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The properties of surface active agent depends<br />

on their chemical structure, related to the<br />

following factors: hydrophilicity, the relative<br />

position of hydrophilic groups, the size of<br />

molecules and the hydrophobic groups<br />

1) hydrophilicity (HLB) is the equilibrium ratio of<br />

the surface active agent’s hydrophilicity and<br />

lipophilicity:<br />

HLB=hydrophilicity of hydrophilic groups<br />

/hyrophobicity of hydrophobic groups<br />

Surface active agent’s HLB value is related to the<br />

HLB value of each of its radicals, the computing<br />

of which is :<br />

HLB=7+Σ(HLB of hydrophilic groups)-Σ(HLB of<br />

hydrophobic groups)

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