CIGS Thin Film Solar Cell Technology Trend and ... - Displaybank

CIGS Thin Film Solar Cell
Technology Trend and
Market Forecast
(2006~2013)
August. 2009

CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
CIGS Thin Film Solar Cell
Technology Trend and
Market Forecast
(2006~2013)
August 2009
Displaybank Co., Ltd.
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
Index
1. Introduction of Solar Cell ............................................................................................................... 8
1.1. Vision of PV........................................................................................................................................................................... 8
1.2. Technical Introduction of Solar Cell by Type ......................... 오류! 책갈피가 정의되어 있지 않습니다.
1.2.1. Crystalline Si Solar Cell ....................................................... 오류! 책갈피가 정의되어 있지 않습니다.
1.2.2. Thin Film a-Si Solar Cell ..................................................... 오류! 책갈피가 정의되어 있지 않습니다.
1.2.3. CIGS Thin Film Solar Cell ................................................... 오류! 책갈피가 정의되어 있지 않습니다.
1.2.4. CdTe Thin Film Solar Cell ................................................... 오류! 책갈피가 정의되어 있지 않습니다.
1.2.5. Dye Sensitized Solar Cell ................................................... 오류! 책갈피가 정의되어 있지 않습니다.
1.3. Comparison of Efficiency Characteristics of Each Thin Film Solar Cell오류! 책갈피가 정의되어 있
지 않습니다.
1.4. Efficiency Development Trend of Each Thin Film Solar Cell오류! 책갈피가 정의되어 있지 않습니
다.
2. CIGS Solar Cell Technology ............................................................................................................ 10
2.1. Structure of CIGS Solar Cell and Operation Mechanism ................................................................................. 10
2.2. Manufacturing Process of CIGS Solar Cell ............................................................................................................. 11
2.2.1. Crystalline Si Solar Cell and Comparison of Manufacturing Process ............................................. 11
2.2.2. Cell Manufacturing Process .............................................. 오류! 책갈피가 정의되어 있지 않습니다.
2.2.2.1. Mo Cathode Electrode Formation ..................... 오류! 책갈피가 정의되어 있지 않습니다.
2.2.2.2. P1 Laser Patterning .................................................. 오류! 책갈피가 정의되어 있지 않습니다.
2.2.2.3. Absorber Layer(CIGS) by Co-evaporation ....... 오류! 책갈피가 정의되어 있지 않습니다.
2.2.2.4. Absorber Layer(CIGS) by Sputtering & Selenization오류! 책갈피가 정의되어 있지 않
습니다.
2.2.2.5. Buffer Layer(CdS) by Chemical bath deposition오류! 책갈피가 정의되어 있지 않습니
다.
2.2.2.6. P2/P3 Mechanical Patterning ............................... 오류! 책갈피가 정의되어 있지 않습니다.
2.2.2.7. Window(ZnO/TCO) Sputtering ............................ 오류! 책갈피가 정의되어 있지 않습니다.
2.3. Roll to Roll Technology ................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
2.4. Classification by CIGS Film Forming Method ........................ 오류! 책갈피가 정의되어 있지 않습니다.
2.5. Technical Comparison of CIGS Solar Cell Makers ................ 오류! 책갈피가 정의되어 있지 않습니다.
2.6. Technical Issue and High Efficiency Technology of CIGS Solar Cell오류! 책갈피가 정의되어 있지
않습니다.
2.7. Result of CIGS Field Test ............................................................... 오류! 책갈피가 정의되어 있지 않습니다.
2.8. Applied Areas of CIGS Solar Cell .............................................. 오류! 책갈피가 정의되어 있지 않습니다.
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
3. Worldwide Makers’ Technology and Commercialization Trend ............................................. 12
3.1. Japan ...................................................................................................................................................................................... 12
3.1.1. Showa Shell Sekiyu .............................................................................................................................................. 12
3.1.1.1. Structure of Solar Cell and Process Technology ......................................................................... 12
3.1.1.2. Product Features and Movement of the Company오류! 책갈피가 정의되어 있지 않
습니다.
3.1.2. Honda Soltec .......................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
3.1.2.1. Structure of Solar Cell and Process Technology오류! 책갈피가 정의되어 있지 않습니
다.
3.1.2.2. Product Features and Movement of the Company오류! 책갈피가 정의되어 있지 않
습니다.
3.1.3. National Institute of Advanced Industrial Science and Technology (AIST) in Japan오류! 책갈
피가 정의되어 있지 않습니다.
3.1.3.1. Structure of Solar Cell and Process Technology오류! 책갈피가 정의되어 있지 않습니
다.
3.2. Germany ................................................................................................ 오류! 책갈피가 정의되어 있지 않습니다.
3.2.1. Wurth Solar ............................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
3.2.1.1. Structure of Solar Cell and Process Technology오류! 책갈피가 정의되어 있지 않습니
다.
3.2.1.2. Product Features and Movement of the Company오류! 책갈피가 정의되어 있지 않
습니다.
3.2.2. Solibro ........................................................................................ 오류! 책갈피가 정의되어 있지 않습니다.
3.2.2.1. Structure of Solar Cell and Process Technology오류! 책갈피가 정의되어 있지 않습니
다.
3.2.2.2. Product Features and Movement of the Company오류! 책갈피가 정의되어 있지 않
습니다.
3.2.3. AVANCIS .................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
3.2.3.1. Structure of Solar Cell and Process Technology오류! 책갈피가 정의되어 있지 않습니
다.
3.2.3.2. Product Features and Movement of the Company오류! 책갈피가 정의되어 있지 않
습니다.
3.2.4. Sulfucell ..................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
3.2.4.1. Structure of Solar Cell and Process Technology오류! 책갈피가 정의되어 있지 않습니
다.
3.2.4.2. Product Features and Movement of the Company오류! 책갈피가 정의되어 있지 않
습니다.
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
3.2.5. Odersun ..................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
3.2.5.1. Structure of Solar Cell and Process Technology오류! 책갈피가 정의되어 있지 않습니
다.
3.2.5.2. Product Features and Movement of the Company오류! 책갈피가 정의되어 있지 않
습니다.
3.3. USA .......................................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
3.3.1. Global Solar ............................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
3.3.1.1. Structure of Solar Cell and Process Technology오류! 책갈피가 정의되어 있지 않습니
다.
3.3.1.2. Product Features and Movement of the Company오류! 책갈피가 정의되어 있지 않
습니다.
3.3.2. Nano Solar ............................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
3.3.2.1. Structure of Solar Cell and Process Technology오류! 책갈피가 정의되어 있지 않습니
다.
3.3.2.2. Product Features and Movement of the Company오류! 책갈피가 정의되어 있지 않
습니다.
3.3.3. IBM .............................................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
3.3.4. MIASOLE ................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
3.3.5. Solyndra .................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
3.3.6. ASCENT Solar .......................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
3.3.6.1. Structure of Solar Cell and Process Technology오류! 책갈피가 정의되어 있지 않습니
다.
3.3.6.2. Product Features and Movement of the Company오류! 책갈피가 정의되어 있지 않
습니다.
3.3.7. Solopower ................................................................................ 오류! 책갈피가 정의되어 있지 않습니다.
3.3.7.1. Structure of Solar Cell and Process Technology오류! 책갈피가 정의되어 있지 않습니
다.
3.3.7.2. Product Features and Movement of the Company오류! 책갈피가 정의되어 있지 않
습니다.
3.4. Korea ....................................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
3.4.1. Teliosolar ................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
3.4.2. LG Micron ................................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
3.4.3. Daiyang Metal ........................................................................ 오류! 책갈피가 정의되어 있지 않습니다.
3.4.4. Samsung Electronics ............................................................ 오류! 책갈피가 정의되어 있지 않습니다.
3.5. Taiwan ..................................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
3.5.1. Nanowin .................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
3.6. Swiss ........................................................................................................ 오류! 책갈피가 정의되어 있지 않습니다.
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
3.6.1. Flisom ......................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
4. Centrotherm’s CIGS Thin Film Turnkey Production Line오류! 책갈피가 정의되어 있지 않습
니다.
4.1. Introduction of Turnkey Production Line ................................. 오류! 책갈피가 정의되어 있지 않습니다.
4.2. Structure of Solar Cell and Process Technology ................... 오류! 책갈피가 정의되어 있지 않습니다.
4.3. Product Features and Movement of the Company ............. 오류! 책갈피가 정의되어 있지 않습니다.
5. Analysis on Patent Trend .............................................. 오류! 책갈피가 정의되어 있지 않습니다.
5.1. Overall Patent Trend ......................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
5.1.1. Yearly Patent Trend ............................................................... 오류! 책갈피가 정의되어 있지 않습니다.
5.1.2. Major Patent Holder of Each Country .......................... 오류! 책갈피가 정의되어 있지 않습니다.
5.1.3. Major Countries’ Main Technical Area .......................... 오류! 책갈피가 정의되어 있지 않습니다.
5.1.4. Nationality Distribution of Patent Holder ................... 오류! 책갈피가 정의되어 있지 않습니다.
5.1.5. Patent Distribution by Detailed Technology .............. 오류! 책갈피가 정의되어 있지 않습니다.
5.1.6. Internatioanl Joint Research Status of Each Country오류! 책갈피가 정의되어 있지 않습니
다.
5.2 Patent Trend by Country ................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
5.2.1. Yearly Patent Trend in Korea ............................................ 오류! 책갈피가 정의되어 있지 않습니다.
5.2.2. Yearly Patnet Trend in USA ............................................... 오류! 책갈피가 정의되어 있지 않습니다.
5.2.3. Yearly Patent Trend in Japan ............................................. 오류! 책갈피가 정의되어 있지 않습니다.
5.2.4. Yearly Patent Trend in Europe .......................................... 오류! 책갈피가 정의되어 있지 않습니다.
5.3 Patent Trend by Maker ..................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
5.3.1. Patent Analysis of Matsushita Electric .......................... 오류! 책갈피가 정의되어 있지 않습니다.
5.3.2. Patent Analysis of Honda .................................................. 오류! 책갈피가 정의되어 있지 않습니다.
5.3.3. Patent Analysis of Showa Shell ....................................... 오류! 책갈피가 정의되어 있지 않습니다.
5.3.4. Patent Analysis of Siemens Solar ................................... 오류! 책갈피가 정의되어 있지 않습니다.
6. CIGS Thin Film Solar Cell Market Forecast(2006~2013) .......................................................... 13
6.1. CIGS Thin Film Solar Cell Market Status(2006~2008) ....................................................................................... 13
6.1.1. Worldwide PV Market Status(2006~2008) ................................................................................................. 13
6.1.2. Worldwide Solar Cell Market Status(2006~2008) ................................................................................... 14
6.1.3. Price Trend of Solar Cell by Technology and Revenue Size Status(2006~2008)오류! 책갈피
가 정의되어 있지 않습니다.
6.1.4. CIGS Thin Film Solar Cell Market Status(2006~2008)오류! 책갈피가 정의되어 있지 않습니
다.
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
6.1.5. Module Price Trend of CIGS Thin Film Solar Cell and Revenue Size Status(2006~2008) 오류!
책갈피가 정의되어 있지 않습니다.
6.2. CIGS Thin Film Solar Cell Market Forecast(2006~2013) ................................................................................... 16
6.2.1. Worldwide PV Market Forecast(2006~2013) ............................................................................................ 16
6.2.2. Worldwide Solar Cell Market Forecast(2006~2013) 오류! 책갈피가 정의되어 있지 않습니다.
6.2.3. Module Price Trend of Solar Cell by Technology and Sales Size Forecast(2006~2013) ... 오류!
책갈피가 정의되어 있지 않습니다.
6.2.4. CIGS Thin Film Solar Cell Market Forecast(2006~2013)오류! 책갈피가 정의되어 있지 않습
니다.
6.2.5. Price Trend of CIGS Thin Film Solar Cell and Sales Size Forecast(2006~2013)오류! 책갈피가
정의되어 있지 않습니다.
7. Index ................................................................................................................................................... 18
7.1. Figure ..................................................................................................................................................................................... 18
7.2. Table ....................................................................................................................................................................................... 26
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
1. Introduction of Solar Cell
1.1. Vision of PV
Today, mankind is using petroleum as a main energy source because it is cheap
and easy to use. However, due to the limit of petroleum reserve, the production is
continuously decreasing and it is endangered to be exhausted in 50 years. The
price is forecasted to be around USD 200 per barrel. As the petroleum is used as
a main energy source, serious problems including air pollutant emission and global
warming due to the greenhouse effect not alone the oil price increase are caused.
In this situation, Kyoto Protocol was adopted in December 1997 to control the
emission of CO2 which is the main cause of global warming, and Korea is planning
to be included in CO2 control countries from 2013. Threrefore, in this situation, a
policy to support diversification of enery source is immediately needed and
securing the technology of renewable energy such as solar energy, wind energy
and hydrolic energy is emerging as an important task to be fulfilled as soon as
possible at national level. Solar cell is attracting attention because it doesn’t have
any problem of pollution and it can be supplied infinitely.
PV is element and system technology that convert solar energy into heat and
electric energy to use, and usually means power generation using solar cell. It is
not only a technology that can produce high value added energy from
environment friendly natural energy, but also is expected to greatly contribute to
the realization of clean and wellfaire society through the independance of national
energy supply. And, every member of the nation can have independant
environment friendly energy source with solar energy. Another value of solar
energy utilization is to help people enjoy comfortable lives in clean environment.
Through PV, distributed power generation installed in houses and buildings which
can be competitive compared to existing power generation method, large saled
power generation, power generation for space and telecommunication satellite are
possible, not alone small scaled independent energy system. To make it possible,
we should improve performance of existing crystalline silicon solar cell and purse
thiner, cheaper solution. Also, technical development is required to make cheaper
and more efficient solution for new large area thin film solar cell and module. And,
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
solar cell module for various applications in construction (BIPV, Building Integrated
Photovoltaic), high efficiency electric conversion and versatile PCS technology using
digital technology, system standardization according to application and required
load, and securing optimum operation technological are also needed.
PV technology is in the center of existing semiconductor, material, electric and
electronics, construction, engineering and chemical industries.
[Table 1-2-2] Inpurities Diffusion Method (Classifed by source)
Class Diffusion Source Diffusion Method
Single Element
As
Source
Direct Diffusion in a sealed tube
Single Element
Glass Layer Formation - drive
2 nd Stage
Au
Source
(gas Diffusion)
Diffusion
Gas source PH 3 , B 2 H 6
Glass Layer Formation - drive
2nd Stage
(gas Diffusion)
Diffusion
Liquid source POCl 3 , BBr 3 , PBr 3
Glass Layer Formation - drive
2nd Stage
(gas Diffusion)
Diffusion
Solid source As 2 O 3 , Sb 2 O 3 , B 2 O 3 , P 2 O 5 Glass Layer Formation - drive
2nd Stage
Diffusion
Solid source BN, As-Si alloy, etc. B 2 O 3 Glass Layer Formation - drive
2nd Stage
Diffusion
CVD film
Doped oxidation Formation – Heat Diffusion
Solid Phase-
SiH 4 -PH 3 -O 2 system
(PSG, BSG, ASSG)
Solid Phase
Si(OC 2 H 5 )-PO(OCH 3 ) 3 system, Doped poly silicon Formation – Heat Diffusion
Diffusion
etc.
(Poly silicon doped with phosphorus and arsenic)
Solid Phase -
Solid Phase Coating film
Glass film is formed by spin coating – Heat Diffusion
Diffusion
Ion Injection PH 3 , PF 6 , BF 3 , AsH 3 etc. Ion Injection – Thermal treatment
(Source: Principle of Solar Cell, Hongreung Publicaiotn)
1 Gas Phase Diffusion Method
In gas phase diffusion method of impurities on the surface of silicon, the process
differs depending on the substance of the impurities which can be one among
solid, liquid and gas. This gas phase diffusion method is used in the most cases
among impurities diffusion methods in making solar cell. In this method, gas
carrier containing impurities to be coated are coated on the exposed subsrate of
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
silicon wafer in a high temperature coating furnace and diffused by thermal
treatment. To compare the different form of impurities to be prepared, gas source
gas phase diffusion method as seen in [Figure 1-2-4], liquid source gas phase
diffusion method in [Figure 1-2-5], and solid source gas phase diffusion method in
[Figure 1-2-6]are shown like below. That is, what makes difference among the
methods is in what form the impurities’ material is prepared prior to be diffused in
carrier gas. In some cases of solid source methods, specific carrier gas is not used
and impurities are coated on the surface of wafer and diffused after they are
evaporated by heat and pressure by filling the wafer cosist of impurities between
wafers which are to form n-p junction layer. Most of cases, boron nitride (BN)
wafer is used for p-type impurity.
2. CIGS Solar Cell Technology
2.1. Structure of CIGS Solar Cell and Operating Mechanism
In basic structure of CIGS thin film solar cell, there is basic PN junction structure.
On each sides of the structure, there is a metal electrode used as cathode
electrode and a transparent electrode as anode electrode.
In terms of the thickness of each layer, Mo layer used as a cathode electode is
4000 ~ 10000Å, CIGS layer used as P layer is 1.5~2μm, CdS layer as N layer is 500
Å, ZnS layer is 500Å, and AZO transparent layer is 1~2 μm thick.
CdS layer is used for an electric buffer of optical absorber and transparent
electrode, and furthermore, it prevents the damage of CIGS thin film when the
transparent electrode is sputter coated in the plasma atmosphere. For transparent
electrode part, ZnO thin film containing some % of Al2O3 is used in the most
cases. And to block the leakage current between buffer layer and transparent
electrode, very thin pure ZnO thin film of 500Å thickness is used.
For subsrate, sodalime glass substrate is typically used. Since sodium substance
included in the sodalime glass helps the crystalline growth of CIGS layer and
performs positively in increasing the efficiendy of the cell, more makers are using
soladime substrate which is inexpensive and commonly used in window glass.
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
[Figure 2-1-1] Structure of CIGS Solar Cell
2.2. Production Process of CIGS Solar Cell
2.2.1. Comparison of Production Process with Crystalline Si Solar Cell
Single crystalline silicon wafer solar cell production consists of ingot process, wafer
process, cell process, and module process, which are 4 completely different
processes, and it has 22 processes in total. On the other hand, CIGS solar cell in
thin film type is produced far simpler process consist of 9 processes.
Since the cell linking process of thin film solar cell is made in simple process of
monolithic patterning and PCO coating process, this process is made by cell maker
together with other processes not by a separated module maker. However, in
solar cell industry where silicon wafer is used, since the characteristics of above
mentioned cell and module process are completely different, the cell is transported
to separated module makers to proceed the process. 하지만 Silicon wafer를 이용
하는 태양 전지 산업에서는 상기 셀과 모듈 공정의 성격이 전혀 다르기 때문에 별
도의 모듈 업체로 셀을 운반하여 공정이 진행된다. And since ingot and wafer has
different process characteristics, each different maker performs production. This
causes higher transportation expenses and supply condition of each maker
becomes more important.
[Figure 2-2-1] Comparison of Process between Crystalline Silicon Solar Cell and Thin Film
Type Solar Cell
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
3. Global Trend of Technology and Commercialization By Maker
3.1. Japan
3.1.1. Showa Shell Sekiyu
3.1.1.1. Structure of Solar Cell and Process Technology
Currently, there are 2 major CIGS solar cell makers in Japan. Both of Showa Shell
Sekiyu and Honda Soltec is applying same technology in CIGS layer formation by
using sputtering technology and thermal treatment technology in H2Se gas
atmosphere. Particularly in the case of Showa Shell Sekiyu, they are applying the
technology in which precursor (Cu, Ga, IN) is sputtered before multiple substrates
are thermal treated at the same time in a furnace with gas atmosphere where
H2Se is diluted. After that, the atmosphere is changed again into a gas where H2S
is diluted and then, it is thermal treated again at much higher temperature (about
550℃).
13
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
In terms of buffer layer, they are using specially developed technology from ZnS,
O, and OH layer in CBD method in order not to use Cd, which is a harmful
substance.
In terms of transparent electrode layer, BZO layer, which has good light
transmittance despite of low electric conductivity, is coated by MOCVD technology.
The metal organic source used in here is less expensive and has better coating
quality in step coverage compared to sputtering.
6. CIGS Thin Film Solar Cell Market Forecast (2006~2013)
6.1. CIGS Thin Film Solar Cell Market Status (2006~2008)
6.1.1. Worldwide PV Market Status(2006~2008)
Although PV industry didn’t draw much attention until 2007 in Korea, global PV
market showed rapid growth since 2004. PV installation market accomplished high
growth with support by each nation’s government. The market size increased from
1.6GWp in 2006 to 2.4 GWp in 2007. In 2008, the market size of Spain and
Germany were 2.3GWp and 1.5GWp, respectively. Total global market size in 2008
was 5.5 GWp with 130% growth year on year.
Especially in Spain, even though the FIT support capacity was limited to 1.2GW in
2008, actuall yearly installation in the feverish market was 2.3 GW, which is 1.2GW
more than limit capacity supported by FIT from the government.
All Contents of this report remain the property of Displaybank
14

CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
[Figure 6-1-1] Global PV Installaion Market and Market Status by Country (2006~2008)
Annual Installed Capacity[GW]
7
6
5
4
3
2
1
PV Market
Growth Rate
1.6
21%
2.4
50%
129%
5.5
140%
120%
100%
80%
60%
40%
20%
Growth Rate[%]
0
2006 2007 2008
0%
2008year
5,513MW
2 nd
3 rd
4 th
2008year
Market
1 st Share
6.1.2. Worldwide Solar Cell Market Status (2006~2008)
(Source: Displaybank, 2009)
With the rapid increase of demand for PV, solar cell production also rapidly grew.
Total production of solar cell in 2007 was 4.4GW, with 69% increase Y/Y, and in
2008, it was 8.1GW with 84% Y/Y. Especially in this period, as Chinese makers
entered the market with aggressive production facility boost and low price strategy,
global solar cell production rapidly increased from 2007 and Chinese market is
sharing over 30% of global solar cell market.
Worldwide PV market accomplished rapid growth by systematical support by each
government as many countries designated PV as green industry and industry of
growing engine for the next generation. Share of top 10 makers of solar cell was
62% in 2006. The share decreased to 53% in 2007 and 45% in 2008. Considering
that the market share of the top ranked maker Q-Cells is just 7%, competition
becomes tough as more makers worldwide enter the solar cell business. In this
situation, we can see that the industry is changing into an industry that requires
15
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
large scaled investment on GW grade production system for high efficiency solar
cell production technology and production cost reduction to survive in the future
solar cell business.
[Figure 6-1-2] Global Production and Market Share Status of Top 10 Solar Cell Makers (2008)
Q‐Cells
570
7%
First Solar
504
6%
Suntech
498
6%
Others
4408
55%
2008
Total
Production
8.1GW
Sunpower
SolarWorld
237
221
3%
3%
Sharp
473
6%
JA Solar
300
4%
Kyocera
290
4%
Yingli
282
3%
Motech
272
3%
(Source: Displaybank, 2009)
[Table 6-1-10] Module Price Status of each Solar Cell Technology(2006~2008)
Item 2006 2007 2008
Crystalline Si Solar Cell
Module
(crystalline-Si)
Thin Film Type Solar Cell
Module
(Thin Film)
c-Si Production(MW)
Price($/W)
Revenue (Bil.$)
Share (%)
a-Si Production(MW)
Price ($/W)
Revenue (Bil.$)
Share (%)
CIGS Production(MW)
Price($/W)
Revenue (Bil.$)
Share (%)
16
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
CdTe Production(MW)
Price($/W)
Revenue (Bil.$)
Share (%)
Production(MW)
Total
Revenue (Bil.$)
Price($/W)
Share (%)
(Source: Displaybank, 2009)
6.2. CIGS Thin Film Solar Cell Market Forecast (2006~2013)
6.2.1. Worldwide PV Market Forecast (2006~2013)
[Figure 6-2-1] Worldwide Economic Outlook(2007~2010)
All Contents of this report remain the property of Displaybank
17

CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
South Korea
Emerging & developing
economics
Advanced
economics
World
[Table 6-2-3] Production and Market Share Forecst of Worldwide Solar Cell by Type/Technology
(2006~2013)
Item 2006 2007 2008 2009F 2010F 2011F 2012F 2013F
c-Si Production
c-Si
Thin
Film
a-Si
CIGS
CdTe
DSSC
Sum
Share
Growth
Production
Share
Production
Share
Production
Share
Production
Share
Production
Share
Growth
All Contents of this report remain the property of Displaybank
18

CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
Total
Production(MWp)
Share
(%)
Growth
(%)
(Source: Displaybank, 2009)
[Figure 6-2-12] Forecast of Demand and Production of Solar Cell (2006~2013)
PV Industry
Beginning Period
poly-Si Shortage
Period
poly-Si Shortage/ Oversupply
Period
[MWp]
30
25
20
15
100%
95%
104%
113%
108%
82%
Solar Cell
Shortage
96% 100% 85%
117%
140%
Solar Cell
Oversupply
122%
113% 120%
108%
107%
100%
160%
140%
100%
80%
Annual Installation Demand
Cell Demand
Cell Producion
Cell Produntion/ Demand Ratio
Cell Produntion/ Demand Balance
10
60%
40%
5
20%
0
2000 2001 2002 2003 2004 2005 2006 2007 2008 2009F 2010F 2011F 2012F 2013F
0%
(Source: Displaybank, 2009)
7. Index
7.1. Figure
All Contents of this report remain the property of Displaybank
19

CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
[Figure 1-2-1] Classification of Solar Cell ............................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 1-2-2] Wafer Production Process for Crystalline Silicon Solar Cell오류! 책갈피가 정의되어
있지 않습니다.
[Figure 1-2-3] Production Process of Crystalline Silicon Solar Cell오류! 책갈피가 정의되어 있지
않습니다.
[Figure 1-2-4] Gas Phase Diffusion Method for Gas Source오류! 책갈피가 정의되어 있지 않습니
다.
[Figure 1-2-5] Gas Phase Diffusion Method for Liquid Source오류! 책갈피가 정의되어 있지 않습
니다.
[Figure 1-2-6] Gas Phase Diffusion Method for Solid Source오류! 책갈피가 정의되어 있지 않습
니다.
[Figure 1-2-7] Result of Surface Organization Process ..... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 1-2-8] Various Surface Treatment of Solar Cell and Electrode Formation오류! 책갈피가
정의되어 있지 않습니다.
[Figure 1-2-9] Production Process of Thin Film Si Solar Cell 오류! 책갈피가 정의되어 있지 않습
니다.
[Figure 1-2-10] Process Flow of Thin Film Si Solar Cell .... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 1-2-11] Basic Structure of Amorphous Silicon Single Junction Solar Cell오류! 책갈피가 정
의되어 있지 않습니다.
[Figure 1-2-12] Technical Development Trend of Thin Film Si Solar Cell by Generation오류! 책갈
피가 정의되어 있지 않습니다.
[Figure 1-2-13] Basic Structure of CIS Thin Film Element and Material and Coating Process Used
in Each Layer ............................................................................ 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 1-2-14] CIS Solar Cell Production Process (Siemens Co.)오류! 책갈피가 정의되어 있지 않
습니다.
[Figure 1-2-15] Structure of CdTe Thin Film Solar Cell ..... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 1-2-16] CBD Recation and Device .............................. 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 1-2-17] Structure of Closed Spaced Sublimation Device (Korea Ceramic Academy, 8(5),
2005) .............................................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 1-2-18] VTD(Vapor Transport Deposition) Method and System Diagram오류! 책갈피가 정
의되어 있지 않습니다.
[Figure 1-2-19] Double Diode and I-V Characteristics by Schottky Contact (KAIST, Ahn, Byeong
Tae) ................................................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 1-2-20] Production Process Diagram of CdTe Thin Film Solar Cell Module오류! 책갈피가
정의되어 있지 않습니다.
[Figure 1-2-21] CdTe Thin FilmSolar Cell Module Automataion Process Using VTD Method (First
solar) .............................................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
20
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
[Figure 1-2-22] CdTe Thin FilmSolar Cell Module Automation Process Using CSS Method (Antec
solar) .............................................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 1-2-23] Structure of Dye-Sensitized Solar Cell and Structure of Ruthenium System Dye. 오
류! 책갈피가 정의되어 있지 않습니다.
[Figure 1-2-24] Operation Principle of Dye-Sensitized Solar Cell오류! 책갈피가 정의되어 있지 않
습니다.
[Figure 1-2-25] Element Production of Gratzel Group ...... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 1-3-1] Comparison of Efficiency Characteristics of Each Thin Film Solar Cell오류! 책갈피
가 정의되어 있지 않습니다.
[Figure 1-4-1] History of Efficiency Improvement of Thin Film Solar Cell오류! 책갈피가 정의되어
있지 않습니다.
[Figure 2-1-1] Structure of CIGS Solar Cell ........................................................................................................... 11
[Figure 2-1-2] Cross Section TEM Picture of CIGS Solar Cell Produced by NREL 오류! 책갈피가
정의되어 있지 않습니다.
[Figure 2-1-3] Cross Section SEM Picture of CIGS Solar Cell Produced by ZSW오류! 책갈피가 정
의되어 있지 않습니다.
[Figure 2-1-4] Structure of Monolithic Thin Film Solar Cell오류! 책갈피가 정의되어 있지 않습니
다.
[Figure 2-2-1] Comparison of Solar Cell Process of Crystalline Silicon Solar Cell and Thin Film
Solar Cell process .................................................................................................................................................... 11
[Figure 2-2-2] CIGS Thin Film Solar Cell Production Process Chart오류! 책갈피가 정의되어 있지
않습니다.
[Figure 2-2-3] Sputtering Principle ............................................ 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 2-2-4] Sputter Cathode Gun and Description of Sputtering Process오류! 책갈피가 정의되
어 있지 않습니다.
[Figure 2-2-5] Structure of Sputter Cathode Gun ............... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 2-2-6] Coparison of Shapes Before And After Mo Patterning오류! 책갈피가 정의되어 있
지 않습니다.
[Figure 2-2-7] Enlarged Picture of Laser Patterned Part ... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 2-2-8] Skeleton Diagram of Co-Evaporation to Form CIGS Layer오류! 책갈피가 정의되어
있지 않습니다.
[Figure 2-2-9] Mimetic Diagram of CIGS Process Used in NREL오류! 책갈피가 정의되어 있지 않
습니다.
[Figure 2-2-10] Monitored Result of Actual Substrate Temperature at Stage 3 Process오류! 책갈
피가 정의되어 있지 않습니다.
[Figure 2-2-11] Complete View of CIGS In-Line Deposition System of ZSW오류! 책갈피가 정의되
어 있지 않습니다.
21
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
[Figure 2-2-12] Skeleton Diagram of Roll to Roll process Production Device for CIGS Production
of Matsushita Electric ............................................................. 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 2-2-13] Skeleton Diagram of CIGS Absorber Fomration Process Using Sputtering by Shell
Solar ............................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 2-2-14] Processing of Rapid Thermal Treatment Furnace for CIGS Absorber Formation
Used by Shell Solar ................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 2-2-15] Chemical Bath Deposition System ............. 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 2-2-16] CIGS Cell Shape with completed P1, P2, and P3오류! 책갈피가 정의되어 있지 않
습니다.
[Figure 2-3-1] Skeleton Diagram of Roll-to-Roll Process of Flexible CIGS Solar Cell오류! 책갈피가
정의되어 있지 않습니다.
[Figure 2-3-2] Production Process of Flexible CIGS Solar Cell by Miasole오류! 책갈피가 정의되어
있지 않습니다.
[Figure 2-3-3] Flexible CIGS Solar Cell Roll (100m x 0.2m) and Cross Section Structure오류! 책갈
피가 정의되어 있지 않습니다.
[Figure 2-4-1] Classification by Fomation Method of CIGS Layer오류! 책갈피가 정의되어 있지
않습니다.
[Figure 2-6-1] Layering Order of CIGS Thin Film Solar Cell and Laser and Mechanical Scribing
Position to Produce Cell Strip ...................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 2-6-2] CIGS Thin Film Solar Cell Strip with Monolithic Wiring오류! 책갈피가 정의되어 있
지 않습니다.
[Figure 2-6-3] Mimetic Diagram of Solar Cell with 2 Terminal Tandem Structure오류! 책갈피가
정의되어 있지 않습니다.
[Figure 2-6-4] Structre and Principle of Multijuction to Increase Theorical Efficiency of CIGS Solar
Cell up to 28% .......................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 2-7-1] Field Test Criteria of Photovoltaic Module 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 2-8-1] Applied Areas of CIGS Solar Cell .................. 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-1-1] 5.59. Structre of CIS Solar Cell Module of Showa Shell Sekiyu Applying ZnO in
Buffer Layer and Process Flow of the 2 nd Plant.오류! 책갈피가 정의되어 있지 않
습니다.
[Figure 3-1-2] Picture of Major Selling Product of Showa Shell Sekiyu오류! 책갈피가 정의되어
있지 않습니다.
[Figure 3-1-3] Applied Area of Rooftop mounted PV Plant of CIGS Module by Showa Shell
Sekiyu ............................................................................................ 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-1-4] Picture of Selling Product of Honda soltec (On module is made by connecting 3
circuits) ......................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-1-5] Picture of Solar Cell Self Produced, Installed, and Used by Honda soltec in Honda
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
soltec Plant ................................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-1-6] System Structure Diagram of Energy Supplied from CIGS Solar Cell to Use in
Hydrogen Generator ........................................ 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-1-7] CIGS Solar Cell Module Sold by Honda Since 2007 and Its Spec. 오류! 책갈피가
정의되어 있지 않습니다.
[Figure 3-1-8] AIST Developed CIGS Module and I-V Curve (Module Size: 10cm×10Cm,
Efficiency : 15.9%) .................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-1-9] Cross Section Structure of Developed Module (Arrow stands for the direction of
current flow) ............................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-1-10] Picture of CIGS Cell Produced on Ceramic Substrate(L) and Polymer Substrate(R)
......................................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-1-11] Result of Evaluation of Cell That Achieved 17.7% Efficiency in Ceramic Substrate
......................................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-1-12] Structure of CIGS Cell Produced on Flexible Substrate오류! 책갈피가 정의되어
있지 않습니다.
[Figure 3-1-13] Comparison of Element Efficiency Characterisstics Depending on the Presence of
ASTL Layer ................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-1-14] Removal Process of Polymer Layer and Above CIGS Element from Glass
Substrate ...................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-2-1] CIGS Thin Film Module(Top) and Spec.(Bottom) of Wurth Solar오류! 책갈피가 정
의되어 있지 않습니다.
[Figure 3-2-2] Structure of AVANCIS CIGS Module (3rd International Workshop on Thin Film PV,
21st November 2007) ...................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-2-3] Process Diagram of CIGS Production Including Evaluation오류! 책갈피가 정의되어
있지 않습니다.
[Figure 3-2-4] Picture of Precursor Coated Cell and Picture After Formation of CIGS Compound
......................................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-2-5] CIS Cell Structre by Sulfucell .......................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-2-6] Production Process of CIS Module by Sulfucell오류! 책갈피가 정의되어 있지 않습
니다.
[Figure 3-2-7] Product Spec. of CIS Module by Sulfercell 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-2-8] CIS Module Production Line of Sulfercell . 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-2-9] Complete View of CIGS Module Production Line of Odersun오류! 책갈피가 정의
되어 있지 않습니다.
[Figure 3-2-10] Picture of CIGS Module Product of Odersun (Multiple cell are connected in a
row) ................................................................................................ 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-2-11] Picture of Flexible CIGS Module Product of Odersun오류! 책갈피가 정의되어 있
23
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
지 않습니다.
[Figure 3-2-12] Applied Areas of CIGS Module Product by Odersun오류! 책갈피가 정의되어 있
지 않습니다.
[Figure 3-3-1] Complete View of CIGS Module Production Line of Global Solar오류! 책갈피가 정
의되어 있지 않습니다.
[Figure 3-3-2] Picture of Global Solar Product and Applied Areas for Mountains오류! 책갈피가
정의되어 있지 않습니다.
[Figure 3-3-3] Product and Application of Global Solar (Glass Plaque Applied Module)오류! 책갈
피가 정의되어 있지 않습니다.
[Figure 3-3-4] Product and Application of Global Solar (Flexible BIPV Applied)오류! 책갈피가 정
의되어 있지 않습니다.
[Figure 3-3-5] Picture of CIGS Film Printing Process of Nanosolar오류! 책갈피가 정의되어 있지
않습니다.
[Figure 3-3-6] Picture of CIGS Photovolatic Module Installation of Nanosolar오류! 책갈피가 정의
되어 있지 않습니다.
[Figure 3-3-7] Device structure(A) and JV characteristics of the PV device(B).오류! 책갈피가 정의
되어 있지 않습니다.
[Figure 3-3-8] CIGS Cell Production Device of MIASOLE . 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-3-9] Shpae of CIGS Cell Produced by MIASOLE오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-3-10] Structure of Solar Cell and Installed Shape of Solindra오류! 책갈피가 정의되어
있지 않습니다.
[Figure 3-3-11] Picture of Solindra Product and Existing Solar Cell Installation오류! 책갈피가 정
의되어 있지 않습니다.
[Figure 3-3-12] Structure of Solar Cell and Coating Method of ASCENT Solar오류! 책갈피가 정의
되어 있지 않습니다.
[Figure 3-3-13] Solar Cell Shape of ASCENT Solar ............. 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-3-14] Skeleton Diagram of Electrode Position Process by Solopower오류! 책갈피가 정
의되어 있지 않습니다.
[Figure 3-3-15] Composition Characteristics of CIGS Layer Formed Applying Roll-to-Roll
Technology and Electrode Position Method오류! 책갈피가 정의되어 있지 않습
니다.
[Figure 3-3-16] Characteristics of CIGS Solar Cell from Solopower Proved by NREL in USA .... 오류!
책갈피가 정의되어 있지 않습니다.
[Figure 3-3-17] Picture of SP1-Series Module and Spec. (Top) by Solopower and I-V
Curve(Bottom) ........................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-4-1] Inline Deposition Device for 200mm x 200mm CIGS Solar Cell Production (L)와
Downward High Heat Linear Evaporation Source (R) Developed by Teliosolar 오
24
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-4-2] Structure Diagram of Belt-source Evaporation Device Developed by OLEDON for
5 th Generation OLED Deposition Device .. 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-4-3] CIGS Solar Cell Module Developed by Teliosolar (L) with 9.17% Efficiency and BIPB
Type CIGS Module(R) ..................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-4-4] Production Process Flow of Thin Film CIGS Solar Cell by LG Micron오류! 책갈피가
정의되어 있지 않습니다.
[Figure 3-4-5] CO-evaporation Device for CIGS Deposition (Top) Daiyang Metal’s R&D Center in
Boston, USA and FastFlex web-coating system for Flexible CIGS Cell Production to be
Supplied by Veeco (Bottom)........................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 3-5-1] CIGS Module Production Process Flow of Nanowin오류! 책갈피가 정의되어 있지
않습니다.
[Figure 3-6-1] CIGS Detailed Structure Module Production process Flow of Filsom오류! 책갈피가
정의되어 있지 않습니다.
[Figure 3-6-2] CIGS Module Production process Flow of Flisom오류! 책갈피가 정의되어 있지 않
습니다.
[Figure 3-6-3] Sample of Prototype의 Flexible CIGS Module Produced by Filsom (Top) and I-V
Curve(Bottom) ........................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 4-1-1] CIGS Thin Film Turnkey Production Line Layout(30~50MW) by Centrotherm ... 오류!
책갈피가 정의되어 있지 않습니다.
[Figure 4-1-2] Sputter Device for CIGS Thin Film of Centrotherm오류! 책갈피가 정의되어 있지
않습니다.
[Figure 4-1-3] Production Cost Structure of CIGS Module오류! 책갈피가 정의되어 있지 않습니다.
[Figure 4-1-4] Cost/Wp Ratio by Items to be Improved with Efficiency Increase of CIGS
Module’s Efficiency ............................................................. 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 4-2-1] Cross Section Structure of Completed CIGS Cell by Centrotherm의 CIGS (Top) and
Picture of the Cell After Integrated Serial Connection오류! 책갈피가 정의되어 있
지 않습니다.
[Figure 4-2-2] CIGS Film Forming Method of Centrotherm오류! 책갈피가 정의되어 있지 않습니
다.
[Figure 4-2-3] CIGS Cell and Module Production Process Flow of Centrotherm오류! 책갈피가 정
의되어 있지 않습니다.
[Figure 4-3-1] Time Frame of Total Solution in 50MW CIGS Module Production Line of
Centrotherm ............................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 5-1-1] Share by Country of Technology Related to CuInSe2 System Solar Cell and
Number of Patent .................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 5-1-2] Each Country’s Position of CuInSe2 System Solar Cell in Portfolio오류! 책갈피가
25
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
정의되어 있지 않습니다.
[Figure 5-1-3] Protfoilo Analysis According to Patent Share and Growth Rate오류! 책갈피가 정의
되어 있지 않습니다.
[Figure 5-1-4] Major Countries’ Main Technical Area ...... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 5-1-5] Patent Countries’ Main Technical Area ....... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 5-1-6] Nationality Distribution of Patent Holder by Technology(Total)오류! 책갈피가 정의
되어 있지 않습니다.
[Figure 5-1-7] Patent Shares by Detailed Technology (Total)오류! 책갈피가 정의되어 있지 않습니
다.
[Figure 5-2-1] Patent Trend of CuInSe 2 System of Solar Cell in Korea오류! 책갈피가 정의되어 있
지 않습니다.
[Figure 5-2-2] Patnet Trend By Technical Area and Term in Korea오류! 책갈피가 정의되어 있지
않습니다.
[Figure 5-2-3] Patent Shares by Detailed Technology (Korea)오류! 책갈피가 정의되어 있지 않습
니다.
[Figure 5-2-4] Yearly Domestic/Foreign Patent Trend and Share (Korea)오류! 책갈피가 정의되어
있지 않습니다.
[Figure 5-2-5] Distribution of Patent Holder’s Nationality by Technology (Korea)오류! 책갈피가
정의되어 있지 않습니다.
[Figure 5-2-6] Distribution of Patent Holder by Techical Area (Korea)오류! 책갈피가 정의되어 있
지 않습니다.
[Figure 5-2-7] Patent Trend of CuInSe 2 System Solar Cell in USA오류! 책갈피가 정의되어 있지
않습니다.
[Figure 5-2-8] Patnet Trend By Technical Area and Term in USA오류! 책갈피가 정의되어 있지 않
습니다.
[Figure 5-2-9] Patent Shares by Detailed Technology (USA)오류! 책갈피가 정의되어 있지 않습니
다.
[Figure 5-2-10] Yearly Domestic/Foreign Patent Trend and Share (USA)오류! 책갈피가 정의되어
있지 않습니다.
[Figure 5-2-11] Distribution of Patent Holder’s Nationality by Technology (USA)오류! 책갈피가
정의되어 있지 않습니다.
[Figure 5-2-12] Distribution of Patent Holder by Techical Area (USA)오류! 책갈피가 정의되어 있
지 않습니다.
[Figure 5-2-13] Patent Trend of CuInSe2 System Solar Cell in Japan오류! 책갈피가 정의되어 있
지 않습니다.
[Figure 5-2-14] Patnet Trend By Technical Area and Term in Japan오류! 책갈피가 정의되어 있지
않습니다.
26
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
[Figure 5-2-15] Patent Shares by Detailed Technology (Japan)오류! 책갈피가 정의되어 있지 않습
니다.
[Figure 5-2-16] Yearly Domestic/Foreign Patent Trend and Share (Japan)오류! 책갈피가 정의되어
있지 않습니다.
[Figure 5-2-17] Distribution of Patent Holder’s Nationality by Technology (Japan)오류! 책갈피가
정의되어 있지 않습니다.
[Figure 5-2-18] Distribution of Patent Holder by Techical Area (Japan)오류! 책갈피가 정의되어
있지 않습니다.
[Figure 5-2-19] Patent Trend of CuInSe2 System Solar Cell in Europe오류! 책갈피가 정의되어 있
지 않습니다.
[Figure 5-2-20] Patnet Trend By Technical Area and Term in Europe오류! 책갈피가 정의되어 있
지 않습니다.
[Figure 5-2-21] Patent Shares by Detailed Technology (Europe)오류! 책갈피가 정의되어 있지 않
습니다.
[Figure 5-2-22] Yearly Domestic/Foreign Patent Trend and Share (Europe)오류! 책갈피가 정의되
어 있지 않습니다.
[Figure 5-2-23] Distribution of Patent Holder’s Nationality by Technology (Europe)오류! 책갈피가
정의되어 있지 않습니다.
[Figure 5-2-24] Distribution of Patent Holder by Techical Area (Europe)오류! 책갈피가 정의되어
있지 않습니다.
[Figure 5-3-1] Patnet Trend of Matsushita Electric by Patent Year오류! 책갈피가 정의되어 있지
않습니다.
[Figure 5-3-2] Yearly Major Patent Trend of Matsushita Electric오류! 책갈피가 정의되어 있지 않
습니다.
[Figure 5-3-3] Competitor Analysis of Matsushita Electric Focused on Citation Relationship (USA
Patent) ........................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 5-3-4] Patnet Trend of Honda by Patent Year ....... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 5-3-5] Competitor Analysis of Honda Focused on Citation Relationship (USA Patent) 오류!
책갈피가 정의되어 있지 않습니다.
[Figure 5-3-6] Patnet Trend of Showa Shell by Patent Year오류! 책갈피가 정의되어 있지 않습니
다.
[Figure 5-3-7] Yearly Major Patent Trend of Showa Shell 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 5-3-8] Competitor Analysis of Showa Shell Focused on Citation Relationship (USA Patent)
......................................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 5-3-9] Competitor Analysis of Siemens Solar Focused on Citation Relationship (USA
Patent) ........................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-1-1] Global PV Installation Market and Market Status by Country (2006~2008)............. 14
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
[Figure 6-1-2] Top 10 Makers’ Production and Market Share Status in Global Solar Cell Market
(2008) ........................................................................................................................................................................... 15
[Figure 6-1-3] Production of Worldwide Solar Cell by Type (2006~2008)오류! 책갈피가 정의되어
있지 않습니다.
[Figure 6-1-4] Market Share of Worldwide Solar Cell by Type (2006~2008)오류! 책갈피가 정의되
어 있지 않습니다.
[Figure 6-1-5] Production Growth of Worldwide Solar Cell by Type (2006~2008)오류! 책갈피가
정의되어 있지 않습니다.
[Figure 6-1-6] Production of Worldwide Solar Cell by Technology (2006~2008)오류! 책갈피가 정
의되어 있지 않습니다.
[Figure 6-1-7] Market Share of Worldwide Solar Cell by Technology (2006~2008)오류! 책갈피가
정의되어 있지 않습니다.
[Figure 6-1-8] Production and Market Share Status of Worldwide Top 10 Thin Film Solar Cell
Makers (2008) ............................................................................ 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-1-9] Production of Worldwide Thin Film Solar Cell by Technology (2006~2008)오류! 책
갈피가 정의되어 있지 않습니다.
[Figure 6-1-10] Market Share of Worldwide Thin Film Solar Cell by Technology (2006~2008) 오류!
책갈피가 정의되어 있지 않습니다.
[Figure 6-1-11] ModulePrice Status of Solar Cell by Technology (2006~2008)오류! 책갈피가 정의
되어 있지 않습니다.
[Figure 6-1-12] Production and Market Size Status of Worldwide Solar Cell Module (2006~2008)
......................................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-1-13] Market Size and Growth Status of Worldwide Solar Cell Module by Type
(2006~2008) ............................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-1-14] Global Market Size Share Status of Solar Cell Module by Type (2006~2008). 오류!
책갈피가 정의되어 있지 않습니다.
[Figure 6-1-15] Production Capacity and Size of CIGS Thin Film Solar Cell (2006~2008)오류! 책
갈피가 정의되어 있지 않습니다.
[Figure 6-1-16] Production of CIGS Thin Film Solar Cell by Substrate (2006~2008)오류! 책갈피가
정의되어 있지 않습니다.
[Figure 6-1-17] Production of CIGS Thin Film Solar Cell by Substrate (2006~2008)오류! 책갈피가
정의되어 있지 않습니다.
[Figure 6-1-18] Price Trend and Decrease Rate Status of CIGS Thin Film Solar Cell Module
(2006~2008) ............................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-1-19] CIGS Thin Film Solar Cell Production and Revenue Size(2006~2008)오류! 책갈피
가 정의되어 있지 않습니다.
[Figure 6-1-20] Module Revenue Size of Solar Cell by Technology (2006~2008)오류! 책갈피가 정
28
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
의되어 있지 않습니다.
[Figure 6-1-21] Share of Module Revenue Size of Solar Cell by Technology (2006~2008)오류! 책
갈피가 정의되어 있지 않습니다.
[Figure 6-2-1] Global Economic Outlook(2007~2010) ..................................................................................... 16
[Figure 6-2-2] New Installation Market Forecast Worldwide PV (2006~2013)오류! 책갈피가 정의
되어 있지 않습니다.
[Figure 6-2-3] New Installation Market Forecast of PV by Country (2009)오류! 책갈피가 정의되
어 있지 않습니다.
[Figure 6-2-4] New Installation Market Forecast of PV by country (2013)오류! 책갈피가 정의되어
있지 않습니다.
[Figure 6-2-5] Production Forecast of Worldwide Solar Cell의 by Type (2006~2013)오류! 책갈피
가 정의되어 있지 않습니다.
[Figure 6-2-6] Market Share Forecast of Worldwide Solar Cell by Type (2006~2013)오류! 책갈피
가 정의되어 있지 않습니다.
[Figure 6-2-7] Production Growth Rate Forecast of Worldwide Solar Cell by Type (2006~2013). 오
류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-2-8] Production Forecast of Worldwide Solar Cell by Technology (2006~2013)오류! 책
갈피가 정의되어 있지 않습니다.
[Figure 6-2-9] Market Share Forecast of Worldwide Solar Cell by Technology (2006~2013) ... 오류!
책갈피가 정의되어 있지 않습니다.
[Figure 6-2-10] Production Forecast of Thin Film Solar Cell by Technology (2006~2013)오류! 책
갈피가 정의되어 있지 않습니다.
[Figure 6-2-11] Market Share Forecast of Thin Film Solar Cell by Technology (2006~2013).... 오류!
책갈피가 정의되어 있지 않습니다.
[Figure 6-2-12] Demand and Production Forecast of Solar Cell (2006~2013) ...................................... 18
[Figure 6-2-13] Module Price Forecast Solar Cell by Technology (2006~2013)오류! 책갈피가 정의
되어 있지 않습니다.
[Figure 6-2-14] Production and Market Size Status of Worldwide Solar Cell Module (2006~2013)
......................................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-2-15] Revenue Size and Growth Forecast of Worldwide Solar Cell Module by Type
(2006~2013) ............................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-2-16] Share of Revenue Size Forecast of Worldwide Solar Cell Module by Type
(2006~2013) ............................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-2-17] Production Capacity and Production Size of CIGS Thin Film Solar Cell
(2006~2013) ............................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-2-18] Production Forecast of CIGS Thin Film Solar Cell by Substrate (2006~2013).. 오류!
책갈피가 정의되어 있지 않습니다.
29
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
[Figure 6-2-19] Share of Production Size Forecast of CIGS Thin Film Solar Cell by Substrate
(2006~2013) ............................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-2-20] Applied Areas of CIGS Thin Film Solar Cell Used for Roof Top Mounted PV
Plant(L) and BIPV for Building Wall............ 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-2-21] Price Trend and Decrease Ratio Status of CIGS Thin Film Solar Cell Module
(2006~2008) ............................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-2-22] Production and Revenue Size Forecast of CIGS Thin Film Solar Cell (2006~2013)
......................................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-2-23] Module Revenue Size Forecast of CIGS and Solar Cell by Technology
(2006~2013) ............................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Figure 6-2-24] Share Module Revenue Size Forecast of CIGS and Solar Cell by Technology
t(2006~2013) .............................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
7.2. Table
[Table 1-2-1] Composition and Characteristics of Etching Solution That Removes Various Flows
of Silicon Substrate ................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
[Table 1-2-2] Impurities Diffusion Method (Classified by Source) ................................................................ 9
[Table 1-2-3] Refractve Index of Anti-Reflection Film by Material오류! 책갈피가 정의되어 있지
않습니다.
[Table 1-2-4] Si Thin Film Forming Process ........................... 오류! 책갈피가 정의되어 있지 않습니다.
[Table 1-2-5] Type and Charisteristics of High Molecule Film 오류! 책갈피가 정의되어 있지 않습
니다.
[Table 1-2-6] Classification of Transparent Electrode ......... 오류! 책갈피가 정의되어 있지 않습니다.
[Table 1-2-7] Work Function of Metal Electrode ................. 오류! 책갈피가 정의되어 있지 않습니다.
[Table 1-4-1] Japan NEDO PV 2030 Roadmap ..................... 오류! 책갈피가 정의되어 있지 않습니다.
[Table 2-2-1] Overview of Materials Used in Cu(In,Ga)Se 2 and CuInS 2 Solar Cells오류!
책갈피가
정의되어 있지 않습니다.
[Table 2-2-2] Factors to be noted in P2 and P3 Patterning Process오류! 책갈피가 정의되어 있지
않습니다.
[Table 2-3-1] Property of Matter of Flexible Substrate, Solar Cell Material, and Barrier Layer 오류!
책갈피가 정의되어 있지 않습니다.
[Table 2-5-1] Comparison of CIGS Solar Cell Technology by Maker오류! 책갈피가 정의되어 있지
않습니다.
[Table 2-6-1] Efficiency of Solar Cell Using Flexible Substrate (AM 1.5 Condition)오류!
책갈피가
정의되어 있지 않습니다.
[Table 2-7-1] Field Test Result between Single Crystalline Silicon Solar Cell and Thin Film Solar
30
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
Cell ................................................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
[Table 3-1-1] Applied Material and processTechnology by Unit process of Showa Shell Sekiyu .. 오
류! 책갈피가 정의되어 있지 않습니다.
[Table 3-1-2] Spec. of Showa Shell Sekiyu’s Major Selling Product오류! 책갈피가 정의되어 있지
않습니다.
[Table 3-1-3] Applied Material and processTechnology by Unit process by Honda Soltec오류! 책
갈피가 정의되어 있지 않습니다.
[Table 3-1-4] Spec. of Major Selling Product of Honda Soltec오류! 책갈피가 정의되어 있지 않습
니다.
[Table 3-1-5] Applied Material and processTechnology by AIST Unit process오류! 책갈피가 정의
되어 있지 않습니다.
[Table 3-2-1] Applied Material and processTechnology by Unit Process오류! 책갈피가 정의되어
있지 않습니다.
[Table 3-2-2] Applied Material and processTechnology by Unit Process오류! 책갈피가 정의되어
있지 않습니다.
[Table 3-2-3] Applied Material and processTechnology by Unit Process오류! 책갈피가 정의되어
있지 않습니다.
[Table 3-2-4] Applied Material and processTechnology by Unit Process오류! 책갈피가 정의되어
있지 않습니다.
[Table 3-2-5] Applied Material and processTechnology by Unit Process오류! 책갈피가 정의되어
있지 않습니다.
[Table 3-3-1] Applied Material and processTechnology by Unit Process of Global Solar오류! 책갈
피가 정의되어 있지 않습니다.
[Table 3-3-2] Applied Material and processTechnology by Unit Process of Global Solar오류! 책갈
피가 정의되어 있지 않습니다.
[Table 3-3-3] Applied Material and Process Technology by Unit process of ASCENT Solar오류! 책
갈피가 정의되어 있지 않습니다.
[Table 3-3-4] Development Performance and Future Objective of Solopower.오류! 책갈피가 정의
되어 있지 않습니다.
[Table 3-4-1] CIGS Solar Cell R & D Makers and Technical Development Trend in Korea오류! 책
갈피가 정의되어 있지 않습니다.
[Table 3-4-2] Introduction of Teliosolar’s Piolot Line and Development Status오류! 책갈피가 정의
되어 있지 않습니다.
[Table 4-1-1] Characteristics of Centrotherm’s CIGS Thin Film Turnkey Production Line오류! 책갈
피가 정의되어 있지 않습니다.
[Table 4-1-2] Capacity Increase of Production Line Following Module Efficiency and Yield
Improvement .............................................................................. 오류! 책갈피가 정의되어 있지 않습니다.
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CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
[Table 4-2-1] Applied Material by Unit Process and Process Technology of Centrotherm오류! 책
갈피가 정의되어 있지 않습니다.
[Table 5-1-1] Portfolio by Unit Period ...................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Table 5-1-2] Top10 Patent Holders in Technical Area of CuInSe2 System Solar Cell오류! 책갈피가
정의되어 있지 않습니다.
[Table 5-1-3] Top10 Patent Holders of Each Country ........ 오류! 책갈피가 정의되어 있지 않습니다.
[Table 5-1-4] Internatioal Joint Invention(Total) ................... 오류! 책갈피가 정의되어 있지 않습니다.
[Table 5-2-1] Internatioal Joint Invention(Korea) ................. 오류! 책갈피가 정의되어 있지 않습니다.
[Table 5-2-2] Internatioal Joint Invention(USA) .................... 오류! 책갈피가 정의되어 있지 않습니다.
[Table 5-2-3] Internatioal Joint Invention(Europe) ............... 오류! 책갈피가 정의되어 있지 않습니다.
[Table 5-3-1] Yearly Patent Status of Matsushita Electric . 오류! 책갈피가 정의되어 있지 않습니다.
[Table 5-3-2] Patent Status of Matsushita Electric by Detailed Technology오류! 책갈피가 정의되
어 있지 않습니다.
[Table 5-3-3] Inventor’s Patent Number by Technology in Matsushita Electric오류! 책갈피가 정의
되어 있지 않습니다.
[Table 5-3-4] Yearly Patent Status of Honda ........................ 오류! 책갈피가 정의되어 있지 않습니다.
[Table 5-3-5] Patent Status of Honda by Detailed Technology오류! 책갈피가 정의되어 있지 않
습니다.
[Table 5-3-6] Inventor’s Patent Number by Technology in Honda오류! 책갈피가 정의되어 있지
않습니다.
[Table 5-3-7] Yearly Patent Status of Showa Shell ............. 오류! 책갈피가 정의되어 있지 않습니다.
[Table 5-3-8] Patent Status of Showa Shell by Detailed Technology오류! 책갈피가 정의되어 있
지 않습니다.
[Table 5-3-9] Inventor’s Patent by Technology in Showa Shell오류! 책갈피가 정의되어 있지 않
습니다.
[Table 5-3-10] Yearly Patent Status of Siemens Solar ....... 오류! 책갈피가 정의되어 있지 않습니다.
[Table 5-3-11] Patent Status of Siemens Solar by Detailed Technology오류! 책갈피가 정의되어
있지 않습니다.
[Table 5-3-12] Inventor’s Patent Number by Technology in Siemens Solar오류! 책갈피가 정의되
어 있지 않습니다.
[Table 6-1-1] Solar Cell Market Share of Worldwide Top 10 Makers (2006~2008)오류! 책갈피가
정의되어 있지 않습니다.
[Table 6-1-2] Production and Market Share of Worldwide Solar Cell by Type (2006~2008) .... 오류!
책갈피가 정의되어 있지 않습니다.
[Table 6-1-3] Production and Market Share of Worldwide Solar Cell by Technology (2006~2008)
......................................................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Table 6-1-4] CdTe Solar Cell Production Cost of First Solar (2006~2008)오류! 책갈피가 정의되어
32
All Contents of this report remain the property of Displaybank

CIGS Thin Film Solar Cell Technical Trend and Market Forecast(2006~2013)
있지 않습니다.
[Table 6-1-5] Worldwide Thin Film Solar Cell by Technology Production and Market
Share(2006~2008) .................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Table 6-1-6] Module Price Status Solar Cell by Technoloty (2006~2008)오류! 책갈피가 정의되어
있지 않습니다.
[Table 6-1-7] Production, Revenue Size and Share Status Worldwide Solar Cell Module
(2006~2008) ............................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Table 6-1-8] Production Capacity, Production Amount and Module Efficiency of CIGS Thin Film
Solar Cell by Maker (2006~2008)...................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Table 6-1-9] Module Price Status of CIGS and Solar Cell by Technology (2006~2008)오류! 책갈
피가 정의되어 있지 않습니다.
[Table 6-1-10] ModulePrice Status of Solar Cell by Technology (2006~2008)....................................... 15
[Table 6-2-1] CdTe Solar Cell Production Cost Forecast of First Solar (2006~2013)오류! 책갈피가
정의되어 있지 않습니다.
[Table 6-2-2] Strength and Weakness of Each Thin FilmSolar Cell Technology오류! 책갈피가 정의
되어 있지 않습니다.
[Table 6-2-3] Production and Market Share Forecast of Worldwide Solar Cell by Type/Technology
(2006~2013) .............................................................................................................................................................. 17
[Table 6-2-4] Module Price Forecast of by Solar Cell Technology (2006~2012)오류! 책갈피가 정
의되어 있지 않습니다.
[Table 6-2-5] Production, Revene Size and Ratio Forecast of Worldwide Solar Cell Module
(2006~2013) ............................................................................... 오류! 책갈피가 정의되어 있지 않습니다.
[Table 6-2-6] Production Capacity and Production Amount Forecast by Maker of CIGS Thin Film
Solar Cell (2006~2013) ........................................................ 오류! 책갈피가 정의되어 있지 않습니다.
[Table 6-2-7] Decrease Ratio Forecast of CIGS Solar Cell Module(2006~2013)오류! 책갈피가 정
의되어 있지 않습니다.
[Table 6-2-8] Price Forecst of CIGS and Solar Cell Module (2006~2013)오류! 책갈피가 정의되어
있지 않습니다.
- End of Report -
All Contents of this report remain the property of Displaybank
33