Proceedings of Topical Meeting on Optoinformatics (pdf-format, 1.21 ...
Proceedings of Topical Meeting on Optoinformatics (pdf-format, 1.21 ... Proceedings of Topical Meeting on Optoinformatics (pdf-format, 1.21 ...
34 OPTOINFORMATICS’05 VR = R * S / L (1) Where: VR = resistivity
SAINT-PETERSBURG, October 17 – 20, 2005 35 HIGH-EFFECTIVE MULTIPLEX HOLOGRAMS IN VOLUME POLYMER MEDIA O.V. Andreeva, A.P. Kushnarenko*, B.B. Lesnichij**, A.P. Nacharov**, A.A. Paramonov** S.I. Vavilov State Optical Institute, 12 Birzhevaya linija, St. Petersburg, Russia, 197198 *Saint-Petersburg State University, 1, Uljanovskaja str., Petrodvorets, St. Petersburg, Russia, 198504 **Saint-Petersburg State University
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34 OPTOINFORMATICS’05<br />
VR = R * S / L (1)<br />
Where:<br />
VR = resistivity <str<strong>on</strong>g>of</str<strong>on</strong>g> volume (Ohm.cm)<br />
R = resistance <str<strong>on</strong>g>of</str<strong>on</strong>g> the material to the flow <str<strong>on</strong>g>of</str<strong>on</strong>g> load (Ohm)<br />
S = surface <str<strong>on</strong>g>of</str<strong>on</strong>g> the electrode (cm 2 ) defined like S = W * t<br />
L = distance between electrodes (cm)<br />
Figure 1. Volume resistivity<br />
technique <str<strong>on</strong>g>of</str<strong>on</strong>g> two points<br />
The test was realized <str<strong>on</strong>g>of</str<strong>on</strong>g> resistivity <str<strong>on</strong>g>of</str<strong>on</strong>g> volume for 5 different types <str<strong>on</strong>g>of</str<strong>on</strong>g> c<strong>on</strong>centrati<strong>on</strong>s<br />
soluti<strong>on</strong>, spilling in our model 4ml <str<strong>on</strong>g>of</str<strong>on</strong>g> soluti<strong>on</strong> for every test. For the measurement <str<strong>on</strong>g>of</str<strong>on</strong>g> the<br />
resistivity <str<strong>on</strong>g>of</str<strong>on</strong>g> volume for every soluti<strong>on</strong>, we use 3 different types <str<strong>on</strong>g>of</str<strong>on</strong>g> electrodes, tin (Sn),<br />
copper (Cu) and aluminium (Al). Obtaining 10000 readings in real time for every test,<br />
hereby to be able to observe the change and the evoluti<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> the c<strong>on</strong>ductive polymer with<br />
regard to the resistivity in the time.<br />
Of the results obtained in the graphic 1 it was possible to observe that the resistivity<br />
<str<strong>on</strong>g>of</str<strong>on</strong>g> the polymer with tin electrodes presents the reacti<strong>on</strong> named oxide - reducti<strong>on</strong> with major<br />
stability, figure 2 (acceptance and not so changeable d<strong>on</strong>ati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> electr<strong>on</strong>s) [5] .<br />
Figure 2. Resistivity <str<strong>on</strong>g>of</str<strong>on</strong>g> the polymer with tin<br />
electrodes and reducti<strong>on</strong> with major stability<br />
In general we can observe <str<strong>on</strong>g>of</str<strong>on</strong>g> 6 graphs that there is major stability for the majority <str<strong>on</strong>g>of</str<strong>on</strong>g><br />
the soluti<strong>on</strong>s and minor values <str<strong>on</strong>g>of</str<strong>on</strong>g> resistivity for the case without dampness.<br />
In the development <str<strong>on</strong>g>of</str<strong>on</strong>g> this process for the present time we can say that the dampness<br />
is a determinant factor in the resistivity <str<strong>on</strong>g>of</str<strong>on</strong>g> the polymer, as what it is necessary to have<br />
major c<strong>on</strong>trol <strong>on</strong> this <strong>on</strong>e. We realize storage <str<strong>on</strong>g>of</str<strong>on</strong>g> holograms with the NiCl 2 , changing the<br />
process <str<strong>on</strong>g>of</str<strong>on</strong>g> polymerizati<strong>on</strong> and time <str<strong>on</strong>g>of</str<strong>on</strong>g> treated. In the Figure 3, shows the curves <str<strong>on</strong>g>of</str<strong>on</strong>g><br />
diffracti<strong>on</strong> efficiency obtained up to the moment.<br />
Figure 3. Curves <str<strong>on</strong>g>of</str<strong>on</strong>g> diffracti<strong>on</strong> efficiency with NiCl 2<br />
1. Available< htttp://www.clariant.com/corporate/internet.nsf/direct/homeopendocument>.<br />
2. Available.<br />
3. B. Ruiz-Limón, Arturo Olivares Pérez, F Silva Andrade, I Fuentes Tapia, Juan Carlos Ibarra<br />
Torres, “Polyvinyl alcohol doped with nickel chloride hexahydrate as c<strong>on</strong>ductor polymer”,<br />
SPIE, Vol. 5351.<br />
4. Available .<br />
5. John R Dyer, “Aplicaci<strong>on</strong>es de espectroscopia de absorción en compuestos orgánicos”, first<br />
Ed. Prentice Hall Internaci<strong>on</strong>al, New Jersey USA, 1973.