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Table 14-4: Comparis<strong>on</strong> of Niobium, Tantalum and Zirc<strong>on</strong>ium Analyses<br />

Comparis<strong>on</strong> of Method to Mean of All Analyses<br />

Standard Lab Method N Nb Ta Zr<br />

STD-L ALS MS81 188 100% 99% 101%<br />

STD-L ALS MS81H 19 101% 100% 101%<br />

STD-L Acme Method 4A 98 103% 91% 103%<br />

STD-L ALS XRF 43 104% 73% 106%<br />

Average in ppm 1,383 144 9,750<br />

STD-M ALS MS81 153 103% 98% 66%<br />

STD-M ALS MS81H 87 101% 96% 95%<br />

STD-M Acme Method 4A 121 109% 90% 106%<br />

STD-M ALS XRF 46 109% 88% 115%<br />

Average in ppm 2,196 227 14,087<br />

STD-H ALS MS81 112 100% 100% 66%<br />

STD-H ALS MS81H 99 98% 96% 111%<br />

STD-H Acme Method 4A 224 98% 95% 111%<br />

STD-H ALS XRF 21 98% 98% 120%<br />

Average in ppm 2,676 301 17,234<br />

STD-H2 ALS MS81 285 96% 36% 29%<br />

STD-H2 ALS MS81H 182 95% 124% 100%<br />

STD-H2 Acme Method 4A 38 93% 99% 80%<br />

STD-H2 ALS XRF 220 94% 124% 100%<br />

Average in ppm 4,132 313 34,323<br />

Note: cases with analytical limits removed<br />

The results indicate <strong>the</strong> following:<br />

• For <strong>the</strong> low grade standard (STD-L), all methods (Acme and ALS) give similar results for<br />

Nb and Zr, but XRF appears to give anomalously low results for Ta. The cause of this is<br />

not known. Standard STD-M is similar.<br />

• For higher grade Zr samples (>1%), MS81 does not give correct results due to analysis<br />

upper limits, however, for Nb and Ta (with <strong>the</strong> excepti<strong>on</strong> of standard H2/S-04-09) <strong>the</strong><br />

results are satisfactory.<br />

• Except for standard H2/S-04-09, Zr values are 6% to 20% higher with XRF than <strong>the</strong><br />

average of all analyses from all labs.<br />

In additi<strong>on</strong>, XRF10 analyses generally show very low standard deviati<strong>on</strong>s.<br />

Technical Report 43-101 – March 13, 2011 Page 14-6<br />

Prepared by Aval<strong>on</strong> Rare Metals Inc.

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