Vol. 15—1961 - NorthEastern Weed Science Society

Vol. 15—1961 - NorthEastern Weed Science Society Vol. 15—1961 - NorthEastern Weed Science Society

08.06.2015 Views

58. . .R. D. &wet' and Joseph Cia).one ])epal'tmen;t of Vegetah1e crops, Cor~ University, Ithaca, N. Y. . * Although cmc-.:(2-ehloroaU71 diethyld1~iocarbsmate) -has found considerable 'Isage on ve$8tablecrops in Eastern United States, it bas not reached its fuU potential as a select1ve herbicide because of its errstic performance. elSC somet:t.mes faUB to control, Weds, and 1ft,' certain situations ~ injure the crop.. For best, performance _it is genere.U:y agreed that CDBCshould be applied' at planting and that ,~1gation should be given if rain does not occur soon after treating. In spite of these precautions, the performance ot cmc under t1~d conditions baa b4itenvariable. ~ purpose ot these investigations was to determine JIOre spec1t1ca1.ly the factors 1ntluenciDg C:r:£Cactivity under field conditions in order to avoid failures due to either crop injury or lack of weed kill. . Revd.ewof Literature '!'he activity of herbicides applied to the soU are known to be 1nf1uenced by marq, env1roD1lleutal and soll factors. Obtaining COIIIIIlerCia11Y acceptable veed control without crop inJury:trOll the proJer dosage at a presl:lD8bly selective soll .herbicide is a function ot the total influence of emtirol'.llDel1t and soil on the herbicide, on tbte veedJJ, and on the crop. The 1ntluencing factors most often. mentioned in CODDectton,nth the activity of cmc are rainfall, soU type, aDd timing. Temperature and formulation are also cited. Dardelson (1957) stated that cmc perto~ poorly with lov soU moisture. Irrigat::t11g great17 eDhanced·weed control. !bwver, delayed applications following rains were poor. He 'concluded the optimum procedure was to apply at time of seeding" and to irrigate if rains were not soon forthcoming. He did not suggest re$So~" tOl" t~ .Y~14b1e peri'01'lDal)ceat CDICunder variations in soU moisture conditions. It was further suagestedthat somewhat higher rates were needed in SUllllel" than 1n the coolert1me of the year.- Be also studied fQl'lllulationa and ~eported that 'ary granular carriers such as-vermiculite and attaclq wereas effective aaliquid formula'tions. otten (1957) reported 01'1 the persistence and movement of ODICin soils. He stated that both temperature and moisture were important factors influencing the loss of activity. His results also clearly showed that although CIIBCcould be leached, it vas rather difficult to move appreciable quantities downward from surface applications. This vas true even nth two inches of water on a Dunkirk sand which contained less than l~ organic matter and less than 4~ clay and sUt combined. lbvever I more CDECvas leached with a given amount of water, if the chemical was added to a wt soil rather than to a dry' soU. He concluded that microbial action vas important in rapid loss of activity at CDECunder field conditions. YPaper JJo. 451 of Department of Vegetable Crops. Sold as Vegedex by ltbnsanto Chemical Co.

Sheets (1959) studied, under laboratory conditions the influence of soU type on the activity of CDEC. He v~particule.rly concerned with organic and cl~ content, ca.tion exchange caPaCity and pH. There was no clear cut influence of e;ny of these characteristic$ on t:Q,ee.ctivity of CIBCas measured by toxicity to oats. Using rates of CDECroughly ten fold that of field applications, he found that with warm, moist conditions all levels of CDECwere rendered relatively innocuous within three months. U6f Gantz and Slife (1960) confirmed the findings Otten (1957) regarding the relative-lack of If!aCh1ng of CDiC with rainfa,ll. ',Tbese'WOrkers studied the persistence of CDECunder 1!1Oistand dry soU conditions at. temperatures of 40 0, 60° .. Boo"and 100°F. They found little loss of activity under either moist or dry soU conditions with the 40° and 6o°tres:tments. Initial activity was the same for wet and dry soUs, regardless 01' temperature. There was no difference in the activity of CDECin the mollitor dry soils at the higher temperatures. except in t,he first· ;t'Wt),weelts. At this time" a much higher level 01',act1vi'tywas ,noted under' 1!lOist,condit:l.ons. 'These findings are at variance with those ofO'tten (1957)wbo found practicaJJ.y cOIIJPlete loss of CDECac'tivi'tyat 82°F in about five d~ in moist soU. M:lnsanto (1959) reports that vola'tUi ty may be an important factor. in- . f'luencing activi'sy of CDEC. Vapor pressure of' CDECis stated 'to be 2.2 x 10- 3 mmof lfg a't 20°C. Water bas a V.P. of 17 mmof Hg at 20°C. l't was cal'culated tha.t'1n; the absence .of' other forces such as physical or chemical adsorbtion, CDECwould, evapera'te in less 'than eight hours at tempera'tures as low as '45°F. An ex:per~ was also rePOrted in which CDEC,and CDAAvereapplied to dry soU, surfaces and some treatments were covered with l/~ of 80il 1DlmediatSly after treating. This soU coveriDg grea'tly increased Randox activity. Only a't very low rates, one pound or less, could a. similar trend be noted for . CDiC. PecUliarly" 'When,samples were watered 1DImediately after "treating, Which, presumably, drsstically re4uced volatUity opPOrtunity, the same general beneficial results :eromcovering CDAAwere noted. This. is highly suggestive that factors otker ..than stra1gbt 'YolatUity mus't be involVed. Since ,'the vapor pressures of CDAAana..,.cDECare of'the same order of magnitude (when actiVit,­ is considered atter a, period of' •a week) it was tabe. expected that the performance of' both herbicides would be about the same. .However, CDECwas distinc'tly less influenced by the shallow soil covering than was CDAA. T~:J.s also suggests that volatility' per se is a qUestionable factor· influencing CDEe,activity. Havis (1959) reported that eight pounds of CDECSP,Plied tea dry soil surfa.ce and then either incorpora.'ted by stirring with a sballow cultivator or applYing one inch of' wa1ier gave very good weed coIrtroJ:. Applying CDECto a we1i soU was 1$8.8 sa.'t1sfactory.. ~1ITing the wet soU decreased the aC'tivity. No suggestion was made as totbe~ possible reasons for CDECvariab1e performance dependent on. soU moisture CoD,diti.ons or mechanical incorporation. Sweet (1960) reported that incorJ;lOration of CDECenhanced weed control and ~a.'tly· increased damage to red beets •. ' He also showed 'that damage to seeded crops under .fjAld And gt"epnho\un~ ~ondi+'iOl'lI'l COfl1d be l"8Mily correlated 59.

Sheets (1959) studied, under laboratory conditions the influence of soU<br />

type on the activity of CDEC. He v~particule.rly concerned with organic and<br />

cl~ content, ca.tion exchange caPaCity and pH. There was no clear cut influence<br />

of e;ny of these characteristic$ on t:Q,ee.ctivity of CIBCas measured by<br />

toxicity to oats. Using rates of CDECroughly ten fold that of field applications,<br />

he found that with warm, moist conditions all levels of CDECwere<br />

rendered relatively innocuous within three months.<br />

U6f<br />

Gantz and Slife (1960) confirmed the findings Otten (1957) regarding<br />

the relative-lack of If!aCh1ng of CDiC with rainfa,ll. ',Tbese'WOrkers studied<br />

the persistence of CDECunder 1!1Oistand dry soU conditions at. temperatures of<br />

40 0, 60° .. Boo"and 100°F. They found little loss of activity under either<br />

moist or dry soU conditions with the 40° and 6o°tres:tments. Initial<br />

activity was the same for wet and dry soUs, regardless 01' temperature. There<br />

was no difference in the activity of CDECin the mollitor dry soils at the<br />

higher temperatures. except in t,he first· ;t'Wt),weelts. At this time" a much<br />

higher level 01',act1vi'tywas ,noted under' 1!lOist,condit:l.ons. 'These findings are<br />

at variance with those ofO'tten (1957)wbo found practicaJJ.y cOIIJPlete loss of<br />

CDECac'tivi'tyat 82°F in about five d~ in moist soU.<br />

M:lnsanto (1959) reports that vola'tUi ty may be an important factor. in- .<br />

f'luencing activi'sy of CDEC. Vapor pressure of' CDECis stated 'to be 2.2 x 10- 3<br />

mmof lfg a't 20°C. Water bas a V.P. of 17 mmof Hg at 20°C. l't was cal'culated<br />

tha.t'1n; the absence .of' other forces such as physical or chemical adsorbtion,<br />

CDECwould, evapera'te in less 'than eight hours at tempera'tures as low as '45°F.<br />

An ex:per~ was also rePOrted in which CDEC,and CDAAvereapplied to dry<br />

soU, surfaces and some treatments were covered with l/~ of 80il 1DlmediatSly<br />

after treating. This soU coveriDg grea'tly increased Randox activity. Only<br />

a't very low rates, one pound or less, could a. similar trend be noted for .<br />

CDiC. PecUliarly" 'When,samples were watered 1DImediately after "treating, Which,<br />

presumably, drsstically re4uced volatUity opPOrtunity, the same general beneficial<br />

results :eromcovering CDAAwere noted. This. is highly suggestive that<br />

factors otker ..than stra1gbt 'YolatUity mus't be involVed. Since ,'the vapor<br />

pressures of CDAAana..,.cDECare of'the same order of magnitude (when actiVit,­<br />

is considered atter a, period of' •a week) it was tabe. expected that the performance<br />

of' both herbicides would be about the same. .However, CDECwas<br />

distinc'tly less influenced by the shallow soil covering than was CDAA. T~:J.s<br />

also suggests that volatility' per se is a qUestionable factor· influencing<br />

CDEe,activity.<br />

Havis (1959) reported that eight pounds of CDECSP,Plied tea dry soil<br />

surfa.ce and then either incorpora.'ted by stirring with a sballow cultivator or<br />

applYing one inch of' wa1ier gave very good weed coIrtroJ:. Applying CDECto a<br />

we1i soU was 1$8.8 sa.'t1sfactory.. ~1ITing the wet soU decreased the aC'tivity.<br />

No suggestion was made as totbe~ possible reasons for CDECvariab1e performance<br />

dependent on. soU moisture CoD,diti.ons or mechanical incorporation.<br />

Sweet (1960) reported that incorJ;lOration of CDECenhanced weed control<br />

and ~a.'tly· increased damage to red beets •. ' He also showed 'that damage to<br />

seeded crops under .fjAld And gt"epnho\un~ ~ondi+'iOl'lI'l COfl1d be l"8Mily correlated<br />

59.

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