Vol. 15—1961 - NorthEastern Weed Science Society

Vol. 15—1961 - NorthEastern Weed Science Society Vol. 15—1961 - NorthEastern Weed Science Society

08.06.2015 Views

)0. Robbins et al(lO) state that "increase in polarity enhances the ap­ parent reactivity (of a herbicide) whereas .increase in its oil-like (a-polar) properties promotes penetration. " They conclude that since the two processes are apparently opposed, there must be an optimum POint in-the balance between them; and this in reality represents a compromise between toXicity and compatibility with the .cuticle. Orgell(9) has observed that cationic and anionic aurractants differ markedly in their effects on absorption of acidic compounds .. and Staniforth(11) states that npn-ionicwetUng agente differ hi action from that of sodium laurel sulfate - an anionic w~tting agent.. . . Currier's observation(l) that root absorptton of dalapon is enhanced by the addition of a s.urfactant is of interest since roots are nor-mafly readily wetted. by water, and thus. perhaps confirms Ennis' earlier observation(4) by indicating some effect on root cell protoplasm. . Knowledge of the effect of surfactants in herbicidal solutions is far from complete; and a 1954 summary by Currier still represents the state of the art fairly well. Foy(5) using both C 14 and Cl 36 labelled dalapon demonstrated the advantages of using wetting agents with dalapon, For example, on the basis of growth inhibition, it appeared that as much dalapon was absorbed by corn in one hour from sprays containing a surfactant as in two weeks from . a solution without a surfactant. Jansen(8) found a wide range .in response to dalapon by both soybeans and corn in tests using 63 different wetting agents in combination with dala:po~ , MATERIALS AND METHODS Prior to the start of tpis experiment. Jansen's data had been re­ viewed and, on the basis of his r eaulte , a number of surfactants which had improved the herbicidal effects of dalapon on corn and soybeans were ten­ tatively selected for use. Some of these were not readily available, so a further selection was made .. and the following surfactants were obtained:

... Surfactant Produced bz: . 31 • Duponal .... f A Flake Anionic E. L du Pont de Nemours and Company Ethomeen 8-15 Cationic Armour Chemical Corporation Tergitol T MN Non-ionic Union Carbide Corporation Polyglyco126-2 Non-ionic The Dow Chemical Company Tests to determine retention on the leave~ of quackgrass and tests to determine the required dosage of dalapon-2-C 4 showed that the nonionic surfactants were superior to both the ionic ones. Ac~ordingly, Tergitol TMN and Polyglycol 26-2 were used in the rest of the experiments. One of the early tests which gives some information concerning the effect of surfactants on the penetration of leaf surfaces was run as follows: A. group of quackgrass plants in the five-leaf stage was selected for uniformity. Glass vials 5 mm, in diameter and 70 mm, in length were filled with various labelled dalapon and wetting agent solutions. and the third leaf of each quackgrass plant was inserted into a vial to a depth of 50 mm, Evaporation and plant uptake were measured after. 24 and 48 hours. After 48 hours, the . plants were harvested and the various parts were ex­. ammed for radioactivity using liquid scintillation counting. Jror-the remainder of the tests" formulations containing unlabelled dalapon sodium salt at a concentration of 10 pounds in 60 gallons were used. A range of wetting agent concentratiOns of 0, 0.05%" 0.10/0" and 0.2% wetting agent in the final herbicide solution was uaed, These percentages are in the higher range of the concentrations of wetting agent used in field applications of dalapon at recommended rates. This experiment was conducted with pot-grown plants of quackgrass (Agropyron repens (L. ) Beauv.}, All test plants were grown from two node sections of quackgrass rhizomes which had been selected for uniform size and weight from a clone. The test plants were produced and held after tr-eatm ent in a Percival controlled envtronmem chamber with a ..day temperature of 78°F. and a night temperature O,f56,oF. ~ having three fC)ur-degree temperature steps between the extremes, The plants were grown under a twelve-hour day length with a maximum intensity of 3,900 foot-candles at bench height. Light intensity was also regulated thr-ough three Incr em ents per cycle, with nine hours ofmaxfm um intensity light during each 24-hour period. Plants W'ere selected for uniformity of sprouts shortly after emer-­ -gence~ and again at the three-leaf stage. A firv:\l selection made when the test was started resulted in an extremely uniform group of plants in the six-leaf stage of growth, each with a three-leaf shoot at the second node. Preliminary trials gave coefficients of variation of from eight to ten percent

)0.<br />

Robbins et al(lO) state that "increase in polarity enhances the ap­<br />

parent reactivity (of a herbicide) whereas .increase in its oil-like (a-polar)<br />

properties promotes penetration. "<br />

They conclude that since the two processes are apparently opposed,<br />

there must be an optimum POint in-the balance between them; and this in<br />

reality represents a compromise between toXicity and compatibility with the<br />

.cuticle.<br />

Orgell(9) has observed that cationic and anionic aurractants differ<br />

markedly in their effects on absorption of acidic compounds .. and<br />

Staniforth(11) states that npn-ionicwetUng agente differ hi action from that<br />

of sodium laurel sulfate - an anionic w~tting agent.. . .<br />

Currier's observation(l) that root absorptton of dalapon is enhanced<br />

by the addition of a s.urfactant is of interest since roots are nor-mafly readily<br />

wetted. by water, and thus. perhaps confirms Ennis' earlier observation(4)<br />

by indicating some effect on root cell protoplasm. . Knowledge<br />

of the effect of surfactants in herbicidal solutions is far from complete;<br />

and a 1954 summary by Currier still represents the state of the art fairly<br />

well.<br />

Foy(5) using both C 14 and Cl 36 labelled dalapon demonstrated the<br />

advantages of using wetting agents with dalapon, For example, on the basis<br />

of growth inhibition, it appeared that as much dalapon was absorbed by<br />

corn in one hour from sprays containing a surfactant as in two weeks from<br />

. a solution without a surfactant.<br />

Jansen(8) found a wide range .in response to dalapon by both soybeans<br />

and corn in tests using 63 different wetting agents in combination with<br />

dala:po~ ,<br />

MATERIALS AND METHODS<br />

Prior to the start of tpis experiment. Jansen's data had been re­<br />

viewed and, on the basis of his r eaulte , a number of surfactants which had<br />

improved the herbicidal effects of dalapon on corn and soybeans were ten­<br />

tatively selected for use. Some of these were not readily available, so a<br />

further selection was made .. and the following surfactants were obtained:

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