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<strong>Trapped</strong> <strong>Annular</strong> <strong>Pressure</strong>:<br />

A Spacer Fluid that Shrinks (Update)<br />

Ron Bland, Ron Foley, Floyd Harvey, Baker Hughes Drilling<br />

Fluids, Ben Bloys, Many Gonzales, Chevron, Robert Hermes,<br />

Los Alamos National Laboratory, John M. Daniel, Floyd<br />

Billings, Ian Robinson, Lucite International, Marlon Allison,<br />

Flow Process Technologies, John Davis, Terry Cassel, Baker<br />

Oil Tools


What is <strong>Trapped</strong> <strong>Annular</strong> <strong>Pressure</strong>?<br />

(or <strong>Annular</strong> <strong>Pressure</strong> Buildup)<br />

•When cement is not<br />

circulated back to surface,<br />

drilling fluids or spacers<br />

become trapped in the<br />

annulus between the top of<br />

cement and the wellhead<br />

•Heat from produced oil/gas<br />

/water causes thermal<br />

expansion of these trapped<br />

annular fluids and can create<br />

more than enough pressure<br />

to collapse casing and tubing<br />

strings


From SPE 89775 - Pattillo, et al


What is <strong>Trapped</strong> <strong>Annular</strong> <strong>Pressure</strong>?<br />

• Mostly an issue in subsea<br />

completed wells<br />

• Previous mitigation techniques<br />

include VIT, heavy walled casing,<br />

nitrogen-based spacers, burst<br />

disks, crushable foam, leaving<br />

cement short of shoe, etc.


A New Approach<br />

• Cooperative research between Chevron and Los Alamos<br />

National Lab led to the development of a shrinking<br />

spacer based on methyl methacrylate (MMA)<br />

• MMA is a liquid monomer that polymerizes to form many<br />

familiar items like plastic windows and acrylic<br />

paperweights, and is the active ingredient in many latex<br />

paints<br />

• MMA shrinks 20% as it changes from emulsified liquid<br />

MMA droplets to tiny solid poly-MMA particles


<strong>Trapped</strong> <strong>Annular</strong> <strong>Pressure</strong><br />

Shrinking Spacer (TAPSS) Formulation<br />

• MMA is emulsified into a standard water-based spacer at<br />

10–50%<br />

•Water<br />

•Biopolymer (for viscosity)<br />

•Barite (1 st test – 12 ppg)<br />

•Emulsifiers<br />

•MMA (1 st test - 28%)<br />

•Defoamer<br />

•Inhibitor<br />

•Initiator (added as spacer is pumped)<br />

•Bicarb & caustic<br />

•Dispersant


TAPSS Preparation Overview<br />

MMA Monomer<br />

Initiator<br />

Solution<br />

Metering<br />

Mixer<br />

MMA/WBM Emulsion<br />

Transported<br />

to Wellsite<br />

Metering<br />

Mixer<br />

Pump<br />

Downhole<br />

Water-Based Mud


Mid-Scale Field Trial<br />

• Test site in Bossier City,<br />

LA had a 500-ft, cased well<br />

• Built an annulus from 7” 7<br />

and 9-5/89<br />

5/8” casing, with 3-3<br />

1/2” pipe within for hot<br />

water injection<br />

• <strong>Pressure</strong> tested


4500<br />

Test Results<br />

<strong>Trapped</strong> <strong>Annular</strong> <strong>Pressure</strong> Mitigation<br />

TAPSS vs. Standard Spacer<br />

4000<br />

3500<br />

Annulus <strong>Pressure</strong> - psi<br />

3000<br />

2500<br />

2000<br />

1500<br />

1000<br />

Polymerization begins<br />

Standard Spacer<br />

500<br />

TAPSS<br />

0<br />

0 20 40 60 80 100 120 140 160 180<br />

Minutes of Annulus Heating


TAPSS After Reaction<br />

Thicker, but still liquid with 28% Poly-MMA


Compatibility with Drilling Operations<br />

• Elastomers<br />

OK<br />

OK<br />

OK<br />

Buna ® (butadiene nitrile)<br />

Viton ® (fluoroelastomer)<br />

Urethanes<br />

• Contamination with Cement – OK<br />

• Contamination with KCl, NaCl or CaCl2 – OK<br />

• Contamination with SBM – OK<br />

• Contamination with standard cement spacer - OK


Off–Shore Procedure<br />

• Shipped to rig in closed-top, vented tanks<br />

• Tank(s) spotted on rig (watch wt. limits)<br />

• Mixed with initiator solution just before going<br />

down hole (initiator is a 5-7% feed)<br />

• Pumped down hole using cement unit, or<br />

similar<br />

• Should not mix with mud system, but 15%<br />

contamination in SBM only moderately reduces<br />

LC50


Safety Issues<br />

• Detailed risk analysis/mitigation process<br />

• Pure MMA has a low flash point - 55 º F, similar to<br />

methanol - only handled in mud plant<br />

• The emulsified spacer has an open cup flash point of<br />

175 º F<br />

• Fumes can accumulate in tank head space and<br />

become a risk (grounding)<br />

• Plan to use the pumping unit to flush water back<br />

through lines and pump skid to original tank


Safety Issues, cont.<br />

• Tank bottoms, wash water, etc. will be treated<br />

with a ‘hot’ initiator to eliminate any unreacted<br />

MMA<br />

• Proper PPE will be specified<br />

• Drips pans under all connections<br />

• Absorbents for small spills<br />

• Surfactants make the LC 50 low, as expected – so<br />

no offshore disposal


Detailed Operations & Safety Plans


Land Test – Carthage, TX<br />

• A quick land trial was held in a<br />

tubing annulus to provide a full<br />

scale test of:<br />

– Safety protocols<br />

– All mixing/metering equipment<br />

and manifolds<br />

– Pumping, and clean-up<br />

procedures<br />

– Initiator behavior


Spacer Mixing Skid<br />

• Meter in<br />

MMA<br />

• Emulsify in a<br />

single pass<br />

• Pump to<br />

transport<br />

tank<br />

MMA in<br />

High Shear<br />

Mixer<br />

Spacer to Tank<br />

Mud in


Manifold


Initiator Addition Skid (rig)<br />

• Meter in<br />

initiator<br />

solution<br />

• Mix well<br />

with spacer<br />

• Charge<br />

main<br />

pumping<br />

unit<br />

Mud in<br />

Initiator in<br />

Mixer<br />

Out to pump<br />

unit & well


Initiator Tank and Addition Skid


Wellhead <strong>Pressure</strong> vs. Time<br />

1200<br />

1000<br />

<strong>Pressure</strong> (psig) at manifold<br />

800<br />

600<br />

400<br />

200<br />

0<br />

0 10 20 30 40 50 60<br />

Time (minutes)


Polymerization vs. Depth<br />

% conversion of<br />

monomer to polymer<br />

120<br />

100<br />

80<br />

60<br />

40<br />

20<br />

0<br />

0 1000 2000 3000 4000 5000 6000 7000 8000<br />

Vertical Depth (feet)


Clean-Up Flushing Effective


Results<br />

• All fluids accurately mixed and well emulsified<br />

• Smooth displacement into well<br />

• <strong>Pressure</strong>d to 1000 psi<br />

• Shrinkage occurred as expected (sampled<br />

during well cleanout):<br />

– Bottom of well (240° F) – hotter than St. Malo<br />

production temperature – reacted quickly<br />

– Top of well – similar temperature to St. Malo<br />

annulus – virtually no reaction<br />

• All equipment cleaned by flushing with rinse<br />

water back to original tank<br />

• No HSE incidents


Preparing for a Deepwater Trial<br />

CVX producing properties - GOMBU<br />

Projects – CVX Op<br />

Projects – Non Op<br />

Discoveries – CVX Op<br />

Petronius<br />

Discoveries – Non Op<br />

Exploration Wells<br />

Gemini<br />

Tahiti #7<br />

10¾” tieback annulus<br />

Q2’09<br />

Tubular Bells<br />

Genesis<br />

Blind<br />

Faith<br />

Cat. Deep<br />

Tahiti<br />

Knotty Head<br />

Great White<br />

Tiger<br />

Tonga<br />

Puma<br />

Big Foot<br />

Discoverer<br />

Deep Seas<br />

Silvertip/Tobago<br />

Trident<br />

Jack<br />

St Malo<br />

Appraisal Projects


Planning a TAPSS Application:<br />

Determine the extent of the problem<br />

1. Model temperatures and pressures in trapped<br />

annulus<br />

– During seal formation<br />

– Maximum during flow testing/production<br />

– Geothermal and hydrostatic<br />

2. Compare the above with casing and seal<br />

assembly ratings to determine the minimum<br />

pressure reduction needed during flow<br />

testing/production to stay within casing/seal<br />

assembly ratings


Planning a TAPSS Application:<br />

Is TAPSS a feasible solution?<br />

3. Calculate fluid volume shrinkage needed at<br />

maximum flow test temperatures/pressures to<br />

achieve pressure reduction in ‘2. 2.’ above<br />

4. Using new fluid volume and pressures from ‘3. 3.’<br />

above, calculate shut-in pressures under<br />

geothermal conditions<br />

5. Are shut-in pressures using new fluid volume<br />

within casing/seal assembly ratings?<br />

6. If no, TAPSS may not be a feasible solution for<br />

well design/flow test schedule


Tieback Example with 16” Liner<br />

Example Deepwater Casing Diagram<br />

Drilling Schematic<br />

Well: Subsea Completion #1 Rig: BA Drillship #1<br />

Mudline Location:<br />

WBS No.<br />

API Well Number:<br />

BHL Location:<br />

Latitude/Longitude.:<br />

RT to MSL (ft): ±90'<br />

OBJECTIVES: Water Depth (ft): ±7000<br />

DIRECTIONAL: Straight Hole<br />

RT to ML (ft): ±7000'<br />

18-3/4" HPWH @ -16' 16' AML<br />

38" Housing @ -12' 12' AML<br />

EVAL GEOLOGIC MARKERS HOLE CASING MUD LOT<br />

PROG OBJECTIVES MD TVD SIZE & CEMENT MW OBG/FG<br />

±7400'<br />

16" LS @ ±7,400<br />

MWD/LWD t/ TD ±300' MD<br />

36" Jetted to ±300' BML<br />

±300' BML<br />

26" Hole<br />

TOS @ 8,509'<br />

8,509' BML<br />

±8800' MD<br />

' BML<br />

TVD<br />

±8800'<br />

10 3/4" X 9-7/8" CROSSOVER @ +/- 9,500'<br />

22" to ±8800'<br />

500' Tail, TOC @ Mud-line, 200% OHE<br />

±17000 MD<br />

TVD<br />

17,000'<br />

13-5/8" TOL @ < 17K'<br />

16"to ±17000'


Planning a TAPSS Application:<br />

Determine extent of pressure relief possible<br />

7. If yes, TAPSS may be a feasible solution and<br />

additional pressure relief may be possible<br />

– Try increasing pressure reduction in ‘A’ above<br />

– Recalculate fluid volume shrinkage required<br />

– Recalculate shut-in pressures under geothermal<br />

conditions using new volume<br />

– Compare with casing/seal assembly design<br />

ratings<br />

– Continue iterations until casing/seal assembly<br />

design ratings are reached


Planning a TAPSS Application:<br />

Determine Fluid Details<br />

8. Calculate trapped annulus volume capacity<br />

9. Adjust for other fluids planned for annulus<br />

10. Difference is maximum TAPSS volume possible<br />

11. What is the desired TAPSS density as pumped<br />

downhole?<br />

12. Calculate TAPSS density as shipped allowing<br />

for initiator dilution<br />

13. Determine maximum tank loading based on<br />

empty tank weight, TAPSS density & rig deck<br />

load limit<br />

14. Calculate number of tanks needed


Planning a TAPSS Application:<br />

What are rig constraints?<br />

15. Choose TAPSS staging area based on:<br />

– Space<br />

– Utility access<br />

– Deck load limit<br />

– Evacuation<br />

– Cement pump if pump is on top deck<br />

16. If cement pump on a lower deck a small HP<br />

pump will probably be needed such as a gravel<br />

pack pump


Thanks to:<br />

• Management of Chevron, Los Alamos<br />

National Laboratory, Baker Hughes Drilling<br />

Fluids, Baker Oil Tools, Flow Process<br />

Technology and Lucite International for<br />

permission to present this work.<br />

• IADC and the Programme Committee for<br />

accepting our abstract


Happiness is No <strong>Annular</strong> <strong>Pressure</strong><br />

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