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Vol. 15—1961 - NorthEastern Weed Science Society

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11/<br />

Persistence of Soil-Incorporated EPTCand Other Carbamates ­<br />

47..<br />

ABSTRACT<br />

.. 21<br />

L. L. Danielson, W. A. Gentner, and L. L. Jansen ­<br />

Studies were initiated in 1958 to determine the herbicidal activity of<br />

several soil-incorporated carbamate herbicides and to investigate the<br />

formulation, soil, and climatological factors involved in their persistence<br />

in the soil. Investigations included preliminary and terminal field<br />

studies and several greenhouse studies.<br />

1. Field studies of EPTC, CDEC,eIPC, isopropyl N-(3-methylphenyl)­<br />

carbamate, BCPC, and CEPCusing the logarithmic sprayer indicated that<br />

EFTCand CDECretained their herbicidal characteristics when soil.incorporated<br />

at rates of 16 IblA or less. EPTCwas more persistent than CDEC, on<br />

the basis of plant bio-assay responses.<br />

2. In greenhouse studies, a soil-incorporated. commercial formulation<br />

of EPTCdissipated most rapidly under conditions of surface-irrigation and<br />

was inversely related to soil organic-matter content.<br />

3. The commercial formulation of EFTCin water was compared to technical<br />

EFTCapplied in acetone, benzene, xylene, kerosene, and No. 2 fuel oil.<br />

Rate of dissipation of EFTCwas most rapid when it was applied in kerosene.<br />

The persistence characteristics of commercial EPTC in water and technical<br />

EFTC in kerosene were confirmed in field studies.<br />

4. Rate of dissipation of soil-incorporated commercial EPTCwas accelerated<br />

as temperatures increased whereas rate of dissipation of technical<br />

EPTCin k~rosene was not significantly affected in the present studies.<br />

5. Several concentrations of selected Burfactants decreased the rate of<br />

dissipation of soil-incorporated technical EPTC formulated in kerosene.<br />

6. These investigations clearly demonstrate that soil-incorporated<br />

carbamates differ widely in selectivity and persistence depending on chemical<br />

structure, formulation, soil composition, method of irrigation, and<br />

temperature. These data have broad implications in the performance of all<br />

soil-incorporated carbamatesand possibly all herbicides applied in organic<br />

solvents. It appears from these data that the period of persistence of<br />

soil-incorporated carbamates can be controlled within limits by the constituents<br />

used in formulation. These data also .euggest the possibili.ty that the<br />

period of actiVity of granular herbicides can be regulated by selectiQn of<br />

suitable solvents, surfactants, and granular carriers having specific<br />

characteristics.<br />

---------..,..-­<br />

v<br />

Paper submitted for publication in <strong>Weed</strong>s.<br />

Plant Physiologists, Crops Research Division, Agricultural Research Ser~<br />

?! vice, U. S. Department of Agriculture, Beltsvillej Maryland~

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