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reducing the cost of hydrogen production by electrolysis - ITM Power

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REDUCING THE COST OF HYDROGEN<br />

4PRODUCTION BY ELECTROLYSIS<br />

CASE STUDY 04


Case Study 04<br />

Reducing <strong>the</strong> Cost <strong>of</strong> Hydrogen Production <strong>by</strong> Electrolysis<br />

Background<br />

<strong>ITM</strong> <strong>Power</strong> is a developer <strong>of</strong> <strong>hydrogen</strong> energy systems based on <strong>electrolysis</strong>.<br />

There are numerous applications for such systems in energy storage, clean fuel<br />

<strong>production</strong> and vehicle refuelling. This case study describes <strong>the</strong> realisation <strong>of</strong> <strong>cost</strong><br />

reduction through advances in materials technology and system simplification.<br />

A number <strong>of</strong> important achievements have been realised, including >35% <strong>cost</strong><br />

reduction for an existing product platform.<br />

The objective <strong>of</strong> this TSB funded project was to reduce <strong>the</strong><br />

<strong>production</strong> <strong>cost</strong> <strong>of</strong> polymer electrolysers to fur<strong>the</strong>r promote <strong>the</strong><br />

introduction <strong>of</strong> <strong>the</strong> wider <strong>hydrogen</strong> economy. A novel alkaline<br />

polymeric membrane material and processing technology were<br />

identified which eliminated <strong>the</strong> significant <strong>cost</strong>s associated with<br />

conventional fluorocarbon membranes and <strong>the</strong> requirement for<br />

expensive precious metal catalysts.<br />

This novel approach allows significant reductions in capital <strong>cost</strong>s,<br />

whilst maintaining high performance (including compatibility with<br />

intermittent renewable energy sources) and extended component<br />

and system lifetimes.<br />

Electrolyser module incorporating <strong>the</strong><br />

low-<strong>cost</strong> alkaline polymeric membrane.<br />

“Alkaline solid polymer <strong>electrolysis</strong> <strong>of</strong>fers<br />

a potentially unique way <strong>of</strong> both eliminating<br />

platinum catalysts and retaining high current<br />

density and durability; essentially getting<br />

<strong>the</strong> best out <strong>of</strong> both PEM and liquid alkaline<br />

technologies. We are very pleased with <strong>the</strong>se<br />

results and have chosen to extend testing.”<br />

Dr Graham Cooley<br />

CEO, <strong>ITM</strong> <strong>Power</strong> Plc


Case Study 04<br />

Reducing <strong>the</strong> Cost <strong>of</strong> Hydrogen Production <strong>by</strong> Electrolysis<br />

Product description<br />

The key advance has been <strong>the</strong> development <strong>of</strong> a new low-<strong>cost</strong> alkaline solid polymer membrane based<br />

on <strong>ITM</strong>’s proprietary membrane technology. The new membrane, toge<strong>the</strong>r with <strong>the</strong> low-<strong>cost</strong> catalysts,<br />

<strong>of</strong>fer an electrolyser stack <strong>cost</strong>ing 43% <strong>of</strong> a similar stack using acidic proton exchange membranes (PEM).<br />

In addition, <strong>the</strong> properties <strong>of</strong> <strong>the</strong> new alkaline membrane enable simplification <strong>of</strong> <strong>the</strong> electrolyser balance<br />

<strong>of</strong> plant, providing routes to fur<strong>the</strong>r <strong>cost</strong> savings.<br />

<strong>ITM</strong> <strong>Power</strong> working in collaboration with its technology partners (Teer Coatings, University <strong>of</strong> Southampton,<br />

Boddingtons) has achieved <strong>the</strong> following improvements:<br />

• A low-<strong>cost</strong> alkaline membrane<br />

• A high ionic conductivity which affords high<br />

current densities and keeps electrolyser stack<br />

sizes small<br />

• High water permeability which allows considerable<br />

simplification <strong>of</strong> <strong>the</strong> water management system so<br />

avoiding <strong>cost</strong>ly balance <strong>of</strong> plant whilst retaining <strong>the</strong><br />

ability to access high current density operation<br />

• Low-<strong>cost</strong> non-precious metal catalysts eliminating<br />

<strong>the</strong> use <strong>of</strong> expensive catalysts<br />

• A process has been developed <strong>by</strong> <strong>ITM</strong>’s<br />

technology partners to produce corrosion<br />

resistant high surface area coatings<br />

• Cyclic and continuous testing has accrued over<br />

1 year’s durability data with no degradation or<br />

loss in performance<br />

These developments <strong>of</strong>fer significant potential for <strong>cost</strong> reduction across a range <strong>of</strong> <strong>ITM</strong>’s product platforms.<br />

ORIGINAL STACK<br />

NEW STACK<br />

6%<br />

6%<br />

12%<br />

7% 1% 7% 1% 9% 9%<br />

12%<br />

6%<br />

6%<br />

18%<br />

18%<br />

1%<br />

1%<br />

33%<br />

33%<br />

11%<br />

11%<br />

11%<br />

11%<br />

1%<br />

1%<br />

59%<br />

59%<br />

9%<br />

9%<br />

End Plates<br />

Pressure Fittings<br />

Bipolar Cells Anode Support MEA Cathode Support<br />

Nuts and Bolts<br />

Materials and system simplification has reduced <strong>cost</strong>s


Case Study 04<br />

Reducing <strong>the</strong> Cost <strong>of</strong> Hydrogen Production <strong>by</strong> Electrolysis<br />

Building on <strong>the</strong> technology developments<br />

The successful development <strong>of</strong> <strong>the</strong> low-<strong>cost</strong> alkaline membrane electrolyser will allow <strong>ITM</strong> <strong>Power</strong> to<br />

reduce <strong>the</strong> <strong>cost</strong> <strong>of</strong> <strong>hydrogen</strong> <strong>production</strong> for products ranging from flame processing for precision welding<br />

and brazing applications to on site vehicle refuelling. For example, <strong>hydrogen</strong> and oxygen produced <strong>by</strong><br />

<strong>electrolysis</strong> can be combusted in a brazing torch and <strong>of</strong>fer advantages as an alternative to oxy-acetylene<br />

and oxy-propane:<br />

1. The oxygen and <strong>hydrogen</strong> are generated<br />

separately, and <strong>the</strong>ir mixture is controlled<br />

to deliver a precise stoichiometric, oxidising<br />

or <strong>reducing</strong> flame – an innovation <strong>of</strong>fering unique<br />

benefits in brazing applications<br />

2. The length <strong>of</strong> <strong>the</strong> flame and <strong>the</strong> heat flux imparted<br />

to <strong>the</strong> work piece can be adjusted instantaneously<br />

<strong>by</strong> adjusting <strong>the</strong> power input to <strong>the</strong> electrolyser<br />

stack – providing a more flexible and user friendly<br />

solution<br />

3. On site gas <strong>production</strong> eliminates <strong>the</strong> need<br />

for any stored gases, removing explosion hazards<br />

and improving process portability<br />

Brazing, soldering and joining processes are a<br />

fundamental requirement for industries as diverse<br />

as refrigeration, air conditioning, ship building,<br />

rail stock, car repairs, jewellery, dental technology<br />

and polishing.<br />

The development <strong>of</strong> a new low-<strong>cost</strong><br />

alkaline solid polymer membrane is<br />

based on <strong>ITM</strong>’s proprietary hydrocarbon<br />

membrane technology.


<strong>ITM</strong> <strong>Power</strong> PLC<br />

22 Atlas Way<br />

Sheffield<br />

S4 7QQ<br />

T: +44 (0) 114 244 5111<br />

W: www.itm-power.com<br />

6588

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