Proceedings of Topical Meeting on Optoinformatics (pdf-format, 1.21 ...

Proceedings of Topical Meeting on Optoinformatics (pdf-format, 1.21 ... Proceedings of Topical Meeting on Optoinformatics (pdf-format, 1.21 ...

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34 OPTOINFORMATICS’05 VR = R * S / L (1) Where: VR = resistivity ong>ofong> volume (Ohm.cm) R = resistance ong>ofong> the material to the flow ong>ofong> load (Ohm) S = surface ong>ofong> the electrode (cm 2 ) defined like S = W * t L = distance between electrodes (cm) Figure 1. Volume resistivity technique ong>ofong> two points The test was realized ong>ofong> resistivity ong>ofong> volume for 5 different types ong>ofong> concentrations solution, spilling in our model 4ml ong>ofong> solution for every test. For the measurement ong>ofong> the resistivity ong>ofong> volume for every solution, we use 3 different types ong>ofong> electrodes, tin (Sn), copper (Cu) and aluminium (Al). Obtaining 10000 readings in real time for every test, hereby to be able to observe the change and the evolution ong>ofong> the conductive polymer with regard to the resistivity in the time. Of the results obtained in the graphic 1 it was possible to observe that the resistivity ong>ofong> the polymer with tin electrodes presents the reaction named oxide - reduction with major stability, figure 2 (acceptance and not so changeable donation ong>ofong> electrons) [5] . Figure 2. Resistivity ong>ofong> the polymer with tin electrodes and reduction with major stability In general we can observe ong>ofong> 6 graphs that there is major stability for the majority ong>ofong> the solutions and minor values ong>ofong> resistivity for the case without dampness. In the development ong>ofong> this process for the present time we can say that the dampness is a determinant factor in the resistivity ong>ofong> the polymer, as what it is necessary to have major control on this one. We realize storage ong>ofong> holograms with the NiCl 2 , changing the process ong>ofong> polymerization and time ong>ofong> treated. In the Figure 3, shows the curves ong>ofong> diffraction efficiency obtained up to the moment. Figure 3. Curves ong>ofong> diffraction efficiency with NiCl 2 1. Available< htttp://www.clariant.com/corporate/internet.nsf/direct/homeopendocument>. 2. Available. 3. B. Ruiz-Limón, Arturo Olivares Pérez, F Silva Andrade, I Fuentes Tapia, Juan Carlos Ibarra Torres, “Polyvinyl alcohol doped with nickel chloride hexahydrate as conductor polymer”, SPIE, Vol. 5351. 4. Available . 5. John R Dyer, “Aplicaciones de espectroscopia de absorción en compuestos orgánicos”, first Ed. Prentice Hall Internacional, New Jersey USA, 1973.

SAINT-PETERSBURG, October 17 – 20, 2005 35 HIGH-EFFECTIVE MULTIPLEX HOLOGRAMS IN VOLUME POLYMER MEDIA O.V. Andreeva, A.P. Kushnarenko*, B.B. Lesnichij**, A.P. Nacharov**, A.A. Paramonov** S.I. Vavilov State Optical Institute, 12 Birzhevaya linija, St. Petersburg, Russia, 197198 *Saint-Petersburg State University, 1, Uljanovskaja str., Petrodvorets, St. Petersburg, Russia, 198504 **Saint-Petersburg State University ong>ofong> Information Technology, Mechanics and Optics, 49 Kronverkskij ave., St. Petersburg, Russia, 197101 E-mail: ali@phoi.ifmo.ru, kushnarenko@front.ru At present paper the technique developed for record ong>ofong> high-effective superposed holograms in polymer medium “Difphen” is reported. The results ong>ofong> investigation ong>ofong> hologram that was obtained by means ong>ofong> angular multiplexing with technology developed are presented. The possibilities ong>ofong> such holograms usage for information storage and producing ong>ofong> elements with special properties based on regular and fractal structures are shown. At the last time because ong>ofong> tremendous growth ong>ofong> optical information technologies the interest to high-resolution holographic recording media also increases. Volume holography suggests effective methods for storage, transformation and processing ong>ofong> huge volume ong>ofong> data. The development ong>ofong> that area is impossible without development ong>ofong> technologies for recording media engineering and methods ong>ofong> hologram producing. On the other hand, interest to recording media is maintained by the fact that there is the possibility to apply holographic media for creation ong>ofong> metamaterials or left-handed materials i.e. structurally organized substance with properties that are unusual for conventional natural materials [1] . The polymeric recording medium with post-exposure amplification “Difphen” [2] (on basis ong>ofong> phenanthroquinone) was developed at the S.I. Vavilov Optical Institute and possesses the number ong>ofong> peculiarities: high resolution (more 5000 mm -1 ), high value ong>ofong> phase modulation, ability to record interference patterns without distortions within wide dynamic range, stability ong>ofong> performance attributes. Polymeric media on basis ong>ofong> phenanthroquinone have well-known abilities ong>ofong> recording ong>ofong> a large number ong>ofong> superposed holograms. Here holograms, recorded on the same area ong>ofong> the sample, are subjected to post-exposure treatment simultaneously and have small value ong>ofong> efficiency. When low-effective superposed holograms are recorded, the dynamic range ong>ofong> material allows to record a large number ong>ofong> holograms with identical characteristics. But it is impossible to use this way for recording ong>ofong> superposed identical holograms with diffraction efficiency close to 100% since changes ong>ofong> spatial distribution ong>ofong> light-sensitive substrate concentration after recording ong>ofong> each hologram.

34 OPTOINFORMATICS’05<br />

VR = R * S / L (1)<br />

Where:<br />

VR = resistivity <str<strong>on</strong>g>of</str<strong>on</strong>g> volume (Ohm.cm)<br />

R = resistance <str<strong>on</strong>g>of</str<strong>on</strong>g> the material to the flow <str<strong>on</strong>g>of</str<strong>on</strong>g> load (Ohm)<br />

S = surface <str<strong>on</strong>g>of</str<strong>on</strong>g> the electrode (cm 2 ) defined like S = W * t<br />

L = distance between electrodes (cm)<br />

Figure 1. Volume resistivity<br />

technique <str<strong>on</strong>g>of</str<strong>on</strong>g> two points<br />

The test was realized <str<strong>on</strong>g>of</str<strong>on</strong>g> resistivity <str<strong>on</strong>g>of</str<strong>on</strong>g> volume for 5 different types <str<strong>on</strong>g>of</str<strong>on</strong>g> c<strong>on</strong>centrati<strong>on</strong>s<br />

soluti<strong>on</strong>, spilling in our model 4ml <str<strong>on</strong>g>of</str<strong>on</strong>g> soluti<strong>on</strong> for every test. For the measurement <str<strong>on</strong>g>of</str<strong>on</strong>g> the<br />

resistivity <str<strong>on</strong>g>of</str<strong>on</strong>g> volume for every soluti<strong>on</strong>, we use 3 different types <str<strong>on</strong>g>of</str<strong>on</strong>g> electrodes, tin (Sn),<br />

copper (Cu) and aluminium (Al). Obtaining 10000 readings in real time for every test,<br />

hereby to be able to observe the change and the evoluti<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> the c<strong>on</strong>ductive polymer with<br />

regard to the resistivity in the time.<br />

Of the results obtained in the graphic 1 it was possible to observe that the resistivity<br />

<str<strong>on</strong>g>of</str<strong>on</strong>g> the polymer with tin electrodes presents the reacti<strong>on</strong> named oxide - reducti<strong>on</strong> with major<br />

stability, figure 2 (acceptance and not so changeable d<strong>on</strong>ati<strong>on</strong> <str<strong>on</strong>g>of</str<strong>on</strong>g> electr<strong>on</strong>s) [5] .<br />

Figure 2. Resistivity <str<strong>on</strong>g>of</str<strong>on</strong>g> the polymer with tin<br />

electrodes and reducti<strong>on</strong> with major stability<br />

In general we can observe <str<strong>on</strong>g>of</str<strong>on</strong>g> 6 graphs that there is major stability for the majority <str<strong>on</strong>g>of</str<strong>on</strong>g><br />

the soluti<strong>on</strong>s and minor values <str<strong>on</strong>g>of</str<strong>on</strong>g> resistivity for the case without dampness.<br />

In the development <str<strong>on</strong>g>of</str<strong>on</strong>g> this process for the present time we can say that the dampness<br />

is a determinant factor in the resistivity <str<strong>on</strong>g>of</str<strong>on</strong>g> the polymer, as what it is necessary to have<br />

major c<strong>on</strong>trol <strong>on</strong> this <strong>on</strong>e. We realize storage <str<strong>on</strong>g>of</str<strong>on</strong>g> holograms with the NiCl 2 , changing the<br />

process <str<strong>on</strong>g>of</str<strong>on</strong>g> polymerizati<strong>on</strong> and time <str<strong>on</strong>g>of</str<strong>on</strong>g> treated. In the Figure 3, shows the curves <str<strong>on</strong>g>of</str<strong>on</strong>g><br />

diffracti<strong>on</strong> efficiency obtained up to the moment.<br />

Figure 3. Curves <str<strong>on</strong>g>of</str<strong>on</strong>g> diffracti<strong>on</strong> efficiency with NiCl 2<br />

1. Available< htttp://www.clariant.com/corporate/internet.nsf/direct/homeopendocument>.<br />

2. Available.<br />

3. B. Ruiz-Limón, Arturo Olivares Pérez, F Silva Andrade, I Fuentes Tapia, Juan Carlos Ibarra<br />

Torres, “Polyvinyl alcohol doped with nickel chloride hexahydrate as c<strong>on</strong>ductor polymer”,<br />

SPIE, Vol. 5351.<br />

4. Available .<br />

5. John R Dyer, “Aplicaci<strong>on</strong>es de espectroscopia de absorción en compuestos orgánicos”, first<br />

Ed. Prentice Hall Internaci<strong>on</strong>al, New Jersey USA, 1973.

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