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Silicon-based solar cells Characteristics and production processes ...

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<strong>Silicon</strong>-<strong>based</strong> <strong>solar</strong> <strong>cells</strong> – characteristics <strong>and</strong> <strong>production</strong> <strong>processes</strong><br />

software were realized with the assumption of the impurity profile type erfc for N D =<br />

3,6x10 20 atom/cm 3 <strong>and</strong> the junction depth of 0,5 μm.<br />

Fig. 6. Energy b<strong>and</strong> displacement <strong>and</strong> creation of photovoltage V as a result of cell<br />

illumination, depending on the concentration of donor impurity N D = 3,6x10 20 atom/cm 3 <strong>and</strong><br />

the homogeneous concentration of acceptor impurity N A =1,5x10 16 atom/cm 3 .<br />

As a result of the cell illumination, the position of the energy bans in the p-type<br />

area becomes lower by the value qV, which is mainly dependent on the acceptor<br />

impurity concentration. The value of the diffusion potential U D depends on the<br />

impurity concentration according to the equation [16]:<br />

2<br />

( N n )<br />

where: k - Boltzmann constant<br />

T - temperature [ o K]<br />

n i - concentration of intrinsic charge carriers<br />

U = kT qln N<br />

(1)<br />

D<br />

A<br />

E<br />

i<br />

The above dependences are highly significant for the design <strong>and</strong> <strong>production</strong><br />

engineering of <strong>solar</strong> <strong>cells</strong> on the basis of crystalline silicon. If we lower the level of<br />

impurity N A in the cell’s base material, this will heighten its resistivity <strong>and</strong> the<br />

15

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