64 m kj izns'k jktf"kZ V.Mu eqDr fo'ofo|ky;] bykgkckn

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14 531 m kj izns’k jktf"kZ V.Mu eqDr fo’ofo|ky;] bykgkckn fo"k; % jlk;u foKku Subject : Chemistry dkslZ ’kh"kZd % fQftdy dsfeLV“h Subject Title : Physical Chemistry vf/kU;kl (Assignment) 2012-2013 Lukrd foKku dk;Z e …ch-,l-lh-‰ Bachelor of Science Programme (B.Sc.) Section - A [k.M - v fo"k; dksM % ;w-th-lh-,p-bZ- Subject Code : UGCHE dkslZ dksM % ;w-th-lh-,p-bZ-04 Course Code: UGCHE-04 vf/kdre vad % 30 Maximum Marks : 30 vf/kdre vad % 18 Maximum Marks : 18 Note : Long Answer Question. Answer should be given in 800 to 1000 words. Answer all questions. All questions are compulsory. uksV % nhkZ m kjh; iz’uA vius iz’uksa ds m kj 800 ls 1000 ’kCnksa esa fy[ksaA lHkh iz’u vfuok;Z gSaA 1. What are the basic assumptions of Kinetic theory of gases 6 xSlksa ds v.kqxfr fl)kar dh eq[;k vfHk/kkj.kk,a D;k gS\ 2. Derive Gibbs - Helmholtz equation. 6 fxCl& gsYegksYVt lehdj.k dks O;qRiUu dhft;sA 3. Define the term phase, component and degree of freedom. Draw the phase diagram of water system. 6 izkoLFkk] vo;o rFkk eqDr voLFkk dh dksfV dks ifjHkkf"kr dhft;sA ty dk izkoLFkk vkjs[k [khafp;sA Section - B [k.M - c vf/kdre vad % 12 Maximum Marks : 12 Note : Short Answer Question. Answer should be given in 200 to 300 words. Answer all questions. All questions are compulsory. uksV % ykq m kjh; iz’uA vius iz’uksa ds m kj 200 ls 300 ’kCnksa esa fy[ksaA lHkh iz’u vfuok;Z gSaA 4. Derive the equation for half life of first order reaction. 3 izFke dksfV vfHkf ;k ds fy;s v/kZ voLFkk ds lehdj.k dh O;qRifRr dhft;sA 5. While a note on catalyst. 3 mRizsjdksa ij fVIi.kh dhft;sA 6. Distinguish between Molecularity and order of a reaction. 3 vk.kfoDrk rFkk vfHkf ;k dh dksfV ds chp vUrj Li"V dhfr;sA 7. Explain the following terms. 3 (i) Molarity (ii) Molality (iii) Mole fraction fuEufyf[kr inksa dh O;k[;k dhft;sA (i) eksjyrk (ii) eksyyrk (iii) eksy va’k ¾¾¾¾¾
15 532 m kj izns’k jktf"kZ V.Mu eqDr fo’ofo|ky;] bykgkckn vf/kU;kl (Assignment) 2012-2013 Lukrd foKku dk;Z e …ch-,l-lh-‰ Bachelor of Science Programme (B.Sc.) fo"k; % jlk;u foKku fo"k; dksM % ;w-th-lh-,p-bZ- Subject : Chemistry Subject Code : UGCHE dkslZ ’kh"kZd % vksjxfud dsfeLV“h dkslZ dksM % ;w-th-lh-,p-bZ- 05 Subject Title : Organic Chemistry Course Code: UGCHE-05 Section - A [k.M - v vf/kdre vad % 30 Maximum Marks : 30 vf/kdre vad % 18 Maximum Marks : 18 uksV % nhkZ m kjh; iz’uA vius iz’uksa ds m kj 800 ls 1000 ’kCnksa esa fy[ksaA lHkh iz’u vfuok;Z gSaA Note : Long Answer Question. Answer should be given in 800 to 1000 words. Answer all questions. All questions are compulsory. 1. Whsat is Isomerism Explain tautomerism with suitable examples. 6 leko;rk D;k gS\ mfpr mnkgj.kksa ds }kjk pyko;rk dh O;k[;k dhft;sA 2. Explain Fridel-Crafts alkylation of benzene. Discuss its limitations also. 6 mi;qDr mnkgj.kksa ds }kjk SN 1 ,oa SN 2 vfHkf ;k dh O;k[;k dhft;sA 3. Explain Fridel- Crafts alkylation of benzene. Discuss its limitations also. 6 csUthu ds hMy- kV“l ,fYdyhdj.k dh O;k[;k dhft;sA budh lhekvksa ij Hkh ppkZ dhft;sA Section - B [k.M - c vf/kdre vad % 12 Maximum Marks : 12 uksV % ykq m kjh; iz’uA vius iz’uksa ds m kj 200 ls 300 ’kCnksa esa fy[ksaA lHkh iz’u vfuok;Z gSaA Note : Short Answer Question. Answer should be given in 200 to 300 words. Answer all questions. All questions are compulsory. 4. Explain Sp 3 hybridization of Alkane. 3 ,Ydsu esa Sp 3 laLdj.k dh O;k[;k dhft;sA 5. Write a note on nucleophile. 3 ukfHkd Lusgh ij laf{kIr fVIi.kh dhft;sA 6. Write a note an geometrical isomerism. 3 ft;ksesfV“dy leko;rk ij fVIi.kh dhft;sA 7. What is markonikoff's rule. Explain with example. 3 ekjdksfudkWQ dk fu;e D;k gS\ mnkgj.k lfgr O;k[;k dhft;sA ¾¾¾¾¾
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Page 3 and 4: 3 5. Derive the wave equation for a
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Page 19 and 20: 19 - ;fn y = (sin 1 x) gks rks fn[k
Page 21 and 22: 21 é1 2 3ù A = ê ú ê 0 5 0 3
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64 42 m kj izns’k jktf"kZ V.Mu eq
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74 8- lgh fodYi dks fVd djsaA ¼d½
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77 m kj izns’k jktf"kZ V.Mu eqDr
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81 efJe
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83 efJe
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87 6. efJeÅeeLeea meneÙelee mesJe
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89 117 Gòej ØeosMe jepeef
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95 123 m kj izns’k jktf"kZ V.Mu e
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99 127 mRrj iznsk jktfkZ V.Mu eqDr
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153 OTHER INFORMATION : Volume 2 :
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189 ╪ ≥ Γ ┼ ┘ 96 G≥ ej e
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64 m kj izns'k jktf"kZ V.Mu eqDr fo'ofo|ky;] bykgkckn

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