido, KOREA<br />

Postal Code : 425-836<br />

http://www.shinil-chemical.net<br />

PJ YOON<br />

R&D Director<br />

pj.yoon@shinil-chemial.net<br />

Phone: +82-31-499-2430<br />

Fax: +82-31-499-1080<br />

E-Mail: shinilchemical@shinil-chemical.net<br />

World Headquarters & Technical Center<br />

1401 Crooks Road<br />

Troy, MI 48346<br />

Insight. Inside. Inteva.<br />

www.intevaproducts.<strong>com</strong><br />

Phone: 248.655.8886<br />

E-mail: info@intevaproducts.<strong>com</strong><br />

Contact Name: Norm Kakarala<br />

Job Title: Senior Technical Fellow<br />

Phone: 249-655-8483<br />

E-Mail: nkakarala@intevaproducts.<strong>com</strong><br />

Products & Services:<br />

SHINCON – Conductive Polymer<br />

SHINSTRA – Engineering Plastic<br />

CNT MASTER BATCH<br />

SHINSTAT – ESD Control Polymer<br />

POLYGLUE – Adhesive Resin<br />

SHINNANO – Nano Polymer<br />

SHINFLAM – Flame Retardant<br />

SPYLON - Thermoplastic Resin<br />

Products & Services:<br />

Inteva has deep roots of more than 90 years as a leading supplier of<br />

Interiors and Closures for leading OEMS around the globe. From<br />

past to present, our innovative excellence helped these systems and<br />

<strong>com</strong>ponents evolve from simply meeting functional needs to fitting<br />

precise buyer lifestyles.<br />

• Interior Systems that meet precise needs for driving<br />

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• Cockpits that raise the bar with <strong>com</strong>plete integration,<br />

assembly, and sequencing services.<br />

• Latch & Closure Systems that embody <strong>com</strong>plexity for<br />

functional simplicity<br />

• Door Modules & Window Lift Systems that reduce costs<br />

and increase reliability


1 Quality Circle<br />

Clinton, TN 37716<br />

Web Site: www.techmerpm.<strong>com</strong><br />

Phone: 865-457-6700<br />

Fax: 865-457-3012<br />

E-Mail: jmurphy@techmerpm.<strong>com</strong><br />

Contact: Jack Murphy<br />

Job Title: Director of Sales .<br />

Phone: 865-457-6700<br />

Techmer PM offers a <strong>com</strong>plete line of<br />

colorant and additive masterbatch<br />

designed for automotive applications.<br />

SWT PC-25 Direct to <strong>TPO</strong> Water Based Coating<br />

The SWT Group Headquarter: 519-967-0020 Stephen Regular<br />

1591 Kildare Rd. Fax: 519-967-1220 Coatings Sales and Technology Manager<br />

Windsor, Ontario, N8W 2W2 519-967-0020, ext 236<br />

www.swtgroup.<strong>com</strong> sregular@swtgroup.<strong>com</strong><br />

SWT PC-25 Direct to <strong>TPO</strong> Water based Coating<br />

SWT has developed a water based coating that adheres directly to <strong>TPO</strong> and polypropylene substrates with no pretreatment. In adhesion testing,<br />

SWT PC-25 had a result of 5B when applied directly to <strong>TPO</strong> and PP while achieving excellent hardness, flexibility, and solvent and humidity<br />

resistance.<br />

The benefits of this coating could provide cost savings and VOC reduction not only to <strong>com</strong>panies already painting <strong>TPO</strong> and polypropylene but<br />

also to <strong>com</strong>panies that would prefer to use these substrates over easier to coat alternatives such as ABS and polyurethanes


CONFERENCE


Material Development


Improving Scratch Performance of Talc-PP and Talc-<strong>TPO</strong> Compounds<br />

Saied H. Kochesfahani* – Rio Tinto Minerals, Denver, CO<br />

Denis Lejour and Frederic Jouffret, Rio Tinto Minerals, Toulouse, France<br />

The scratch performance of talc-PP and talc-<strong>TPO</strong> <strong>com</strong>pounds has been of great interest<br />

especially in automotive interior and exterior applications where appearance plays an<br />

important role in the customer approval of car quality. While polypropylene or <strong>TPO</strong><br />

based automotive parts offer many cost/performance advantages over other materials,<br />

the scratch and mar performance of these products typically does not fulfill all customer<br />

expectations.<br />

Talc offers a great affinity with polypropylene and is, therefore, the reinforcing additive of<br />

choice in many PP and <strong>TPO</strong> <strong>com</strong>pounds, where it significantly improves the rigidity and<br />

dimensional stability of the products. However, the mineral-filled <strong>TPO</strong> <strong>com</strong>pounds still<br />

lack a desirable scratch and mar performance. Significant effort has been focused on<br />

understanding the scratch and mar behavior of plastics and specifically PP based<br />

material in recent years, in which Rio Tinto Minerals has played a pioneering role in<br />

understanding the effect of talc on scratch performance and identifying solutions to<br />

improve the scratch performance of talc-reinforced plastics.<br />

The objective of this study is to conduct systematic scratch performance analyses<br />

utilizing a very large database of talc-PP and talc-<strong>TPO</strong> samples at Rio Tinto Minerals to<br />

understand the effect of talc parameters (particle size, crystalline structure, mineralogy,<br />

etc.) and scratch additives on the scratch performance of talc-PP and talc-<strong>TPO</strong><br />

<strong>com</strong>pounds, and to identify the best performing talc-based formulations for improved<br />

scratch resistance. The newly developed scratch test method at Texas A&M University<br />

and the associated ASTM and ISO standard methods were used in this study to<br />

consistently <strong>com</strong>pare and evaluate the scratch performance of different samples. This<br />

paper presents the results of these analyses and introduces Rio Tinto Minerals current<br />

best solution for improving scratch performance in talc-PP and talc-<strong>TPO</strong> <strong>com</strong>pounds.<br />

*Speaker: Dr. Saied Kochesfahani is Development Manager for polymer applications at Rio Tinto<br />

Minerals. He holds a Ph.D. in Chemical Engineering from the University of Toronto, and has authored or<br />

co-authored about 40 publications. He has been a member of Tappi for over 13 years and joined <strong>SPE</strong> in<br />

2006. Phone: 303-713-5231, Email: saied.kochesfahani@riotinto.<strong>com</strong>.


Abstract<br />

High Performance Reinforcement:<br />

A Pathway to Density Reduction<br />

While Maintaining Physical Properties of Polyolefin Composites<br />

K. David Lake<br />

Milliken Chemical, 920 Milliken Road<br />

Spartanburg, SC 29304<br />

Light-weighting initiatives in the automotive industry continue to be a driving force for the<br />

development of new lower density / higher performance <strong>com</strong>posites. With new CAFE<br />

standards on the horizon along with the continued development of vehicles using<br />

alternative energy sources, the demand for lighter weight and structurally sound<br />

automotive parts may now be at an all time high.<br />

To address this market need, Milliken Chemical is now <strong>com</strong>mercializing a new mineralbased<br />

reinforcing additive for polyolefin <strong>com</strong>posites. This additive, known as HPR (high<br />

performance reinforcement) will serve to <strong>com</strong>plement and surpass Milliken's current<br />

offering of Hyperform® nucleating agents in enabling excellent physical properties with<br />

reduced density as <strong>com</strong>pared to other conventionally filled polyolefins. For instance,<br />

<strong>com</strong>pared to talc-filled polypropylene, HPR will typically provide <strong>com</strong>parable or superior<br />

performance with only about one-third of conventional talc concentrations. Therefore,<br />

part weight reductions up to 15 - 20% may be readily achieved. Supporting illustrations<br />

in this presentation will include <strong>com</strong>parative data in flexural modulus, shrinkage, tensile<br />

strength, impact strength, and heat deflection temperature.<br />

While imparting exceptional flexural modulus properties to polyolefins that rival those<br />

obtained with chopped glass, HPR may also be considered for high stiffness applications<br />

where a superior surface finish is desired. In this regard, examples relating to scratch<br />

resistance, gloss, and surface appearance will also be provided. These <strong>com</strong>bined<br />

attributes may even provide an environment for light-weighting to be considered via thinwalling<br />

of parts that are now made with conventional unfilled polyolefins.


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />

Speaker’s Biography<br />

Name:<br />

David Lake<br />

Title:<br />

Development Associate<br />

Company:<br />

Milliken Chemical<br />

Experience (Brief Summary):<br />

David has been employed by Milliken and Co. since 1983 and for<br />

the last 18 years has worked in Milliken Chemical’s Polymer<br />

Additives business. There he has worked in various roles<br />

including research, technical service, field support, project<br />

management, and applications development. He has developed<br />

extensive expertise in formulating, clarifying, and nucleating<br />

polypropylene and has also gained wide experience in<br />

numerous extrusion and molding processes where<br />

polypropylene articles are fabricated. David has played an<br />

integral role for his <strong>com</strong>pany in the development and<br />

<strong>com</strong>mercialization of key successful clarifiers and nucleators in<br />

the Millad® and Hyperform® product lines. He is currently<br />

involved with Milliken Chemical’s efforts to expand into<br />

reinforcing additives for polypropylene. David is the lead or coauthor<br />

of 7 issued US patents.<br />

Education:<br />

B.S. Chemistry, Presbyterian College – 1983<br />

Industry/Trade Affiliations:<br />

American Chemical Society and Society of Plastics Engineers


DonBeuke@aol.<strong>com</strong> - Technical Consultant 918-914-2947<br />

GO GREEN with MOS Hige Fiber for Light Weighting, Fast Cycle Time,<br />

and Improved Quality <strong>TPO</strong>'s<br />

Donald Beuke with Mitsui Plastics Inc.<br />

ABSTRACT<br />

As gasoline prices, manufacturing and materials continue to rise; automobile manufactures are<br />

turning to parts molded with lighter weight filled <strong>TPO</strong>’s. With the advent of MOS Hige fiber<br />

from Ube and marketed and serviced by Mitsui, molder saves money and car <strong>com</strong>pany achieves<br />

improved quality parts and improved fuel efficiency. 8-10 % of a 70% masterbatch of 0.5x15<br />

micron magnesium oxy-sulfate (MOS) whisker fibers at 70% can be <strong>com</strong>bined with 0-10 % talc to<br />

provide <strong>TPO</strong>’s with:<br />

1) Lower cost molded parts (molder);<br />

a. 15-35% reduction in mold cycle time<br />

b. 10-15% weight reduction<br />

2) Fuel savings (consumer) GO GREEN;<br />

a. Reduced weight = fuel savings<br />

3) Quality Improvements (car <strong>com</strong>pany);<br />

a. Low shrinkage<br />

b. reduction of scratch and mar<br />

c. improved molded-in color (higher color saturation from resin rich surface)<br />

d. high flow resulting in smoother, flatter surface.<br />

e. increased sound absorption for quieter interior parts<br />

Talc filled <strong>TPO</strong> with MOS Hige A Talc filled <strong>TPO</strong> control<br />

PP 73-82 % PP 70%<br />

Tafmer 10% Tafmer 10%<br />

Talc 0-7% Talc 20%<br />

70% MOS fiber MB 8-10%<br />

Density 0.92-.099 Density 1.05<br />

Flex Mod 1600-2,500MPa Flex Mod 2,400MPa<br />

MFR 20-50 g/10min MFR 8.7g/10min<br />

Impact -40c 6.6m/sec to -30c N.Izod Impact -30 N. Izod<br />

Part thickness 2.7 mm Part thickness 3.0 mm<br />

Part weight 7.65 lbs Part weight 9 lbs<br />

Cycle time 45 seconds Cycle time 60 seconds<br />

Fuel savings: $3.24 Fuel savings: 0<br />

Presenter: Don Beuke is on his 35 th anniversary as a Chemist and Engineer in product & market development, sales,<br />

and technical service of plastics and additives. He holds a variety of patents with many of the previous <strong>com</strong>panies he<br />

worked for. These <strong>com</strong>panies are; PPG Coatings and Resins Division, Ciba-Geigy Plastics Additives Dept, Phillips 66<br />

Company Plastics Division, Petrolite Polymers Division, Wed-Tech Compounding (now Ingenia) . He is currently,<br />

employed for over 14 years as a Technical and Marketing consultant exclusively with Mitsui & Co. (USA) Inc. and<br />

Mitsui Plastics Inc.


Improved Glass-fiber Reinforced Polypropylene for Structural Applications<br />

Alberto Prieto, Product and Application Development Engineer<br />

Steve Davis, Customer Project Manager<br />

LyondellBasell Industries<br />

Abstract:<br />

Structural applications are one of the fastest growing segments for polypropylene due to advances<br />

such as long glass fiber reinforcement (LGF). Front-end carriers, instrument panel carriers, and<br />

running boards are all examples of applications where the use polypropylene has been enabled by<br />

LGF. There are several approaches possible for making parts reinforced by LGF, including<br />

conventional <strong>com</strong>pounds or to use a direct injection molding <strong>com</strong>pounder (D-LFT) to <strong>com</strong>pound<br />

at the press. More recently, attention has turned to ways to save cost versus LGF <strong>com</strong>pounds.<br />

LyondellBasell has developed a new generation of short glass fiber reinforced materials with<br />

improved stiffness and tensile strength which have replaced LGF in several applications. These<br />

new developments will be discussed in detail with application examples. LyondellBasell has also<br />

contributed to the advancement of the D-LFT process through the development of high melt flow<br />

rate resins and <strong>com</strong>pounds which are successfully used in the D-LFT processes. This includes<br />

two <strong>SPE</strong> Innovation Award-winning applications.<br />

LyondellBasell Industries’ Hosta<strong>com</strong> EYS 755P <strong>com</strong>pounded polypropylene (PP) resin is being used to<br />

produce the front-end carrier for the Volkswagen Golf/Jetta/Bora platform. This application won the 2007<br />

<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> Innovation Award in the Process/Assembly/Enabling Technology category. The part is<br />

produced by AKsys de Mexico, who uses the Krauss-Maffei Injection-Molding Compounder (IMC)<br />

process. This is the first front-end module in North America to use KraussMaffei’s twin-screw Injection<br />

Molding Compounder (IMC) to mix and mold long glass.<br />

Photo: Society of Plastics Engineers


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong>: Speaker Bios<br />

KRAIBURG TPE Corporation<br />

2625 N. Berkeley Lake Road, Suite 100<br />

Duluth, GA 30096 USA<br />

Phone: (678) 584-5020 • Fax: (678) 584-0500<br />

Website: www.kraiburg-tpe.<strong>com</strong><br />

Custom engineered TPE and more…<br />

KRAIBURG TPE manufactures thermoplastic elastomers based on<br />

HSBC (hydrogenated styrene block copolymers) and markets them<br />

all around the world. In addition to custom solutions, the <strong>com</strong>pany<br />

offers, under the THERMOLAST® and HIPEX® brand names, a<br />

broad spectrum of standardized <strong>com</strong>pounds to cover a wide range<br />

of applications. The <strong>com</strong>pany produces at sites in Germany, the<br />

US and Malaysia. KRAIBURG TPE also maintains sales offices in<br />

the USA, UK, France, Italy, Spain, China and India.<br />

Address line: 2625 N. Berkeley Lake Road<br />

Suite 100<br />

City: Duluth<br />

State/Province: GA<br />

Postal Code: 30096<br />

Web Site: www.Kraiburg-TPE.<strong>com</strong><br />

Phone: 678-584-5020<br />

Fax: 678-584-0500<br />

E-Mail: Info-USA@Kraiburg-TPE.<strong>com</strong><br />

Contact Name Keith W. Dunlap<br />

Job Title: Director, Sales and Marketing<br />

Phone: 678-584-5193<br />

E-mail: Keith.Dunlap@Kraiburg-TPE.<strong>com</strong><br />

High-Performance TPE’s for Stringent <strong><strong>Auto</strong>motive</strong> Applications


High-Performance TPE’s for Stringent <strong><strong>Auto</strong>motive</strong> Applications<br />

John Chiao and Keith Dunlap<br />

Thermoplastic elastomers (TPE’s) have been widely used in the automotive industry for their cost advantages<br />

and performance benefits such as processing versatility and lighter part weight for improved fuel economy.<br />

However However, the the utilization of of TPE’s TPE s in automotive under under-hood hood <strong>com</strong>ponents <strong>com</strong>ponents has been limited limited by the the stringent<br />

requirements of high temperature and medium resistance (oils, fuels, fluids, etc…) Recently, KRAIBURG TPE<br />

has developed an innovative TPE based material technology tailored for these challenging environments and<br />

applications. A series of materials have been launched with properties that were only attainable in the past by<br />

high-performance rubber <strong>com</strong>pounds processed using time-consuming vulcanization. This new generation of<br />

TPE’s, branded as HIPEX ® , , offers similar properties p p of those found in high-performance g p rubber <strong>com</strong>pounds. p<br />

They have <strong>com</strong>bined the ability to withstand temperatures up to 170oC and exhibit chemical resistance to motor<br />

oils, fuels, greases, and coolants. In addition to adhering to polyamide (PA) and polyacetal (POM), HIPEX ®<br />

products demonstrate optimal adhesion to polybutylene terephthalate (PBT), and thus cover most engineering<br />

polymers utilized in the engine <strong>com</strong>partment. The materials show good process-ability under typical<br />

thermoplastic molding conditions. HIPEX ® resins are suitable for a number of applications inside and out outside<br />

th the engine i bbay, iincluding l di seals, l plugs, l caps, gaskets, k t ddrive i bbelts, lt ttubes, b connectors, t hhoses, cables bl and d even<br />

noise and vibration dampening. They can be used as a replacement for acrylic elastomers (ACM) or ethyleneacrylic<br />

elastomers (AEM) and are ideally suited for working temperature performance up to 150oC. This presentation will describe the typical make up of HIPEX ®<br />

and <strong>com</strong>pare p the pperformance of current polymers p y and<br />

technologies used in stringent automotive applications. Finally,<br />

it will <strong>com</strong>pare those polymers in a cost vs. benefit analysis of<br />

materials targeted for rubber replacement, higher cost<br />

polymeric material replacement, processing ease, and need for<br />

secondary operations.<br />

We thank you in advance for your consideration.<br />

Kraiburg TPE Corporation 2625 N. Berkeley Lake Road, Suite 100, Duluth, GA 30096


Keith W. Dunlap, Director of Sales and Marketing, KRAIBURG TPE<br />

Keith has over 15 year experience in the plastics industry with executive level management experience in global<br />

markets with <strong>com</strong>panies that produced and distributed engineering thermoplastic resins, films and sheet systems,<br />

processed plastics for automotive, medical, consumer and industrial applications and <strong>com</strong>pounded elastomeric<br />

materials for specific application requirements. He has held positions of increasing responsibility for <strong>com</strong>panies that<br />

include GE Plastics, Bayer’s Polymers Division, Porex Corporation and KRAIBURG TPE. He is a graduate of Northern<br />

Illinois University in Engineering and has <strong>com</strong>pleted post graduate MBA work at the University of New Hampshire in<br />

addition he holds a minor in Graphic Arts and has business leadership and marketing certifications from the John F.<br />

Welch Leadership Development Center at Crotonville, NY. Keith resides in Atlanta, GA and has a son of 11 years.<br />

John J. Chiao PHD, Senior Scientist, KRAIBURG TPE<br />

Dr. John Chiao manages the quality and development department at KRAIBURG TPE. His daily responsibilities range<br />

from developing new TPE formulations for consumer, industrial and automotive applications, to providing technical<br />

services for worldwide customers. Dr. Chiao has over 11 years of industry experience in specialty chemicals, resins<br />

and polymeric materials. Prior to joining KRAIBURG TPE, he worked as a senior scientist with Cytec Specialty<br />

Chemicals and R&D manager with Tesa Tape. Dr. Chiao has co-authored more than 25 technical publications and<br />

patents on TPEs, UV/EB curable resins, pressure sensitive adhesives, nano<strong>com</strong>posites, and conducting polymers. He<br />

holds a Ph.D. in polymer chemistry from Michigan State University, an MBA in Financial Management from Georgia<br />

State University, and a B.S. in polymer science from Nanjing University (China). John lives in Marietta, GA with his<br />

wife and two children.


Abstract:<br />

Polypropylene Property Modification using Vistamaxx Specialty<br />

Elastomers and Exact Plastomers<br />

Felix Zacarias<br />

ExxonMobil Chemical Company<br />

388 South Main Street<br />

Akron, OH 44311<br />

330-849-5159<br />

This paper presents the basic principles of modifying the properties of polypropylene (PP) using<br />

Vistamaxx specialty elastomers (propylene specialty elastomers) and Exact plastomers in applications<br />

requiring impact modification and flexibility. Although both can be used to gain these properties, the precise<br />

physical properties obtained can be significantly different due to their level of <strong>com</strong>patibility with PP. A<br />

study of different blends of each polymer with PP resin was examined and a side by side <strong>com</strong>parison of the<br />

key properties reported. By using this <strong>com</strong>parison, the <strong>com</strong>pound or dry blend can be optimized by using the<br />

correct polymer selection to meet specific application needs. The results from this work will provide<br />

re<strong>com</strong>mendations on material selections for <strong>com</strong>pounding applications when using propylene specialty<br />

elastomers and plastomers.<br />

Applications Technology Development Engineer<br />

email: felix.zacarias@exxonmobil.<strong>com</strong><br />

phone: 330-849-5159


New Higher Impact Efficiency Elastomers for High Performance Rigid <strong>TPO</strong>s<br />

Kim L. Walton 1 , Mark Berard 1 , Theresa Hermel-Davidock 1 , Phillip Hustad 1 ,<br />

Jim Hemphill 1 , Didem Oner-Deliormanli 1 , Russell Barry 2<br />

Dow Elastomers<br />

The Dow Chemical Company<br />

1 Freeport, TX 77541<br />

2 Horgen, Switzerland<br />

Specifications for rigid <strong>TPO</strong>’s continue to evolve. In a recent Voice of the Customer<br />

survey along the <strong>TPO</strong> <strong>com</strong>pound value chain, the interviewees indicated that new rigid<br />

<strong>TPO</strong> specifications will call for an increase in flexural modulus with no change in lowtemperature<br />

impact resistance. Thus, <strong>TPO</strong> suppliers face increasing challenges to find<br />

the right <strong>com</strong>bination of polypropylene, impact , and reinforcing agent to meet ever more<br />

demanding performance requirements.<br />

A new family of high efficiency impact modifiers has been developed to meet these<br />

increasing demands. The new impact modifier exhibits 15 – 20% higher impact<br />

efficiency than best-in-class, <strong>com</strong>mercial ethylene/1-octene copolymers (EO). It exhibits<br />

equivalent low-temperature, high-speed dart impact efficiency as styrene/ethylene-1butene/styrene<br />

block copolymers with 15% higher modulus in <strong>TPO</strong> at equivalent levels.<br />

Characterization and performance of this new class of impact modifiers will be discussed.<br />

IDI@ -30C, % ductile<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

New Impact Modifier<br />

1700 1800 1900 2000 2100 2200<br />

Chord Modulus, MPa<br />

0.5 dg/min, 0.863 g/cc EO<br />

6.7 m/s dart speed<br />

Figure 1 Comparison of new impact modifier with <strong>com</strong>mercial EO elastomer used in<br />

rigid, reactor-<strong>TPO</strong> <strong>com</strong>pound


Kim L. Walton Biography<br />

Kim Walton received his Bachelor of Science degree in Polymer Science from the<br />

University of Southern Mississippi and his Master of Science degree in Macromolecular<br />

Science from Case Western Reserve University. From 1983 – 1996, Mr. Walton worked<br />

for The Dow Chemical Company in a variety of applications including chlorinated<br />

polyethylene for single ply roofing and vinyl siding impact modification, biaxially<br />

oriented polyethylene film and ethylene/1-octene copolymer based cross-linked foams.<br />

He joined DuPont Dow Elastomers L.L.C in 1996 where his development focus was on<br />

Engage® for flexible automotive interior applications, blow molding, and<br />

thermoforming. He rejoined Dow in July, 2005 and is leading the technical development<br />

for polyolefin elastomers and plastomers. He is a senior member of the Society of<br />

Plastics Engineers. He is an author or co-author of ten patents and twenty two outside<br />

publications.<br />

Contact Information<br />

Kim L. Walton<br />

Dow Elastomers<br />

The Dow Chemical Company<br />

2301 Brazosport Blvd., B-1470<br />

Freeport, TX 77541<br />

Phone: 979-238-3466<br />

Fax: 979-238-0235<br />

email: klwalton@dow.<strong>com</strong>


Abstract:<br />

Low Density <strong>TPO</strong> Development for <strong><strong>Auto</strong>motive</strong> Exterior and Interior Applications<br />

Todd Glogovsky<br />

LyondellBasell Industries<br />

An increase in public awareness regarding environmental issues backed by State and Federal<br />

Agencies has influenced consumers purchasing behavior and North America Businesses.<br />

Federal and State sponsored limits on carbon emissions through initiatives such as “Cap and<br />

Trade” are impacting the North American <strong><strong>Auto</strong>motive</strong> Industry. These initiatives have spawned<br />

new technology developments to meet new environmental requirements. Weight reduction<br />

targets will provide benefits of piece part cost, transportation cost, and environmental saving<br />

which can be applied to the business’s best interest. LyondellBasell Industries has utilized new<br />

catalyst and <strong>com</strong>pounding technologies to develop novel polymers and polymer blends with<br />

equal or better mechanical performance and dimensional control while providing significant<br />

weight reductions. These technologies are being applied to the design of plastic resins for <strong>TPO</strong><br />

exterior and interior <strong>com</strong>ponents. This presentation will summarize these activities.


Breaking New Ground with Thermoplastic Polyolefin Body Panels<br />

Neil Fuenmayor, Customer Project Manager<br />

Todd Glogovsky, Technical and Marketing Manager<br />

LyondellBasell Industries<br />

Abstract:<br />

Thermoplastic Polyolefins (<strong>TPO</strong>s) are <strong>com</strong>monly used for automotive exterior<br />

applications like bumper fascia for their light weight and excellent cost/performance<br />

balance versus other engineering thermoplastics. Improvements in <strong>TPO</strong> stiffness/impact<br />

balance and reduced coefficient of linear thermal expansion (CLTE) have enabled <strong>TPO</strong> to<br />

be considered for vertical body panel applications such as fenders, tailgates, and roof<br />

spoilers. This paper will examine the state of the art of <strong>TPO</strong> materials suitable for body<br />

panel applications and give specific application examples, such as the Ford Kuga<br />

illustrated below.<br />

LyondellBasell Industries’ Hifax TRC 280X <strong>com</strong>pounded polypropylene (PP) resin is<br />

being used to produce the tailgate outer panel and the roof spoiler for the Kuga, Ford’s<br />

new European crossover model. It is the first time Ford in Europe has used an advanced<br />

polyolefin in a body panel application.<br />

Photo: Ford Motor Company


Strain Hardening of Polypropylene-Clay Nano<strong>com</strong>posite Melts in Uniaxial<br />

Extensional Flow<br />

Tanmay Pathak* and K. Jayaraman<br />

Dept. of Chemical Engineering and Materials Science, Michigan State University<br />

Strain hardening of polymer melts in elongational flow is important for a<br />

variety of polymer processing operations such as thermoforming, foaming and blow<br />

molding. It is well known that linear polypropylene does not strain harden in melt<br />

extensional flow. The effect of dispersing two different organoclays at different levels<br />

in linear polypropylene on the transient uniaxial extensional viscosity has been<br />

investigated in this work. The matrix polymer was a linear polypropylene grafted with<br />

maleic anhydride (PP-g-MA); two different grades of organoclay with different ionic<br />

surfactants were used as filler. The neat PP-g-MA matrix did not show any strain<br />

hardening at different extensional strain rates. The nano<strong>com</strong>posite melt with (I.44P)<br />

organoclay exhibited significant level of strain hardening at several extensional strain<br />

rates whereas the nano<strong>com</strong>posite melt with (I.30P) organoclay showed much lesser<br />

strain hardening at those extensional rates, as can be seen in Figure 1. The I.44P clay<br />

has a quaternary ammonium ion surfactant with two C-18 tails as <strong>com</strong>pared to I.30P<br />

clay which has a primary ammonium ion surfactant with single alkyl tail. The extent<br />

of strain hardening for the nano<strong>com</strong>posites was also investigated based on several<br />

other factors such as the amount of maleic anhydride in matrix and its molecular<br />

weight, the clay loading, and also the effect of melt temperature.<br />

η E + (Pas)<br />

1.0E+07<br />

1.0E+06<br />

1.0E+05<br />

1.0E+04<br />

150°C<br />

1.0E+03<br />

Neat PP-g-MA<br />

1.0E+02<br />

1.0E+01<br />

0.1 s-1<br />

0.5 s-1<br />

1.0 s-1<br />

2.0 s-1<br />

0.01 0.1 1 10 100<br />

t (sec)<br />

X 100<br />

X 10<br />

5 wt% I.30P clay<br />

5wt% I.44P clay<br />

Fig 1: Uniaxial melt extensional viscosity: Neat PP-g-MA shows no strain hardening;<br />

Nano<strong>com</strong>posite with 5wt% I.30P clay shows lesser strain hardening, and the one with<br />

5wt% I.44P clay shows significant strain hardening.<br />

*Speaker: Tanmay Pathak is a graduate student at Michigan State University. He<br />

holds a B.E degree in Chemical Engineering and is currently pursuing a doctoral<br />

degree in Chemical Engineering at Michigan State University under the guidance of<br />

Dr K. Jayaraman.


Unique flow of polypropylene at the weld line behind an obstacle in injection molding<br />

Yutaka Kobayashi, 1,3 Gensei Teramoto, 1 Toshitaka Kanai 2,3<br />

1 Prime Polymer Company, Limited, Sodegaura-City, Chiba 299-0265, Japan<br />

2 Idemitsu Kosan Company, Limited, Ichihara-City, Chiba 299-0193, Japan<br />

3 Graduate School of Natural Science & Technology, Kanazawa University, Kanazawa-City,<br />

Ishikawa 920-1192, Japan<br />

Abstract<br />

This paper deals with weld line of metallic mold-in-color polypropylene behind an obstacle in<br />

an injection molded plaque. Broad uneven gloss section was observed visually along weld line<br />

after disappearing V-notch weld. Generally, disk-shaped metallic pigments were oriented<br />

parallel to the wall by laminar flow. The pigments at the weld behind an obstacle were ordered<br />

vertically at the core zone in the plaque. When the pigments were eliminated from PP, black line<br />

was observed at the same position of the metallic weld. From the measurement of crystal<br />

structure, black line was caused by rapid cooling of molten resin. Although an irregular flow<br />

pattern was not simulated by a flow analysis, it was suggested that elongational flow occurred<br />

along weld line after fading away V-notch weld. The unique flow made order the pigments<br />

obliquely at the advancing flow-front and disturb the subsequent flow of hot resin which<br />

transferred heat to the crystallizing place.<br />

Short biography<br />

Yutaka Kobayashi is a senior research associate in Prime Polymer Co. Ltd,.(a joint<br />

<strong>com</strong>pany of Mitsui Chemical and Idemitsu Kosan (Japan)). He entered Idemitsu in 1985.<br />

He has been developing Polypropylene (PP) <strong>com</strong>pounds in Prime Polymer since 2005<br />

and studying in a doctoral program of Kanazawa University (Japan) since <strong>2009</strong>. He<br />

specializes in morphology of PP induced by injection molding.


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong><strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />

Speaker’s Biography<br />

Name: Yutaka Kobayashi<br />

Title: Senior research associate<br />

Company: Prime Polymer Co. Ltd,.<br />

(a joint <strong>com</strong>pany of Mitsui Chemical and Idemitsu Kosan (Japan))<br />

* Present: Senior researcher & senior manager<br />

Advanced Composites, Inc.<br />

1062 S Fourth avenue, Sidney, OH 45365<br />

Experience (Brief Summary):<br />

<strong>2009</strong> July: Advanced Composites, Inc.<br />

2005 April: Prime Polymer Co., Ltd.<br />

1985 April: Idemitsu Kosan Co., Ltd.<br />

I has been developing Polypropylene (PP) <strong>com</strong>pounds for 24 years. I<br />

specialize in morphology of PP induced by injection molding.<br />

Education:<br />

<strong>2009</strong>- A student in a doctoral program of Kanazawa University<br />

(Japan)<br />

1985; Graduate Gumma University (Japan), MS<br />

1982; Graduate Gumma University (Japan), BA<br />

Industry/Trade Affiliations:


Special Session


About the Instructor<br />

Shane Vandekerkhof<br />

Shane Vandekerkhof joined the RJG Team in 2003 as a member of the Customer Support team, where he quickly<br />

gained knowledge and understanding of RJG’s systems and hardware. He quickly became qualified to conduct on-site<br />

training for RJG customers that included hands-on training on RJG’s software and equipment.<br />

After two years Shane took on the role of Business Development for Europe where he was responsible for creating new<br />

accounts, supporting existing accounts, and working with sales representatives. He traveled extensively during this<br />

period to lay the groundwork for RJG to expand into this region. He established contacts and researched the area for<br />

further expansion.<br />

Shane is currently one of RJG’s Trainer/Consultants. His background, knowledge and abilities made the transition into<br />

this role an easy one. His responsiblities include teaching RJG Systematic courses as well as Master Molder<br />

Certification courses. Shane’s quick grasp of molding essentials have made him a valuable member of the RJG Team.<br />

Before <strong>com</strong>ing to RJG Shane attended Michigan State University, Davenport University, and Northwestern Michigan<br />

College where he studied Computer Information systems.<br />

What some of Shane’s students had to say about their training:<br />

“Course had excellent content which is applicable in a real world setting – not just textbook – instructor was<br />

enthusiastic and presented great real world examples.” Jerry Driscoll – Panduit<br />

“A clear, systematic approach to a very interactive process. RJG’s use of training & techniques coupled with<br />

technology make them a world class partner.” Stephen Balsam – L&L Products<br />

“Great job of breaking the process down to easy to understand pieces.” Chris Benbow –Flextronics<br />

RJG, Inc. ~ 3111 Park Drive ~ Traverse City, MI 49686 USA ~ Phone: 231-946-3111 ~ Fax: 231-947-6403 ~ Web: www.rjginc.<strong>com</strong>


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />

RJG Special Session – 4 hrs, including video lab demonstration<br />

Session Title: Injection Molding & Advanced Process Control<br />

Session Moderator: David Okonski – General Motors<br />

Session Presenter: Shane Vandekerkhof – RJG, Inc<br />

Description: Special session on advanced process control and trouble-shooting for the<br />

injection-molding process to help participants achieve a <strong>com</strong>petitive<br />

advantage in the global market.<br />

Session Content (via PowerPoint media/presentation):<br />

• Polymer Basics<br />

o Overview of Polymerization – focus on polypropylene (PP) and<br />

polyethylene (PE) and the <strong>com</strong>pounding of PP and PE into a <strong>TPO</strong> alloy<br />

o Commonly used fillers/reinforcements and their effects on the material<br />

properties – such as strength and impact – of <strong>TPO</strong><br />

o Effect of polymer chain variation on morphology:<br />

� Molecular weight / molecular weight distribution<br />

� Polymer viscosity and its impact on the injection-molding process<br />

• Decoupled Molding Strategies – define “Decoupled Molding”<br />

o Define the basic benefits of a Decoupled I Process<br />

o Define the basic benefits of a Decoupled II Process<br />

o Define the basic benefits of a Decoupled III Process<br />

o Define and discuss the underlying principles of “Scientific Injection<br />

Molding for (Advanced) Process Control”<br />

• Troubleshooting the Injection-Molding Process<br />

o Discuss cause/effect of some <strong>com</strong>mon defects:<br />

� Relate material variation (lot-to-lot and mat’l-to-mat’l) to defects<br />

� Relate machine variation to defects<br />

� Relate tool variation to defects<br />

o Defect focus (proceeding from simple to the more advanced):<br />

� A general discussion of Shorts, Flash, & Sink<br />

� Surface defects – such as gloss, tiger striping and gate blush – for<br />

an as-molded, non-grained & grained, class A interior part<br />

� Minimize dimensional variations due to warp for a body-side<br />

cladding<br />

� Minimize the effect of residual stress on the impact properties of a<br />

fascia<br />

Lab demonstration via internet video link to RJG Laboratory in Traverse City, Michigan<br />

• Demo of current eDART (process monitoring) system<br />

• Live troubleshooting lab<br />

o Produce defects and interact with attendees on possible causes<br />

o Verify root causes using eDART system


Application Development


Robert Eller Associates LLC<br />

CONSULTANTS TO THE PLASTICS AND RUBBER INDUSTRIES<br />

TECHNICAL / ECONOMIC / MARKET ANALYSIS & MANAGEMENT DECISIONS<br />

4000 Embassy Parkway · Suite 208 · Akron, OH 44333-8328 USA<br />

Phone 330-670-9566 / Fax 330-670-9844<br />

E-mail: bobeller@robertellerassoc.<strong>com</strong> / Home Page: http://www.robertellerassoc.<strong>com</strong>/<br />

Effects of the <strong>Global</strong> Economic Situation on <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong>s<br />

Robert Eller<br />

Abstract: The global recession has severely impacted automotive markets and demand for automotive<br />

<strong>TPO</strong>s. The recent uptick in the market is promising, but the automotive plastics paradigm and the<br />

associated supply chain have shifted. This new paradigm is creating opportunities for increased<br />

demand for automotive <strong>TPO</strong>s driven by fuel economy requirement shifts, increased emphasis on<br />

weight reduction, increased modular construction and the demand for global vehicle platforms. The<br />

new paradigm offers <strong>TPO</strong> opportunities in:<br />

- Advanced battery applications<br />

- New applications associated with polyolefin-based <strong>com</strong>posites (both mineral filled and advanced<br />

long fiber reinforced)<br />

- Exterior panels<br />

- A new generation of absorption <strong>com</strong>ponents<br />

- Multi-shot molded <strong>com</strong>ponents<br />

- An expanded range of soft touch applications<br />

This paper explores the macroeconomic shifts associated with the global recession and the impacts on<br />

automotive demand, the supply chain, and opportunities for <strong>TPO</strong>s in the new automotive plastics<br />

paradigm.<br />

r/mydox/<strong>SPE</strong> <strong>TPO</strong> <strong>2009</strong>/Abstract REA <strong>SPE</strong> <strong>TPO</strong> <strong>2009</strong>.doc


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong><br />

Oct 5 – 7, <strong>2009</strong><br />

<strong>TPO</strong> Development for the 2010 and Beyond<br />

Sassan Tarahomi<br />

IAC North America<br />

ABSTRACT 1<br />

2008 was a wake-up call to all of us in the automotive industry, especially the material engineers and<br />

purchasing managers who were shocked by crude oil price rising to $145 per barrel. We all knew chemicals<br />

derived directly from crude oil such as Ethylene, Propylene, Butylenes, Butadiene and so many others would<br />

follow oil price and eventually their prices sky rocketed to new highs. In the summer and fall of 2008<br />

Polypropylene price was hovering around $1.00 /lb which in turn forced <strong>TPO</strong> prices to go up as well.<br />

Do we need more refineries to process more oil to lower resin cost?<br />

Well, in early 1980’s, there were about 300 refineries in the U.S with a <strong>com</strong>bined capacity of 18 million barrels<br />

of oil per day. Now, with great improvement in our efficiency we have only 149 refineries producing same amount<br />

of oil per day as 30 years ago.<br />

Why don’t we build more refineries?<br />

New refineries require tremendous financial <strong>com</strong>mitments which take anywhere from 20 to 30 years to<br />

amortize. With record oil prices in the last year or so, it would make perfect sense to invest in building new<br />

refineries. Then why, there hasn't been a new refinery built in the US since 1976. Answer is oil is depleting at a<br />

very fast rate, there would not be any oil to refine 20 years from now, and therefore building new refineries would<br />

not make sense, because there won't be enough oil left to refine by the time new refineries could pay for<br />

themselves. Answer is not more refineries.<br />

The objective of this paper is to closely examine key factors effecting <strong>TPO</strong> price in the next several decades<br />

and to provide a guideline for developing new <strong>TPO</strong> resins for <strong><strong>Auto</strong>motive</strong> and other industries.<br />

1 Author: Sassan Tarahomi, Material Eng. Manager, IAC N.A., Dearborn, Michigan


Over-Molding New Cost Effective Soft Touch TPV on Polypropylene<br />

Substrates with Improved Surface Durability, Soft / Dry Feel, and High<br />

Temperature Resistance.<br />

Jeffrey Valentage and Hermann-Josef Holz ExxonMobil Chemical Company<br />

<strong>Global</strong> <strong><strong>Auto</strong>motive</strong> Marketing, Polymers<br />

Abstract:<br />

The perceived quality of the vehicle interior is dominated by the “look” and “feel” of the<br />

interior surfaces. A broad range of materials with different levels of perceived quality is<br />

currently used. The products range from injection molded neat PP on the low end up to<br />

assembled multi-layer structures with thermoformed skins or leather for luxury vehicles.<br />

2-Component injection molding (2-K) allows the construction of an all polyolefinic<br />

system consisting of a stiff PP substrate for carrying load and a grained thin top-layer<br />

skin to give improved <strong>com</strong>fort.<br />

A new Santoprene TM TPV product has been developed for 2K molding a soft touch skin<br />

over polypropylene based substrates. The new TPV product offers several performance<br />

advantages, which include:<br />

- High flow for ease of molding a thin skin layer<br />

- Product stability over a broad temperature range<br />

• Maintains dry soft feel<br />

• Minimal gloss change<br />

- High Durability: scratch, mar and abrasion resistance<br />

- Low emissions<br />

- Provides system cost savings while improving the interior appeal: Eliminates the<br />

needed for secondary steps such as soft touch paint or a separate skin/foam laminate<br />

The presentation will focus on the aforementioned performance attributes of the new<br />

product and review the advantages / disadvantages of the various overmolding techniques.<br />

Speaker: Jeffrey Valentage has been involved in the plastics automotive industry for<br />

over 20 years. He began his career as a Process/Project Engineer and Manufacturing<br />

Manager at a major plastics molder, joined the ExxonMobil Chemical-<strong><strong>Auto</strong>motive</strong><br />

Business Unit, Farmington Hills, MI in 1997, and served as an Applications Engineer and<br />

OEM Account Manager. Jeffrey is currently focusing on global automotive marketing<br />

for polymers at the ExxonMobil Chemical Headquarters in Houston, TX. Jeffrey holds a<br />

BS degree in Business Administration from the University of Phoenix.<br />

jeff.valentage@exxonmobil.<strong>com</strong>


Digital Color Solutions for <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> Applications<br />

Jim Harper, Techmer PM, Clinton, TN<br />

Nearly every vehicle system is envisioned and evaluated using virtual, <strong>com</strong>puter-aided imaging tools.<br />

<strong><strong>Auto</strong>motive</strong> parts subject to critical color evaluation, however, have been excluded from the <strong>com</strong>puter<br />

revolution. The nuances of color, its subjective nature, metamerism, textural effects and the like, have<br />

caused development to proceed through a tedious sample-making and visual approval process, only to<br />

converge on a set of <strong>com</strong>promised colors. Digital tools and color development processes now exist to<br />

accelerate the master approval process. The objective of the paper is to describe and illustrate the<br />

advantages of digital color development as a precursor to physical sample making.<br />

<strong>TPO</strong> color, molded in various grains, represents one subset of the overall interior color. Since the color<br />

development plaque issued by an OEM is typically an injection-molded part, <strong>TPO</strong> color matching is<br />

usually straightforward. Obtaining parts approval may be somewhat more <strong>com</strong>plicated since the final<br />

part might be adjusted for lightness/darkness due to grain, lighting, and viewing angles used to<br />

subjectively evaluate the part.<br />

Other <strong>com</strong>ponents, textiles for example,<br />

are dissimilar to the master plaque in<br />

many ways. As thin-section parts,<br />

frequently colorants used in the master<br />

plaque cannot be used in textiles due to<br />

lightfastness considerations. The textile<br />

texture is dramatically different from the<br />

master plaque and every submission is an<br />

interpretation or a guess as to what the<br />

appearance group is trying to achieve. At<br />

the end of the process all of the interior<br />

parts are mutually <strong>com</strong>pared and must<br />

have the same hue in three illuminants.<br />

Obtaining the final, critical match for<br />

every <strong>com</strong>modity that meets the<br />

approver’s subjective standard is difficult.<br />

Digital development, using real-world colorants as the basis for mathematical color modeling, is able to<br />

harmonize color at the front of the process. Color is applied digitally to the various interior textures and<br />

provides the <strong>com</strong>munication interface to evaluate color formulations before samples are made.<br />

Afterwards, a preliminary set of physical samples based on a digital approval can verify color, harmony,<br />

and weathering performance--all at the beginning of the mastering process.


STRUCTURE-PROPERTY RELATIONSHIP STUDY OF NOVEL<br />

METALLOCENE-BASED R-<strong>TPO</strong> FOR INTERIOR PARTS<br />

By Shouichi Fukunaga 1 , Kenji Matsuoka 1 , Kouichi Honda 1 , Kiyoshi Yukawa 2 , and<br />

Motoko Ito 3<br />

1<br />

Japan Polypropylene Corporation, Product Technical Center 1<br />

2<br />

Japan Polypropylene Corporation, Polymerization Technical Center<br />

Toho-cho 1, Yokkaichi, Mie 510-0848, Japan<br />

3<br />

Japan Polypropylene Corporation, Marketing & Overseas Business Group, Sales &<br />

Marketing Division<br />

4-14-1,Shiba, Minato-ku, Tokyo 108-0014, Japan<br />

Abstract<br />

<strong>TPO</strong>s have be<strong>com</strong>e increasingly popular for manufacturing automotive exterior and<br />

interior parts mainly because of their many apparent advantages, including light weight,<br />

recyclability, productivity, low cost, etc. For interior parts applications, <strong>TPO</strong>s are<br />

expected to replace PVC and PU foam materials if further improvements in <strong>TPO</strong><br />

properties, such as softness, gloss, grain retention, stickiness, abrasion, and scratch<br />

resistance, can be made. To address the above challenges, JPP has recently developed an<br />

advanced metallocene catalyst technology for our original gas-phase HORIZONE<br />

process to produce a series of novel R-<strong>TPO</strong>s that possess unique property attributes<br />

unmatched by conventional Z-Nat R-<strong>TPO</strong>s. In this presentation, we will highlight the<br />

attractive physical and mechanical properties of a series of soft R-<strong>TPO</strong>s and show their<br />

p otentials for automotive interior parts applications.<br />

Stickiness<br />

(Anti-Bleed out<br />

Good<br />

Property)<br />

Low Temperature<br />

Resistance -40<br />

(Tg:°C)<br />

Flexural Modulus (MPa)<br />

0<br />

-20<br />

Bad<br />

Worse<br />

0<br />

80<br />

100<br />

120<br />

140<br />

200<br />

400<br />

600<br />

800<br />

80<br />

Heat resistance<br />

(Tm:°C)<br />

40<br />

80<br />

Charpy Impact<br />

Strength(23 °C)<br />

(kJ/m2 Charpy Impact<br />

Strength(23 °C)<br />

(kJ/m ) 2 )<br />

60<br />

40<br />

20<br />

Transparency<br />

(Haze:%(2mm sheet))<br />

WELNEX ® WELNEX ®<br />

Conv. R-<strong>TPO</strong>(RCP Base)<br />

Conv. R-<strong>TPO</strong>(Homo Base)<br />

Fig. 1. Schematic Showing Physical Property Differences of the Novel Metallocene R-<strong>TPO</strong><br />

WELNEX TM Against Conventional R-<strong>TPO</strong>s.


Superior Appearance Material in Airbag Cover Applications<br />

Dr. Nadeem Bokhari<br />

<strong>Auto</strong>liv North America<br />

Kousuke Ohtani<br />

Tetsuya Hisayama<br />

Noboru Yamaguchi<br />

Sumitomo Chemical Co., Ltd.<br />

Abstract:<br />

Airbag covers in automotive applications require a specific rigidity in applications such as in<br />

driver and passenger airbag systems. One key criteria used in evaluating materials has<br />

been their impact strength at low temperature deployments without breaking or tearing<br />

beyond the tear seam design. In addition to this performance criteria, the molded part must<br />

provide good cosmetics since it is clearly visible to the occupants inside the vehicle. To<br />

balance such diversified requirements, olefinic elastomer-based <strong>TPO</strong> and styrenic<br />

elastomer-based TPS have been used in these applications.<br />

Currently, the incumbent technologies have been challenged in trying to satisfy both<br />

performance and cosmetics when producing a non-painted cover. The challenge is trying<br />

to maintain part performance and low gloss through the tear seam where most cosmetic<br />

defects occur. Areas of high or uneven gloss require manufacturers to cover these defects<br />

with paint in order to pass the visual quality requirements of their customers.<br />

Under such circumstances, the authors have developed a new material technology that<br />

delivers the cosmetic requirements on non-painted airbag covers while maintaining the most<br />

demanding performance requirements in cold temperature deployments.<br />

Dr. Nadeem Bokhari<br />

<strong>Auto</strong>liv North America, American Technical Center<br />

TEL: 248-276-7853, FAX: 248-475-9835<br />

E-mail: nadeem.bokhari@autoliv.<strong>com</strong><br />

Sumitomo Chemical Co., Ltd. Petrochemicals Research Laboratory<br />

TEL: +81-436-61-5352, FAX: +81-436-61-5344<br />

E-mail: ohtanik2@sc.sumitomo-chem.co.jp


Optimization of Scratch Resistance for Molded in<br />

Color (MIC) Interior <strong>TPO</strong> Injection Molded Plastics<br />

Abstract<br />

Renee Hotton<br />

General Motors Corporation<br />

As customer dissatisfaction with interior trim pieces is tracked by the JDPowers question<br />

on surface durability there is a need to increase the surface durability of the molded in<br />

color parts. In particular, door lowers are parts that are susceptible to scratching those<br />

results in a poor surface appearance.<br />

An assessment of the various parameters that can affect surface durability was conducted<br />

using talc filled <strong>TPO</strong> materials to determine the optimum set. The following P – diagram<br />

shows the control factors, noise factors, and the outputs used for the evaluation.<br />

Control Factors:<br />

Grain<br />

Gloss<br />

Material<br />

Color<br />

Interior Trim Plaque<br />

Noise Factors:<br />

Molding Condition<br />

Aging<br />

Piece to Piece (Test to Test)<br />

Outputs:<br />

Erickson Score<br />

(STB)<br />

The presentation will include a detailed description of the Design for Six Sigma<br />

methodology used, the factors that were evaluated and the test results that were obtained.<br />

The interpretation of the test results relative to the optimization direction will also be<br />

discussed.<br />

Speaker: Renee Hotton is a Materials Engineer in the Material and Corrosion<br />

Engineering Department at General Motors Corporation. Her current responsibility is in<br />

Interior Plastics for a variety of programs. Renee has a Bachelor of Science Degree in<br />

Chemical Engineering from Michigan State University. Email: renee.a.hotton@gm.<strong>com</strong>.


Process/Surface


Mar Resistance Testing and Evaluation of Thermoplastic<br />

Olefins<br />

Robert L. Browning 1* , Peng Liu 1 , Hung-Jue Sue 1 and Kevin Reid 2<br />

1 Polymer Technology Center, Department of Mechanical Engineering<br />

Texas A&M University, College Station, TX 77843, USA<br />

2 Phillips-Sumika, Bartlesville Technical Center, Bartlesville, OK 74004<br />

Abstract<br />

Throughout the history of the field of tribology, little has been done to assign explicit<br />

definitions to the terms associated with the various types of surface damage from sliding<br />

contacts. A deep investigation reveals that each of these terms can be described by a<br />

unique testing and evaluation scenario.<br />

Our past work in the field of tribology, with close association with various sectors of the<br />

polymer industry, has sought to disambiguate these terms and has been met with a fair<br />

amount of success. This study<br />

aims at investigating “mar”<br />

behavior on polymer surfaces via<br />

development of an effective<br />

testing and analysis methodology<br />

derived from the current<br />

ASTM/ISO scratch test method<br />

and has been applied to model<br />

<strong>TPO</strong> systems with and without<br />

slip additive that possess high and<br />

low gloss surfaces.<br />

Percentage Change<br />

-100<br />

Abrasion Characterization of High Gloss <strong>TPO</strong><br />

150<br />

100<br />

50<br />

0<br />

-50<br />

Gloss<br />

Roughness (Ra)<br />

-150<br />

0 1 2 3 4 5 6<br />

It will be shown how gloss,<br />

Applied Normal Load (N)<br />

surface roughness and digital<br />

image contrast are inter-related regarding mar testing and evaluation of <strong>TPO</strong>s. The<br />

implications of this new test methodology <strong>com</strong>pared to the current industrial practices<br />

will also be discussed.<br />

* Speaker: Robert Browning (B_Squared02@yahoo.<strong>com</strong>) is currently working on <strong>com</strong>pleting his doctoral<br />

degree in Material Science & Engineering. His research is concerned with polymer structure-property<br />

relationships with an emphasis on tribological behavior.


Process Development Session:<br />

Aluminum Tooling for Injection Molding Seminar Agenda<br />

Plenary Presentation: Aluminum Tooling for Injection Molding of <strong>TPO</strong> Materials<br />

Patti Tibbenham, Ford Motor Company<br />

Mold Design Improvements, Surface Coatings, Heat Transfer and Part Price Opportunities<br />

Robert Beard, P.E., President of Robert A. Beard & Associates Inc.<br />

Properties of Aluminum Materials for Injection Molds<br />

Dave Wirth, Clinton Aluminum<br />

Designing Production Aluminum Molds<br />

Greg Eidenberger, Paragon Die & Engineering<br />

Case Studies of Production Aluminum Tooling<br />

Dave Dickerson: DRS Industries<br />

Manifold Considerations (Thermal 2-3d Analysis)<br />

Rich Oles: Plastic Services Group Inc. (PSG)<br />

Lessons Learned in Graining and Repair of Aluminum Tooling for Injection Molding<br />

Ron Smierciak: Alcoa<br />

The automotive industry is constantly driving toward cost opportunities, faster time to<br />

market and improved quality. In addition, the industry is moving toward more niche vehicles<br />

with lower production volumes. These drivers make aluminum tooling a current and important<br />

topic of interest in the automotive plastics industry.<br />

All aspects of aluminum tooling will be included from the perspective of the OEM, tier 1<br />

suppliers, mold manufacturers, to the material suppliers. This discussion will include an open<br />

forum on current and past successes and failures utilizing this technology for production molds.<br />

Aluminum material grades and applications will be reviewed. Mold manufacturing design<br />

details and cost savings opportunities for production aluminum molds will be highlighted. Case<br />

studies of current production tools for automotive applications will be discussed. Additionally,<br />

specific hot runner considerations for aluminum will be covered with 2d and 3d thermal<br />

simulations of the cooling characteristics <strong>com</strong>paring conventional steel and aluminum materials.<br />

Finally, lessons learned in the graining and repair of aluminum tooling for injection molds will<br />

be included.<br />

Aluminum tooling is not appropriate for every automotive plastic <strong>com</strong>ponent, and this is<br />

more apparent once individuals understand the realities of aluminum tooling. All of the speakers<br />

have cooperated to make this seminar an educational opportunity; informing the conference<br />

participants so everyone can make their own individual decisions relative to production<br />

aluminum tooling.<br />

Speakers:<br />

Patricia Tibbenham is a technical expert in Plastics Research at Ford Motor Company. She<br />

holds a BS in Mechanical Engineering from GMI and a MS in Engineering Management from<br />

Wayne State University. Patricia has spent over 20 years working on plastic <strong>com</strong>ponents in the<br />

automotive industry and she holds several U.S. Patents. Email: ptibbenh@ford.<strong>com</strong>


Robert Beard is a licensed Professional Engineer with over 40 years experience in the plastics<br />

industry. He is a Honored Fellow member of <strong>SPE</strong>. For the past 6 years, he has concentrated on<br />

getting existing and new molds to be better heat exchangers and reducing cycle times by 20% to<br />

40%. www.Plastic-Solvers.<strong>com</strong><br />

David Wirth is the North American Aluminum Mold Specialist and Midwest Sales Manager for<br />

Clinton Aluminum and Stainless Steel. He plays an active role in marketing Clinton Aluminum<br />

and is currently working with a mill to develop and bring to market a new alloy for the injection<br />

mold market. David also worked at ThyssenKrupp Specialty Steel Tool Steel Division, covering<br />

Wisconsin, Iowa and Minnesota for Die Cast and Injection Mold Markets.<br />

Greg Eidenberger is the Sales Manager for Paragon D&E located in Grand Rapids, Michigan.<br />

Greg has been with Paragon for over 28 years, as a Detail Draftsman, Tool Designer, Program<br />

Manager, Technical Sales, Business Unit Manager and now the Sales Manager for the last 5<br />

years. Greg has been instrumental in working with many of Paragon's customers who are using<br />

Aluminum Alloy's for Medium and Low Volume Production Tooling.<br />

Dave Dickerson is the Plant Manger for DRS Industries in Holland, Ohio. Dave has been with<br />

the <strong>com</strong>pany since 1989 starting as a plastic injection mold maker apprentice, with a focus solely<br />

on aluminum plastic injection molds. Dave served his apprenticeship with DRS, be<strong>com</strong>ing a<br />

journey mold maker and worked through the years as a working Shop Foreman. The Plant<br />

Manager position was offered to Dave in 1999, where as his duties are to oversee the day to day<br />

operations of an aluminum mold builder/plastic injection molder. In 1999 DRS started to<br />

produce and run aluminum low volume tooling for plastic injection molded parts, and has<br />

be<strong>com</strong>e the authority on the construction and running of production aluminum tools.<br />

Richard Oles started out setting up and operating multi-spindle screw machines, turned Mold<br />

Maker, Engineering manager, IT manager, General Manager, President and CEO over the past<br />

23 years. Each position built off the experience of the prior, and then he entered into the Hot<br />

Runner manifold world in 1999 with a Swiss based firm. This role set the stage for his current<br />

position as CEO of North America operations for the German based Hot Runner manufacturer,<br />

PSG Plastic Service Group, Inc.<br />

Ron Smierciak, Market Development Manager, Alcoa Forgings and Extrusions – Ron has been<br />

engaged with the development of Alcoa’s mold alloy, QC-10, since 2005. He is responsible for<br />

the product development of Alcoa QC-10. Ron actively promotes the benefits of aluminum<br />

tooling to molders and original equipment manufacturers in North America, Europe, and Asia.<br />

Prior to his involvement with Alcoa and QC-10, Ron developed products for thin film coatings<br />

serving the semiconductor and flat panel display industries.


Mechanical Modeling of Scratch Induced Periodic Damage<br />

Han Jiang 1* , John D. Whit<strong>com</strong>b 2 and Hung-Jue Sue 1<br />

Polymer Technology Center, Department of Mechanical Engineering 1<br />

Department of Aerospace Engineering 2<br />

Texas A&M University, College Station, TX 77843, USA<br />

Abstract<br />

Regardless of the polymer type, periodic occurrence of scratch-induced damage features<br />

is <strong>com</strong>monly observed. The above phenomenon is believed to be the result of a “stickslip”<br />

process involving the scratch tip.<br />

The stick-slip process is caused by the presence of a horizontal degree of freedom of the<br />

tip and the oscillation between the static and kinetic frictional behaviors. In addition, the<br />

tip geometry and material<br />

pile-up ahead of the 300 Distance Between Periodic Scratch Damage<br />

scratch tip will further<br />

<strong>com</strong>plicate the scratch tip<br />

movement during scratch.<br />

250<br />

200<br />

1 2<br />

2 [( μμ s − μμ<br />

k ) F n + κκ<br />

δδ<br />

e F n ]<br />

D =<br />

k h<br />

Periodic Distance<br />

To understand this 150<br />

Blunter tip<br />

<strong>com</strong>plex phenomenon, a<br />

simplified analytical<br />

100<br />

Scratch<br />

indentation<br />

model on the stick-slip<br />

phenomenon is proposed<br />

to account for the<br />

observed periodic scratchinduced<br />

damage features<br />

50<br />

0<br />

0 5 10 15<br />

Scratch Normal Load<br />

20<br />

Without<br />

indentation<br />

25 30<br />

on polymer surfaces. Through the above modeling effort, fundamental understanding of<br />

the scratch behavior under various scratch conditions is gained. Implication of the above<br />

study for fundamental understanding of the mechanical nature of the ASTM/ISO scratch<br />

test is also discussed.<br />

* Speaker: Han Jiang (jianghantamu@gmail.<strong>com</strong>) is conducting his post-doctoral research at Texas A&M<br />

University. His research focuses include structure-property relationship of polymers and <strong>com</strong>posites,<br />

damage & failure analysis, tribology, finite element modeling, constitutive relationship, etc.


Update on Developments for Scratch and Mar Additives;<br />

Effect of the additive formulation on the scratch performance<br />

and other secondary attributes<br />

Nikolas Kaprinidis*. Per Magnus Kristiansen, Martin Brunner and Johanne Wilson<br />

Ciba Corporation, a part of the BASF group, 540 White Plains Road, Tarrytown, NY 10591<br />

Abstract<br />

As the automotive industry be<strong>com</strong>es increasingly <strong>com</strong>petitive, scratch and mar performance is<br />

progressively more important to automotive OEM’s. Such performance directly affects consumer<br />

perception, which is being tracked by agencies such as J.D. Powers. This has led to closer<br />

scrutiny by OEM’s on the various test methods and a reconsideration of the acceptable standards<br />

is taking place. The previous benchmark of scratch resistance at 10N loading, usually determined<br />

by the popular 5 finger test method is no longer acceptable by many automotive OEM’s as they<br />

strive for increased product performance.<br />

Improving scratch performance for <strong>TPO</strong>s can be ac<strong>com</strong>plished by additive technologies, of which<br />

there are by now several ones available on the market. Although little differentiation is seen at<br />

scratch levels of 10 N, the differences be<strong>com</strong>e more apparent at loadings of 15 N and higher.<br />

Besides scratch resistance, secondary attributes are be<strong>com</strong>ing even more important and will be<br />

considered by automotive OEM’s since they also contribute to the overall consumer perception of<br />

the vehicle. The efficacy and performance of anti-scratch additives may vary based upon the<br />

<strong>com</strong>position and type of resin, as well as other additives present in the formulation which – in<br />

<strong>com</strong>bination – may lead to undesired effects. The second part of the paper will discuss such “side<br />

effects” caused by other additives.<br />

Figure 1: Comparison of scratch performance in 20% talc filled <strong>TPO</strong> for three <strong>com</strong>mercial<br />

scratch additives using Erichsen Cross-cut test method<br />

ΔL (scratch visibility)<br />

8<br />

6<br />

4<br />

2<br />

0<br />

blank blank<br />

5 N 10 N 15 N<br />

0.5% 0.5% Slip Slip<br />

3% 3% SR2 SR2<br />

3% 3% SR SR 11


* Dr. Nikolas Kaprinidis (Speaker) is responsible for application and product development<br />

department at Ciba – a part of the BASF group. He holds a Ph. D in Physical Organic Chemistry<br />

from New York University and spent two post-doctoral stays at UC Berkeley and Columbia<br />

University. He has published extensively and holds patents in various application areas of<br />

plastics. Dr. Kaprinidis is a member of ACS and has been with the <strong>com</strong>pany 11 years. Tel: 914-<br />

785-2739; e-mail: nikolas.kaprinidis@ciba.<strong>com</strong>


ABSRACT FOR <strong>SPE</strong> AUTOMOTIVE <strong>TPO</strong> <strong>2009</strong> <strong>Conference</strong><br />

Presentation Title: Atmospheric Pressure Plasma: Surface Treatment for Bonding and<br />

Painting Applications Without Wet Chemistry<br />

Speaker Name: Shaun Glogauer<br />

Speaker Job Title: Sales And Marketing Manager – Plasmatreat North America<br />

The presentation for this conference will consist of a brief introduction to plasma and<br />

plasma technology, outlining how the process works in laymen’s terms. Plasma is<br />

basically excited air molecules that work to clean and activate a surface for bonding and<br />

coating applications. This process can often lead to the elimination of aggressive<br />

primers, adhesion promoters, and solvent wiping applications. In other words, there are<br />

some truly revolutionary applications possible with this technology from both an<br />

environmental and quality standpoint. The ultimate goal is to reduce or eliminate wet<br />

chemistry in the process. Following this introduction, there will be a description of<br />

practical applications within the automotive industry as well as a few very short videos to<br />

illustrate the technology. The presentation will conclude with a brief summary and a<br />

question and answer period.


Latest Developments in Coatings Technology that Provides Striking<br />

Appearance and Durability over <strong>TPO</strong><br />

Arjun Dhake<br />

Dhake Industries<br />

Abstract<br />

Thermoplastic polyolefin (<strong>TPO</strong>) substrates continue to be used more and more in various<br />

automotive interior applications. At the same time, automotive designers are demanding<br />

more sophisticated and futuristic finishes on the interior of cars while still meeting all of<br />

the durability requirements.<br />

With the latest developments from Dhake Industries, auto designers can <strong>com</strong>bine the<br />

wanted aesthetic appeal with lower cost materials like <strong>TPO</strong> to give the ultimate in lowcost<br />

yet luxurious interiors.<br />

With the use of proprietary coating formulations, Dhake Industries can apply numerous<br />

types of metallic colors to any <strong>TPO</strong> substrate. This includes the much sought after<br />

chrome-look coatings in the automotive industry. <strong>Auto</strong> designers trend towards bright<br />

chrome or satin chrome plating on many interior <strong>com</strong>ponents. Now coatings that<br />

simulate bright chrome and satin chrome plating can be used on lower cost <strong>TPO</strong><br />

substrates to achieve a similar look at a much lower cost. The material cost is decreased<br />

by using <strong>TPO</strong> instead of typical ABS or PC/ABS for plating. Also, the cost of painting is<br />

much less than the cost of plating.<br />

Dhake Industries has been a leader in chrome-look and metallic coating formulations, and<br />

has developed various products to decorate <strong>TPO</strong> materials with these kinds of colors.<br />

With and without the use of adhesion promoters, this paper will examine the various<br />

methods of coating <strong>TPO</strong> to give the look and durability that the auto industry desires.<br />

Speaker Information:<br />

Arjun Dhake has received his B.S.E. in Chemical Engineering from The University of<br />

Michigan and his M.B.A. from The Ross School of Business at The University of<br />

Michigan. Arjun is currently Vice President of Business Development at Dhake<br />

Industries, a global paint and coating manufacturer for the automotive industry.<br />

Email: adhake@dhakeindustries.<strong>com</strong> Phone: 734-420-0101


Study of Scratch Resistance of Polypropylene Compound for<br />

<strong>Auto</strong>mobile<br />

LI Yonghua, YANG Bo, LUO Zhongfu, JIN Shan<br />

(KingFa Sci.& Tech.Co., Ltd., Guangzhou, 510520,China)<br />

ABSTRACT: Scratch resistance is critical for plastic auto parts to maintain their new<br />

appearance. In this study, the effect of scratch-resistant additive content on the<br />

scratch resistance of talc-filled ethylene-α-olefin copolymer/polypropylene blends for<br />

auto interior parts was investigated by scratch morphology, scratch width, and change<br />

of lightness. The effect of grained surface type on the scratch resistance was also<br />

examined. The results indicated that the addition of 1.5% scratch-resistant additive<br />

significantly improved scratch resistance. Scratch resistance was dependent on the<br />

depth, angle, and concentration of grains. Scratch resistance decreased with<br />

increasing depth, angle, and concentration of grains.<br />

The scratch test followed the Volkswagen interior scratch test standard PV3952. 40×<br />

40mm pattern(Fig 1). 10N was applied at a speed of 1000 mm/min.<br />

Fig 1 Scratch test surface pattern<br />

Speaker: Shan Jin, Graduate Student, Michigan State University, Office Phone:<br />

517-355-2220 email: jinshan@msu.edu<br />

Authors: LI Yonghua, YANG Bo, LUO Zhongfu, Kingfa Science & Tech Co.<br />

Contact Information: LI Yonghua, liyonghua@kingfa.<strong>com</strong>.cn, or liyhp@163.<strong>com</strong>


New and Innovative Testing Technologies for Effect Finishes<br />

Greg Shrider and Richard Scott : BYK - Gardner USA<br />

The look of effect finishes is continuously changing to create distinct visual appearances.<br />

Therefore, the range of effect pigments – different aluminum grades to special pearlescent<br />

pigments – used in automotive and industrial applications is increasing. Designers are<br />

seeking for colors which can change their look depending on the lighting conditions to<br />

pronounce the styling of a product. These types of effect finishes can appear grayish under<br />

cloudy sky, but start to live with colorful sparkling effects in the sunshine.<br />

On the other hand color harmony with add-on parts, uniform application without causing<br />

undesirable effects such as “cloudiness or mottling” and easy as well as cost efficient repair<br />

(liquid metal) is be<strong>com</strong>ing more and more of a challenge.<br />

New and innovative testing technologies were developed to quantify special effects such as<br />

sparkle, graininess and mottling with image analysis. The factors influencing the total color<br />

impression will be discussed and explained using several practical application examples.<br />

1


Abstract<br />

Conventional and Low VOC Bonding Solutions for <strong>TPO</strong><br />

Materials<br />

Walt Polifka<br />

Adchem Corporation<br />

<strong>TPO</strong> materials, with their low surface energy characteristics, present unique bonding challenges for<br />

manufacturers of pressure sensitive adhesives. Add into the equation a second substrate, such as, a foam,<br />

vinyl, other low energy surface finish or material and the bonding challenge increases. Adhesive tape<br />

construction and the adhesive used play a role in a successfully engineered bonding solution. <strong>TPO</strong>’s<br />

engineered for specific applications will require the bonding system also satisfy the requirements of the<br />

application. Emerging interest in Low VOC adhesive systems further <strong>com</strong>plicates bonding choices.<br />

<strong><strong>Auto</strong>motive</strong> interior and other industrial specifications will be impacted by Low VOC adhesive technology.<br />

Adchem will explore available adhesive chemistries, the challenges and solutions they provide for the <strong>TPO</strong><br />

user.<br />

Surface Energy by Substrate<br />

(Dynes/cm)<br />

Stainless Steel 400+<br />

Glass 60+<br />

Polycarbonate 52<br />

Epoxy 48<br />

ABS 46<br />

Anodized Aluminum 34<br />

HDPE 34<br />

Fluoropolymer 32<br />

LDPE 32<br />

Rigid PVC 32<br />

Urethane 32<br />

Polyester 30<br />

PP 30<br />

<strong>TPO</strong> 30<br />

Walt Polifka has been part of the Business Development team of Adchem Corporation for over ten years.<br />

He is responsible for new business development for pressure sensitive tape products in several industrial<br />

markets. His prior experience includes 15 years in fluid handling equipment and 14 years experience with<br />

polyester resin and urethane foam chemistries. Walt holds a B.S. degree in Chemical Engineering from<br />

Lehigh University. He and his wife Nan currently live in the Pocono Mountains region of Pennsylvania.


Executive Panel


Executive Management Panelists<br />

Matt Carroll is engineering group manager-Materials for Body Exterior, Electrical and<br />

Batteries at General Motors Co. Carroll was previously body vehicle systems engineer<br />

for the 2006MY Buick® Lucerne. Before joining the automaker, Carroll worked for both a<br />

<strong>TPO</strong> supplier and a paint supplier. He holds a Master’s Degree in Chemical Engineering<br />

from Wayne State University and was a member of the <strong>SPE</strong> Detroit Section Board from<br />

2005-2007. Carroll also has nine publications and one patent to his credit.<br />

Dr. David Cole, chairman of the Center for <strong><strong>Auto</strong>motive</strong> Research (CAR), is an<br />

internationally renowned speaker, writer, and expert on the automotive industry and<br />

will also be a keynote speaker at this year’s <strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong>.<br />

Cole was formerly director of the Office for the Study of <strong><strong>Auto</strong>motive</strong> Transportation<br />

(OSAT) at the University of Michigan’s Transportation Research Institute. Through CAR,<br />

Cole organizes an annual <strong><strong>Auto</strong>motive</strong> Management Briefing. This year’s event, held<br />

August 4-7, was entitled “Today’s Turmoil: A Foundation for Success.” He has worked<br />

extensively on internal-<strong>com</strong>bustion engines, vehicle design, and overall automotive<br />

industry trends. His recent research has focused on strategic issues related to<br />

restructuring of the North American industry and trends in globalization, technology,<br />

market factors, and human-resource requirements. Cole holds B.S. degrees in<br />

Mechanical Engineering and Mathematics, an M.S.M.E. and a Ph.D. – all from the<br />

University of Michigan.<br />

Stephen Dwyer is senior vice-president at LyondellBasell Polyolefins where he is<br />

responsible for its automotive business in the Americas. He has worked in the olefins<br />

industry for over 28 years at both Exxon Chemicals and LyondellBasell Polyolefins<br />

serving in various leadership roles in both North America and Europe. Dwyer has also<br />

published and presented numerous papers on the olefins industry and technological<br />

developments.<br />

Nand Kochhar is chief engineer-<strong>Global</strong> Materials Engineering & Standards, and<br />

executive technical leader-<strong>Global</strong> CAE at Ford Motor Co. Previous assignments at Ford<br />

have included chief engineer-Core Vehicle Engineering, chief engineer-Vehicle<br />

Attributes & CAE, vehicle engineering manager-F Series® Super Duty truck, and chassis<br />

design & release manager-Mondeo® in Europe. Kochhar has also held several<br />

supervisory and technical specialist positions within North American Product<br />

Development at the automaker.<br />

Jeff Makarewicz has been vice-president-Materials Engineering Division at the Toyota<br />

Technical Center (TTC), the North American research arm for Toyota Motor Engineering<br />

& Manufacturing, North America, Inc. (TEMA) since 2008, where he has responsibility<br />

for materials R&D, including materials research, design, development and evaluation.<br />

Makarewicz joined TTC in 1990 as an engineer in the Materials Engineering Department,<br />

Paint & Finishing Group and spent two years at Toyota Motor Corp. in Nagoya, Japan


working on anti-corrosion materials evaluation, design, and development. Prior to<br />

joining Toyota, Makarewicz worked for BASF in the Paint and Colorants Division. He<br />

holds numerous patents and earned a B.S. degree in Chemistry from the University of<br />

Michigan.<br />

Executive Management Moderators<br />

Bob Eller is president, Robert Eller Associates LLC (REA), a firm specializing in<br />

management consulting for the global plastics and rubber industries where he and his<br />

team carry out numerous technology, strategy, and manufacturing analyses, pricing<br />

forecasts, product positioning analyses, and crisis-management analyses in automotive<br />

plastics for clients around the world. Prior to forming his own firm in 1991, Eller worked<br />

in various positions at ExxonMobil, A. D. Little, Phillip Townsend Associates, Charles<br />

River Associates, and Multibase. Eller holds an undergraduate degree in Chemical<br />

Engineering from Massachusetts Institute of Technology and M.S. degrees in Polymer<br />

Science and Chemical Engineering from Brooklyn Polytechnic.<br />

Ron Price has spent over 35 years in polymer global business management, marketing,<br />

and sales involving both engineering and olefin polymers, primarily in the durable goods<br />

and automotive sectors. In fact, he launched over 20 new polymers and alloys to the<br />

automotive industry. He has worked at <strong>com</strong>panies such as DuPont, Borg Warner<br />

Chemicals, ExxonMobil, and Huntsman and continues to be active as a marketing and<br />

business consultant for new business, strategic marketing, and sales development. He<br />

has published over 25 articles and has made hundreds of presentations at regional,<br />

national, and international events. Price is also a recipient of three awards from the<br />

Detroit Section of <strong>SPE</strong>: Outstanding Achievement (2000), Lifetime Achievement (2005)<br />

and Outstanding Member (2006). He also was inducted as an Honored Service Member<br />

(2007) by <strong>SPE</strong> International.


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />

75


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />

76


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />

77


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />

78


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />

79


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />

80


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />

81


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />

82


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />

83


<strong>SPE</strong> <strong><strong>Auto</strong>motive</strong> <strong>TPO</strong> <strong>Global</strong> <strong>Conference</strong> <strong>2009</strong><br />

84

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