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UV Weathering and Related Test Methods - Cabot Corporation

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Artificial weathering chambers<br />

a) Q<strong>UV</strong> fluorescent light source<br />

<strong>Weathering</strong> chambers have been developed to provide a Q<strong>UV</strong><br />

weathering.<br />

The Q<strong>UV</strong> simulates the effect of sunlight with fluorescent ultraviolet<br />

(<strong>UV</strong>) lamps, while rain <strong>and</strong> dew are simulated by the condensation of<br />

humidity. As stated previously, the <strong>UV</strong> light only represents roughly 5%<br />

of the sunlight but it is responsible for most of the polymer<br />

degradation. Also, materials are often tested with equipment, which<br />

simulate only the shortest wavelengths (<strong>UV</strong>).<br />

The <strong>UV</strong>-B range includes the shortest wavelengths found in sunlight.<br />

Therefore, for many applications, it is a fast <strong>and</strong> efficient method.<br />

Q<strong>UV</strong> equipment uses two main types of lamps: <strong>UV</strong>A-340 <strong>and</strong> <strong>UV</strong>B-<br />

313.<br />

As shown in Figures 1 <strong>and</strong> 2, while these lamps have different light<br />

emission spectrum, they are both characterized by a maximum of<br />

emission in the <strong>UV</strong> range.<br />

<strong>UV</strong>A provides a reasonable match of the <strong>UV</strong> region of the solar<br />

spectrum, but this match is no longer valid for the long wavelengths<br />

(visible, IR).<br />

<strong>UV</strong>B lamps also emit <strong>UV</strong> light, but the maximum of the emission<br />

spectrum is shifted towards short wavelengths compared to the <strong>UV</strong>A<br />

lamps. The <strong>UV</strong>B-313 lamp is a widely used type of fluorescent <strong>UV</strong><br />

lamp that provides fast test results. However, as shown in Figure 2,<br />

the spectrum contains short wavelengths, which are not present in<br />

the solar radiation.<br />

Irradiance (W/2/nm)<br />

1.2<br />

1.0<br />

0.8<br />

0.6<br />

0.4<br />

0.2<br />

0.0<br />

270<br />

Figure 1: <strong>UV</strong>A-340 spectrum Figure 2: <strong>UV</strong>B-313 spectrum<br />

<strong>UV</strong>A-340 versus Sunlight<br />

<strong>UV</strong>A-340<br />

290 310 330 350 370 390<br />

Wavelength (nm)<br />

Sunlight<br />

By courtesy of QPanel<br />

Irradiance (W/m2/nm)<br />

1.2<br />

1.0<br />

0.8<br />

0.6<br />

0.4<br />

0.2<br />

0.0<br />

<strong>UV</strong>B Lamps versus Sunlight<br />

<strong>UV</strong>B-313<br />

QFS-40<br />

270 290 310 330 350 370 390<br />

Wavelength (Nm)<br />

Sunlight<br />

By courtesy of QPanel<br />

9

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