GPS-X Technical Reference

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Digestion Models 286 Figure 10-10 - Stoichiometric Parameters The second set of stoichiometric parameters consists of yields. The relative amounts of chemical components produced by the biological reactions in the anaerobic digester are specified by these yields. Other stoichiometric parameters in this sub-menu are the dissociation constants used to calculate the ionized components in the pH model incorporated in the basic model. The dissociation constant for ammonium (kncon) is defined for 20 degrees Celsius and is temperature sensitive, i.e., the model corrects it for temperature changes using the following equation: Equation 10.14 GPS-X Technical Reference
287 Digestion Models The rest of the dissociation constants are not corrected for temperature changes in the basic model. Gas transfer parameters are also defined on this form. The mass transfer coefficient for carbon dioxide gas (sco2) between the liquid and gas phases (KLaco2) is not corrected by temperature in the basic model. Henry's law constant for carbon dioxide (henryco2) is also included in this item and is not corrected for temperature. Anaerobic Digestion Model #1 (ADM1) Anaerobic Digestion Model #1 (ADM1) (Batstone et al., 2002) is implemented in GPS-X according to the ADM1 COST Benchmark (Rosen and Jeppsson, 2002), with the following changes: Several differential equations that describe the acid-base equilibrium of the system (equations for S va-, S bu-, S pro-, S ac-, S hco3-, and S nh3) have been converted to algebraic equations as described in Table B.3 of Batstone et al. (2002). These processes are very fast and contribute to the stiffness of the system of differential equations. The differential equation for S h2 has been converted to an algebraic equation to improve the simulation speed. This process is very fast and contributes to the stiffness of the system of differential equations. This approach is described by Rosen et al. (2005). These changes substantially increase the solution speed of ADM1 in GPS-X and allow an integration algorithm other than Gear’s Stiff to be used. Double Precision arithmetic should be used when solving ADM1 in GPS-X (accessed in Options > Preferences > Build tab) The structured model includes five process steps including disintegration, hydrolysis, acidogenesis, acetogenesis and methanogenesis. The model uses 32 dynamic state variables, 6 acid-base kinetic processes, 19 biochemical processes, and 3 gas-liquid transfer processes. A simplified ADM1 material flow diagram is shown in Figure 10-11. For a full description of the model, the reader is referred to Batstone et al,. (2002). Implementation details are found in Rosen and Jeppsson (2002). GPS-X Technical Reference
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GPS-X Technical Reference GPS-X Ver
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Table of Contents iii Table of Cont
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v Table of Contents Sedimentation M
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vii Table of Contents Real Time Clo
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ix Table of Contents Figure 6-6 - P
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xi Table of Contents Figure 10-8 -
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xiii Table of Contents Figure 15-6
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xv Table of Contents Table 6-2 - Mo
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17 Modelling Fundamentals Experimen
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19 Modelling Fundamentals The proce
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21 Modelling Fundamentals Overview
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23 Modelling Fundamentals Primary a
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25 Modelling Fundamentals Vesilin
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27 GPS-X Objects CHAPTER 2 GPS-X Ob
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29 GPS- X Objects The mass balance
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31 GPS- X Objects Combining Equatio
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33 GPS-X State Variable Libraries S
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35 GPS-X State Variable Libraries C
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37 GPS-X State Variable Libraries C
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39 GPS-X Composite Variable Librari
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41 GPS-X Composite Variable Calcula
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55 Composite Variable Calculations
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61 Influent Models CHAPTER 5 Influe
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63 Influent Models Figure 5-3 - Inf
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65 Influent Models The three influe
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67 Influent Models Total runoff (Q
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69 Influent Models These inputs are
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71 Influent Models CODFractions COD
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73 Influent Models TSSCOD Figure 5-
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75 Influent Models Figure 5-13 - CN
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77 Influent Models CN and CNIP Libr
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83 Influent Models INFLUENT OBJECTS
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85 Influent Models Figure 5-22 - In
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87 Influent Models Chemical Dosage
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89 Influent Models Figure 5-29 - Ac
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91 Influent Models Figure 5-33 - Se
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93 Influent Models Figure 5-36 - Se
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95 Suspended Growth Models where: V
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97 Suspended Growth Models The baro
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99 Suspended Growth Models Oxygen M
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101 Suspended Growth Models In the
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103 Suspended Growth Models The SOT
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105 Suspended Growth Models Standar
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107 Suspended Growth Models The reg
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109 Suspended Growth Models SUMMARY
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111 Suspended Growth Models Figure
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113 Suspended Growth Models General
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115 Suspended Growth Models Number
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117 Suspended Growth Models Elevati
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121 Suspended Growth Models AERATIO
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123 Suspended Growth Models The ent
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125 Suspended Growth Models The org
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127 Suspended Growth Models Process
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129 Suspended Growth Models It i
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131 Suspended Growth Models Nitroge
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133 Suspended Growth Models Include
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135 Suspended Growth Models
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137 Suspended Growth Models Althoug
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139 Suspended Growth Models Particu
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141 Suspended Growth Models 9. Grow
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143 Suspended Growth Models 21. Sto
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145 Suspended Growth Models 33. Gro
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147 Suspended Growth Models To mode
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149 Suspended Growth Models Algebra
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151 Suspended Growth Models The sto
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153 Suspended Growth Models Decay o
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155 Suspended Growth Models SUGGEST
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157 Suspended Growth Models Special
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159 Suspended Growth Models Table 6
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161 Suspended Growth Models The GPS
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163 Suspended Growth Models where:
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165 Suspended Growth Models The max
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167 Suspended Growth Models If yo
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169 Suspended Growth Models ANAEROB
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171 Suspended Growth Models Simple
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173 Suspended Growth Models With th
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175 Suspended Growth Models Manual
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177 Suspended Growth Models Equatio
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179 Suspended Growth Models The met
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181 Suspended Growth Models Pond Mo
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183 Suspended Growth Models Special
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185 Suspended Growth Models Se
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187 Suspended Growth Models aerated
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193 Suspended Growth Models Calcula
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195 Suspended Growth Models The vap
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197 Suspended Growth Models Oxygen
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199 Suspended Growth Models Estimat
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203 Suspended Growth Models Enterin
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209 Suspended Growth Models MODELLI
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211 Suspended Growth Models TEMPERA
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213 Suspended Growth Models Table 6
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215 Suspended Growth Models The PAC
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217 Suspended Growth Models CHAPTER
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219 Attached-Growth Models Each lay
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221 Attached-Growth Models Equation
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223 Attached-Growth Models The mode
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225 Attached-Growth Models The phys
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227 Attached-Growth Models Liquid F
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229 Attached-Growth Models This con
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231 Attached-Growth Models The next
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233 Attached-Growth Models The SBC
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Page 251 and 252: 251 Attached-Growth Models Figure 7
Page 253 and 254: 253 Sedimentation and Flotation Mod
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Page 327 and 328: 327 Tools Object Figure 11-19 - Spe
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337 Tools Object PH TOOL Take a sam
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339 Tools Object These concentratio
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341 Tools Object LOW-PASS FILTERING
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343 Tools Object Control Variable P
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345 Tools Object The individual mod
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347 Tools Object PID in Position Fo
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349 Tools Object The following para
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351 Tools Object The controller tun
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353 Tools Object When both the proc
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355 Tools Object TIMER CONTROL The
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357 Tools Object Controller - The c
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359 Tools Object (qcon is the crypt
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361 Operating Cost Models CHAPTER 1
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363 Operating Cost Models The energ
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365 Operating Cost Models OPERATING
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367 Operating Cost Models OPERATING
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369 Operating Cost Models CALIBRATI
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371 Operating Cost Models Category
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373 Optimizer If after the reflecti
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375 Optimizer In the objective func
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377 Optimizer Figure 14-2 - Optimiz
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379 Optimizer Figure 14-3 - Example
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381 Optimizer SUMMARY OF THE OPTIMI
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383 Optimizer Use specified standar
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385 Optimizer Level of significance
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387 Optimizer APPENDIX A: MAXIMUM L
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389 Optimizer In GPS-X the log-like
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391 Optimizer Note that the user ca
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393 Optimizer Gradient of the Objec
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395 Optimizer Hessian of the Object
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397 Optimizer For the maximum likel
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399 Optimizer Percentage Variation
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401 Optimizer GPS-X reports the F-v
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403 Optimizer The sum of squares ra
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405 Optimizer To check for violatio
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407 Optimizer If the sample autocor
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409 Optimizer APPENDIX C: NOMENCLAT
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411 Optimizer APPENDIX D: REFERENCE
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413 Miscellaneous CHAPTER 15 Miscel
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415 Miscellaneous As compared to th
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417 Miscellaneous A typical GPS-X o
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419 Miscellaneous RESIDUAL PLOTS Fo
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421 Miscellaneous Figure 15-6 - Res
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423 Miscellaneous REAL TIME CLOCK T
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425 Miscellaneous Figure 15-9 - Ste
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427 Miscellaneous Figure 15-11 - In
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429 Miscellaneous The smoothing fun
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431 Miscellaneous The Gear's Stiff
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Appendix A - Petersen Matrices A-1
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ASM2d in CNPLIB Appendix A - Peters
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15 Lysis of XBP 16 Lysis of XPP 17
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NewGeneral in CNPLIB Appendix A - P
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NewGeneral in CNPLIB Appendix A - P
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Component i Process Rates Appendix
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2 Appendix A - Prefermenter Peterse
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D-2 Appendix D - References Brockwe
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D-4 Appendix D - References Hur, D.
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D-6 Appendix D - References Reilly,
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D-8 Appendix D - References Wuhrman
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