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Scientific Report 2007-2009<br />

Geophysics<br />

G2. Solar spectrophotometry to measure O 3 , NO 2 , UV irradiance and<br />

polysulphone dosimetry to quantify human UV exposure<br />

The discovery of the Antarctic ozone hole in 1985 and<br />

the stratospheric ozone (O 3 ) downward trend at middle<br />

latitudes, observed since the 1970s, have hightened<br />

the interest within the scientific community on a possible<br />

increase of solar UV irradiance at the Earth’ surface.<br />

Current evidence suggests that UV exposure is the major<br />

causative factor in several short and long term skin<br />

and eyes diseases, whereas the only well-established beneficial<br />

effect of solar UV radiation is the production of<br />

vitamin D3, essential for bones health. Although the<br />

stratospheric O 3 downward trend is well documented<br />

and its relationship to UV irradiance is established, the<br />

understanding of the global UV climate, including variability<br />

and trends, is still not easily detectable. The<br />

role of cloud cover, aerosol and pollutants which, in<br />

turn may have a time behavior, is still under study.<br />

Although the availability of UV measurements of high<br />

quality from ground-based instruments has increased in<br />

the last decades, reliable UV time series are shorter than<br />

the total O3 series.<br />

In addition, most of ambient UV data consists of irradiance<br />

data while little is still known about UV exposure.<br />

The differently oriented body parts receive changing<br />

levels of radiation which is itself continuously changing,<br />

thus the quantification of human UV exposure is<br />

a complex issue being directly linked to the features of<br />

ambient UV irradiance under different conditions (i.e.<br />

urban, mountain, coastal sites), as well as to individual<br />

behavioural and cultural factors. As a result, even in areas<br />

of relatively low ambient UV radiation it is possible<br />

to experience relatively high personal exposure levels.<br />

The Meteorology research group (GMET) has carried<br />

out, since 1992, high quality UV and total ozone and nitrogen<br />

dioxide (NO 2 ) measurements using Brewer spectrophotometry.<br />

The Rome UV series is the longest time<br />

series in Italy (Fig.1).<br />

UVB-1 broad-band radiometer operational since 2000.<br />

In the last few years the GMET group participated to<br />

the investigation of solar UV variability in Europe [1].<br />

That study shows that changes in solar zenith angle are<br />

the major responsible, on a diurnal and annual basis,<br />

and that clouds play a significant role in modifying the<br />

UV pattern.<br />

In addition the GMET group contributed to the validation<br />

studies of satellite-derived total O 3 and UV data<br />

from the Ozone Monitoring Instrument (OMI), investigating<br />

the possible sources of uncertainty in an urban<br />

site [2]. Besides the remote sensing activity, the GMET<br />

group is involved in studies on the quantification of UV<br />

exposure using polysulphone (PS) dosimetry (Fig.2).<br />

Figure 2: PS dosimeters on the Brewer spectrophotometer<br />

during a calibration campaign (University Campus).<br />

Two field experiments were carried out in mountainous<br />

areas on the Alps [3] and on the beach of a<br />

popular sea-side location in central Italy [4] involving<br />

volunteering skiers and sunbathers respectively. The<br />

studies yielded new important data resulting in a better<br />

understanding of UV exposure of outdoor occupational<br />

and leisure activities of Italians and providing information<br />

relevant to the future health policies regarding the<br />

potential detrimental effects from overexposure to UV<br />

radiation.<br />

References<br />

1. G. Seckmeyer et al., Photochem. Photobiol. Sci. 83, 1<br />

(2007).<br />

2. I. Ialongo et al., Atmos. Chem. Phys. 8, 3283 (2008).<br />

3. A.M. Siani et al., Atmos. Chem. Phys. 8, 3749 (2008).<br />

4. A.M. Siani et al., Photochem. Photobiol. 85, 171 (2009).<br />

Figure 1: Climatological UV Index (thick line) at Rome<br />

(clear sky data 1992–2008) for each day of the year. The<br />

index is a measure of the intensity of UV radiation relevant to<br />

effects on the human skin. Thin line is 1 standard deviation.<br />

The color codes indicate exposure categories.<br />

Authors<br />

A.M. Siani, G.R. Casale, I. Ialongo<br />

http://www.phys.uniroma1.it/gr/gmet/index.html<br />

Erythemal Dose Rates (i.e. the incoming solar radiation<br />

on a horizontal surface convolved with the erythema<br />

action spectrum) have been also determined by YES<br />

<strong>Sapienza</strong> Università di Roma 167 Dipartimento di Fisica

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