divipan 100 ec r-17111 - Makhteshim-Agan SA (Pty) Ltd

U
MATERIAL SAFETY DATA SHEET
Page : 1 of 4
Revised edition no : 2
Date : 10/1/2005
Supersedes : 4/7/2004
DIVIPAN 100 EC R-17111
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
Trade name
Chemical formula
Use
Company identification
Emergency phone nr
: DIVIPAN 100 EC
: C4H7Cl2O4P : 2,2-dichlorovinyl dimethyl phosphate
: Insecticide
: Makhteshim Chemical Works Ltd.
PO Box 60
Beer Sheva 84100 Israel.
Fax : +972-8-6296848
: 972-3-6106666 Subscription no. 36789 (Makhteshim)
2. COMPOSITION / INFORMATION ON INGREDIENTS
This product is considered to be hazardous and contains hazardous components.
Substance name Value(s) CAS No EC No Index No Classification
Dichlorvos (ISO) : 1000 g/l 000062-73-7 200-547-7 015-019-00-X T+; R26
T; R24/25
R43
N; R50
Xylene : ca 16 % 001330-20-7 215-535-7 601-022-00-9 R10
Xn; R20/21
Xi; R38
3. HAZARDS IDENTIFICATION
Main hazards
Physical/Chemical Hazards
Human Health Hazards
Environmental hazard
: THIS COMPOUND INHIBITS CHOLINESTERASE.
: Flammable
: Toxic in contact with skin and if swallowed.
Very toxic by inhalation.
May cause sensitization by skin contact.
: Very toxic to aquatic organisms.
4. FIRST AID MEASURES
Undesirable human health effects : Exposure may result in excessive sweating , weakness , salivation , nausea ,
bradycardia , tachycardia , bronchorrhea , cough , bronchospasm ,
lung oedema , small pupils , central nervous depression , fasciculation ,
convulsions , headache , faintness and giddiness .
Inhalation
: Remove victim to fresh air. Keep victim warm and at rest. If breathing is difficult,
give oxygen. If not breathing, give artificial respiration. Immediately get medical
attention.
Ingestion
: Do not induce vomiting. Wash out mouth with plenty of water. Never give anything
by mouth to an unconscious person. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Immediately get medical attention.
Skin contact
: Wash clothing separately before re-use . Immediately get medical attention.
Remove affected clothing and wash all exposed skin area with soap and water,
followed by warm water rinse.
Eye contact : Wash off with plenty of water. Immediately consult an eye specialist .
Note to physician
: Antidote 1: Atropine sulfate
Antidote 2: Obidoxime chloride or Pralidoxime (PAM).
If ingested perform gastric lavage and administer activated charcoal.
Makhteshim Chemical Works Ltd.
PO Box 60 Beer Sheva 84100 Israel. Fax : +972-8-6296848

U
MATERIAL SAFETY DATA SHEET
Page : 2 of 4
Revised edition no : 2
Date : 10/1/2005
Supersedes : 4/7/2004
DIVIPAN 100 EC R-17111
5. FIRE-FIGHTING MEASURES
Extinguishing media : For small fire : carbon dioxide , dry chemical .
For large fire : water spray , alcohol resistant foam .
Special procedures
: Fight fires from a protected location . Dike fire control water for later disposal.
Keep container cool by spraying with water .
Special exposure hazards
: Thermal decomposition generates : carbon dioxide , carbon monoxide , hydrogen
chloride , phosphorus oxides .
Protection against fire
: Wear proper protective equipment. Self-contained breathing apparatus.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Use appropriate protection (see section 8).
Environmental precautions
: Dispose of this material and its container at hazardous or special waste collection
point. Do not discharge into the environment . Do not allow to enter sewage
system . If the product has contaminated surface water, inform the appropriate
authorities.
After spillage and/or leakage : Collect and contain as much free liquid as possible. Absorb in sand or other inert
material . Dike for recovery or absorb with appropriate material. Disposal according
to the local legislation . Wash away remainder with plenty of water .
7. HANDLING AND STORAGE
Handling
: Do not breathe gas/fumes/vapour/spray . Avoid contact with skin and eyes.
Storage
: Keep locked up. Keep container dry . Keep container tightly closed. Keep only in
the original container in a cool, well ventilated place.
Packing : Fluorinated or coextruded polyethylene containers .
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Industrial hygiene
: Ventilation required. Emergency eye wash fountains and safety showers should be
available in the immediate vicinity of any potential exposure. Wash hands
thoroughly after handling. Wash clothing before re-using.
Occupational Exposure Limits
TLV-TWA [ppm] : Dichlorvos : 0.1 ( skin )
TWA [mg/m3] : Dichlorvos : 0.9 ( skin )
- Respiratory protection : During spraying wear suitable respiratory equipment.
- Skin protection : Wear protective clothing .
- Hand protection : Wear suitable gloves.
- Eye protection : Chemical goggles or safety glasses.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state
: Liquid
Colour
: Clear
Odour
: Faint aromatic
Specific gravity : 1.28-1.36
Molecular weight : Dichlorvos : 221
Initial boiling point [°C] : Dichlorvos : 234.1
Vapour pressure : Dichlorvos 2.1 mPa ( 25 °C )
Vapour pressure mm/Hg : Xylene : 10 (30 °C )
Solubility in water
: Dichlorvos : 18 g/l
Flash point [°C] :28
Makhteshim Chemical Works Ltd.
PO Box 60 Beer Sheva 84100 Israel. Fax : +972-8-6296848

U
MATERIAL SAFETY DATA SHEET
Page : 3 of 4
Revised edition no : 2
Date : 10/1/2005
Supersedes : 4/7/2004
DIVIPAN 100 EC R-17111
9. PHYSICAL AND CHEMICAL PROPERTIES (continued)
Explosion limits : Xylene : 0.8% - 7.0%
Log P octanol : Dichlorvos :1.9
10. STABILITY AND REACTIVITY
Physico-chemical stability
Hazardous decomposition products
Hazardous Polymerization
: Stable under normal conditions.
: Thermal decomposition generates : carbon dioxide , carbon monoxide , hydrogen
chloride , phosphorus oxides .
: Will not occur.
Materials to avoid : Avoid contact with : strong bases , strong acids , metals .
Conditions to avoid : Avoid temperatures above 35 °C
11. TOXICOLOGICAL INFORMATION
Toxicity information : No toxicological information is known on the product. The data below are for 100%
Dichlorvos (Pesticide Manual).
Rat oral LD50 [mg/kg] :50
Rat dermal LD50 [mg/kg] :90
Rat inhalation LC50 [mg/l/4h] :0.34
Dermal irritation (rabbit)
: Slight irritant
Eyes irritation (rabbit)
: Slight irritant
Sensitization
: Guinea pig maximization test: Sensitizer
Carcinogenicity
: Not carcinogenic
Mutagenicity
: No evidence of genotoxicity
Reproductive toxicity
: Not teratogenic in animal experiments
12. ECOLOGICAL INFORMATION
Ecological effects information : No ecological information is known on the product. The data below are for 100%
Dichlorvos (Pesticide Manual).
96 H-LC50 - Rainbow trout [mg/l] : 200
48 H-EC50 - Daphnia magna [µg/l] :0.2
IC50 72h Algae [mg/l] : 52.8
LD50 Birds [mg/kg] : 300 ( Japanese quail )
24 ( Bobwhite quail )
Bees LD50 [µg/Bee] :0.29
13. DISPOSAL CONSIDERATIONS
Disposal
: Dispose in a safe manner in accordance with local/national regulations.
14. TRANSPORT INFORMATION
- UN No. : 3017
- Proper shipping name : ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE
(1000 g/l Dichlorovos/16 % Xylene)
- Packing group :II
- Class :6.1
- H.I. nr : :63
- ADR/RID
Makhteshim Chemical Works Ltd.
PO Box 60 Beer Sheva 84100 Israel. Fax : +972-8-6296848

U
MATERIAL SAFETY DATA SHEET
Page : 4 of 4
Revised edition no : 2
Date : 10/1/2005
Supersedes : 4/7/2004
DIVIPAN 100 EC R-17111
14. TRANSPORT INFORMATION (continued)
- ADR class :6.1
- ADR Packing group :II
Sea transport
- IMDG-Marine pollution :Yes
15. REGULATORY INFORMATION
EU Classification
Symbol(s)
: This product is provisionally labelled by the supplier in accordance to the EU
regulations;
R Phrase(s)
S Phrase(s)
: T+: Very toxic
N: Dangerous for the environment.
: R10 - Flammable.
R24/25 - Toxic in contact with skin and if swallowed.
R26 - Very toxic by inhalation.
R43 - May cause sensitization by skin contact.
R50 - Very toxic to aquatic organisms.
: S02 - Keep out of the reach of children.
S13 - Keep away from food, drink and animal feedingstuffs.
S20 - When using do not eat or drink.
S23 - Do not breathe gas/fumes/vapour/spray.
S24 - Avoid contact with skin.
S28 - After contact with skin, wash immediately with plenty of water and soap .
S35 - This material and its container must be disposed of in a safe way.
S36/37 - Wear suitable protective clothing and gloves.
S38 - In case of insufficient ventilation, wear suitable respiratory equipment.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (
show the label when possible).
S53 - Avoid exposure - obtain special instructions before use.
S57 - Use appropriate container to avoid environmental contamination.
S61 - Avoid release to the environment. Refer to special instructions/Safety data
sheets.
16. OTHER INFORMATION
Text of R-phrases in heading 2 :
R10 - Flammable.
R20/21 - Harmful by inhalation and in contact with skin.
R24/25 - Toxic in contact with skin and if swallowed.
R26 - Very toxic by inhalation.
R38 - Irritating to skin.
R43 - May cause sensitization by skin contact.
Print date : 10/1/2005
DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However,
the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of
handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and
other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in
any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used
only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
End of document
Makhteshim Chemical Works Ltd.
PO Box 60 Beer Sheva 84100 Israel. Fax : +972-8-6296848