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CONFIDENTIAL<br />

© 2011 Attolight AG. All Rights Reserved.<br />

CONFIDENTIAL<br />

1


attolight<br />

<br />

CONFIDENTIAL<br />

Attolight AG<br />

EPFL Innovation Square<br />

PSE D<br />

1015 Lausanne<br />

Switzerland<br />

t +41 21 626 0100<br />

March 21, 2013<br />

The Attolight CL System<br />

www.attolight.com<br />

Jean Berney<br />

Attolight AG Switzerland / www.attolight.com<br />

© 2013 Attolight AG. All Rights Reserved.<br />

2


Who are we<br />

CONFIDENTIAL<br />

Swiss<br />

Company<br />

Spin-Off of EPFL<br />

Swiss Federal Institute of Technology<br />

Located in PSE on EPFL campus<br />

over 100 companies<br />

© 2013 Attolight AG. All Rights Reserved.<br />

3


Introduction<br />

CONFIDENTIAL<br />

Cathodoluminescence refers to the light<br />

emitted by a sample under electron<br />

irradiation.<br />

An e-beam generates several signals<br />

• Back Scattered Electrons (BSE)<br />

BSE<br />

primary e - beam<br />

SE<br />

• X Rays<br />

• Secondary Electrons (SE)<br />

• Cathodoluminescence (CL)<br />

• Auger electrons<br />

• ....<br />

X rays<br />

CL<br />

© 2013 Attolight AG. All Rights Reserved.<br />

4


Introduction<br />

CONFIDENTIAL<br />

Text<br />

• Level 1<br />

Cathodoluminescence (CL) is a Spectroscopy method<br />

featuring nanometer spatial resolution<br />

study • Level of nanometer 2 sized structures<br />

100 nm<br />

study of crystallographic<br />

defects<br />

5 µm<br />

TiO2 nanoparticles for solar cells<br />

TDs on GaN surface<br />

© 2013 Attolight AG. All Rights Reserved.<br />

5


Traditional CL approach<br />

CONFIDENTIAL<br />

Cathodoluminescence in a SEM<br />

• Acquire an SEM<br />

• Buy a CL add-on (light collection mirror<br />

and detection system) and combine<br />

Major drawbacks<br />

• At least two manufacturers involved<br />

• Interfacing difficulties, especially at low<br />

temperature<br />

• Cumbersome alignment, unstable<br />

+<br />

© 2013 Attolight AG. All Rights Reserved.<br />

6


Attolight CL System<br />

Integrated Cathodoluminescence<br />

CONFIDENTIAL<br />

• One System - One Supplier<br />

• Hybrid Microscope<br />

• Optimized for CL<br />

• Low beam energy<br />

• High flexibility<br />

• Easy to use<br />

© 2013 Attolight AG. All Rights Reserved.<br />

7


© 2012 Attolight AG. All Rights Reserved.<br />

• NO clean room environment<br />

• Fast installation in less than 24<br />

hours<br />

• Remote control interface


Attolight CL System<br />

Embedded Optical Microscope<br />

CONFIDENTIAL<br />

• Zero Alignment<br />

High Stability<br />

• Achromatic<br />

UV - IR without realignment<br />

• High Aperture (NA 0.71)<br />

Highest Collection Efficiency<br />

• Evolutive Optical System<br />

Optical Hub to easily interface<br />

PL, µPL, Raman, ...<br />

• Large Field of View<br />

Quantitative Measurements &<br />

Optical Imaging<br />

Attolight CL<br />

FOV 300µm<br />

OM 300µm<br />

FOV<br />

Standard CL<br />

Focal Spot<br />

© 2013 Attolight AG. All Rights Reserved.<br />

9


Attolight CL System<br />

Cryogenic Nanopositioning Stage<br />

CONFIDENTIAL<br />

• Helium Cryostat<br />

Allows for temperature<br />

dependent studies 15K - 300K<br />

• SEM optimized Designed<br />

Low vibration and low drift<br />

• 6-degrees-of-freedom<br />

positioning stage<br />

All possible degrees of freedom<br />

& Pivot Point Lock<br />

© 2013 Attolight AG. All Rights Reserved.<br />

10


Attolight CL System<br />

Time-Resolved Cathodoluminescence<br />

CONFIDENTIAL<br />

SE<br />

• Optimized for pulsed operation<br />

No degradation of spatial<br />

resolution in pulsed mode<br />

• Field upgradable<br />

Upgrade from standard system<br />

can be done in the user<br />

laboratory<br />

• New dimension to your data<br />

Measure local lifetime and<br />

charge carrier dynamics<br />

intensity (a.u.)<br />

100<br />

10<br />

0 400 800 1200<br />

time (ps)<br />

© 2013 Attolight AG. All Rights Reserved.<br />

11


Attolight CL System<br />

Intuitive control interface<br />

CONFIDENTIAL<br />

• Computer controlled switching<br />

between measurement modes<br />

• UV - IR without re-alignment<br />

• Remote control and<br />

surveillance<br />

• Open data format to read on<br />

any platform<br />

• Fast user training, ideal for<br />

multi-user facility<br />

• Easy to use touch screen based<br />

control console<br />

© 2013 Attolight AG. All Rights Reserved.<br />

12


Applications<br />

Gallium Arsenide single photon emitters<br />

CONFIDENTIAL<br />

AlGaAs Quantum Dots in<br />

Core-Shell Nanowires<br />

• GaAs QDs embedded in<br />

AlGaAs shell<br />

• Emission Range 620 nm<br />

- 750 nm<br />

(1 -1 2)<br />

(-2 -1 1)<br />

(1 2 1)<br />

GaAs AlGaAs (Al rich) AlGaAs (Al poor) (Al)GaAs QD<br />

«Self-assembled quantum dots in a nanowire system for quantum photonics», Heiss, Fontcuberta, Fontana et al.,<br />

Nature Mater. 2013<br />

© 2013 Attolight AG. All Rights Reserved.<br />

13


Applications<br />

Gallium Arsenide single photon emitters<br />

CONFIDENTIAL<br />

2500<br />

GaAs<br />

blue: QDs<br />

red: GaAs core<br />

2000<br />

CL Intensity (counts)<br />

1500<br />

1000<br />

QDs<br />

500 nm<br />

500<br />

Conditions<br />

0<br />

600<br />

700<br />

800<br />

Wavelength (nm)<br />

900<br />

• T = 10K, controlled<br />

• 5 keV<br />

• 1 ms / spectrum<br />

1 µm<br />

• 128 x 128 spectra<br />

• measurement time < 2 min<br />

© 2013 Attolight AG. All Rights Reserved.<br />

14


Applications<br />

Sulfur diffusion in CdTe Solar Cell Junction<br />

CONFIDENTIAL<br />

CdTe<br />

Cd(Te,S)<br />

CdS<br />

Clear interdiffusion of sulfur a the solar cell junction<br />

Dr. Aidan Taylor, Researcher of thin film materials, Durham University<br />

© 2013 Attolight AG. All Rights Reserved.<br />

15


Applications<br />

Carrier diffusion length in Diamond<br />

CONFIDENTIAL<br />

• CL line mapping on FIB lamella<br />

• Exciton diffusion in Boron<br />

doped diamond<br />

• Measurement of diffusion<br />

length in function of dopant<br />

concentration<br />

José Pinero, Specialist on high power device application of diamond, University of Cadiz, paper submitted for publication.<br />

© 2013 Attolight AG. All Rights Reserved.<br />

16


Applications<br />

Strain analysis in Zinc Oxide<br />

CONFIDENTIAL<br />

SE<br />

spectral shifts of exciton peak depending on local strain<br />

386 nm<br />

CL<br />

384 nm<br />

100µm<br />

382 nm<br />

380 nm<br />

378 nm<br />

Xuewen Fu, Specialist on electronic and mechanical coupling an applications of ZnO nanowires, Beijing University<br />

© 2013 Attolight AG. All Rights Reserved.<br />

17


Applications / Production<br />

Validation of new product generation<br />

CONFIDENTIAL<br />

GaN based alloys for power<br />

electronics<br />

• Verification of growth<br />

homogeneity<br />

• Each AlGaN layer emits at a<br />

different wavelength<br />

CL<br />

SE<br />

5 µm<br />

Rapid qualification of new<br />

designs and fabrication<br />

processes<br />

© 2013 Attolight AG. All Rights Reserved.<br />

18


Applications / Production<br />

Qualification of LED substrates<br />

CONFIDENTIAL<br />

• TDs show as dark spot due to<br />

non-radiative recombination in<br />

their vicinity<br />

• Easy measure of TDD<br />

• TDD ≃ 30 ⨉ 10 6 cm -2<br />

10µm<br />

10µm<br />

SE<br />

LED failure analysis<br />

CL<br />

© 2013 Attolight AG. All Rights Reserved.<br />

19


Applications<br />

Failure analysis on Silicon<br />

X 2.4K<br />

SE<br />

CONFIDENTIAL<br />

Detection of defects at 1.6 µm in<br />

Silicon<br />

4<br />

3<br />

Exciton peak<br />

6<br />

Defect<br />

20 µm<br />

2<br />

5<br />

1000<br />

8<br />

7<br />

6<br />

Intensity (a.u.)<br />

100<br />

5<br />

4<br />

3<br />

2<br />

8<br />

7<br />

6<br />

5<br />

Intensity (a.u.)<br />

3x10 2 4<br />

4<br />

3<br />

1000<br />

1050<br />

1100<br />

1150<br />

Wavelength (nm)<br />

1200<br />

1500<br />

1550<br />

1600<br />

Wavelength (nm)<br />

1650<br />

1700<br />

© 2013 Attolight AG. All Rights Reserved.<br />

20


Applications<br />

Local Lifetime Measurements - ZnO<br />

CONFIDENTIAL<br />

Nanobelts<br />

Text<br />

• Level 1<br />

• Level 2<br />

XX<br />

D o X<br />

X<br />

Intensity (arb. units)<br />

• Week emission from the green band at<br />

300K<br />

• well resolved excitionic transmission<br />

=> excellent material for optoelectronics <br />

3.28 3.30 3.32 3.34 3.36 3.38 3.40 3.42 3.44 3.46<br />

© 2013 Attolight AG. All Rights Reserved.


Applications<br />

CONFIDENTIAL<br />

Local Lifetime Measurements - ZnO Nanobelts<br />

CL energy shift (10 meV)<br />

CL intensity fluctuation<br />

© 2013 Attolight AG. All Rights Reserved.


Applications<br />

CONFIDENTIAL<br />

Local Lifetime Measurements - ZnO Nanobelts<br />

Exciton CL decay<br />

constant t rad<br />

I X<br />

(t)∝ 1 )<br />

Exp+<br />

−t<br />

τ r * +<br />

# 1<br />

% + 1<br />

$ τ r<br />

τ nr<br />

I X<br />

(0)∝ 1 η = τ nr<br />

τ r τ r<br />

+τ nr<br />

Local variation of exciton non-radiative<br />

lifetime along the nanobelt axis<br />

&<br />

(<br />

'<br />

−1<br />

,<br />

.<br />

-.<br />

non-radiative lifetime<br />

100%<br />

87%<br />

77%<br />

60%<br />

53%<br />

40%<br />

Excitation spot<br />

© 2013 Attolight AG. All Rights Reserved.


energy (nm)<br />

Applications<br />

Wide bandgap material<br />

CONFIDENTIAL<br />

Other Spectroscopy Tools<br />

Attolight CL<br />

• expensive (far UV)<br />

• low spatial resolution<br />

• difficult to use<br />

• not versatile<br />

260<br />

230<br />

Boron Nitride<br />

200<br />

0 200 400<br />

time (ps)<br />

© 2013 Attolight AG. All Rights Reserved.<br />

24


attolight<br />

Attolight AG<br />

EPFL Innovation Square<br />

PSE D<br />

1015<br />

Description<br />

Lausanne<br />

Switzerland<br />

t<br />

The<br />

+41<br />

core<br />

21 626<br />

piece<br />

0100<br />

of Attolight's instrument is a<br />

custom designed scanning electron microscope<br />

www.attolight.com<br />

(SEM). SEM is a widely used scanning probe<br />

technology since it has the ability to image the<br />

surface features of a sample with very high<br />

spatial resolutions going below one nanometer<br />

(10 -9 m) today. An SEM consists of an electron<br />

source and electron optics that focuses the<br />

electron beam to a nanometer sized spot. The<br />

image (or map) is constructed by scanning the<br />

electron beam over the sample point by point<br />

(see Fig. 1). The impinging electron beam on<br />

the sample surface creates secondary electrons<br />

and photons that are emitted. At each scanned<br />

point on the sample, the intensity of the secondary<br />

electron (SE) signal is recorded and a<br />

pixel is shown on the screen with a grey scale<br />

level proportional to the SE signal intensity.<br />

incoming<br />

electron beam<br />

TECHNOLOGY BRIEF<br />

Attolight uses a proprietary technology to create<br />

ultrashort electron pulses instead of a continuous<br />

electron beam (see Fig. 2). The SEM<br />

and electron source have to be custom designed<br />

to reach high spatial resolutions and<br />

short pulses. Our new tool will deliver a few<br />

nanometers spatial resolution and pulses<br />

shorter than 10 picoseconds (1 picosecond =<br />

10 -12 s) at a repetition rate of typical 80 MHz<br />

(repetition rate can be changed easily). The<br />

photoelectric effect is used to create such short<br />

electron pulses: short UV laser pulses are sent<br />

on a thin metal film which creates short electron<br />

pulses. The design and manufacturing of<br />

the electron source is a core competence of<br />

Attolight. A lot of care has to be taken in designing<br />

the electron source and the electron<br />

optics in order to keep the pulses short and<br />

well focused and still intense enough to carry<br />

out measurements.<br />

electrons<br />

incoming<br />

electron beam<br />

Sample<br />

light<br />

Fig. 2 Attolight technology<br />

electrons<br />

Sample<br />

light<br />

Fig. 1 Principle of standard SEM<br />

Time resolved spectroscopy<br />

This is our “home” application in the R&D market.<br />

Initially, the tool was built for this application.<br />

We exploit a phenomena called cathodoluminescence<br />

(CL): some semiconductors emit<br />

light when they are bombarded with an electron<br />

beam containing electrons carrying a certain<br />

energy. This light is called CL and contains<br />

a lot of information on optical properties of the<br />

material under test. CL is often used to analyse<br />

semiconductor based nanostructures since the<br />

spatial resolution is very high. CL is a excitation<br />

spectroscopy technique with very high spatial<br />

resolution.<br />

Our idea was not just to look at a continuous<br />

CL signal but also at the lifetime of the signal<br />

in the picosecond regime. To achieve this we<br />

adapted an ultrafast light detector (STREAK<br />

camera) to our instrument. We call this tool<br />

pTRCL (picosecond time-resolved CL).<br />

© 2011 Attolight AG - All rights reserved.


attolight<br />

Attolight AG<br />

EPFL Innovation Square<br />

PSE D<br />

1015<br />

TRCL is<br />

Lausanne<br />

a High-Resolution Technique<br />

Switzerland<br />

t<br />

Given<br />

+41 21<br />

the<br />

626<br />

context<br />

0100<br />

of developing nanosciences,<br />

there is currently a growing interest in obtaining<br />

local information about light-emitting<br />

www.attolight.com<br />

phenomena in condensed matter. In particular,<br />

dynamical information such as the luminescence<br />

decay time is of major importance to<br />

analyse the competition between radiative and<br />

nonradiative processes in materials and nanostructures<br />

designed to serve in optoelectronic<br />

devices.<br />

However, while it is easy to measure the photoluminescence<br />

decay dynamics with a spatial<br />

resolution of a few hundreds of squared micrometers,<br />

achieving such measurements at<br />

the scale of a few tens of nanometers is still<br />

challenging.<br />

Therefore, in most instances, TR-PL experiments<br />

only provide information that is integrated<br />

over a number of light-emitting nanoobjects<br />

and over a number of competitive<br />

processes: radiative processes themselves, carrier<br />

transfer among different radiative or nonradiative<br />

centers, nonradiative carrier recombination…<br />

In the case of individual nano-objects or of<br />

materials comprising a variety of light-emitting<br />

sub-structures, such integrated information is<br />

not detailed enough and leads to conjectural<br />

analyses of the recorded data.<br />

On the other hand, thanks to a strongly localized<br />

excitation, TRCL permits to isolate (spatially<br />

and spectrally) the different light sources<br />

and to analyse their dynamical characteristics<br />

separately.<br />

Interest of Temperature-dependent TRCL<br />

Like for other spectroscopic techniques the<br />

possibility to use cryogenic temperatures has<br />

several beneficial effects.<br />

First of all, by hindering thermally-enhanced<br />

nonradiative recombinations, low temperatures<br />

increase drastically the signal-to-noise ratio.<br />

For the same reason, the CL decay dynamics<br />

measured at low-temperatures are closer (if<br />

TECHNICAL NOTE<br />

not exactly identical) to the purely radiative<br />

dynamics.<br />

Indeed, the effective decay time, τCL, is related<br />

to the radiative (τR) and nonradiative (τNR)<br />

lifetimes by: τCL =(τR-1 + τNR-1)-1. In other<br />

words, when the sample is placed at low temperatures,<br />

the nonradiative lifetime becomes<br />

so long that the effective lifetime is close to the<br />

radiative lifetime. The latter is a precious piece<br />

of information, especially in the study of lowdimensional<br />

semiconductor systems such as<br />

quantum wells or quantum dots.<br />

The second favourable effect of low temperatures<br />

is the reduction of emission linewidths.<br />

Whenever several optical transitions, corresponding<br />

to various recombination mechanisms,<br />

are close in energy, this linewidth reduction<br />

permits to separate these mechanisms.<br />

In CL, this point is quite often very profitable<br />

because the different mechanisms can correspond<br />

to different localizations in space. In<br />

TRCL, the temporal behaviours pertaining to<br />

these different mechanisms can be studied<br />

separately.<br />

The third advantage of low temperatures is<br />

that it reduces the diffusion of carriers across<br />

the sample and generally favours optical recombination<br />

of localised excitons. Consequently,<br />

the CL images obtained are sharper:<br />

the resolution, specially in monochromatic detection<br />

mode, is enhanced.<br />

There is also clearly an interest for experiments<br />

conducted under variable temperature conditions.<br />

This is particularly true when dealing<br />

with carrier diffusion/capture processes that<br />

can be studied by analysing the CL rise-times.<br />

Their behaviour when T is changed, along with<br />

the appropriate modelling, provides crucial<br />

information on diffusion coefficients, energy<br />

transfer mechanisms, activation energies…<br />

TRCL is an Excitation Spectroscopy Technique<br />

Contrary to the intuitive approach, cathodoluminescence,<br />

when seen as a mapping method,<br />

does not show, strictly speaking, where the<br />

emitted light comes from. In fact, it rather correlates,<br />

with very high resolution, the 2D coor-<br />

© 2011 Attolight AG - All rights reserved.


attolight<br />

dinates of the excitation spot with the emission<br />

of light AG by the sample, wherever this<br />

Attolight<br />

EPFL emission Innovation really takes Square place.<br />

PSE In other D words, in CL, the high resolution is a<br />

1015 unique Lausanne characteristic of the excitation, not of<br />

Switzerland<br />

the emission.<br />

t +41 21 626 0100<br />

In many cases, especially in low-quality samples,<br />

where the carrier diffusion lengths are<br />

www.attolight.com<br />

small, the<br />

above remark is of little relevance: the CL emission<br />

indeed takes place where the electronic<br />

excitation has been<br />

delivered, at least within the accuracy limited<br />

by the size of the generation volume and by<br />

the carrier diffusion lengths. Typically, a resolution<br />

of a few hundred nanometers is reached.<br />

But in high-quality samples, the situation can<br />

be totally different. For example, for the complex<br />

pyramidal quantum systems of Ref. [1],<br />

wherever the excitation spot is placed on the<br />

pyramid, the quantum dot at the tip of the<br />

pyramid is efficiently alimented by scattered<br />

carriers and it efficiently emits light at a characteristic<br />

wavelength. Therefore the CL image<br />

shows an entirely “white” pyramid although it<br />

is quite clear that light does not come from the<br />

entire pyramid, but rather from a zone that<br />

does not exceed a few nanometers at the tip of<br />

the pyramid.<br />

In this case of high-quality samples, the high<br />

diffusion length paradoxically destroys the spatial<br />

resolution of the CL experiment.<br />

Luckily, “time is on our side”: the temporal<br />

resolution provided by TRCL allows measuring<br />

the rising dynamics of luminescence signals at<br />

a given wavelength, as a function of the position<br />

of the excitation spot. It therefore provides<br />

an unprecedented insight into dynamical phenomena<br />

such as carrier diffusion and capture.<br />

In the above example, the rise-time of the CL<br />

from the tip-quantum dot is a growing function<br />

of the distance between the excitation<br />

spot and the tip and a simple model yields important<br />

characteristics such as diffusion<br />

lengths.<br />

In summary, for the study of high-quality<br />

samples where the carrier diffusion lengths are<br />

large, the time-resolution is a necessary ingredient.<br />

By careful analysis of luminescence rise-times<br />

under variable conditions of temperature and<br />

of distance from the emitting object, TRCL<br />

permits to characterize the ambipolar transport<br />

of electron-hole pairs (or excitons), which the<br />

other techniques (µPL – SNOM) cannot achieve.<br />

[1] M. Merano et al., Nature 438, 479 (2005)<br />

About the author<br />

Pierre Lefebvre<br />

Research Director at CNRS<br />

Pierre Lefebvre is a senior researcher<br />

in Physics specialized<br />

in optical properties of semiconductors,<br />

nanosciences and<br />

nanotechnology. He was the founder and first<br />

director of the Center of Competence in Nanosciences<br />

for the South-West of France. Interested<br />

in testing and promoting new concepts<br />

based on nanophysics for novel applications in<br />

optics, information technologies, solar energy.<br />

© 2011 Attolight AG - All rights reserved.


Be Part of the New<br />

Cathodoluminescence<br />

Revolution<br />

Attolight CL / Discover Quantitative Cathodoluminescence<br />

at High Space and Time Resolution<br />

Overview<br />

The Attolight CL system is the first quantitative cathodoluminescence system offering a spatial<br />

resolution below 10 nm, a field of view of 300 µm, and an optional 10 ps time resolution mode.<br />

Attolight CL combines a proprietary scanning electron microscope (SEM) with an integrated<br />

light microscope. The light microscope is embedded within the electron objective lens of the<br />

SEM so that their field of view match each other. Acquiring cathodoluminescence (CL) maps<br />

has never been easier : no optical alignment is required and the specimen is positioned thanks<br />

to the light microscope. The system is optimized to achieve superior CL performance without<br />

compromising the SEM performance. It offers an outstanding optical aperture (f/0.5), a constant<br />

and superior photon collection efficiency over the whole field of view, and a low electron beam<br />

energy range (3–10 kV) for enhanced resolution of CL maps.<br />

Attolight CL is the only system on the market that enables quantitative benchmarking of<br />

cathodoluminescence emission from one specimen to the other. Its unique ability to reveal<br />

ultra-trace impurities and crystallographic defects not visible using other imaging modes<br />

opens new possibilities for research and development of semiconductor materials, phosphor,<br />

ceramic, rock and glass.<br />

A 6-degrees-of-freedom displacement system insures arbitrary positioning of your specimen<br />

with 1 nm increments. For advanced applications requiring a deep understanding of the<br />

fundamental properties of a material or high cathodoluminescence emission efficiency,<br />

an optional cryogenic nanopositioning stage can be installed. It features temperature control<br />

between 20 K and 300 K and includes a patented mechanical design to minimize drifts<br />

and vibrations.<br />

Attolight CL is also the first cathodoluminescence microscope featuring an optional timeresolved<br />

detector with an unmatched 10 picoseconds time resolution. Time-resolved<br />

cathodoluminescence is the perfect technology for charge carrier dynamics and lifetime<br />

measurements in opto-electronic materials.<br />

Key Benefits<br />

– Zero alignment : patented achromatic light microscope<br />

embedded in the column of a proprietary scanning<br />

electron microscope<br />

– No compromise : up to 10 nm spatial resolution in both<br />

continuous and time-resolved mode from 3 kV to 10 kV<br />

– Specimen benchmarking : very large field of view (300 µm)<br />

enabling quantitative cathodoluminescence<br />

– High light collection efficiency : numerical aperture of<br />

0,71 (f/0,5)<br />

– Arbitrary movements : innovative 6-degrees-of-freedom<br />

nano-positioning stage (down to 1 nm displacement<br />

increments)<br />

– Optional innovative low vibration cryostat for temperature<br />

measurements between 20K and 300K<br />

– Optical hub for integration of the Attolight CL instrument<br />

in a larger spectroscopic system<br />

– Optional Time-Resolved Cathodoluminescence (TRCL)<br />

mode : optimized for pulse operations up to 10 ps without<br />

any degradation of the spatial resolution. Enables lifetime<br />

and charge carrier dynamics measurements


Applications<br />

– LED performance and reliability<br />

– GaN power transistors<br />

– Threading Dislocation Density (TDD)<br />

– Carriers lifetimes and dynamics<br />

– Solar cells efficiency<br />

– Development of nanoscale optolectronic devices<br />

ZnO nano-belts. The acquisition of a CL map (left) does not affect the detection<br />

of secondary electrons (right)<br />

Cathodoluminescence is the ideal tool to measure threading dislocations density<br />

in GaN (left) ; they appear as dark spots because of non radiative recombination<br />

in their vicinity. A secondary electron scan of the same region cannot identify any<br />

threading dislocations (right).<br />

Product Specifications<br />

Measurements Mode<br />

– Optical microscope imaging<br />

– Cathodoluminescence mapping (polychromatic,<br />

monochromatic and hyperspectral)<br />

– Secondary electrons (SE) mapping<br />

– Time-resolved cathodoluminescence (time-resolved option)<br />

– Simultaneous SE and CL imaging<br />

Electron Optics<br />

– Schottky field emission gun (continuous system) or<br />

picosecond pulsed photoelectron gun (time-resolved<br />

option). Acceleration voltage : 3–10 kV<br />

– Electron optical column with electro-magnetic lenses,<br />

magnetic deflectors and astigmatism correctors. Optimized<br />

for continuous and pulsed operation.<br />

– Highest spatial resolution : < 10 nm from 3 to 10 kV<br />

– Analytical working distance : 3 mm<br />

– No loss of SE resolution in cathodoluminescence mode<br />

– Field-upgradable to picosecond pulsed photoelectron gun<br />

Probe Current<br />

– E-beam : 1pA to 20 nA<br />

Light Optics<br />

– Light microscope embedded within the electron optics<br />

– Fully achromatic reflective objective : 180 nm – 1.6 µm<br />

– Aperture : NA 0.71 (f/0.5)<br />

– Field of View : >300 µm (electronic and optical)<br />

– Optical Resolution :


Be Part of the New<br />

Cathodoluminescence<br />

Revolution<br />

Nanopositioning Stage<br />

– Specimen diameter : ø 25x1.5 mm<br />

– 6 degrees of freedom for arbitrary movements (compatible<br />

with cryostat option)<br />

– Travel range : 25 mm (X and Y), 3 mm (Z), 3° tilt (X and Y),<br />

35° rotation (Z)<br />

– Smallest increment : 1nm<br />

– Repeatability (full travel range) : 100nm<br />

– Repeatability (100 nm range) : < 2nm<br />

Low Temperature Cryostat<br />

– Helium cold finger for low vibrations<br />

– Minimal temperature range : 20K–300K<br />

– Advanced digital temperature controller<br />

Facility Specifications<br />

– Power : 7 standard wall plugs (230V, 50Hz) delivering<br />

10A each<br />

– Pressurized air for microscope valves and optical table,<br />

pressure of 551 kPa (80psi) max.<br />

– Nitrogen to purge the chamber<br />

– Weight :<br />

CL system : 250 kg<br />

Optical Table : 650kg<br />

– Environment: temperature 20°C +/-3°C, relative humidity<br />

below 70 % RH, stray AV magnetic fields<br />

< 100 nT asynchronous<br />

< 300 nT synchronous for line times > 20 ms<br />

(50 Hz mains)<br />

260<br />

Lay-out<br />

The Attolight CL is mounted on an optical table with four<br />

active isolation legs. Its footprint is 1.2 m x 1.5 m. Allow for<br />

1 to 1.5m space around the table to circulate and install an<br />

operator.<br />

230<br />

wavelength (nm)<br />

200<br />

1514<br />

0<br />

200 400<br />

3200<br />

1209<br />

time (ps)<br />

1500<br />

Time and spectrum-resolved cathodoluminescence of Boron Nitride. The<br />

spectrum is generated by focusing a pulsed electron beam on a specific point of<br />

the specimen. A streak camera is used for the detection. Deep UV spectroscopy<br />

becomes as simple as visible spectroscopy.<br />

1000<br />

4000<br />

Attolight AG © 2012. We are constantly improving the performance of our products, so all specifications are subject to change without notice.


Be Part of the New<br />

Cathodoluminescence<br />

Revolution<br />

Attolight CL / Analytical Services : Get an immediate and easy<br />

access to critical data to boost your material research programs<br />

Attolight has developed breakthrough technology in cathodoluminescence which will open<br />

a new area of investigation in semiconductor material research. Attolight now offers immediate<br />

access to data that will significantly impact your processes, your technological research and<br />

development roadmap.<br />

Q. Why does Attolight, an equipment manufacturer, provide analytical and consulting services <br />

A. Typically in response to one of two situations :<br />

a → Our client needs to push forward their research or process development but<br />

has no budget to add capital equipment :<br />

– Your current characterization methods do not allow you to achieve a full understanding<br />

of your material system or structure, perhaps cathodoluminescence will<br />

fill in the gaps and allow you to reach clear conclusions.<br />

– You have come up against a specific process (or quality) issue and would like to see<br />

if cathodoluminescence could provide the information needed to solve the issue.<br />

– You already use photoluminescence technique but have found you need a higher<br />

spatial resolution or sensitivity to acquire the data you really need.<br />

b → Our client is making (or has made) a case for capital funding confident that<br />

high reso lution CL is a game changing technology for their research and process<br />

development.<br />

– You are confident, but your funding authorities still demand proof in the form<br />

of preliminary results showing the type of data that can not be obtained by other<br />

methods available to you.<br />

– You have a material/device with unique properties, you believe high resolution<br />

CL will provide the key data with which you can explain those properties in order<br />

to win funding for further development of your new material/device.<br />

– You have applied for funding but it will take many months to arrive, you need<br />

to push the research forward to maintain your lead until the Attolight system<br />

is delivered.<br />

Our laboratory in Switzerland provides analytical testing services and solutions, using the latest<br />

cathodoluminescence technology developed by Attolight. Our solutions enables the characterization<br />

of a variety of nano scale structures including : nanoparticles, nanotubes, quantum<br />

dots, defects, dopant inclusions, silicon wafer and ingot quality control for PV applications, GaN<br />

wafer quality control for LED and power devices. Attolight has also developed a proprietary<br />

solution to count the threading dislocation densities on wafers, offering a significant cost ownership<br />

benefit over the traditional TEM method.<br />

For more application on our analytical<br />

service capabilities please contact us :<br />

t + 41 21 626 0100


Headquarter – Attolight AG<br />

EPFL Innovation Square / PSE D<br />

1015 Lausanne / Switzerland<br />

t +41 21 626 0100<br />

contact@attolight.com<br />

www.attolight.com

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