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GPS-X Technical Reference

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145 Suspended Growth Models<br />

33. Growth of methylotrophs on methanol using NO 2 as electron acceptor:<br />

This represents the second step of denitrification. The stoichiometry of this<br />

process is developed by considering partial reduction of NO 2-N to N 2-N.<br />

The rate expression for the process uses an inhibition term for oxygen and a<br />

saturation term for the NO 2-N. The reaction rate expression also reduces the<br />

amount of biomass mediating the reaction by the fraction of NO 2-N to total<br />

NO X nitrogen available in the system. It is assumed that when the<br />

methylotroph biomass is converting NO 2-N to N 2-N, it is not participating in<br />

the conversion of NO 3-N to NO 2-N.<br />

34. Decay of methylotrophs: Decay of methylotrophs is modelled using first<br />

order reaction rate, with respect to the biomass concentration.<br />

Processes mediated by Anaerobic Microorganisms<br />

The MANTIS2 model includes processes mediated by anaerobic microorganisms. These<br />

processes present the key transformations observed in strict anaerobic environment like<br />

anaerobic digester and other modifications of anaerobic treatment technology. These<br />

processes are adapted from the anaerobic digestion model developed at University of<br />

Cape Town (UCTADM1). The process rate and stoichiometry was converted from molar<br />

units to COD units. The process stoichiometry was also modified to include the mass<br />

balances for phosphorus, Ca, Mg, K, cation and anion species. The scheme of anaerobic<br />

biodegradation assumes that the anaerobic biomass decay takes place according to the<br />

decay processes listed above. The slowly degradable substrate is then hydrolyzed<br />

anaerobically according to process 4. The resulting soluble fermentable substrate is then<br />

converted to CH 4 and H 2 by the processes described below.<br />

35. Growth of fermentive bacteria at low H 2: This process models the<br />

fermentation by acidogens under low H 2 partial pressure. The process<br />

stoichiometry is developed based on a conversion of model fermentable<br />

substrate (glucose) to acetic acid, H 2 and CO 2. The kinetic expression for the<br />

process uses a H 2 inhibition term to reduce the reaction rate as the partial<br />

pressure of H 2 increases.<br />

36. Growth of fermentive bacteria at high H 2: This process models the<br />

fermentation by acidogens under high H 2 partial pressure. The process<br />

stoichiometry is developed based on a conversion of model fermentable<br />

substrate (glucose) to acetic acid, propionic acid, H 2 and CO 2. The kinetic<br />

expression for the process uses a H 2 saturation term to account for increased<br />

rate at higher partial pressure of H 2<br />

<strong>GPS</strong>-X <strong>Technical</strong> <strong>Reference</strong>

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