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Woods et al. 495Effect of oxidation state and solventSeveral factors can influence the effectiveness of a metal scavenger, one of which isthe oxidation state of the metal. In these studies the removal of Pd(II) as trans-di(µacetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II)(3) and Pd(0) as tetrakis-(triphenylphosphine)palladium(0) (4) was investigated.3 4In pilot scale studies, a 30 in column was packed with 400 mL of Deloxan ® THPII or Deloxan ® MP (Figure 1a). A dimethylformamide (DMF) solution containingeither 62.5 ppm or 71.0 ppm of both Pd(II) and Pd(0) as 3 and 4 was passed throughthe column at 4 EBV’s (empty bed volumes) per hour at room temperature.Figure 1 (a) Illustration of pilot column used in this study; (b) Illustration of labscalesetup
496 Transition Metal RemovalDeloxan ® THP II and MP were found to be effective at removing Pd from DMFsolutions containing both Pd(II) and Pd(0) in the fixed bed mode. As Table 1 showsby the time the process solution had reached the second sample port the level of Pdremaining in the effluent was reduced from 62.5 ppm or 71.0 ppm to
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Catalysis ofOrganic Reactions
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14. Catalyst Manufacture: Laborator
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62. Catalysis of Organic Reactions,
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108. Metal Oxides: Chemistry and Ap
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CRC PressTaylor & Francis Group6000
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xiii14. The Transformation of Light
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xviien Catalisis y Petroquimica (UN
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xix56. Transition Metal Removal fro
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xxiiiChronology of Organic Reaction
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To Zsuzsanna and Tim
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Jones et al. 31. On the Use of Immo
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Jones et al. 5three-phase tests in
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Jones et al. 7In the HKR of rac-epi
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Jones et al. 9term performance char
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Jones et al. 115. A. S. Gruber, D.
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Moses et al. 132. Supported Re Cata
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Moses et al. 15perrhenate, followed
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Moses et al. 17SnCOSnMe 4≡SiOReO
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Moses et al. 19(AlOSi) of the cube.
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Moses et al. 212.510 3 k obs / s -1
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Wang et al. 233. Catalytic Hydrogen
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Wang et al. 25The rate expressions
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Wang et al. 27Schiff’s base forma
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Wang et al. 29AcknowledgementsWe gr
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32Halophosphite LigandsIn 1970, Pru
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34Halophosphite LigandsThe ligands,
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36Halophosphite LigandsTable 2 Temp
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38Halophosphite Ligands3. P. W. N.
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40Monolithic Bioreactorstrength for
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42Monolithic BioreactorMenten equat
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Gőbölös et al. 456. Highly Selec
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Gőbölös et al. 47was practically
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Gőbölös et al. 49noteworthy that
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Gőbölös et al. 51Figure 2 NMR sp
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Gőbölös et al. 53internal TMS in
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56Hydrotalcite-like Catalysts[A n-
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58Hydrotalcite-like Catalystssample
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Mantilla, Tzompantzi, Torres and G
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68Synthesis of MIBKwe examined the
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70Synthesis of MIBK1412Conversion (
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72Synthesis of MIBK4,4’-dimethyl
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74Synthesis of MIBKobtained for MIB
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Ardizzi et al. 7710. The Control of
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Ardizzi et al. 79type acidity at th
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Ardizzi et al. 81procedure describe
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84Phenol Benzoylationconsecutive Fr
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86Phenol BenzoylationThis does not
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II. Symposium on Catalytic Oxidatio
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92Oxidation with Microchannel Immob
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100 Propylene Partial OxidationThe
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102 Propylene Partial OxidationSiO
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104 Propylene Partial Oxidation0.01
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106 Propylene Partial Oxidation0.02
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108 Propylene Partial OxidationRefe
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110Oxidation of n-Pentanemethacryli
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112Oxidation of n-PentaneFReqox1ox2
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114Oxidation of n-Pentanethe presen
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116Oxidation of n-PentaneIn the mec
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118Oxidation of n-PentaneReferences
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120TEMPO Oxidation of Alcoholsthe u
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122TEMPO Oxidation of AlcoholsThe r
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124TEMPO Oxidation of Alcoholsany d
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126TEMPO Oxidation of Alcoholsconce
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128TEMPO Oxidation of AlcoholsMNT :
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130TEMPO Oxidation of Alcoholsuptak
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132Aminoalcohols to Aminocarboxylic
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142Bromine-Free TEMPO-Based Catalys
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148CO OxidationP25 TiO 2 , respecti
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150CO Oxidation0.02(a)21802110(b)21
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152CO Oxidationcarboxylate species
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Yamauchi 15519. 2006 Murray Raney A
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Yamauchi 157transformation is schem
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Yamauchi 159The X-ray diffraction p
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Yamauchi 161was -0.0009, -0.0032 an
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Yamauchi 163shown in Fig. 12. It wa
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Yamauchi 165These fine particles we
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168Nitrobenzene Hydrogenationfurthe
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170Nitrobenzene Hydrogenationhydrog
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172Nitrobenzene HydrogenationThe co
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174Nitrobenzene HydrogenationHence
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176Nitrobenzene Hydrogenation10. G.
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178 Hydrogenation of Dehydrolinaloo
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188Modeling Mass Transfer Hydrogena
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198 Fructose HydrogenationHOHCCH 2O
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200 Fructose HydrogenationTable 1.
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202 Fructose Hydrogenationmmol form
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204 Fructose Hydrogenationthe subst
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206 Fructose Hydrogenationcleave th
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208 Fructose Hydrogenationfulfills
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210 Fructose Hydrogenationis not th
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Disselkamp et al. 21324. Cavitating
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Disselkamp et al. 215column. In a p
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Disselkamp et al. 217selectivity es
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Disselkamp et al. 219hydrogenated (
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Disselkamp et al. 221A somewhat mor
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Disselkamp et al. 223Scheme 4.cis-2
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Disselkamp et al. 225conventional c
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Ostgard et al. 22725. The Treatment
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Ostgard et al. 229Table 1. The reac
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Ostgard et al. 231metal atoms. Thes
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Ostgard et al. 233In conclusion, th
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Kuusisto, Mikkola and Salmi 23526.
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Kuusisto, Mikkola and Salmi 237100A
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Kuusisto, Mikkola and Salmi 2399. B
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242 1-Phenyl-1-Propyneof cis-β-met
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244 1-Phenyl-1-Propynealkene. When
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Musolino, Apa, Donato and Pietropao
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Gőbölös and Margitfalvi 25329. R
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Gőbölös and Margitfalvi 255maxim
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Gőbölös and Margitfalvi 257Y=421
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Rothenberg et al. 26130. How to Fin
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Rothenberg et al. 263By dividing th
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Rothenberg et al. 265pre-define the
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Rothenberg et al. 267Table 1. Parti
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Rothenberg et al. 269Experimental S
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Angueira and White 27131. Novel Chl
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Angueira and White 273optimizedgeom
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Angueira and White 275F igure 4 - c
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Angueira and White 277Table 1. 27 A
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Angueira and White 279obtained from
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Robitaille, Clément, Chapuzet and
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Cao, White, Wang and Frye 28933. Se
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Cao, White, Wang and Frye 291Experi
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294Chiral Ferrocene Ligandsnew Twin
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296Chiral Ferrocene LigandsTable 1.
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298Chiral Ferrocene Ligandsprevents
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300Chiral Ferrocene LigandsConclusi
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302Chiral Ferrocene Ligandsextracte
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304 Catalyst Library DesignIn gas p
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306 Catalyst Library Designd−(b 0
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308 Catalyst Library DesignBasic Pr
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310 Catalyst Library DesignD in com
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312 Catalyst Library DesignCatalyst
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314 Catalyst Library Design27. S. H
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316 Dendrimer TemplatesWe are devel
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318 Dendrimer TemplatesThe differen
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320 Dendrimer TemplatesWe encounter
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322 Dendrimer TemplatesThe 100 cm -
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328Rearrangement of 3,4-Epoxy-1-But
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3382,5-Dimethyl-2,4-Hexadieneharves
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3402,5-Dimethyl-2,4-Hexadienestabil
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3422,5-Dimethyl-2,4-Hexadiene10086Y
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3442,5-Dimethyl-2,4-Hexadienereacti
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3462,5-Dimethyl-2,4-Hexadiene8. www
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348Heteropoly AcidsSOOO O+ +OS1 2 3
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350Heteropoly AcidsTable 3. Acylati
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352Heteropoly AcidsSiO 2 is the bes
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Diez, Di Cosimo and Apesteguia 3554
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Diez, Di Cosimo and Apesteguia 357T
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Diez, Di Cosimo and Apesteguia 359A
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Diez, Di Cosimo and Apesteguia 361I
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Diez, Di Cosimo and Apesteguia 3630
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VI. Symposium on “Green” Cataly
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378 Polyurethane from Natural OilMe
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380 Polyurethane from Natural Oilco
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382 Polyurethane from Natural Oilfr
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384 Polyurethane from Natural OilTh
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386 Carbonylation of Chloropinacolo
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396 Recycling Homogeneous Catalysts
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406“Green” Catalysts for Biodie
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416 Production of BiodieselTable 1.
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418 Production of Biodieselto a mas
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420 Production of BiodieselEthyl st
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422 Production of Biodiesel10080Sel
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424 Production of Biodieselproduct
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Marincean et al. 42747. Glycerol Hy
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Marincean et al. 429Experimental Se
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Marincean et al. 431neutralize all
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Marincean et al. 433suggesting that
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Marincean et al. 435increasing from
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Kocal 43748. Developing Sustainable
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Kocal 439description of the four st
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Kocal 441metallurgy in parts of the
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Kocal 443that capital investment co
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Page 475 and 476: 448Propylene Oxidation to POSupercr
Page 477 and 478: 450Propylene Oxidation to POTable 1
Page 479 and 480: 452Propylene Oxidation to PO
Page 482 and 483: Riermeier et al. 45550. catASium ®
Page 484 and 485: Riermeier et al. 457It is interesti
Page 486 and 487: Riermeier et al. 459Reaction of the
Page 488: Riermeier et al. 461References1. I.
Page 491 and 492: 464 Chiral 2-Amino-1-Phenylethanolp
Page 493 and 494: 466 Chiral 2-Amino-1-PhenylethanolI
Page 495 and 496: 468 Chiral 2-Amino-1-Phenylethanola
Page 497 and 498: 470 t-Butanol DehydrationResults an
Page 499 and 500: 472 t-Butanol Dehydrationcomprises
Page 502 and 503: Pohlmann et al 47553. Leaching Resi
Page 504 and 505: Pohlmann et al 477this study. In th
Page 506: Pohlmann et al 479Experimental Sect
Page 509 and 510: 482 Reductive AlkylationSince the p
Page 511 and 512: 484 Reductive AlkylationTable 2. Re
Page 514 and 515: Wolf, Seebald and Tacke 48755. Acce
Page 516 and 517: Wolf, Seebald and Tacke 489100Norma
Page 518 and 519: Wolf, Seebald and Tacke 4911,88Figu
Page 520 and 521: Woods et al. 49356. Transition Meta
Page 524 and 525: Woods et al. 497
Page 526: Woods et al. 499removed the samples
Page 529 and 530: 502 Electroreductive Catalytic Ullm
Page 531 and 532: 504 Electroreductive Catalytic Ullm
Page 534 and 535: Catalysis of Organic Reactions 507A
Page 536 and 537: Catalysis of Organic Reactions 509K
Page 538: Catalysis of Organic Reactions 511T
Page 541 and 542: 514 Keyword Indexcarboncarbon dioxi
Page 543 and 544: 516 Keyword Indexethanolamine 16 13
Page 545 and 546: 518 Keyword IndexNi, activated 25 2
Page 547: 520 Keyword Indexsuccinimido ketone
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