Soil Generic Assessment Criteria for Human Health Risk ... - ESdat

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www.esdat.net Esdat Environmental Database Management Software +61 2 8875 7948 Antimony CAS7440360 AssessorA: AndreasNeymeyer, BuroHappold AssessorB: MikeRogers,OPUSJOYNESPIKELtd Finalreview: Panel/SF Date 09/04/2009 Date 09/04/2009 Date 26/08/2009 Recommended Justification:UKpopulationestimateofdietrayintakefromFSA2006totaldietstudy MDI MDIoral Units 2.5 ugday1 Organisation Date Media Value Units Description Reference Weblink FoodStandardsAgency(FSA) Jan09 food 2.5 gday1 Estimateofpopulationdietraryintakefrom FSA,2009.Measurementoftheconcentrationsof http://www.food.gov.uk/ totalfoodsurveyof20foodgroupsfrom24 metalsandotherelementsfromthe2006UKtotaldiet multimedia/pdfs/fsis0909 metals.pdf UKtowns study EuropeanFoodSafetyAuthority (EFSA) 27/03/2009 food 42 gday1 ARestrictionof0.04mg/kgoffood(asSb)is applied.Thisrestrictionwouldallowfor10%of theTDIbeingallocatedtofoodcontact materials. TDI6ug/kg(bw)/dayx70kg(bw)=420ug/dayx 10%=42ug/day TheEFSAJournal(2004)24,113,Opinionofthe www.efsa.europa.eu ScientificPanelonfoodadditives,flavourings,processing/en.htm aidsandmaterialsincontactwithfood(AFC)ona requestfromtheCommissionrelatedtoa2ndlistof substancesforfoodcontactmaterials. (http://www.efsa.europa.eu/cs/BlobServer/Scientific_O pinion/opinion_afc_06_en1,0.pdf) WHOGuidelinesforDrinking WaterQuality 27/03/2009 water[assuming 5g/lindrinking waterand2l water consumption)] 10 gday1 "Theconcentrationsindrinkingwaterappear tobelessthan5g/litre"(alsonote:UK DrinkingWaterStandards(DWS)forantimony =5ugday1)" USEPA,1984;Longtin,1985 (http://www.who.int/water_sanitation_health/dwq/che micals/antimony.pdf) www.who.int/water_ sanitation_health/dw q/guidelines/en WHOGuidelinesforDrinking WaterQuality 27/03/2009 oraltotal 70 gday1 Dailyoraluptakeofantimonyrangesfrom10 to70g GebelT.1999.Metalle/Antimon.In:Wichmann SchlipköterFülgraff,eds.Umweltmedizinisches Handbuch,17.Ergänzungslieferung(November1999). Landsberg,ecomed. (http://www.who.int/water_sanitation_health/dwq/che micals/antimony.pdf) www.who.int/water_ sanitation_health/dw q/guidelines/en InternationalAntimonyOxide IndustryAssociation 27/03/2009 oraltotal 70 gday1 Thedailyintakefromfoodandwaterranges fromto10to70micrograms(g)perday. AntimonyTrioxideFrequentlyAskedQuestions:March 2006 (http://www.nihonseiko.co.jp/english/environment/060 418faq_e.pdf) MDI Recommended MDIinh Units Justification:AsreportedinSlooffW(1992)Exploratoryreport.Antimonyandantimonycompounds.Bilthoven, RijksinstituutvoordeVolksgezondheidenMilieuhygiene. 0.46 ugday1 Organisation Media Value Units Description Reference Weblink WHOGuidelinesforDrinking WaterQuality 27/03/2009 Air 0.46 gday1 Exposureofthetypicalurbanpopulationto antimonyfromairisestimatedtobe between60and460ng/dayperperson SlooffW(1992)Exploratoryreport.Antimonyand antimonycompounds.Bilthoven,Rijksinstituutvoorde VolksgezondheidenMilieuhygiene. http://www.nihonsei ko.co.jp/english/envi ronment/060418faq _e.pdf www.who.int/water_ sanitation_health/dw q/guidelines/en InternationalAntimonyOxide IndustryAssociation 27/03/2009 Air 0.15 gday1 Themainsourcesofantimonyinurbanairare fromindustrialdust,caremissionsandfueloil combustion,butstillareverylow (0.15ug/kg/day). AntimonyTrioxideFrequentlyAskedQuestions:March 2006 (http://www.nihonseiko.co.jp/english/environment/060 418faq_e.pdf) http://www.nihonsei ko.co.jp/english/envi ronment/060418faq _e.pdf Page 3 of 4 EIC proforma antimony.xls 17/11/2009
www.esdat.net Esdat Environmental Database Management Software +61 2 8875 7948 MikeRogers,OPUSJOYNES AndreasNeymeyer,Buro Substance: Antimony CASNumber: CAS7440360 Assessor: 1streviewer: 2ndreviewer: Panel/SF PIKELtd Happold PhaseatAmbient ChemicalFormula: Sb Solid(Metal) Date: 09Apr09 Date: 09Apr09 Date: 26Aug09 http://srdata.nist.gov/solubility/ Tempertaure http://webbook.nist.gov/chemistry/ http://cs3-hq.oecd.org/scripts/hpv/ A B C D E F G H ADDITIONALREFERENCES ADDITIONALREFERENCES ADDITIONALREFERENCES HOWARD,1990 LIDE,2008 MACKAYetal,2006 MERCK,2006 MONTGOMERY,2007 MONTGOMERY,1997 NIST,2005 OECD,2000 NationalToxicologyProgram RiskAssessmentInformationSystem(RAIS) U.S.EnvironmentalProtectionAgency. Recommended Property Units CalculatedValue Ref.Temp(C) Rationale References [online]. 2005. LiteratureValue SourceUnits SR7Units Ref.Temp(C) SourceUnits SR7Units Ref.Temp(C) SourceUnits SR7Units Ref.Temp(C) SourceUnits SR7Units Ref.Temp(C) SourceUnits SR7Units Ref.Temp(C) SourceUnits SR7Units Ref.Temp(C) SourceUnits SR7Units Ref.Temp(C) SourceUnits SR7Units Ref.Temp(C) SourceUnits SR7Units Ref.Temp(C) SourceUnits SR7Units Ref.Temp(C) SourceUnits SR7Units Ref.Temp(C) RequiredParameters mg/L mg/L Ref.Temp(C) g/L mg/L Ref.Temp(C) mg/L mg/L Ref.Temp(C) mg/L mg/L Ref.Temp(C) mg/L mg/L Ref.Temp(C) mg/L mg/L Ref.Temp(C) mg/L mg/L Ref.Temp(C) mg/L mg/L Ref.Temp(C) mg/L mg/L Ref.Temp(C) mg/L mg/L Ref.Temp(C) mg/L mg/L Ref.Temp(C) Solubility(S)10oCwhere possible.(Useunit converterifsourceprovides differentunits) mg/L n/a 9.87E+05 25 Maximumreportedvalue forallantimony compoundsbasedon AntimonyChloridefrom Lide2008 Geomean InsertValues 9.87E+05 25 InsertValues 9.90E+04 25 0.00E+00 InsertValues InsertValues 2.76E+00 22 1.75E+00 18 0.00E+00 0.00E+00 987000 9.90E+04 2.76E+00 1.75E+00 9.87E+02 9.90E+04 2.76E+00 1.75E+00 25 25 22 18 Dimensionless Dimensionless Ref.Temp(C) Dimensionless Dimensionless Ref.Temp(C) Dimensionless Dimensionless Ref.Temp(C) Dimensionless Dimensionless Ref.Temp(C) Dimensionless Dimensionless Ref.Temp(C) Dimensionless Dimensionless Ref.Temp(C) Dimensionless Dimensionless Ref.Temp(C) Dimensionless Dimensionless Ref.Temp(C) Dimensionless Dimensionless Ref.Temp(C) Dimensionless Dimensionless Ref.Temp(C) Dimensionless Dimensionless Ref.Temp(C) Largerangeinvaluesno SoilWaterPartition cm 3 .g 1 NA NA recommendedvalue Coefficient derived mgkg–1FW Source:BAESetal(1984) Soiltoplantconcentration plantpermg NA 0.2 n/a OakRidgeNational factorGreenVegetables kg–1DWsoil Laboratory mgkg–1FW Source:BAESetal(1984) Soiltoplantconcentration plantpermg NA 0.03 n/a OakRidgeNational factorRootVegetables kg–1DWsoil Laboratory mgkg–1FW Soiltoplantconcentration plantpermg NA n/a factorTuberVegetables kg–1DWsoil mgkg–1FW Soiltoplantconcentration plantpermg NA n/a factorHerbaceousFruit kg–1DWsoil mgkg–1FW Soiltoplantconcentration plantpermg NA n/a factorShrubFruit kg–1DWsoil mgkg–1FW Soiltoplantconcentration plantpermg NA n/a factorTreeFruit kg–1DWsoil SoilPlantavailability Dimensionless NA 5 n/a Source:SR3formetals correctionfactor Average InsertValues n/a InsertValues n/a InsertValues n/a InsertValues n/a InsertValues n/a InsertValues n/a InsertValues n/a InsertValues n/a InsertValues n/a 4.50E+01 n/a 2.34E+02 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a 45.00 n/a 1.26 n/a 45 1.26 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a 501 501.00 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a 200 200.00 n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a n/a Rootshoot,rootrootstore, roottuberandroottofruit Dimensionless NA 0.5 n/a Source:SR3formetals correctionfactors DermalAbsorptionfactor Dimensionless NA 0 n/a Soiltodusttransportfactor Dimensionless NA 0.5 n/a Source:SR3formetalsin absenceofotherdata Source:SR3inabsenceof otherdata
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