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Three - University of Arkansas Physics Department

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Journal <strong>of</strong> Electronic Materials, Vol. 27, No. 7, 1998<br />

Regular Issue Paper<br />

Evaluation <strong>of</strong> 1nP:Fe Parameters by Measurement <strong>of</strong> Two<br />

Wave Mixing Photorefractive and Absorptive Gain<br />

M. CHAUVET,' G.J. SALAMO,' D.F. BLISS,^ and G. BRYANT~<br />

1.-<strong>University</strong> <strong>of</strong> <strong>Arkansas</strong>, <strong>Physics</strong> <strong>Department</strong>, Fayetteville, AK 72701, 2.-Rome Laboratory,<br />

U.S.A.F., Hanscom AFB, MA 01731<br />

In this paper, we present two-wave mixing absorption gain measurements in<br />

1nP:Fe in the 960-1035 nm wavelength range. The measured absorption gain is<br />

shown to be positive for long wavelength but changes sign for shorter wavelength.<br />

By simultaneously measuring the photorefractive gain and the absorption<br />

gain, we deduce the values <strong>of</strong> the photo-ionization cross sections related to<br />

the iron deep level trap. Finally, the study <strong>of</strong> the temperature dependence <strong>of</strong> the<br />

absorption gain allows us to evaluate a temperature shift <strong>of</strong> the iron level with<br />

respect to the conduction band <strong>of</strong> -4 x lo4 eV/K.<br />

Key words: Absorptive gain, InP:Fe, photorefractivity, two wave mixing<br />

INTRODUCTION<br />

Semi-insulating iron doped indium phosphide<br />

(1nP:Fe) is <strong>of</strong> interest for the development <strong>of</strong> optoelectronic<br />

components. For this reason, it is important<br />

to understand the role <strong>of</strong> iron on the electronic<br />

and optical performance <strong>of</strong> 1nP:Fe devices. This role is<br />

strongly related to the position and behavior <strong>of</strong> the<br />

iron level, as well as to the iron optical cross sections.<br />

In this paper, we exploit photorefractive two wave<br />

mixing (TWM) experiments to determine the optical<br />

cross sections as well as the temperature dependence<br />

<strong>of</strong> the iron energy level. These TWM experiments are<br />

based on observing the mutual influence <strong>of</strong> two coherent<br />

beams <strong>of</strong> unequal intensity crossing in a 1nP:Fe<br />

crystal. We measure the change <strong>of</strong> intensity level <strong>of</strong><br />

the weaker beam (signal beam) after propagation in<br />

the crystal under the presence <strong>of</strong> the strong beam<br />

(pump beam). A TWM gain r can then be calculated<br />

assuming that the intensity <strong>of</strong> the weak beam follows<br />

the solution:<br />

Where Iso and I,, are the intensity <strong>of</strong> the signal in the<br />

(Received August 25, 1997; accepted January 26, 1998)<br />

absence and in the presence <strong>of</strong> the strong beam,<br />

respectively. The TWM gain is composed <strong>of</strong> rEO, the<br />

electro-optic gain, Ta, the absorption gain and T, the<br />

absorption-induced index gain. These gains all come<br />

initially from a redistribution <strong>of</strong> the charges on the<br />

iron deep level under the influence <strong>of</strong> the interference<br />

grating formed by the two beams. Specifically, rEO is<br />

the electro-optic gain that is measured when the<br />

energy coupling is created by the space charge field<br />

associated with the linear electro-optic effect. This<br />

electro-o tic gain has been extensively studied in<br />

1nP:Fe<br />

1s<br />

as well as in numerous photorefractive<br />

and is commonly named the photorefractive<br />

gain. The absorptive gain5 ra takes place<br />

because <strong>of</strong> the absorption grating formed by the ~ e"<br />

and ~ e sinusoidal ~ ' redistribution resulting in a spatial<br />

modulation <strong>of</strong> the absorption. The absorption<br />

gain is usually neglected but it has been reported for<br />

photorefractive crystal such as6 BaTi03 and G~As.~"<br />

This absorption grating is accompanied by an index<br />

grating giving energy coupling or a gain T,. The total<br />

gain is simply the sum <strong>of</strong> the contribution <strong>of</strong> each<br />

individual gain: r = rEO + ra + ran<br />

THEORY<br />

The photorefractive effect is present in 1nP:Fe<br />

because <strong>of</strong> a spatial redistribution <strong>of</strong> the free carriers

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