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Three - University of Arkansas Physics Department

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APPLIED PHYSICS LETTERS VOLUME 75, NUMBER 4<br />

Proton irradiation effects on the intersubband transition in GaAsIAIGaAs<br />

multiple quantum wells with bulk or si~perlattice barriers<br />

M. 0. ~anasreh~)<br />

Air Force Reseclrch Luh (AFRWVSSS), 3550 Aberdeen AIV,<br />

:Vew Mexico 87117-5776<br />

SE, Bldg 426, Kirtlawd .4FB<br />

P. Ballet, J. B. Srnathers, and G. J. Salarno<br />

Departrnenf <strong>of</strong> <strong>Physics</strong>, Uni~versie <strong>of</strong> Arkunsas. Fayeueville, Arkn~rsus 72701<br />

Chennupati Jagadish<br />

<strong>Department</strong> <strong>of</strong> Elecfronic Muferiirl.~ Engineering, Research School <strong>of</strong> Physical Scietlces utul Engineering,<br />

Australian Matior~al Univcrsi~, Cnnbew, ACT 0200. .4ustralici<br />

(Received 13 April 1999; accepted for publication 4 June 1999)<br />

The optical absorption spectra, measured at either 77 or 300 K, <strong>of</strong> the intersubband transition in<br />

Si-doped GaAslAIGaAs multiple quantum wells were studied before and after I MeV proton<br />

irradiation. The intersubband transition in samples with superlattice barriers was conlpletely washed<br />

out after irradiation with doses as low as 1.OX 10'%m-'. Thc total integrated areas <strong>of</strong> the<br />

intersubband transitions were studied as a hnction <strong>of</strong> doses. Tt was observed that the intersubband<br />

transitions in samples with superlattice barriers degradc at a fastcr ratc as compared to those<br />

transitions in samples with bulk barriers. O 1999 American Institute <strong>of</strong> <strong>Physics</strong>.<br />

[SOOO3-695 I (99)03730-41<br />

Proton irradiation effect on the intersubband transitions<br />

in 111-V semiconductor quanhim wells received little attention<br />

thus far. The desire to study this effect is based - on<br />

tw<strong>of</strong>old. First, intersubband transitions form the basis <strong>of</strong> a<br />

new generation <strong>of</strong> long and very long wavelength infrared<br />

detectors.'-3 Second, space application is one <strong>of</strong> the most<br />

recent uses <strong>of</strong> this class <strong>of</strong> detectors, hence, the su~ivability<br />

<strong>of</strong> these detectors in space and radiation environment becomes<br />

very important. Charge ionization and atomic displacement<br />

are the most important effects in irradiated semiconductor<br />

inaterials and devices. Charge ionization plays a<br />

major role in the device perfomlance since irradiation induced<br />

charge accun~ulation has a detriment effect on electronic<br />

and optoclcctronic devices. Generally speaking, the<br />

chargc ionization effect is scnsitive to the tcnlperature (Ti) at<br />

which the irradiation is performed. On the other hand, irradiation<br />

induced atomic displaccrnent affect both devices and<br />

materials. It is more pr<strong>of</strong>ound at high doses and less sensitive<br />

to 7,.<br />

Irradiation effects on the intersubband transitions in<br />

GaAslAlGaAs multiple quantum wells (MQWs) and related<br />

compounds have not been thoroughly studied. Gamma-ray<br />

irradiation effect on the intersubband transitions in InGaAsI<br />

AIGaAs MQWs have been reported.' Preliminary results on<br />

the electron irradiation effects on intersubband transitions in<br />

InGaAsIAIGaAs MQWs have been reported recently.' A recent<br />

report6 on the proton irradiation effect on GaAs quantum<br />

well lasers indicates that there is a wavelength shift in<br />

the lasing spectra. However, the proton irradiation effects on<br />

the intersubband transitions have not been reported yet. In<br />

this letter, we report on the proton irradiation effect on optical<br />

absorption spectra <strong>of</strong> the intersubband transitions in<br />

"Electronic mail: manasreo@plk.af.mil<br />

n-type GaAsIAIGaAs MQWs. It will be shown t!-i.tt thc intensity<br />

<strong>of</strong> the intersubband transitions is drauilrrically decreased<br />

as a function <strong>of</strong> irradiation doses. which can b~ tuplained<br />

in tenns <strong>of</strong> trapping <strong>of</strong> the hvo-dimensionsl clccrro~ls<br />

in the quantum wells by the irradiation indcc~~i ,(:,:,:.:+ .. r ! ~<br />

addition, we observed that intersubband traiisi~ions i ~.<br />

samples with superlattice barriers degrade faster than th~se<br />

transitions in samples with bulk bamers as the irr:rdisti~n<br />

dose is increased. .. . .<br />

Two multiple quantum well structures used in t4ie<br />

present study were grown by the molecular-bc;rm epitauy<br />

technique on a semi-insulating GaAs substrate with li.5-<br />

pm-thick GaAs buffer layer and -200-A-thick GaAs cap<br />

layer. The structures <strong>of</strong> the two wafers are shown in Table I. .<br />

The barriers <strong>of</strong> the wafer labeled "B" are made <strong>of</strong> live periods<br />

~l~a~s!~aAs superlattices. While the barlies <strong>of</strong> the .<br />

wafer labeled "A" is bulk AIGaAs. The wonl "bufk" is<br />

used here to indicate that the barrier is not a supesi:~ttice. The<br />

well regions were Si-doped {[Si] = 2 X IO'%II-'J. Se\ c~;l<br />

samples were cut and irradiated with different 4osi.s <strong>of</strong>! .<br />

MeV protons beam. The infrared absorption sI1:ctra were<br />

recorded at the Brewster's angel <strong>of</strong> Ga.4~ (77"1 from the<br />

nornlal using a BOMEM Fourier-transfoml interfcronietci..in ..<br />

T.4HLE 1. Structures <strong>of</strong> the wafers used In the present ~~LI(I) 411 ~afc!,<br />

were SI-dopcd m thc well ([SII=ZOA 101Jcm-2} The barrt~~ m.~tcr~nla ol<br />

wafer B are made <strong>of</strong> AIGaAs/GaAs supcrlatt~ce<br />

Wafcr<br />

A<br />

--<br />

Well thickness (A) 75 105<br />

GaAs<br />

Barrier material AI,,Gan7As AI,,.,G>+,,,~\a G:v\s<br />

Harrier thickness (I\) 100 ~()(...:i<br />

Barrier period<br />

...<br />

MQWs period 10 SO<br />

0003-695119917~(4)1525/31$15.00 525 0 1999 American Institu:.: <strong>of</strong> <strong>Physics</strong><br />

Copyright Q2001. All Rights Reserved.

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