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Singh and Chuang 1050.064m/e = 32 (O 2 ) m/e = 41 (C 3 H 6 )0.05Flow Rate (ml/min)32m/e = 29 (propionaldehyde)m/e = 2 (H 2 )Flow Rates (ml/min)0.040.030.02m/e = 58 (propylene oxide)100.01m/e = 43 (acetone)0m/e = 44 (CO 2 ) m/e = 45(iso-propanol)50 100 150 200 250Temperature(°C)50 100 150 200 250Temperature (°C)Figure 5. Calibrated MS profiles of reactants and products during TPR of propylenepartial oxidation over Au/TiO 2 -SiO 2 (Catalyst weight = 0.14 g).TPR results over Au/TiO x -SiO 2Fig. 6 shows the IR-TPR of C 3 H 6 partial oxidation over Au/TiO x -SiO 2 . Theinteraction of Ar/C 3 H 6 /H 2 /O 2 with the catalyst surface at 50 °C led to decrease in theband intensity of OH vibration at 3741 cm -1 and the formation of a 1662 cm -1 (C=Oof adsorbed acetone ) band. Mass spec. results in Fig. 7 shows the reaction producedpropionaldehyde, acetone, and CO 2 . The rate of product formation peaked at 140 o C.Table 2 shows the activity of Au/TiO x -SiO 2 and Au/TiO 2 -SiO 2 for propylenepartial oxidation at 200 °C under transient condition.Table 2 Activity and selectivity of the catalysts during TPR studies at 200 °CCatalystWeight(gm)Conversion(%)C 3 H 6 /H 2 /O 2Selectivity(%)CO 2 /C 2 H 5 CHO/(CH 3 ) 2 CO/(CH 3 ) 2 COH/POAu/TiO x 0.085 11.7/46/4.8 10.2/74.8/13.6/0/0-SiO 2Au/TiO 2-SiO 20.140 22.7/76.2/19 4.8/71.4/21/1.8/0.91
106 Propylene Partial Oxidation0.0237413688T (°C)2001750.023737340430932951291516621635T (°C)200175IR Intensity (A.U.)150125100IR Intensity (A.U.)CO 2 (g)15012550100503800 3650 3500Wavenumber (cm -1 )4000360032002800 2400 2000Wavenumber (cm -1 )Figure 6. In situ IR spectroscopy of TPR of propylene partial oxidation overAu/TiO x -SiO 2 .160012008005m/e = 41 (C 3 H 6 )Flow Rate (cc/min)4321m/e = 32 (O 2 )m/e = 2 (H 2 )m/e = 29 (propionaldehyde)m/e = 43 (acetone)m/e = 44 (CO 2 )040 80 120 160 200Temperature (°C)Figure 7. MS analysis during TPR of propylene partial oxidation over Au/TiO x -SiO 2 (catalyst weight = 0.085 g).
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Catalysis ofOrganic Reactions
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14. Catalyst Manufacture: Laborator
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62. Catalysis of Organic Reactions,
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108. Metal Oxides: Chemistry and Ap
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CRC PressTaylor & Francis Group6000
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xiii14. The Transformation of Light
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xviien Catalisis y Petroquimica (UN
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xix56. Transition Metal Removal fro
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xxiiiChronology of Organic Reaction
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To Zsuzsanna and Tim
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Jones et al. 31. On the Use of Immo
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Jones et al. 5three-phase tests in
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Jones et al. 7In the HKR of rac-epi
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Jones et al. 9term performance char
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Jones et al. 115. A. S. Gruber, D.
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Moses et al. 132. Supported Re Cata
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Moses et al. 15perrhenate, followed
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Moses et al. 17SnCOSnMe 4≡SiOReO
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Moses et al. 19(AlOSi) of the cube.
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Moses et al. 212.510 3 k obs / s -1
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Wang et al. 233. Catalytic Hydrogen
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Wang et al. 25The rate expressions
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Wang et al. 27Schiff’s base forma
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Wang et al. 29AcknowledgementsWe gr
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32Halophosphite LigandsIn 1970, Pru
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34Halophosphite LigandsThe ligands,
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36Halophosphite LigandsTable 2 Temp
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38Halophosphite Ligands3. P. W. N.
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40Monolithic Bioreactorstrength for
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42Monolithic BioreactorMenten equat
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Gőbölös et al. 456. Highly Selec
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Gőbölös et al. 47was practically
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Gőbölös et al. 49noteworthy that
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Gőbölös et al. 51Figure 2 NMR sp
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Gőbölös et al. 53internal TMS in
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Page 95 and 96: 68Synthesis of MIBKwe examined the
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Page 139 and 140: 112Oxidation of n-PentaneFReqox1ox2
Page 141 and 142: 114Oxidation of n-Pentanethe presen
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Page 145 and 146: 118Oxidation of n-PentaneReferences
Page 147 and 148: 120TEMPO Oxidation of Alcoholsthe u
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Page 151 and 152: 124TEMPO Oxidation of Alcoholsany d
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Page 155 and 156: 128TEMPO Oxidation of AlcoholsMNT :
Page 157 and 158: 130TEMPO Oxidation of Alcoholsuptak
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Yamauchi 15519. 2006 Murray Raney A
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Yamauchi 157transformation is schem
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Yamauchi 159The X-ray diffraction p
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Yamauchi 161was -0.0009, -0.0032 an
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Yamauchi 163shown in Fig. 12. It wa
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Yamauchi 165These fine particles we
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168Nitrobenzene Hydrogenationfurthe
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170Nitrobenzene Hydrogenationhydrog
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172Nitrobenzene HydrogenationThe co
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174Nitrobenzene HydrogenationHence
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176Nitrobenzene Hydrogenation10. G.
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178 Hydrogenation of Dehydrolinaloo
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188Modeling Mass Transfer Hydrogena
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198 Fructose HydrogenationHOHCCH 2O
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200 Fructose HydrogenationTable 1.
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202 Fructose Hydrogenationmmol form
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204 Fructose Hydrogenationthe subst
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206 Fructose Hydrogenationcleave th
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208 Fructose Hydrogenationfulfills
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210 Fructose Hydrogenationis not th
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Disselkamp et al. 21324. Cavitating
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Disselkamp et al. 215column. In a p
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Disselkamp et al. 217selectivity es
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Disselkamp et al. 219hydrogenated (
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Disselkamp et al. 221A somewhat mor
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Disselkamp et al. 223Scheme 4.cis-2
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Disselkamp et al. 225conventional c
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Ostgard et al. 22725. The Treatment
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Ostgard et al. 229Table 1. The reac
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Ostgard et al. 231metal atoms. Thes
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Ostgard et al. 233In conclusion, th
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Kuusisto, Mikkola and Salmi 23526.
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Kuusisto, Mikkola and Salmi 237100A
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Kuusisto, Mikkola and Salmi 2399. B
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242 1-Phenyl-1-Propyneof cis-β-met
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244 1-Phenyl-1-Propynealkene. When
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Musolino, Apa, Donato and Pietropao
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Gőbölös and Margitfalvi 25329. R
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Gőbölös and Margitfalvi 255maxim
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Gőbölös and Margitfalvi 257Y=421
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Rothenberg et al. 26130. How to Fin
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Rothenberg et al. 263By dividing th
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Rothenberg et al. 265pre-define the
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Rothenberg et al. 267Table 1. Parti
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Rothenberg et al. 269Experimental S
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Angueira and White 27131. Novel Chl
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Angueira and White 273optimizedgeom
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Angueira and White 275F igure 4 - c
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Angueira and White 277Table 1. 27 A
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Angueira and White 279obtained from
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Cao, White, Wang and Frye 28933. Se
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Cao, White, Wang and Frye 291Experi
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294Chiral Ferrocene Ligandsnew Twin
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296Chiral Ferrocene LigandsTable 1.
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298Chiral Ferrocene Ligandsprevents
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300Chiral Ferrocene LigandsConclusi
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302Chiral Ferrocene Ligandsextracte
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304 Catalyst Library DesignIn gas p
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306 Catalyst Library Designd−(b 0
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308 Catalyst Library DesignBasic Pr
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310 Catalyst Library DesignD in com
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312 Catalyst Library DesignCatalyst
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314 Catalyst Library Design27. S. H
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316 Dendrimer TemplatesWe are devel
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318 Dendrimer TemplatesThe differen
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320 Dendrimer TemplatesWe encounter
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322 Dendrimer TemplatesThe 100 cm -
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328Rearrangement of 3,4-Epoxy-1-But
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3382,5-Dimethyl-2,4-Hexadieneharves
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3422,5-Dimethyl-2,4-Hexadiene10086Y
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348Heteropoly AcidsSOOO O+ +OS1 2 3
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350Heteropoly AcidsTable 3. Acylati
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352Heteropoly AcidsSiO 2 is the bes
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378 Polyurethane from Natural OilMe
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380 Polyurethane from Natural Oilco
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382 Polyurethane from Natural Oilfr
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384 Polyurethane from Natural OilTh
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386 Carbonylation of Chloropinacolo
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396 Recycling Homogeneous Catalysts
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406“Green” Catalysts for Biodie
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416 Production of BiodieselTable 1.
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418 Production of Biodieselto a mas
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420 Production of BiodieselEthyl st
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422 Production of Biodiesel10080Sel
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424 Production of Biodieselproduct
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Marincean et al. 42747. Glycerol Hy
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Marincean et al. 429Experimental Se
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Marincean et al. 431neutralize all
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Marincean et al. 433suggesting that
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Kocal 43748. Developing Sustainable
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Kocal 439description of the four st
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Kocal 441metallurgy in parts of the
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Kocal 443that capital investment co
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Kocal 4455. J.J. Siirola, An Indust
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448Propylene Oxidation to POSupercr
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450Propylene Oxidation to POTable 1
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452Propylene Oxidation to PO
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Riermeier et al. 45550. catASium ®
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Riermeier et al. 457It is interesti
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Riermeier et al. 459Reaction of the
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Riermeier et al. 461References1. I.
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464 Chiral 2-Amino-1-Phenylethanolp
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466 Chiral 2-Amino-1-PhenylethanolI
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468 Chiral 2-Amino-1-Phenylethanola
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470 t-Butanol DehydrationResults an
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472 t-Butanol Dehydrationcomprises
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Pohlmann et al 47553. Leaching Resi
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Pohlmann et al 477this study. In th
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Pohlmann et al 479Experimental Sect
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482 Reductive AlkylationSince the p
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484 Reductive AlkylationTable 2. Re
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Wolf, Seebald and Tacke 48755. Acce
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Wolf, Seebald and Tacke 489100Norma
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Wolf, Seebald and Tacke 4911,88Figu
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Woods et al. 49356. Transition Meta
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Woods et al. 495Effect of oxidation
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Woods et al. 497
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Woods et al. 499removed the samples
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502 Electroreductive Catalytic Ullm
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504 Electroreductive Catalytic Ullm
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Catalysis of Organic Reactions 507A
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Catalysis of Organic Reactions 509K
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Catalysis of Organic Reactions 511T
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514 Keyword Indexcarboncarbon dioxi
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516 Keyword Indexethanolamine 16 13
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518 Keyword IndexNi, activated 25 2
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520 Keyword Indexsuccinimido ketone
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