25.06.2015 Views

Glow Stick: A Chemiluminescence - Quantum

Glow Stick: A Chemiluminescence - Quantum

Glow Stick: A Chemiluminescence - Quantum

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

<strong>Glow</strong> <strong>Stick</strong>: A <strong>Chemiluminescence</strong><br />

By: Kassandra Brady


History<br />

• Edwin A. Chandros<br />

– 1960<br />

– Bell Labs<br />

– Murray Hill, New Jersey


History<br />

• Michael M. Rauhut<br />

– American Cyanamid<br />

– Stamford, Connecticut<br />

• E. Earl Cranor<br />

– Research in commercial uses<br />

– Created the typical structure


is(2,4,6-trichlorophenyl)oxalate<br />

• C 14 H 4 Cl 6 O 4<br />

• Irritant<br />

• The prefix bis- means two


is(2,4,6-trichlorophenyl)oxalate


Hydrogen Peroxide


Fluorescent Dyes<br />

9,10-bis(phenylethynyl)anthracene (green)<br />

9,10-diphenylanthracene (blue)


Rhodamine B (red)<br />

Rubrene (yellow)


How a <strong>Glow</strong> <strong>Stick</strong> Works Chemically<br />

hydrogen peroxide<br />

sodium salicylate<br />

bis(2,4,6-trichlorophenyl)oxalate<br />

2<br />

1,2-dioxetanedione<br />

2,4,6-trichlorophenol<br />

Fluorophore<br />

Fluorophore*<br />

2 CO2<br />

Fluorophore<br />

Light


How We Make a <strong>Glow</strong> <strong>Stick</strong> Work<br />

• Structure<br />

– Hydrogen Peroxide encased in a glass container<br />

within the plastic tube<br />

– bis(2,4,6-trichlorophenyl)oxalate and fluorescent<br />

dye encased within the plastic tube


How to make a glow stick


<strong>Chemiluminescence</strong><br />

• Light producing<br />

• Does not produce a significant amount of heat<br />

• Electromagnetic radiation


<strong>Chemiluminescence</strong> Reaction<br />

2<br />

2H 2<br />

O<br />

O 2<br />

N 2<br />

hv<br />

Luminol Excited state Product


<strong>Chemiluminescence</strong> In World Around Us<br />

• Fireflies and Jellyfish<br />

• <strong>Glow</strong> <strong>Stick</strong>s<br />

– Natural Disasters<br />

– Military<br />

– Safety

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!