Vol. 15â1961 - NorthEastern Weed Science Society
Vol. 15â1961 - NorthEastern Weed Science Society Vol. 15â1961 - NorthEastern Weed Science Society
)0. Robbins et al(lO) state that "increase in polarity enhances the ap parent reactivity (of a herbicide) whereas .increase in its oil-like (a-polar) properties promotes penetration. " They conclude that since the two processes are apparently opposed, there must be an optimum POint in-the balance between them; and this in reality represents a compromise between toXicity and compatibility with the .cuticle. Orgell(9) has observed that cationic and anionic aurractants differ markedly in their effects on absorption of acidic compounds .. and Staniforth(11) states that npn-ionicwetUng agente differ hi action from that of sodium laurel sulfate - an anionic w~tting agent.. . . Currier's observation(l) that root absorptton of dalapon is enhanced by the addition of a s.urfactant is of interest since roots are nor-mafly readily wetted. by water, and thus. perhaps confirms Ennis' earlier observation(4) by indicating some effect on root cell protoplasm. . Knowledge of the effect of surfactants in herbicidal solutions is far from complete; and a 1954 summary by Currier still represents the state of the art fairly well. Foy(5) using both C 14 and Cl 36 labelled dalapon demonstrated the advantages of using wetting agents with dalapon, For example, on the basis of growth inhibition, it appeared that as much dalapon was absorbed by corn in one hour from sprays containing a surfactant as in two weeks from . a solution without a surfactant. Jansen(8) found a wide range .in response to dalapon by both soybeans and corn in tests using 63 different wetting agents in combination with dala:po~ , MATERIALS AND METHODS Prior to the start of tpis experiment. Jansen's data had been re viewed and, on the basis of his r eaulte , a number of surfactants which had improved the herbicidal effects of dalapon on corn and soybeans were ten tatively selected for use. Some of these were not readily available, so a further selection was made .. and the following surfactants were obtained:
... Surfactant Produced bz: . 31 • Duponal .... f A Flake Anionic E. L du Pont de Nemours and Company Ethomeen 8-15 Cationic Armour Chemical Corporation Tergitol T MN Non-ionic Union Carbide Corporation Polyglyco126-2 Non-ionic The Dow Chemical Company Tests to determine retention on the leave~ of quackgrass and tests to determine the required dosage of dalapon-2-C 4 showed that the nonionic surfactants were superior to both the ionic ones. Ac~ordingly, Tergitol TMN and Polyglycol 26-2 were used in the rest of the experiments. One of the early tests which gives some information concerning the effect of surfactants on the penetration of leaf surfaces was run as follows: A. group of quackgrass plants in the five-leaf stage was selected for uniformity. Glass vials 5 mm, in diameter and 70 mm, in length were filled with various labelled dalapon and wetting agent solutions. and the third leaf of each quackgrass plant was inserted into a vial to a depth of 50 mm, Evaporation and plant uptake were measured after. 24 and 48 hours. After 48 hours, the . plants were harvested and the various parts were ex. ammed for radioactivity using liquid scintillation counting. Jror-the remainder of the tests" formulations containing unlabelled dalapon sodium salt at a concentration of 10 pounds in 60 gallons were used. A range of wetting agent concentratiOns of 0, 0.05%" 0.10/0" and 0.2% wetting agent in the final herbicide solution was uaed, These percentages are in the higher range of the concentrations of wetting agent used in field applications of dalapon at recommended rates. This experiment was conducted with pot-grown plants of quackgrass (Agropyron repens (L. ) Beauv.}, All test plants were grown from two node sections of quackgrass rhizomes which had been selected for uniform size and weight from a clone. The test plants were produced and held after tr-eatm ent in a Percival controlled envtronmem chamber with a ..day temperature of 78°F. and a night temperature O,f56,oF. ~ having three fC)ur-degree temperature steps between the extremes, The plants were grown under a twelve-hour day length with a maximum intensity of 3,900 foot-candles at bench height. Light intensity was also regulated thr-ough three Incr em ents per cycle, with nine hours ofmaxfm um intensity light during each 24-hour period. Plants W'ere selected for uniformity of sprouts shortly after emer- -gence~ and again at the three-leaf stage. A firv:\l selection made when the test was started resulted in an extremely uniform group of plants in the six-leaf stage of growth, each with a three-leaf shoot at the second node. Preliminary trials gave coefficients of variation of from eight to ten percent
- Page 1 and 2: THE USE OF VEGETATIVECHARACTERISTIC
- Page 3 and 4: In a few grasses with smooth sheath
- Page 5 and 6: 5. FACTORSINFLUEUCINGTHE PERFORFANC
- Page 7 and 8: 7. The introduction of synthetic or
- Page 9 and 10: The com;onents the distribution of
- Page 11 and 12: grains. We early found that the oat
- Page 13 and 14: 13. Atrazine Days following cpm/O.
- Page 15 and 16: 15. not find an abundant production
- Page 17 and 18: Weed Control In Suburbia 1 Howard H
- Page 19 and 20: For establishing new lawns, I would
- Page 21 and 22: Any improvement that you can make i
- Page 23 and 24: PROMISINGNEWCHEMICALSFORWEEDCONTROL
- Page 25 and 26: 25. Promis ins results have also be
- Page 27 and 28: 27. (Lycbnis alba), cinquefoil (Pot
- Page 29: THE EFFECTS OF ADDED PENETRANT AIDS
- Page 33 and 34: 33. 33. of scintillation solution,
- Page 35 and 36: Table 3. The Net Counts Per Minute
- Page 37 and 38: The comparisons for lower leaves, s
- Page 39 and 40: 39. SUMMARY Tests using 2-C 14-1abe
- Page 41 and 42: 41. RECENTDEVELOPMENTS IN THEUSE OF
- Page 43 and 44: second application be made not late
- Page 45 and 46: 45. Combinations of vegadex-Randox
- Page 47 and 48: 11/ Persistence of Soil-Incorporate
- Page 49 and 50: Plot size varied from 9 sq. ft. to
- Page 51 and 52: Lower rates of R-1856 were tested o
- Page 53 and 54: greenhouse tests are listed below.
- Page 55 and 56: PROGRESSREPORTON LAY-BYUEEDCONTROLI
- Page 57 and 58: 57. Table 1. Effect of sodium silic
- Page 59 and 60: Sheets (1959) studied, under labora
- Page 61 and 62: M, ',. • • •• • " ' Treat
- Page 63 and 64: Figure 1. Relative performance trea
- Page 65 and 66: A duplicate test was started August
- Page 67 and 68: 67. "he two tests which dealt with
- Page 69 and 70: 69. CONTROLOF WEEDSIN VEGETABLECROP
- Page 71 and 72: 71.' TABLE 3. RESPONSE OF VEGETABLE
- Page 73 and 74: 73. COHBIltit.TloNS' OF cnu:'PITH C
- Page 75 and 76: 75. Results The delay in applicatio
- Page 77 and 78: 77. Summary Logarithmic, tank-mixed
- Page 79 and 80: (' ( ( Table 1 Rates and Dates of H
)0.<br />
Robbins et al(lO) state that "increase in polarity enhances the ap<br />
parent reactivity (of a herbicide) whereas .increase in its oil-like (a-polar)<br />
properties promotes penetration. "<br />
They conclude that since the two processes are apparently opposed,<br />
there must be an optimum POint in-the balance between them; and this in<br />
reality represents a compromise between toXicity and compatibility with the<br />
.cuticle.<br />
Orgell(9) has observed that cationic and anionic aurractants differ<br />
markedly in their effects on absorption of acidic compounds .. and<br />
Staniforth(11) states that npn-ionicwetUng agente differ hi action from that<br />
of sodium laurel sulfate - an anionic w~tting agent.. . .<br />
Currier's observation(l) that root absorptton of dalapon is enhanced<br />
by the addition of a s.urfactant is of interest since roots are nor-mafly readily<br />
wetted. by water, and thus. perhaps confirms Ennis' earlier observation(4)<br />
by indicating some effect on root cell protoplasm. . Knowledge<br />
of the effect of surfactants in herbicidal solutions is far from complete;<br />
and a 1954 summary by Currier still represents the state of the art fairly<br />
well.<br />
Foy(5) using both C 14 and Cl 36 labelled dalapon demonstrated the<br />
advantages of using wetting agents with dalapon, For example, on the basis<br />
of growth inhibition, it appeared that as much dalapon was absorbed by<br />
corn in one hour from sprays containing a surfactant as in two weeks from<br />
. a solution without a surfactant.<br />
Jansen(8) found a wide range .in response to dalapon by both soybeans<br />
and corn in tests using 63 different wetting agents in combination with<br />
dala:po~ ,<br />
MATERIALS AND METHODS<br />
Prior to the start of tpis experiment. Jansen's data had been re<br />
viewed and, on the basis of his r eaulte , a number of surfactants which had<br />
improved the herbicidal effects of dalapon on corn and soybeans were ten<br />
tatively selected for use. Some of these were not readily available, so a<br />
further selection was made .. and the following surfactants were obtained: