Restorative Procedure - Kerr Hawe

Restorative Procedure - Kerr Hawe Restorative Procedure - Kerr Hawe

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All you need is Kerr Adhesives Restorative Procedure Adhesives Bonding & Adhesion Prof. David Watts, Dr. Nick Silikas, University of Manchester, UK The mechanism of enamel bonding is based on a micro-mechanical bond between the resin and the phosphoric acid conditioned rough surface of the enamel.Enamel conditioning remains the most commonly used method to bond resin-composites to enamel surface. It provides strong bonds. Enamel conditioning may be regained by re-etching the surface and applying the resin, thus recovering the required shear bond strength at the enamel-resin interface, and allowing the resin to mechanically bond onto its surface. Dentine however has a much more complex structure than enamel. Prior to dentine-bonding, the removal or modification of the smear layer is indicated to clear the openings of the dentine tubules by conditioning the surface of the dentine. A fluid adhesive is then applied over the dentine and cured, ensuring that optimum wetting of the surface and absorption into the dentinal tubules is achieved; thus creating an inter-penetrating network with the demineralised collagen in the dentinal tubules, hence forming the hybrid layer. Preservation of the hybrid layer prior to the application of the hydrophobic resin restoration is imperative for an efficient bond to form between the resin and dentine. Therefore, any contamination of any region of the adhesive system would evidently jeopardise the integrity of the bond. The mechanism proposed for this material was to bond to the organic component of the dentine, namely the collagen. The first work to investigate the mechanism of bonding to the dentine was by Nakabayashi (1). He first identified a layer between the resin and dentine substrate referred to as “hybrid” dentine, in that it was the organic components of the dentine that had been permeated by resin. The term “hybrid layer” has now become synonymous with bonding of resins to etched dentine. There has been a tremendous amount of research done on the hybrid layer, its structure, formation and how it can be improved. This layer has also been referred to as the “resin-dentine interdiffusion zone” (2). Classification Numerous dentine bonding agents have been commercially introduced. These changes have been referred by some people as “generations”, implying that there was a chronological development. This can be very confusing. A more consistent and logical approach is to classify bonding agents by the number of steps needed to complete the bonding process. “Three-step” or “Conventional” systems This group typically consists of three separate application steps: etching, priming and adhesive resin. They are also known as “etch-and-rinse” 7

systems. Although they were the first ones introduced, they are still widely used and have been shown to provide reliable bonding. Their main drawback seems to be technique sensitivity, since any deviation from the recommended procedure will result in inferior bonding. “Two-step” systems This group can be subdivided into two subgroups: i) they have a separate etch and have combined the priming and bonding steps. These systems are often referred to as “Single-bottle” systems. Similar problems found with the “Three-step” system can also be seen here. ii) etching and priming steps are combined together and bonding is separate. This is referred to as “Self-etching primers”. An acidic resin etches and infiltrates the dentine simultaneously. The tooth does not need to be rinsed which decreases the clinical application time and also reduces technique sensitivity by eliminating the need to maintain the dentine in a moist state. “One-bottle” or “All-in-one” systems This is when all steps are combined into one process. Their mode of action is similar to that of the “self-etching primers”, but the bonding resin is also incorporated. It is considered that these do not etch as effectively as the previous ones. They are the most recently introduced so limited clinical data is available. Bonding mechanism This micromechanical coupling of restorative materials to dentine, via an intermediate adhesive layer, is referred to as dentine bonding (3). The resin in the primer and bonding step penetrates the collapsed collagen fibrils (after demineralisation), and forms an interpenetrating network. This layer had been described extensively and in great detail (4, 5). The thickness of the hybrid layer ranges from less than 1 µm for the all-in-one systems to up to 5 µm for the conventional systems. The bond strength is not dependent on the thickness of the hybrid layer, as the self-etching priming materials have shown bond strengths greater than many other systems but exhibit a thin hybrid layer. The etching, rinsing and drying process cause the dentine to collapse due to the loss of the supporting hydroxyapatite structure. The collapsed state of collagen fibrils was hindering the successful diffusion of the resin monomers. To overcome this problem, two approaches were introduced. The first one is called “dry-bonding technique” and involves air-drying of dentine after etching and subsequent application of a waterbased primer that can re-expand the collapsed collagen (6, 7). The second one is the “wet bonding technique” in which the demineralized collagen is supported by residual water after washing (8). This allows the priming solution to diffuse throughout the collagen fibre network more successfully. However, when it comes to clinical practice, it is very difficult to find the correct balance of residual moisture. Excess water can be detrimental to bonding and these problems have been described as “overwetting phenomena” (9). Since the “dry-bonding technique” is considered to be significantly less technique sensitive, it should be preferred over the most difficult to standardize “wet bonding technique” (2). Relevant in-vitro bond strength studies can provide a useful indication of the prospective clinical success of a system. However, the highest level of evidence for comparing the efficiency of a bonding system is obtained from randomised clinical trials. Randomised clinical trials with elongated the treatment periods will be very useful in assessing both the effectiveness of a particular group and a particular method of application. References 1. Nakabayashi N, Kojima K, Masuhara E. The promotion of adhesion by the infiltration of monomers into tooth substrates. J Biomed Mater Res 1982;16:265-273. 2. Van Landuyt K, De Munck J, Coutinho E, Peumans M, Lambrechts P, Van Meerbeek B. Bonding to Dentin: Smear Layer and the Process of Hybridization. In: Eliades G, Watts DC, Eliades T, editors. Dental Hard Tissues and Bonding Interfacial Phenomena and Related Properties Berlin: Springer; 2005. p. 89-122. 3. Eick JD, Gwinnett AJ, Pashley DH, Robinson SJ. Current concepts on adhesion to dentin. Crit Rev Oral Biol Med 1997;8:306-335. 4. Van Meerbeek B, Braem M, Lambrechts P, Vanherle G. Morphological characterization of the interface between resin and sclerotic dentine. J Dent Res 1994;22:141-146. 5. Van Meerbeek B, Inokoshi S, Braem M, Lambrechts P, Vanherle G. Morphological aspects of the resin-dentin interdiffusion zone with different dentin adhesive systems. J Dent Res 1992;71:1530-1540. 6. Finger WJ, Balkenhol M. Rewetting strategies for bonding to dry dentin with an acetone-based adhesive. J Adhes Dent 2000;2:51-56. 7. Frankenberger R, Krämer N, Petschelt A. Technique sensitivity of dentin bonding: effect of application mistakes on bond strength and marginal adaptation. Oper Dent 2000;25:324-330. 8. Kanca JI. Effect of resin primer solvents and surface wetness on resin composite bond strength to dentin. Am J Dent 1992;5:213-215. 9. Tay FR, Gwinnett JA, Wei SH. Micromorphological spectrum from overdrying to overwetting acid-conditioned dentin in water-free acetonebased, single-bottle primer/adhesives. Dent Mater 1996;12:236-244. 8 Your practice is our inspiration.

systems. Although they were the first ones<br />

introduced, they are still widely used and have<br />

been shown to provide reliable bonding. Their<br />

main drawback seems to be technique sensitivity,<br />

since any deviation from the recommended<br />

procedure will result in inferior bonding.<br />

“Two-step” systems<br />

This group can be subdivided into two subgroups:<br />

i) they have a separate etch and have combined<br />

the priming and bonding steps. These systems<br />

are often referred to as “Single-bottle” systems.<br />

Similar problems found with the “Three-step”<br />

system can also be seen here.<br />

ii) etching and priming steps are combined together<br />

and bonding is separate. This is referred to as<br />

“Self-etching primers”. An acidic resin etches and<br />

infiltrates the dentine simultaneously. The tooth<br />

does not need to be rinsed which decreases<br />

the clinical application time and also reduces<br />

technique sensitivity by eliminating the need to<br />

maintain the dentine in a moist state.<br />

“One-bottle” or “All-in-one” systems<br />

This is when all steps are combined into one<br />

process. Their mode of action is similar to that of<br />

the “self-etching primers”, but the bonding resin is<br />

also incorporated. It is considered that these do<br />

not etch as effectively as the previous ones. They<br />

are the most recently introduced so limited clinical<br />

data is available.<br />

Bonding mechanism<br />

This micromechanical coupling of restorative<br />

materials to dentine, via an intermediate adhesive<br />

layer, is referred to as dentine bonding (3). The<br />

resin in the primer and bonding step penetrates<br />

the collapsed collagen fibrils (after demineralisation),<br />

and forms an interpenetrating network. This<br />

layer had been described extensively and in great<br />

detail (4, 5). The thickness of the hybrid layer<br />

ranges from less than 1 µm for the all-in-one<br />

systems to up to 5 µm for the conventional systems.<br />

The bond strength is not dependent on the<br />

thickness of the hybrid layer, as the self-etching<br />

priming materials have shown bond strengths<br />

greater than many other systems but exhibit a<br />

thin hybrid layer. The etching, rinsing and drying<br />

process cause the dentine to collapse due to the<br />

loss of the supporting hydroxyapatite structure.<br />

The collapsed state of collagen fibrils was hindering<br />

the successful diffusion of the resin monomers.<br />

To overcome this problem, two approaches were<br />

introduced. The first one is called “dry-bonding<br />

technique” and involves air-drying of dentine after<br />

etching and subsequent application of a waterbased<br />

primer that can re-expand the collapsed<br />

collagen (6, 7). The second one is the “wet bonding<br />

technique” in which the demineralized collagen is<br />

supported by residual water after washing (8). This<br />

allows the priming solution to diffuse throughout<br />

the collagen fibre network more successfully.<br />

However, when it comes to clinical practice, it is<br />

very difficult to find the correct balance of residual<br />

moisture. Excess water can be detrimental to<br />

bonding and these problems have been described<br />

as “overwetting phenomena” (9). Since the<br />

“dry-bonding technique” is considered to be<br />

significantly less technique sensitive, it should<br />

be preferred over the most difficult to standardize<br />

“wet bonding technique” (2).<br />

Relevant in-vitro bond strength studies can provide<br />

a useful indication of the prospective clinical<br />

success of a system. However, the highest level of<br />

evidence for comparing the efficiency of a bonding<br />

system is obtained from randomised clinical trials.<br />

Randomised clinical trials with elongated the<br />

treatment periods will be very useful in assessing<br />

both the effectiveness of a particular group and<br />

a particular method of application.<br />

References<br />

1. Nakabayashi N, Kojima K, Masuhara E. The promotion of adhesion by<br />

the infiltration of monomers into tooth substrates. J Biomed Mater Res<br />

1982;16:265-273.<br />

2. Van Landuyt K, De Munck J, Coutinho E, Peumans M, Lambrechts P,<br />

Van Meerbeek B. Bonding to Dentin: Smear Layer and the Process of<br />

Hybridization. In: Eliades G, Watts DC, Eliades T, editors. Dental Hard<br />

Tissues and Bonding Interfacial Phenomena and Related Properties Berlin:<br />

Springer; 2005. p. 89-122.<br />

3. Eick JD, Gwinnett AJ, Pashley DH, Robinson SJ. Current concepts on<br />

adhesion to dentin. Crit Rev Oral Biol Med 1997;8:306-335.<br />

4. Van Meerbeek B, Braem M, Lambrechts P, Vanherle G. Morphological<br />

characterization of the interface between resin and sclerotic dentine.<br />

J Dent Res 1994;22:141-146.<br />

5. Van Meerbeek B, Inokoshi S, Braem M, Lambrechts P, Vanherle G.<br />

Morphological aspects of the resin-dentin interdiffusion zone with<br />

different dentin adhesive systems. J Dent Res 1992;71:1530-1540.<br />

6. Finger WJ, Balkenhol M. Rewetting strategies for bonding to dry dentin<br />

with an acetone-based adhesive. J Adhes Dent 2000;2:51-56.<br />

7. Frankenberger R, Krämer N, Petschelt A. Technique sensitivity of dentin<br />

bonding: effect of application mistakes on bond strength and marginal<br />

adaptation. Oper Dent 2000;25:324-330.<br />

8. Kanca JI. Effect of resin primer solvents and surface wetness on resin<br />

composite bond strength to dentin. Am J Dent 1992;5:213-215.<br />

9. Tay FR, Gwinnett JA, Wei SH. Micromorphological spectrum from<br />

overdrying to overwetting acid-conditioned dentin in water-free acetonebased,<br />

single-bottle primer/adhesives. Dent Mater 1996;12:236-244.<br />

8<br />

Your practice is our inspiration.

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