Stormwater Pollution Prevention Plan - Phoenix Sky Harbor ...
Stormwater Pollution Prevention Plan - Phoenix Sky Harbor ... Stormwater Pollution Prevention Plan - Phoenix Sky Harbor ...
City of Phoenix January 28, 2013 Page 3 • EPA Method 8260B (Volatile Organic Compounds) - (Samples: 12087-S1, 12087- S2, 12087-S3, 12087-EX@3.5', 12087-EX@5', 12087-NW@3', 12087-E@4', 12087-SE@2.5', and 12087-W@3') • EPA Method 8310 (Polynuclear Aromatic Hydrocarbons) - (Samples: 12087-S1- Comp, 12087-S2-Comp, 12087-S3-Comp, 12087-EX@3.5', 12087-EX@5', 12087-NW@3', 12087-E@4', 12087-SE@2.5', and 12087-W@3') • ADEQ Method 8015AZ R.1 (Total Petroleum Hydrocarbons) - (Samples: 12087- S1-Comp, 12087-S2-Comp, 12087-S3-Comp, 12087-EX@3.5', 12087-EX@5', 12087-NW@3', 12087-E@4', 12087-SE@2.5', and 12087-W@3') For VOC analysis, samples were collected using disposable Terra Core® samplers and methanol extraction kits provided by the laboratory. To reduce the potential for cross-contamination and possible inaccurate results, the sampling equipment was decontaminated prior to inception of sampling activities. Sampling equipment was decontaminated between each use through a staged, triple rinse procedure. A Chain-of- Custody record was developed on-site prior to submittal of samples to the analytical laboratory to document proper Chain-of-Custody activities and correct sample handling procedures. Waste Sampling - Four Corners collected one composite sample of representative materials from the impacted soils stockpile from a minimum of eight locations. The composite sample, Sample 12087-WS-01, of impacted soils for disposal was collected in a decontaminated glass jar provided by the laboratory and were submitted to an analytical laboratory for waste characterization analysis as follows. • EPA Method 8260B (Volatile Organic Compounds) • EPA Method 6010B/7471A (Total 8 RCRA Metals) • EPA Method 8310 (Polynuclear Aromatic Hydrocarbons) • ADEQ Method 8015AZ R.1 (Total Petroleum Hydrocarbons) The waste soil sample collected for VOC analysis were not composited. The sample was collected from an area of soil with the greatest fuel odor or a representative location of the stockpile as determined by field personnel. To reduce the potential for cross-contamination and possible inaccurate results, the sampling equipment was decontaminated prior to inception of sampling activities. Sampling equipment was decontaminated between each use through a staged, triple rinse procedure. A Chain-of-Custody record was developed onsite prior to submittal of the samples to the analytical laboratory to document proper Chain-of-Custody activities and correct sample handling procedures. ANALYTICAL RESULTS The laboratory analytical reports for soil sampling activities are provided in Attachment B, Laboratory Reports and Chain-of-Custody Forms. The analytical results are summarized in Tables 1 through 4 included in Attachment C, Tables. Four Corners Environmental, Inc. 960 North Sinagua Heights Drive, Flagstaff, Arizona 86004-7870 (928) 714-9374 (f) (928) 714-9375 10030 North 49 th Lane, Glendale, Arizona 85302-2417 (623) 931-2211 (f) (623) 931-2202
City of Phoenix January 28, 2013 Page 4 Confirmation Sampling Results: Four Corners collected 12 soil samples from the Salt River Biodiesel Release area on September 24, 2012. Volatile Organic Compounds - Analytical results are summarized in Table 1, Volatile Organic Compounds, Attachment C. Analyses of cleanup confirmation samples using EPA Method 8260B did not report concentrations of VOCs above applicable Arizona Department of Environmental Quality (ADEQ) residential Soil Remediation Levels (rSRLs), and reporting limits (RLs) and method detection limits (MDLs) were below rSRLs. Total Petroleum Hydrocarbons - Analytical results are summarized in Table 2, Total Petroleum Hydrocarbons, Attachment C. Analysis of the roadway samples for TPHs using ADEQ Method 8015AZ R.1 detected C10-C22 DRO and C22-C32 ORO. There are currently no ADEQ rSRLs established for C10- C22 DRO or C22-C32 ORO. Analysis of the soil confirmation samples from the excavation zone for TPHs using ADEQ Method 8015AZ R.1 detected C10-C22 DRO in four of the samples, other samples were below laboratory detection limits. There is currently no ADEQ rSRL established for C10-C22 DRO. C22-C32 ORO was not detected in the samples above laboratory detection limits. Polynuclear Aromatic Hydrocarbons - Analytical results are summarized in Table 3, Polynuclear Aromatic Hydrocarbons, Attachment C. Analyses of cleanup confirmation samples using EPA Method 8310 did not report concentrations of PAHs above applicable rSRLs, and RLs and MDLs were below rSRLs. Waste Soil Sampling Results: Four Corners collected one composite waste soil sample(12087-WS-01) from the resulting stockpile on September 25, 2012. Volatile Organic Compounds - Analytical results are summarized in Table 1. Analysis of the waste soil sample using Method 8260B for VOCs detected concentrations of 1,2,4-trimethylbenzene and 1,3,5- trimethylbenzene above the ADEQ rSRLs. Other compounds detected were below applicable ADEQ rSRLs. However, MDLs for 1,2,3-trichloropropane and vinyl chloride for the waste soil sample exceeded the ADEQ rSRL Total Petroleum Hydrocarbons - Analytical results are summarized in Table 2. Analysis of the waste soil sample using ADEQ Method 8015AZ R.1 TPHs detected a concentration C10-C22 DRO. There is currently no ADEQ rSRL established for C10-C22 DRO. C22-C32 ORO was not detected in the sample above laboratory detection limits. Polynuclear Aromatic Hydrocarbons - Analytical results are summarized in Table 3. Analysis of the waste soil sample using Method 8310 for PAHs detected naphthalene at a concentration below the ADEQ rSRLs. The sample did not contain detectable concentrations of other target analytes. Total Metals - Analytical results are summarized in Table 4, Total Metals Analytical Data, Attachment C. Analysis of the waste soil samples for total metals using Method SW 6010B/7471A detected concentrations of arsenic, barium, chromium, lead, mercury, and silver. Concentrations of metals did not exceed the Four Corners Environmental, Inc. 960 North Sinagua Heights Drive, Flagstaff, Arizona 86004-7870 (928) 714-9374 (f) (928) 714-9375 10030 North 49 th Lane, Glendale, Arizona 85302-2417 (623) 931-2211 (f) (623) 931-2202
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City of <strong>Phoenix</strong><br />
January 28, 2013<br />
Page 4<br />
Confirmation Sampling Results: Four Corners collected 12 soil samples from the Salt River Biodiesel<br />
Release area on September 24, 2012.<br />
Volatile Organic Compounds - Analytical results are summarized in Table 1, Volatile Organic Compounds,<br />
Attachment C. Analyses of cleanup confirmation samples using EPA Method 8260B did not report<br />
concentrations of VOCs above applicable Arizona Department of Environmental Quality (ADEQ)<br />
residential Soil Remediation Levels (rSRLs), and reporting limits (RLs) and method detection limits<br />
(MDLs) were below rSRLs.<br />
Total Petroleum Hydrocarbons - Analytical results are summarized in Table 2, Total Petroleum<br />
Hydrocarbons, Attachment C. Analysis of the roadway samples for TPHs using ADEQ Method 8015AZ<br />
R.1 detected C10-C22 DRO and C22-C32 ORO. There are currently no ADEQ rSRLs established for C10-<br />
C22 DRO or C22-C32 ORO.<br />
Analysis of the soil confirmation samples from the excavation zone for TPHs using ADEQ Method<br />
8015AZ R.1 detected C10-C22 DRO in four of the samples, other samples were below laboratory detection<br />
limits. There is currently no ADEQ rSRL established for C10-C22 DRO. C22-C32 ORO was not detected<br />
in the samples above laboratory detection limits.<br />
Polynuclear Aromatic Hydrocarbons - Analytical results are summarized in Table 3, Polynuclear Aromatic<br />
Hydrocarbons, Attachment C. Analyses of cleanup confirmation samples using EPA Method 8310 did not<br />
report concentrations of PAHs above applicable rSRLs, and RLs and MDLs were below rSRLs.<br />
Waste Soil Sampling Results: Four Corners collected one composite waste soil sample(12087-WS-01)<br />
from the resulting stockpile on September 25, 2012.<br />
Volatile Organic Compounds - Analytical results are summarized in Table 1. Analysis of the waste soil<br />
sample using Method 8260B for VOCs detected concentrations of 1,2,4-trimethylbenzene and 1,3,5-<br />
trimethylbenzene above the ADEQ rSRLs. Other compounds detected were below applicable ADEQ<br />
rSRLs. However, MDLs for 1,2,3-trichloropropane and vinyl chloride for the waste soil sample exceeded<br />
the ADEQ rSRL<br />
Total Petroleum Hydrocarbons - Analytical results are summarized in Table 2. Analysis of the waste soil<br />
sample using ADEQ Method 8015AZ R.1 TPHs detected a concentration C10-C22 DRO. There is<br />
currently no ADEQ rSRL established for C10-C22 DRO. C22-C32 ORO was not detected in the sample<br />
above laboratory detection limits.<br />
Polynuclear Aromatic Hydrocarbons - Analytical results are summarized in Table 3. Analysis of the waste<br />
soil sample using Method 8310 for PAHs detected naphthalene at a concentration below the ADEQ rSRLs.<br />
The sample did not contain detectable concentrations of other target analytes.<br />
Total Metals - Analytical results are summarized in Table 4, Total Metals Analytical Data, Attachment C.<br />
Analysis of the waste soil samples for total metals using Method SW 6010B/7471A detected concentrations<br />
of arsenic, barium, chromium, lead, mercury, and silver. Concentrations of metals did not exceed the<br />
Four Corners Environmental, Inc.<br />
960 North Sinagua Heights Drive, Flagstaff, Arizona 86004-7870 (928) 714-9374 (f) (928) 714-9375<br />
10030 North 49 th Lane, Glendale, Arizona 85302-2417 (623) 931-2211 (f) (623) 931-2202