Handbook of Energy Storage for Transmission or ... - W2agz.com

Handbook of Energy Storage for Transmission or ... - W2agz.com Handbook of Energy Storage for Transmission or ... - W2agz.com

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EPRI Proprietary Licensed Material Proceedings of the International Seminars on Double Layer Capacitors and Similar Energy Storage Devices Volumes 1 through 11. Available through Florida Educational Seminars, Inc., Boca Raton, Florida (1991 – 2001) Y. Kobayashi, Acceleration Coefficient of the Molded Electric Double Layer Capacitor, NEC Corporation Websites: www.faradnet.com, www.POWERSOURCES.net, manufacturer websites are listed in Table 3. Glossary Asymmetric capacitor – See type III capacitor and type IV capacitor Electrochemical capacitor, double layer capacitor, electric double layer capacitor, supercapacitor, ultracapacitorcommon names for the type of capacitor in which electrical energy is stored in an electric double layer by means of separation of charge at an interface between a solid electrode and electrolyte. Ultracapacitor and supercapacitor are trademarked names. Energy, Capacitor - The ideal (maximum) value of the electrical energy stored in a capacitor. For the first-order model of a capacitor, it is equal to ½ CV 2 where C is the capacitance and V is the working voltage on the capacitor. Energy, Specific – Energy per unit mass usually expressed as Watt-hours/kilogram or kilojoules/kilogram. Energy density - Energy per unit volume, usually expressed as Watt-hours/liter or kilojoules/liter. Equivalent series resistance - The value of the resistance element when a capacitor is modeled as a series RLC circuit. ESR can be measured using current interrupt methods or by AC impedance techniques. It contributes to dynamic losses in the capacitor, that is, losses experienced only during charge or discharge. ESR is a lumped element value that arises from the leads, current collectors, electrodes, separators, contacts, and other resistance elements. Impedance (Z) – The ratio V/I of a capacitor where V is a voltage (periodic in time) applied to the component and I is the resultant current. Z is a complex quantity, having real and imaginary parts. It represents the current flow response to an applied timedependent voltage. Leakage current - The steady-state current drawn by a capacitor after being charged. It is responsible for static energy losses . The leakage current is established by resistor R p , the equilavent resistance in parallel with the capacitor which is sometimes referred to as the self-discharge resistance. The leakage current is time dependent when the capacitor is held at a constant voltage and the current required to maintain this voltage decreases with time as the capacitor comes to an equilibrium-charge state. Power (maximum) - The ideal (maximum) value of the power that can be delivered by a capacitor. For the first-order model of a capacitor, it is equal to V 2 /4R where V is the working voltage on the capacitor and R is the equivalent series resistance. Electrochemical Capacitors 54

EPRI Proprietary Licensed Material Power, Specific – Power per unit mass usually expressed as kilowatts/kilogram. Power density - Power per unit volume usually expressed as kilowatts/liter. Pulse Ragone plot – The relationship showing the energy delivered by a capacitor during a given discharge time. This plot shows the effective energy density of the capacitor for different discharge periods. Ragone plot – The power and energy relationship commonly used to compare different energy storage devices. The plot is usually shown as a log – log scale with specific power for the independent variable and specific energy for the dependent variable. Symmetric capacitor – See type I capacitor and type II capacitor type I electrochemical capacitor - The first type of electrochemical capacitors developed. These are of symmetric design and utilizing two activated carbon electrodes with sulfuric acid or potassium hydroxide electrolyte. type II electrochemical capacitor – The type of electrochemical capacitor with symmetric design utilizing activated carbon electrodes and an organic electrolyte. Organic electrolytes allow operation at higher voltage. Type II electrochemical capacitors are probably the most common type in use today. type III electrochemical capacitor - The type electrochemical capacitor that is of asymmetric design, using one activated carbon electrode and one high capacity batterylike electrode with an aqueous electrolyte. type IV electrochemical capacitor - The type electrochemical capacitor that is of asymmetric design, using one activated carbon electrode and one high capacity batterylike electrode with an organic electrolyte. There are no commercial type IV products; this technology is the subject of present research. (Telcordia Technologies, Inc. is sampling an asymmetric type IV capacitor that has a carbon cathode and a Li-titanate anode that uses an organic electrolyte. Electrochemical Capacitors 55

EPRI Proprietary Licensed Material<br />

Proceedings <strong>of</strong> the International Seminars on Double Layer Capacit<strong>or</strong>s and Similar<br />

<strong>Energy</strong> <strong>St<strong>or</strong>age</strong> Devices Volumes 1 through 11. Available through Fl<strong>or</strong>ida Educational<br />

Seminars, Inc., Boca Raton, Fl<strong>or</strong>ida (1991 – 2001)<br />

Y. Kobayashi, Acceleration Coefficient <strong>of</strong> the Molded Electric Double Layer Capacit<strong>or</strong>,<br />

NEC C<strong>or</strong>p<strong>or</strong>ation<br />

Websites: www.faradnet.<strong>com</strong>, www.POWERSOURCES.net, manufacturer websites are<br />

listed in Table 3.<br />

Glossary<br />

Asymmetric capacit<strong>or</strong> – See type III capacit<strong>or</strong> and type IV capacit<strong>or</strong><br />

Electrochemical capacit<strong>or</strong>, double layer capacit<strong>or</strong>, electric double layer capacit<strong>or</strong>,<br />

supercapacit<strong>or</strong>, ultracapacit<strong>or</strong> – <strong>com</strong>mon names <strong>f<strong>or</strong></strong> the type <strong>of</strong> capacit<strong>or</strong> in which<br />

electrical energy is st<strong>or</strong>ed in an electric double layer by means <strong>of</strong> separation <strong>of</strong> charge at<br />

an interface between a solid electrode and electrolyte. Ultracapacit<strong>or</strong> and supercapacit<strong>or</strong><br />

are trademarked names.<br />

<strong>Energy</strong>, Capacit<strong>or</strong> - The ideal (maximum) value <strong>of</strong> the electrical energy st<strong>or</strong>ed in a<br />

capacit<strong>or</strong>. F<strong>or</strong> the first-<strong>or</strong>der model <strong>of</strong> a capacit<strong>or</strong>, it is equal to ½ CV 2 where C is the<br />

capacitance and V is the w<strong>or</strong>king voltage on the capacit<strong>or</strong>.<br />

<strong>Energy</strong>, Specific – <strong>Energy</strong> per unit mass usually expressed as Watt-hours/kilogram <strong>or</strong><br />

kilojoules/kilogram.<br />

<strong>Energy</strong> density - <strong>Energy</strong> per unit volume, usually expressed as Watt-hours/liter <strong>or</strong><br />

kilojoules/liter.<br />

Equivalent series resistance - The value <strong>of</strong> the resistance element when a capacit<strong>or</strong> is<br />

modeled as a series RLC circuit. ESR can be measured using current interrupt methods<br />

<strong>or</strong> by AC impedance techniques. It contributes to dynamic losses in the capacit<strong>or</strong>, that is,<br />

losses experienced only during charge <strong>or</strong> discharge. ESR is a lumped element value that<br />

arises from the leads, current collect<strong>or</strong>s, electrodes, separat<strong>or</strong>s, contacts, and other<br />

resistance elements.<br />

Impedance (Z) – The ratio V/I <strong>of</strong> a capacit<strong>or</strong> where V is a voltage (periodic in time)<br />

applied to the <strong>com</strong>ponent and I is the resultant current. Z is a <strong>com</strong>plex quantity, having<br />

real and imaginary parts. It represents the current flow response to an applied timedependent<br />

voltage.<br />

Leakage current - The steady-state current drawn by a capacit<strong>or</strong> after being charged. It is<br />

responsible <strong>f<strong>or</strong></strong> static energy losses . The leakage current is established by resist<strong>or</strong> R p<br />

, the<br />

equilavent resistance in parallel with the capacit<strong>or</strong> which is sometimes referred to as the<br />

self-discharge resistance. The leakage current is time dependent when the capacit<strong>or</strong> is<br />

held at a constant voltage and the current required to maintain this voltage decreases with<br />

time as the capacit<strong>or</strong> <strong>com</strong>es to an equilibrium-charge state.<br />

Power (maximum) - The ideal (maximum) value <strong>of</strong> the power that can be delivered by a<br />

capacit<strong>or</strong>. F<strong>or</strong> the first-<strong>or</strong>der model <strong>of</strong> a capacit<strong>or</strong>, it is equal to V 2 /4R where V is the<br />

w<strong>or</strong>king voltage on the capacit<strong>or</strong> and R is the equivalent series resistance.<br />

Electrochemical Capacit<strong>or</strong>s 54

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