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viii<br />

Contents<br />

7. Role of Nanopores in Regulating Reactivity and<br />

Transport of Uranium in Subsurface Sediments 195<br />

Huifang Xu and Hun-Bok Jung<br />

7.1 Introduction 195<br />

7.2 Behaviors of Nanopore Surface and Nanopore<br />

Water 200<br />

7.3 Nanopore Surface on U(VI) Sorption and<br />

Desorption in Model Systems 202<br />

7.4 Reduction of U(VI) Sorbed on Nanoporous and<br />

Non-Nanoporous Alumina 204<br />

7.5 Desorption of U-Contaminated Sediments 206<br />

7.6 U(VI) Sorption and Desorption of<br />

Uncontaminated Sediments 209<br />

7.7 Conclusions 216<br />

Part II Biominerals 223<br />

8. Biomineralization of Natural Nanomaterials 225<br />

Jun Wu, Juming Yao, and Yurong Cai<br />

8.1 Introduction 225<br />

8.2 Calcium Phosphate-Based Nano-Biominerals 228<br />

8.3 Calcium Carbonate-Based Nano-Biominerals 234<br />

8.4 Fe-Based Nano-Biominerals 238<br />

8.5 Si-Based Nano-Biominerals 240<br />

8.6 Summary 241<br />

9. Magnetic Nanoparticles in Magnetosomes 249<br />

André Körnig and Damien Faivre<br />

9.1 Introduction 249<br />

9.2 Magnetotactic Bacteria 251<br />

9.3 Magnetosomes 254<br />

9.3.1 Magnetosome Membrane 255<br />

9.3.2 Structure and Composition of<br />

Magnetosome Crystals 256<br />

9.3.3 Morphology of Magnetosome Crystals 257<br />

9.3.4 Dimensions of Magnetosomes 258<br />

9.3.5 Chain Assembly of Magnetosomes 259<br />

9.4 Hierarchical Structuring of Magnetosomes 260<br />

9.5 Application of Nanocrystals and Magnetosomes 261<br />

9.6 Conclusions 262

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