Influence of the Processes Parameters on the Properties of The ...

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Nomenclature and Abbreviations Abbreviation INPT Institut National Polytechnique de Toulouse CIRIMAT Centre Interuniversitaire de Recherche et d'Ingénierie des Matériaux LAAS Laboratoire d'Architecture et d'Analyse des Systèmes LGC Laboratoire de Génie Chimique 2 D Two Dimensions 3 D Three Dimensions ASTM American Society <strong>of</strong> Testing and Materials SS Stainless Steel CO 2 Carbon dioxide scCO 2 Supercritical carbon dioxide TIPS Thermally Induced Phase Separation FTIR Fourier transform infrared UV Ultraviolet radiation SEM Scanning electron microscopy TEM Transmission electron microscopy -CT Micro-computer tomography DSC Differential Scanning Calorimetry SL-EOS Sanchez and Lacombe’ Equation <strong>of</strong> State MHR Mark Houwink’ Relationship BME Basement membrane extract ECM Extracellular matrix PLA Poly(lactic acid) P L,D LA Poly D-Lactic acid P L,DL LA Poly D,L-Lactic acid PLGA Poly(lactic-co-glycolic acid) PCL Poly(-caprolactone) PGA Poly(glycolic acid) PI polyimide PC polycarbonate AMPEG α-amino-ω-methoxy-polyethylene glycol HA Hyaluronic acid GlcA Glucuronic acid Am-CP Amorphous calcium phosphate Ap-TCP Apatitic tricalcium phosphate TCP Amorphous tricalcium phosphate BCP Biphasic calcium phosphate αTCP α-Tricalcium phosphate TCP -Tricalcium phosphate CaP calcium phosphate DCPA Dibasic calcium phosphate anhydrate DCPD Dibasic calcium phosphate dihydrate HAp Hydoxyapatite OCP Octocalcium phosphate TCP Tricalcium phosphate TEA Triethylamine THF Tetrahydr<strong>of</strong>urane vii
Abbreviations Classical Unit P c Critical Pressure bar P sat Saturation Pressure bar T c Critical Temperature o C T sat Saturation Temperature o C T g Glass transition temperature °C T m Melting temperature C t co Co-grinding time minute t sat Saturation time minute dP/dt Depressurization rate bar/s m Melting enthalpy J.g -1 m Melting enthalpy <strong>of</strong> <strong>the</strong> totally cystallised polymer J.g -1 c Crystallization enthalpy J.g -1 Degree <strong>of</strong> crystallinity C p Variation <strong>of</strong> heat capacity J.g -1 .mol -1 D Diffusivity m 2 s -1 D dg Desorption diffusion coefficient at plasticized state m 2 s -1 D dp Desorption diffusion coefficient at glassy state m 2 s -1 Z Zeldovich factor Intrinsic Viscosity dL.g -1 inh Inherent Viscosity dL.g -1 rel Relative Viscosity M n Number average mass molecular Dalton M w Weight average mass molecular Dalton M vis Viscosity average mass molecular Dalton K Mark Houwink’ constant dL.g -1 a Mark Houwink’ constant Liquid-Solid Contact Angle ° γ L Surface Tension <strong>of</strong> Liquid mJ/m 2 γ S Surface Tension <strong>of</strong> Solid mJ/m 2 γ SL Solid-liquid interfacial tension mJ/m 2 γ SV Solid-vapour interfacial tension mJ/m 2 p γ S Polar component <strong>of</strong> surface energy mJ/m 2 d γ S Dispersive component <strong>of</strong> surface energy mJ/m 2 LW S Lifshitz–van der Waals component <strong>of</strong> surface energy mJ/m 2 AB S Acid–Base component <strong>of</strong> surface energy mJ/m 2 − γ S Basic Composnent <strong>of</strong> Surface mJ/m 2 + γ S Acid Composnent <strong>of</strong> Surface mJ/m 2 δ t Hildebrand’ solubility parameter (M Pa) 1/2 δ d Dispersive Hansen’ solubility parameter (M Pa) 1/2 δ H Hydrogen Hansen’ solubility parameter (M Pa) 1/2 δp Polar Hansen’ solubility parameter (M Pa) 1/2 Ø f Foam thickness mm Ø p Pellet thickness mm d f Foam diameter mm d p Pellet diameter mm m f Foam mass mg m p Pellet mass mg f Foam density viii
Page 1 and 2: Institut National Polytechnique de
Page 4: iii Dedicated to My Fathe</
Page 7 and 8: pleased I was to work with all memb
Page 10 and 11: Publications and Conferences The wo
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Page 36 and 37: Table 8.1: Polymers with different
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Chapter 1. Polylactide Based Bio-Ma
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Chapter 2. Processes</stron
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Chapter 3. Analytical Methods and D
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. Chapter 3. Analytical Methods and
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Chapter 5. Characterization <strong
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