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Scientific Report 2007-2009<br />

Condensed matter physics and biophysics<br />

C5. Phenomenology of transport properties in matter<br />

Transport properties are among the most relevant<br />

properties for the study and characterization of matter.<br />

They may reveal fundamental informations on the electronic<br />

state in solids (such as bandwidth, mobility, localization<br />

effects) or on the mobility of particles in fluids.<br />

Aimed to the study of transport phenomena under<br />

different conditions, our group has developed several experimental<br />

setups which allow us to measure electrical<br />

transport of different materials under a very wide range<br />

of external parameters: temperature (4.2 to 300 K and<br />

above), magnetic fields (up to 16 T), frequency (dc, rf<br />

and microwaves up to 65 GHz). We also developed ad<br />

hoc setups to study the resistivity tensor in anisotropic<br />

materials and microwave resistivity over a very wide,<br />

continuous spectrum.<br />

During the last three years, our group has been using<br />

the measured transport properties to study the dynamical<br />

behaviour of several materials under different physical<br />

conditions. The research has been mainly devoted<br />

to the study of superconductors (both in the normal and<br />

in the superconducting state), while recently the attention<br />

has been also focused on other materials (conducting<br />

polymers, complex liquids).<br />

Figure 1: c-axis resistivity of HTSC as a function of temperature<br />

at different magnetic fields.<br />

For what concerns superconductors, the research has<br />

been focused on the anomalous transport properties of<br />

High temperature superconductors (HTCS) even in their<br />

normal state (i.e. above T c ). The behaviour of resistivity<br />

as a function of temperature reveal several uncommon<br />

features, which are not fully explained by current<br />

theories. Some years ago we proposed a model for the<br />

description of the conductivity in HTCS in their normal<br />

state based on the role of internal barriers. In the last<br />

years, we exploited and extended this model to include<br />

other aspects of the measured properties of superconductors:<br />

charge confinement above T c [1,2], nonlinearity<br />

(both above and below T c ) [4], to end up with the<br />

common interpretation of superfluid (below T c ) and pair<br />

formation (above T c ) within a single phenomenological<br />

frame. Parallel to this study, we studied the specific<br />

case of MgB 2 and in particular its characteristic double<br />

band. Using the measurements at microwave frequencies,<br />

we have been able to identify the contribution of<br />

each band and the contribution of thermal fluctuations<br />

to the obesrved resistivity below T c [3].<br />

Figure 2: Microwave resistivity of MgB 2 as a function of<br />

magnetic field at T=15K. The difference between H c2 as determined<br />

by dc measurements and microwave measurements<br />

is explained in terms of thermal fluctuations.<br />

Conducting polymers films has been studied both at<br />

low frequency (d.c.) and at microwave frequencies. The<br />

growth of these films is not as reproducible as in the<br />

case of common solids. A reliable study can thus be<br />

made only by measuring large sets of samples, in order<br />

to catch the mean behaviours. To this end, we developed<br />

a fast and reliable method to measure the conductivity<br />

of these samples. The combined structural and<br />

electrical characterization allowed us to understand several<br />

relevant aspects of the growing mechanism and the<br />

relevance of microscopic and mesoscopic scale transport<br />

(article submitted to Appl. Phys. A)<br />

The study of complex liquids is still in a ”work in<br />

progress” phase. We realized a cell for the measurement<br />

of the complex permittivity of liquid samples up to 40<br />

GHz. After a relatively long setup procedure, a relevant<br />

data set has been collected (elaboration is in progress).<br />

References<br />

1. M.Giura et al., Supercond. Sci. Technol. 20, 54 (2007)<br />

2. M.Giura et al., Physica C 460-462, 831 (2007)<br />

3. S.Sarti et al., Jou. Supercond. Novel Mag.. 20, 51 (2007)<br />

4. M.Giura et al., Phys. Rev. B 79, 144504 (2009)<br />

Authors<br />

M.Giura, R.Fastampa, S.Sarti<br />

https://server2.phys.uniroma1.it/doc/sarti/g20-<br />

group.html<br />

<strong>Sapienza</strong> Università di Roma 58 Dipartimento di Fisica

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