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1.8<br />

Molar H/Corg Ratios<br />

1.6<br />

1.4<br />

1.2<br />

1.0<br />

0.8<br />

0.6<br />

0.4<br />

Proposed upper limit <strong>for</strong> biochars<br />

Thermochemically altered<br />

Not thermochemically altered feedstock<br />

0.2<br />

1<br />

0.0<br />

0 100 200 300 400 500 600 700<br />

Temperature (°C)<br />

2<br />

3<br />

4<br />

5<br />

6<br />

Figure A5.1: Relationship between molar H:C org ratios <strong>and</strong> temperature of thermochemically altered<br />

organic matter in comparison to untreated biomass. Dashed line is the upper limit of 0.7. Data points<br />

below the 0.7 line are thermochemically altered materials that are considered to be thermochemically<br />

“converted” (data from Sevilla <strong>and</strong> Fuertes, 2009ab; Calvelo Pereira et al, 2011; Enders et al., 2012).<br />

7<br />

8<br />

9<br />

10<br />

11<br />

12<br />

13<br />

14<br />

15<br />

16<br />

17<br />

References<br />

Enders A., Hanley K., Whitman T., Joseph S. <strong>and</strong> Lehmann J. Characterization of biochars to<br />

evaluate recalcitrance <strong>and</strong> agronomic per<strong>for</strong>mance. Bioresource Technology (BITE-D-11-<br />

04505). Published online.<br />

Keiluweit M., Nico P.S., Johnson M.G. <strong>and</strong> Kleber M. (2010) Dynamic molecular structure of<br />

plant-derived black carbon (biochar). Environmental Science <strong>and</strong> Technology 44:1247-<br />

1253.<br />

Sevilla M. <strong>and</strong> Fuertes A.B. (2009a) Chemical <strong>and</strong> structural properties of carbonaceous<br />

products obtained by hydrothermal carbonization of saccharides. Chemistry - A<br />

European Journal 15:4195-4203.<br />

<strong>St<strong>and</strong>ardized</strong> <strong>Product</strong> <strong>Definition</strong> <strong>and</strong> <strong>Product</strong> <strong>Testing</strong> <strong>Guidelines</strong> <strong>for</strong> Biochar That Is Used in Soil 34

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