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Vol. 54—2000 - NorthEastern Weed Science Society

Vol. 54—2000 - NorthEastern Weed Science Society

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ABSORPTION, TRANSLOCATION AND METABOLISMOF ISOXAFLUTOLE IN<br />

YELLOW FOXTAIL (Setaria luteseens).<br />

S. Kushwaha" and P. C. Bhowmik'<br />

ABSTRACT<br />

Ourpreliminarystudieshaveshownyellow foxtail [Setaria lutescens (Weigel)<br />

Hubb.] to be less sensitive to isoxaflutole [5-cyclopropyl-4-(2-methylsulphonyl-4­<br />

trilluromethylbenzoyl) isoxazole]. Experimentswere conducted to study the extent of<br />

absorption,translocationof foliarapplied,andmetabolismof rootappliedisoxaflutolein<br />

yellow foxtail. Ring labeled "C isoxallutole was applied to three-leaf seedlings in half<br />

strength Hoagland solution. Plants were harvested 3, 6, 12,24, 48, 72, 96 and 120 hours<br />

aIler treatment. Plants were sectioned in treated leaf, leaves above treated leaf, leaves<br />

below treated leaf androots.Theamountof '''cisoxaflutolein variousplantparts was<br />

determined by digesting the plant samples in biological oxidizer. By the end of 48 h,<br />

foliar absorption reached to the maximum of 67.4% of total applied radioactivity. Treated<br />

leaf, leaves above treated leaf, leaves below treated leaf and roots had 45.0, 6.4, 15.6 and<br />

0.5%radioactivityrespectively.Formetabolismstudyof root appliedisoxaflutole,plants<br />

were harvested at 72 and 168 h. Plant extract was subjected to thin layer chromatography.<br />

Thetotalradioactivitywas identifiedas isoxaflutole,diketonitrilemetabolite,unknown<br />

metabolite A and benzoic acid, and the distribution was 4.6, 64.5, 7.3 and 17.9'/0at 72 h,<br />

and 4.1,55.8,9.5 and 24.2% at 168 h, respectively.<br />

'Graduate Research Assistant and Professor of <strong>Weed</strong> <strong>Science</strong>, Department of Plant and<br />

Soil <strong>Science</strong>s, University of Massachusetts, Amherst, MA 01003.<br />

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