WIND ENERGY SYSTEMS - Cd3wd

WIND ENERGY SYSTEMS - Cd3wd WIND ENERGY SYSTEMS - Cd3wd

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Chapter 7—Asynchronous Loads 7–45 Figure 17: Plot showing the effect of temperature on electrolysis cell characteristics at 3000 psi. keeping the acid concentration constant within the electrolyte. On the oxygen side, two water molecules are decomposed into one neutral oxygen gas molecule, four electrons which move off to the right within the metal screen, and four positive hydrogen ions which move through the solid electrolyte. These four ions receive four electrons coming from the left and become two molecules of hydrogen gas on the hydrogen side of the solid electrolyte. The two faces of the SPE sheet are coated with a very thin film of catalyst to help the reaction occur. Platinum black works well but other catalysts are being developed for reasons of cost and availability. The spaces for the water and gas next to the SPE sheet are formed by a multi-layer expanded metal screen package. The open spaces between the screen strands provide a low resistance flow path for the water and gases. The screen provides physical support for the SPE sheet to help it withstand high differential pressures and acts as an electrical current conductor. The fluid cavities are sealed around the edges by a silicon rubber gasket. This gasket also provides electrical insulation so current flows only where desired. Adjacent cells are separated by a metal sheet which provides mechanical separation of gases but does not contribute directly to gas production. Early problems with the silicon rubber gasket have led to the testing of other separators. One version replaced the silicon rubber gasket and metal sheet with a sheet of molded carbon Wind Energy Systems by Dr. Gary L. Johnson November 21, 2001

Chapter 7—Asynchronous Loads 7–46 Figure 18: Solid polymer electrolyte electrolysis cell. and titanium foil shield[15]. This separator is molded from a mixture of carbon and phenolic resin. The SPE sheet itself acts as the gasket. On the cathode (hydrogen) side, porous carbon fiber paper replaced the metal screen. On the anode (oxygen) side, the metal screen is formed of either perforated titanium foil, fabricated by acid etching, or porous titanium plate fabricated by a powder metallurgy process. Other developments in materials can be expected with the SPE cell as it continues toward wide commercialization. Increasing the temperature increases the efficiency of the SPE cell just as it does with the alkaline cell. An increase in temperature from 180 o F to 300 o F reduced the cell voltage from 1.83 to 1.70 V at 1000 A/ft 2 for the GE cell[15]. This corresponds to a thermal efficiency improvement from 81 to 87 percent. Material problems become even more severe at temperatures above 300 o F (150 o C) so this may be a practical upper limit for temperature. The efficiency of the SPE cell does not vary strongly with pressure since the current does not have to flow through a liquid electrolyte filled with gas bubbles. In fact, the GE efficiency goal for their SPE cell is 93 percent at 100 psi (0.69 MPa) and 88 percent at 600 psi (4.14 MPa)[15]. If pipeline pressure is not required, it may be more cost effective to operate the SPE cell at relatively low pressures. It might be mentioned that water only needs to be supplied to the oxygen side of the SPE cell. The water on the hydrogen side is necessary to the reaction but is not used up, except for the water vapor that is carried off by the hydrogen gas. The cell only requires three fluid connections, one for water and two for the gases. This simplifies construction somewhat as Wind Energy Systems by Dr. Gary L. Johnson November 21, 2001

Chapter 7—Asynchronous Loads 7–45<br />

Figure 17: Plot showing the effect of temperature on electrolysis cell characteristics at 3000<br />

psi.<br />

keeping the acid concentration constant within the electrolyte. On the oxygen side, two water<br />

molecules are decomposed into one neutral oxygen gas molecule, four electrons which move<br />

off to the right within the metal screen, and four positive hydrogen ions which move through<br />

the solid electrolyte. These four ions receive four electrons coming from the left and become<br />

two molecules of hydrogen gas on the hydrogen side of the solid electrolyte.<br />

The two faces of the SPE sheet are coated with a very thin film of catalyst to help the<br />

reaction occur. Platinum black works well but other catalysts are being developed for reasons<br />

of cost and availability.<br />

The spaces for the water and gas next to the SPE sheet are formed by a multi-layer<br />

expanded metal screen package. The open spaces between the screen strands provide a low<br />

resistance flow path for the water and gases. The screen provides physical support for the<br />

SPE sheet to help it withstand high differential pressures and acts as an electrical current<br />

conductor. The fluid cavities are sealed around the edges by a silicon rubber gasket. This<br />

gasket also provides electrical insulation so current flows only where desired. Adjacent cells<br />

are separated by a metal sheet which provides mechanical separation of gases but does not<br />

contribute directly to gas production.<br />

Early problems with the silicon rubber gasket have led to the testing of other separators.<br />

One version replaced the silicon rubber gasket and metal sheet with a sheet of molded carbon<br />

Wind Energy Systems by Dr. Gary L. Johnson November 21, 2001

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