1.1 MB pdf - Bolsa Chica Lowlands Restoration Project

1.1 MB pdf - Bolsa Chica Lowlands Restoration Project 1.1 MB pdf - Bolsa Chica Lowlands Restoration Project

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SECTION 3: ANALYSIS Cadmium Background levels of cadmium in the Bolsa Chica Lowland sediments are estimated to be < 0.66 mg/Kg dw. This value represents the 91st and 95th percentile levels for the all sample and surface data sets, respectively. This data set had a large number of nondetect values (i.e., flagged with “U” in the database) that occur at higher concentrations in the data set. The resulting cumulative percent plots (Appendix E, Figures E-10a, E-11, and E-12) show a two-stepped curve. There were 368 samples out of the total 581 samples that were nondetects. The same value (0.66 mg/Kg) was at the 91st percentile level for the all sample data set when the nondetect values were removed. The resulting cumulative percent plot (Appendix E, Figure E-10b) shows a smooth curve rising to the break point, where the curve becomes discontinuous and starts to rise more steeply. A similar value of < 0.65 mg/Kg dw was estimated from the subsurface sample data set (86th percentile). Chromium Background levels of chromium in the Bolsa Chica Lowlands are estimated to be < 43 mg/Kg dw. This value represents the 94th and 90th percentile value for the all sample and surface data sets, respectively. A lower value (< 32 mg/Kg dw) was estimated from the subsurface sediment samples that represents the 96th percentile value for that data set. All three cumulative percent plots for chromium rise in a relatively smooth line to the break points, where the curves become less continuous and begin to rise more sharply (Appendix E, Figures E-13 through E-15). Cobalt The background level of cobalt for the Bolsa Chica Lowlands was estimated to be < 10.1 mg/Kg dw. This value represents the 93rd and 94th percentile value for the all sample and subsurface groups, respectively. A slightly lower value (< 10 mg/Kg dw) was estimated from the surface sediment data, representing the 91st percentile level. All three cumulative percent plots for cobalt rise in a relatively smooth line to the break points, where the curves become less continuous and begin to rise more sharply (Appendix E, Figures E-16 through E-18). Copper Background levels for copper in the Bolsa Chica Lowland sediments were estimated to be < 26.1 mg/Kg dw. This value was derived from the all sample data and represented the 91st percentile level. A slightly higher value was estimated from the surface (< 30 mg/Kg dw) sediment sample data set (91st percentile). A lower value was estimated from the subsurface (< 20.6 mg/Kg dw) sediment sample data set (94th percentile). Figure 3-2 shows the cumulative percent plot for all the copper samples and the break point in the curve where the upper limit of the background level was estimated. All three cumulative percent plots for copper rise in a relatively smooth line to the break points, where the curves begin to rise more sharply (Appendix E, Figures E-19 through E-21). Lead Background levels for lead in the Bolsa Chica Lowland sediments were estimated to be < 48 mg/Kg dw. This value represents the 95th and 92nd percentile levels for the all sample and surface data sets, respectively. A lower value of < 17.3 mg/Kg dw was estimated from SAC/143368(003.DOC) 3-15 ERA REPORT 7/31/02

SECTION 3: ANALYSIS the subsurface sediment samples and represents the 97th percentile value. All three cumulative percent plots for lead rise in a relatively smooth line to the break points, where the curves become less continuous and begin to rise more sharply (Appendix E, Figures E-22 through E-24). Mercury Background levels for mercury in Bolsa Chica sediments were estimated at < 0.28 mg/Kg dw. This value represents the 98th percentile for the all sample data set. When only detected values were considered in the all sample data set, the value represents the 93rd percentile. A value of < 0.23 mg/Kg dw (96th percentile) was estimated from surface sediment data set and a value of < 0.15 mg/Kg dw (95th percentile) was estimated from the subsurface sediment data set. This data set also had a large number of nondetect values with 391 samples out of the total 581 samples that were flagged as nondetects. The resulting cumulative percent plots (Appendix E, Figures E-25a, E-26, and E-27) show a two-stepped curve. When only the detect values were considered, the resulting cumulative percent plot shows a smooth curve to the break point, where the curve starts to rise more steeply (Appendix E, Figure E-25b). Nickel Background levels for nickel in the Bolsa Chica Lowland sediments were estimated to be < 30 mg/Kg dw. This value represents the 95th and 93rd percentile levels for the all sample and surface data sets, respectively. A lower value of < 19.1 mg/Kg dw was estimated from the subsurface sediment samples and represents the 95th percentile value. All three cumulative percent plots for nickel rise in a relatively smooth line to the break points, where the curves become less continuous and begin to rise more sharply (Appendix E, Figures E-28 through E-30). Selenium The background levels for selenium in Bolsa Chica sediments were estimated at < 0.54 mg/Kg dw. This value represents the 78th and the 96th percentile values for the all sample and surface data sets, respectively. When the nondetect values are removed, this value represents the 94th percentile value for the all sample group. The different cumulative percent plots for the two data sets are presented in Figures 3-5a and 3-5b. The break point on the cumulative percent plot without nondetects (Figure 3-5b) provides a clearer view of the change in slope for selenium concentrations. The estimated values for the subsurface (< 0.49 mg/Kg dw) sediment samples were similar to that estimated from the all sample and surface sample groups. This data set also had a large number of nondetect values with 368 samples out of the total 580 samples that were flagged as nondetects. The resulting cumulative percent plots for selenium (Appendix E, Figures E-31a and E-33) show a stepped curve. The cumulative percent plots for the surface sediments (Figure E-32) and the all sediment plot with only the detected values (Figure E-31b) show a smooth curve to the break points, where the curves become discontinuous and rise more steeply. Silver The background level for silver in Bolsa Chica sediments is estimated to be < 0.22 mg/Kg dw. This value represents the 80th percentile value for the all sample data set. As was done for selenium, the all sample data set was also plotted without nondetect values in order to more ERA REPORT 3-16 SAC/143368(003.DOC) 7/31/02

SECTION 3: ANALYSIS<br />

Cadmium<br />

Background levels of cadmium in the <strong>Bolsa</strong> <strong>Chica</strong> Lowland sediments are estimated to be<br />

< 0.66 mg/Kg dw. This value represents the 91st and 95th percentile levels for the all sample<br />

and surface data sets, respectively. This data set had a large number of nondetect values<br />

(i.e., flagged with “U” in the database) that occur at higher concentrations in the data set.<br />

The resulting cumulative percent plots (Appendix E, Figures E-10a, E-11, and E-12) show<br />

a two-stepped curve. There were 368 samples out of the total 581 samples that were nondetects.<br />

The same value (0.66 mg/Kg) was at the 91st percentile level for the all sample data<br />

set when the nondetect values were removed. The resulting cumulative percent plot<br />

(Appendix E, Figure E-10b) shows a smooth curve rising to the break point, where the curve<br />

becomes discontinuous and starts to rise more steeply. A similar value of < 0.65 mg/Kg dw<br />

was estimated from the subsurface sample data set (86th percentile).<br />

Chromium<br />

Background levels of chromium in the <strong>Bolsa</strong> <strong>Chica</strong> <strong>Lowlands</strong> are estimated to be<br />

< 43 mg/Kg dw. This value represents the 94th and 90th percentile value for the all sample<br />

and surface data sets, respectively. A lower value (< 32 mg/Kg dw) was estimated from the<br />

subsurface sediment samples that represents the 96th percentile value for that data set. All<br />

three cumulative percent plots for chromium rise in a relatively smooth line to the break<br />

points, where the curves become less continuous and begin to rise more sharply<br />

(Appendix E, Figures E-13 through E-15).<br />

Cobalt<br />

The background level of cobalt for the <strong>Bolsa</strong> <strong>Chica</strong> <strong>Lowlands</strong> was estimated to be<br />

< 10.1 mg/Kg dw. This value represents the 93rd and 94th percentile value for the all<br />

sample and subsurface groups, respectively. A slightly lower value (< 10 mg/Kg dw) was<br />

estimated from the surface sediment data, representing the 91st percentile level. All three<br />

cumulative percent plots for cobalt rise in a relatively smooth line to the break points,<br />

where the curves become less continuous and begin to rise more sharply (Appendix E,<br />

Figures E-16 through E-18).<br />

Copper<br />

Background levels for copper in the <strong>Bolsa</strong> <strong>Chica</strong> Lowland sediments were estimated to be<br />

< 26.1 mg/Kg dw. This value was derived from the all sample data and represented the 91st<br />

percentile level. A slightly higher value was estimated from the surface (< 30 mg/Kg dw)<br />

sediment sample data set (91st percentile). A lower value was estimated from the subsurface<br />

(< 20.6 mg/Kg dw) sediment sample data set (94th percentile). Figure 3-2 shows the<br />

cumulative percent plot for all the copper samples and the break point in the curve where<br />

the upper limit of the background level was estimated. All three cumulative percent plots<br />

for copper rise in a relatively smooth line to the break points, where the curves begin to rise<br />

more sharply (Appendix E, Figures E-19 through E-21).<br />

Lead<br />

Background levels for lead in the <strong>Bolsa</strong> <strong>Chica</strong> Lowland sediments were estimated to be<br />

< 48 mg/Kg dw. This value represents the 95th and 92nd percentile levels for the all sample<br />

and surface data sets, respectively. A lower value of < 17.3 mg/Kg dw was estimated from<br />

SAC/143368(003.DOC) 3-15 ERA REPORT<br />

7/31/02

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