SAFETY DATA SHEET Ultraseal PC504/66 - AMI-CON

Revision Date 13/12/2012
Revision 8
Supersedes date 19/10/2010
SAFETY DATA SHEET
Ultraseal PC504/66
According to Regulation (EC) No 1907/2006
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name
Ultraseal PC504/66
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Sealant.
1.3. Details of the supplier of the safety data sheet
Supplier
Ultraseal International
Godiva Place
Coventry
CV1 5PN
UK
+44 (0)24 7625 8444
+44 (0)24 7655 1402
MSDS@ultraseal.co.uk
1.4. Emergency telephone number
+44 (0)20 8911 2530
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (1999/45/EEC) Xi;R36. R43.
2.2. Label elements
Contains
Labelling
HYDROXYPROPYL METHACRYLATE
Irritant
Risk Phrases
Safety Phrases
2.3. Other hazards
R36
Irritating to eyes.
R43
May cause sensitisation by skin contact.
S24/25 Avoid contact with skin and eyes.
S26
In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S37
Wear suitable gloves.
S51
Use only in well-ventilated areas.
S47/49A
Keep only in original container at temperatures not exceeding 25°C.
SU1
Protect from sunlight
This product does not contain any PBT or vPvB substances.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
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Ultraseal PC504/66
HYDROXYPROPYL METHACRYLATE 50 - 100%
CAS-No.: Proprietary EC No.: 248-666-3
Classification (EC 1272/2008)
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Classification (67/548/EEC)
Xi;R36.
R43.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort
continues.
Ingestion
DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Get
medical attention.
Skin contact
Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water.
Get medical attention if any discomfort continues.
Eye contact
Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly
wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure.
Inhalation.
Irritation of nose, throat and airway.
Ingestion
No specific symptoms noted.
Skin contact
Prolonged skin contact may cause redness and irritation.
Eye contact
Irritation of eyes and mucous membranes.
4.3. Indication of any immediate medical attention and special treatment needed
Treat Symptomatically.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Fire can be extinguished using: Water spray. Foam, carbon dioxide or dry powder.
Unsuitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
Specific hazards
Carbon dioxide (CO2). Carbon monoxide (CO).
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water. Be aware of danger of explosion.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
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For personal protection, see section 8.
6.2. Environmental precautions
Ultraseal PC504/66
Do not discharge into drains, water courses or onto the ground.
6.3. Methods and material for containment and cleaning up
Ventilate well. Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers. Do not
contaminate water sources or sewer. Inform Authorities if large amounts are involved.
6.4. Reference to other sections
For personal protection, see section 8. See section 11 for additional information on health hazards. Collect and dispose of spillage as
indicated in section 13.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Store below 25°C. Protect from
freezing and direct sunlight.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
No exposure limits noted for ingredient(s).
8.2. Exposure controls
Protective equipment
Process conditions
Provide eyewash station.
Engineering measures
Well-ventilated area.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. In case of inadequate ventilation or when the product is heated, use suitable respiratory equipment with gas filter
(type A2).
Hand protection
Nitrile gloves are recommended. Be aware that the liquid may penetrate the gloves. Frequent change is advisable.
Eye protection
Use approved safety goggles or face shield.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash
promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink
or smoke.
Environmental Exposure Controls
Keep container tightly sealed when not in use.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance
Colour
Liquid
Light (or pale). Straw.
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Odour
Solubility
Initial boiling point and boiling range
Not available.
Melting point (°C)
Not available.
Mild (or faint).
Forms an emulsion.
Relative density 1.005 - 1.015 @ 20 °c
Vapour density (air=1)
Not available.
Evaporation rate
Not available.
pH-Value, Conc. Solution
Not available.
Viscosity 32 - 34 s @ 20 °c
Solubility Value (G/100G H2O@20°C)
Not available.
Decomposition temperature (°C)
Not available.
Odour Threshold, Lower
Not available.
Odour Threshold, Upper
Not available.
Flash point
Auto Ignition Temperature (°C)
Not available.
Flammability Limit - Lower(%)
Not available.
Flammability Limit - Upper(%)
Not available.
Partition Coefficient
(N-Octanol/Water)
Not available.
Explosive properties
Not available.
Oxidising properties
Not available.
9.2. Other information
Not available.
96 C
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
10.2. Chemical stability
Stable under normal temperature conditions.
10.3. Possibility of hazardous reactions
Hazardous Polymerisation
May polymerize violently.
Polymerisation Description
Ultraseal PC504/66
Store in original container to avoid contamination. Polymerises easily with evolution of heat. Keep cool. Avoid heat. Avoid light.
10.4. Conditions to avoid
Polymerises when heated. Avoid heat, flames and other sources of ignition. Avoid exposure to high temperatures or direct sunlight. Avoid
contact with acids and oxidising substances.
10.5. Incompatible materials
Materials To Avoid
Strong oxidising substances. Strong reducing agents. Inorganic peroxides. Organic peroxides/hydroperoxides. Strong acids. Strong
alkalis.
10.6. Hazardous decomposition products
Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2).
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Ultraseal PC504/66
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Toxicological information
No information available.
Germ cell mutagenicity:
This substance has no evidence of mutagenic properties.
Carcinogenicity:
This substance has no evidence of carcinogenic properties.
Reproductive Toxicity:
This substance has no evidence of toxicity to reproduction.
Inhalation
May cause irritation to the respiratory system.
Skin contact
Irritating to skin. May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Route of entry
Skin and/or eye contact.
Target Organs
Skin Eyes
Medical Symptoms
Skin irritation. Irritation of eyes and mucous membranes.
Toxicological information on ingredients.
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Toxic Dose 1 - LD 50
> 2000 mg/kg (oral rat)
Ultraseal PC504/66
HYDROXYPROPYL METHACRYLATE
Acute toxicity:
Acute Toxicity (Dermal LD50)
> 5000 mg/kg Rat
Respiratory or skin sensitisation:
Sensitising.
Germ cell mutagenicity:
Based on available data the classification criteria are not met.
Carcinogenicity:
Estimated Value
This substance has no evidence of carcinogenic properties.
Reproductive Toxicity:
No evidence of reproductive toxicity in animal studies
Specific target organ toxicity - single exposure:
Not classified as a specific target organ toxicant after a single exposure.
Specific target organ toxicity - repeated exposure:
STOT - Repeated exposure
NOAEL 300 mg/kg Oral Rat
Not classified as a specific target organ toxicant after repeated exposure.
Aspiration hazard:
Not anticipated to present an aspiration hazard based on chemical structure.
Inhalation
No specific health warnings noted.
Ingestion
No specific health warnings noted.
Skin contact
May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Route of entry
Skin and/or eye contact.
Target Organs
Skin Eyes
Irritation of eyes and mucous membranes.
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
Acute Toxicity - Fish
Not available.
Acute Toxicity - Aquatic Invertebrates
Not available.
Acute Toxicity - Aquatic Plants
Not available.
Acute Toxicity - Microorganisms
Not available.
Chronic Toxicity - Fish Early life Stage
Not available.
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Chronic Toxicity - Aquatic Invertebrates
Not available.
Acute Toxicity - Terrestrial
Not available.
Ultraseal PC504/66
Ecological information on ingredients.
HYDROXYPROPYL METHACRYLATE
Acute Toxicity - Fish
LC50 48 hours 493 mg/l Leuciscus idus (Golden orfe)
Acute Toxicity - Aquatic Invertebrates
EC50 48 hours 380 mg/l Daphnia magna
NOEC 48 hours 24.1 mg/l Daphnia magna
Acute Toxicity - Aquatic Plants
EC50 72 hours > 97.2 mg/l Freshwater algae
NOEC 72 hours 97.2 mg/l Freshwater algae
12.2. Persistence and degradability
Degradability
The product is expected to be biodegradable.
Ecological information on ingredients.
Degradability
HYDROXYPROPYL METHACRYLATE
Biodegradable according to the appropriate OECD test. This product is expected to be removed in a wastewater treatment plant. Oxides rapidly
by photochemical reactions in air
12.3. Bioaccumulative potential
Bioaccumulative potential
Bioaccumulation is unlikely to be significant because of the low water solubility of this product.
Partition coefficient
Not available.
Ecological information on ingredients.
Bioaccumulative potential
HYDROXYPROPYL METHACRYLATE
Bioaccumulation is unlikely to be significant because of the low water solubility of this product.
Partition coefficient
Pow 0.97
12.4. Mobility in soil
Mobility:
The product has poor water-solubility.
Ecological information on ingredients.
Mobility:
Mobile.
12.5. Results of PBT and vPvB assessment
Not relevant
Ecological information on ingredients.
HYDROXYPROPYL METHACRYLATE
This product does not contain any PBT or vPvB substances.
12.6. Other adverse effects
Not known.
Ecological information on ingredients.
HYDROXYPROPYL METHACRYLATE
Not available.
HYDROXYPROPYL METHACRYLATE
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Ultraseal PC504/66
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Dispose of waste and residues in accordance with local authority requirements.
SECTION 14: TRANSPORT INFORMATION
General
14.1. UN number
The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
Transport Labels
No transport warning sign required.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Statutory Instruments
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).
Approved Code Of Practice
Classification and Labelling of Substances and Preparations Dangerous for Supply.
Guidance Notes
CHIP for everyone HSG(108).
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
15.2. Chemical Safety Assessment
No chemical safety assessment has been carried out.
SECTION 16: OTHER INFORMATION
Revision Date 13/12/2012
Revision 8
Supersedes date 19/10/2010
Risk Phrases In Full
R36
R43
Irritating to eyes.
May cause sensitisation by skin contact.
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Hazard Statements In Full
H319
H317
Causes serious eye irritation.
May cause an allergic skin reaction.
Ultraseal PC504/66
Disclaimer
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. Ultraseal International shall not
be held liable for any damage resulting from contact with or handling of the above product.
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