1.1 MB pdf - Bolsa Chica Lowlands Restoration Project
1.1 MB pdf - Bolsa Chica Lowlands Restoration Project 1.1 MB pdf - Bolsa Chica Lowlands Restoration Project
SECTION 4: RISK CHARACTERIZATION • Bolsa Bay – Inner Bolsa Bay (Cell IB) and Outer Bolsa Bay (Cell OB) • Full Tidal – Cells 1, 1A, 3 through 8, 15 through 18, 43, 44, 51, 58, 59, 61, and 62 • Future Full Tidal – Cells 14, 19 through 40, and 63 • Garden Grove – Winterburg Flood Control Channel – Cell 52 • Gas Plant Pond Area – offsite areas downgradient from the former gas plant, south of Cells 11 and 12 • Muted Tidal plus Rabbit Island – Cells 41, 42, 45 through 50, 53, 55, 60, 66, and 67 • Seasonal Ponds – Cells 2, 9 through 13 The receptors evaluated for terrestrial (e.g., upland) exposures consisted of terrestrial plants and invertebrates, Belding’s savannah sparrow (or “sparrow”), American kestrel (or “kestrel”), western harvest mouse (“mouse”), and coyote (“coyote”). Evaluation areas within the Lowlands that were assessed for potential risks to terrestrial receptors included Future Full Tidal, Gas Plant Pond Area, Muted Tidal plus Rabbit Island, and Seasonal Ponds. The receptors evaluated for aquatic and semi-aquatic exposures consisted of aquatic plants, invertebrates, and fish; black-crowned night-heron (or “heron”); black-necked stilt (“stilt”); and least tern (or “tern”). The evaluation areas within the Lowlands that were assessed for potential risks to aquatic and semi-aquatic receptors included Bolsa Bay, Full Tidal, Future Full Tidal, Garden Grove-Wintersburg Flood Control Channel, Gas Plant Pond Area, Muted Tidal plus Rabbit Island, and Seasonal Ponds. 4.1.1 Sediment /Soil – Terrestrial Receptors Sediment/soil from evaluation areas identified above as terrestrial habitat were evaluated for potential risks to terrestrial receptors. Risk estimates were calculated for terrestrial plants and invertebrates, as well as upland birds, and mammals. The results for chemicals with HQs exceeding 1 are presented in Table 4-1 for plants and invertebrates and in Table 4-2 for birds and mammals. The HQs for all detected chemicals are presented in Appendix I, Tables I-1 and I-2. 4.1.1.1 Future Full Tidal Terrestrial Plants Terrestrial plants were quantitatively evaluated through comparison to RTVs from literature sources (Table 3-25) as site-specific toxicity values were not derived for terrestrial plants. Chronic NOECs were only available for a limited number of COPECs, so most of the comparisons were conducted using chronic LOECs. A summary of HQs exceeding one for terrestrial plants is presented in Table 4-1. Two chemicals, nickel and selenium, exceeded chronic NOECs with HQs of 650 and 384, respectively. Comparisons to chronic LOECs resulted in 17 inorganics and 4 organics posing a possible risk (Category B). The HQs ranged from 1.9 for 4-nitrophenol to 850 for lead. Of those chemicals exceeding chronic LOECs, 4 were evaluated using an exposure point concentration that was ½ the reporting limit for a non-detect. SAC/143368(004.DOC) 4-3 ERA REPORT 7/31/02
SECTION 4: RISK CHARACTERIZATION Terrestrial Invertebrates Terrestrial invertebrates were quantitatively evaluated through comparison to RTVs from literature sources as site-specific toxicity values were not derived (Table 3-26). Similar to plants, most RTVs available were for chronic LOECs and only a few chronic NOECs were used. Risk estimates for terrestrial invertebrates (Table 4-1) indicated that cadmium (HQ=19) and zinc (HQ=116) exceeded chronic NOECs. Chronic LOECs were exceeded by 11 inorganic and 7 organic chemicals indicating a possible risk (Category B) for these COECs. The HQs ranged from 1 to 565; vanadium (HQ=565), mercury (HQ=380), and chromium (HQ=313) had the highest HQs. Of those chemicals exceeding chronic LOECs, 2 were evaluated using an exposure point concentration that was ½ the reporting limit for a non-detect. Upland Birds Birds were evaluated quantitatively through comparison of estimated total daily dosages to chronic NOAEL and LOAEL RTVs obtained from the literature (Table 3-27). Site-specific toxicity values and acute toxicity values were not obtained for birds. Two upland bird species were used for screening at the Future Full Tidal including sparrow and kestrel (Table 4-2). Sparrows were more sensitive to chemical concentrations (i.e., had a higher HQ) than kestrels. Six metals exceeded NOAELs and two, lead and zinc, also exceeded LOAELs. LOAELs were not available for barium, chromium and vanadium so resulting risk to these chemicals is uncertain (Category U). Some possible risk (Category C) is posed by cobalt for both receptors and lead and zinc for kestrels because the LOAEL was not exceeded. Lead and zinc pose a possible risk (Category B) to sparrows because both the NOAEL and LOAEL were exceeded. NOAEL-based HQs ranged from 1.1 for barium (sparrow) to 13 for lead (sparrow). LOAEL-based HQs for sparrows were 1.4 for lead and 1.01 for zinc. Mammals Mammals were quantitatively evaluated in a similar manner as birds, with the harvest mouse and the coyote as representative species of mammals using the Future Full Tidal area (Table 4-2). Inorganics were the only COECs for these receptors. The potential risk was uncertain (Category U) for cobalt and vanadium because LOAELs were not available. There is some possible risk (Category C) from exposure to barium and lead because the LOAELs were not exceeded. The highest NOAEL HQ was 69 for barium (mouse). 4.1.1.2 Gas Plant Pond Area Terrestrial Plants COPECs detected in the Gas Plant Pond Area that exceeded available chronic NOECs for terrestrial plants consisted of selenium and nickel with HQs of 11 and 1.7, respectively (Table 4-1). Chronic LOECs were exceeded by 11 chemicals indicating a possible risk (Category B). Of these chemicals, arsenic (HQ=41), benzo(g,h,i) perylene (HQ=23), and benzo(a)pyrene (HQ=21) had the highest HQs. Of those chemicals exceeding chronic LOECs, 5 were evaluated using an exposure point concentration that was ½ the reporting limit for a non-detect. Terrestrial Invertebrates Available chronic NOECs for terrestrial invertebrates were not exceeded, but arsenic, chromium, copper, vanadium, and acenaphthene all exceeded chronic LOECs indicating a possible risk to terrestrial invertebrates from these COECs. HQs ranged from 1.1 to 3.8 (Table 4-1). ERA REPORT 4-4 SAC/143368(004.DOC) 7/31/02
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SECTION 4: RISK CHARACTERIZATION<br />
Terrestrial Invertebrates<br />
Terrestrial invertebrates were quantitatively evaluated through comparison to RTVs from<br />
literature sources as site-specific toxicity values were not derived (Table 3-26). Similar to<br />
plants, most RTVs available were for chronic LOECs and only a few chronic NOECs were<br />
used. Risk estimates for terrestrial invertebrates (Table 4-1) indicated that cadmium (HQ=19)<br />
and zinc (HQ=116) exceeded chronic NOECs. Chronic LOECs were exceeded by 11 inorganic<br />
and 7 organic chemicals indicating a possible risk (Category B) for these COECs. The HQs<br />
ranged from 1 to 565; vanadium (HQ=565), mercury (HQ=380), and chromium (HQ=313)<br />
had the highest HQs. Of those chemicals exceeding chronic LOECs, 2 were evaluated using<br />
an exposure point concentration that was ½ the reporting limit for a non-detect.<br />
Upland Birds<br />
Birds were evaluated quantitatively through comparison of estimated total daily dosages to<br />
chronic NOAEL and LOAEL RTVs obtained from the literature (Table 3-27). Site-specific<br />
toxicity values and acute toxicity values were not obtained for birds. Two upland bird<br />
species were used for screening at the Future Full Tidal including sparrow and kestrel<br />
(Table 4-2). Sparrows were more sensitive to chemical concentrations (i.e., had a higher HQ)<br />
than kestrels. Six metals exceeded NOAELs and two, lead and zinc, also exceeded LOAELs.<br />
LOAELs were not available for barium, chromium and vanadium so resulting risk to these<br />
chemicals is uncertain (Category U). Some possible risk (Category C) is posed by cobalt for<br />
both receptors and lead and zinc for kestrels because the LOAEL was not exceeded. Lead<br />
and zinc pose a possible risk (Category B) to sparrows because both the NOAEL and<br />
LOAEL were exceeded. NOAEL-based HQs ranged from <strong>1.1</strong> for barium (sparrow) to 13 for<br />
lead (sparrow). LOAEL-based HQs for sparrows were 1.4 for lead and 1.01 for zinc.<br />
Mammals<br />
Mammals were quantitatively evaluated in a similar manner as birds, with the harvest<br />
mouse and the coyote as representative species of mammals using the Future Full Tidal area<br />
(Table 4-2). Inorganics were the only COECs for these receptors. The potential risk was<br />
uncertain (Category U) for cobalt and vanadium because LOAELs were not available. There<br />
is some possible risk (Category C) from exposure to barium and lead because the LOAELs<br />
were not exceeded. The highest NOAEL HQ was 69 for barium (mouse).<br />
4.<strong>1.1</strong>.2 Gas Plant Pond Area<br />
Terrestrial Plants<br />
COPECs detected in the Gas Plant Pond Area that exceeded available chronic NOECs for<br />
terrestrial plants consisted of selenium and nickel with HQs of 11 and 1.7, respectively<br />
(Table 4-1). Chronic LOECs were exceeded by 11 chemicals indicating a possible risk<br />
(Category B). Of these chemicals, arsenic (HQ=41), benzo(g,h,i) perylene (HQ=23), and<br />
benzo(a)pyrene (HQ=21) had the highest HQs. Of those chemicals exceeding chronic<br />
LOECs, 5 were evaluated using an exposure point concentration that was ½ the reporting<br />
limit for a non-detect.<br />
Terrestrial Invertebrates<br />
Available chronic NOECs for terrestrial invertebrates were not exceeded, but arsenic, chromium,<br />
copper, vanadium, and acenaphthene all exceeded chronic LOECs indicating a possible risk to<br />
terrestrial invertebrates from these COECs. HQs ranged from <strong>1.1</strong> to 3.8 (Table 4-1).<br />
ERA REPORT 4-4 SAC/143368(004.DOC)<br />
7/31/02